TW349937B - Esterification process - Google Patents
Esterification processInfo
- Publication number
- TW349937B TW349937B TW086108209A TW86108209A TW349937B TW 349937 B TW349937 B TW 349937B TW 086108209 A TW086108209 A TW 086108209A TW 86108209 A TW86108209 A TW 86108209A TW 349937 B TW349937 B TW 349937B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- orthoester
- esterification
- esterification process
- polyesterification
- Prior art date
Links
- 230000032050 esterification Effects 0.000 title abstract 3
- 238000005886 esterification reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 2
- 150000002905 orthoesters Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9612161.1A GB9612161D0 (en) | 1996-06-11 | 1996-06-11 | Esterification process |
Publications (1)
Publication Number | Publication Date |
---|---|
TW349937B true TW349937B (en) | 1999-01-11 |
Family
ID=10795084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW086108209A TW349937B (en) | 1996-06-11 | 1997-06-13 | Esterification process |
Country Status (25)
Country | Link |
---|---|
US (1) | US5866710A (zh) |
EP (2) | EP0812818B1 (zh) |
JP (1) | JP4354541B2 (zh) |
KR (1) | KR100567476B1 (zh) |
CN (1) | CN1068864C (zh) |
AR (1) | AR007540A1 (zh) |
AT (2) | ATE207866T1 (zh) |
AU (1) | AU730131B2 (zh) |
BR (1) | BR9703577A (zh) |
CA (1) | CA2207111A1 (zh) |
CO (1) | CO4810331A1 (zh) |
CZ (1) | CZ176297A3 (zh) |
DE (2) | DE69726200T2 (zh) |
DK (1) | DK0812818T3 (zh) |
ES (2) | ES2211678T3 (zh) |
GB (1) | GB9612161D0 (zh) |
HU (1) | HU218143B (zh) |
MX (1) | MX9704069A (zh) |
MY (1) | MY115541A (zh) |
NO (1) | NO307961B1 (zh) |
PL (1) | PL194313B1 (zh) |
PT (2) | PT812818E (zh) |
RU (1) | RU2178783C2 (zh) |
TR (1) | TR199700487A3 (zh) |
TW (1) | TW349937B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI466863B (zh) * | 2013-03-21 | 2015-01-01 | Chang Chun Plastics Co Ltd | 對苯二甲酸二(2-乙基己酯)之製造方法 |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6255441B1 (en) | 1998-04-17 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
DE19825350A1 (de) * | 1998-06-05 | 1999-12-09 | Basf Ag | Thermoplastische Polyesterformmasse mit verbesserter Stabilität |
US6130191A (en) * | 1998-09-29 | 2000-10-10 | Henkel Corporation | Process for the preparation of trimethylolpropane caprylate/caprate |
US6664413B1 (en) | 1998-11-19 | 2003-12-16 | A. E. Staley Manufacturing Co. | Process for production of esters |
KR20000059815A (ko) * | 1999-03-09 | 2000-10-05 | 한형수 | 지방족 폴리에스테르 제조방법 |
US6075115A (en) * | 1999-10-19 | 2000-06-13 | E. I. Du Pont De Nemours And Company | Process for the production of 5-sulfo isophthalate bis-glycolate ester metal salts and oxysulfonated polyesters made therefrom |
US6166170A (en) * | 1999-12-02 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Esterification catalysts and processes therefor and therewith |
DE60019638T2 (de) | 1999-12-10 | 2005-09-22 | Equipolymers Gmbh | Katalysatorsysteme für polykondensationsreaktionen |
US6372879B1 (en) | 2000-01-07 | 2002-04-16 | Atofina Chemicals, Inc. | Polyester polycondensation with catalyst and a catalyst enhancer |
US6355817B1 (en) * | 2000-07-15 | 2002-03-12 | Exxonmobil Chemical Patents Inc. | Optimized catalyst addition to enhance esterification catalyst performance |
US6303738B1 (en) | 2000-08-04 | 2001-10-16 | E. I. Du Pont De Nemours And Company | Esterification process |
US7767612B2 (en) * | 2000-11-21 | 2010-08-03 | Johnson Matthey Plc | Esterification catalyst, polyester process and polyester article |
DE10059612A1 (de) | 2000-12-01 | 2002-06-20 | Bayer Ag | Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern |
US6914107B2 (en) | 2001-01-24 | 2005-07-05 | E. I. Du Pont De Nemours And Company | Catalyst composition and process therewith |
US6489433B2 (en) | 2001-02-23 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Metal-containing composition and process therewith |
US6855797B2 (en) | 2002-04-25 | 2005-02-15 | E. I. Du Pont De Nemours And Company | Stable aqueous solutions comprising titanium and zinc and process therewith |
KR20030084183A (ko) * | 2002-04-25 | 2003-11-01 | 켐엔텍 주식회사 | 폴리에스테르의 제조방법 |
US20030203811A1 (en) | 2002-04-25 | 2003-10-30 | Putzig Donald Edward | Stable aqueous solutions comprising titanium and zinc and process therewith |
US6841505B2 (en) * | 2002-07-26 | 2005-01-11 | E..I. Du Pont De Nemours And Company | Titanium-zirconium catalyst compositions and use thereof |
GB0228267D0 (en) * | 2002-12-04 | 2003-01-08 | Johnson Matthey Plc | Catalyst and process |
JP2006509070A (ja) * | 2002-12-04 | 2006-03-16 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | 有機金属触媒組成物及び前記触媒を用いるポリウレタン製造プロセス |
JP4529485B2 (ja) * | 2003-03-07 | 2010-08-25 | 三菱化学株式会社 | ポリエステル重合触媒、その製造方法、及びそれを用いたポリエステルの製造方法 |
RU2310667C2 (ru) * | 2003-06-17 | 2007-11-20 | Мицуи Кемикалз, Инк. | Титансодержащий раствор, катализатор для получения сложного полиэфира и способ получения смолы на основе сложного полиэфира |
DE10336883A1 (de) * | 2003-08-08 | 2005-03-10 | Basf Ag | Kunststoff, insbesondere Polyurethan enthaltend ein sterisch gehindertes, verestertes Amin |
GB0323386D0 (en) * | 2003-10-07 | 2003-11-05 | Johnson Matthey Plc | Catalyst for manufacture of esters |
KR100760027B1 (ko) | 2006-09-22 | 2007-09-18 | 이수화학 주식회사 | 고정층형 반응기를 이용한 바이오디젤의 연속식 제조방법 |
KR100849206B1 (ko) * | 2006-12-21 | 2008-07-31 | 주식회사 자연사랑 | 무독성 생분해성 수용성 폴리에스테르 수지 제조 방법 |
MY146637A (en) | 2007-03-13 | 2012-09-14 | Exxonmobil Chem Patents Inc | Batch esterification |
DE102007031474A1 (de) * | 2007-07-05 | 2009-01-08 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Butandioldimethacrylaten |
KR101044393B1 (ko) * | 2007-12-27 | 2011-06-27 | 주식회사 엘지화학 | 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법 |
DE102008040221A1 (de) * | 2008-07-07 | 2010-01-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von (Meth)acrylsäureestern |
JP5326741B2 (ja) | 2008-09-29 | 2013-10-30 | 東レ株式会社 | ポリエステル重合触媒およびそれを用いるポリエステルの製造方法 |
EP2287225A1 (en) | 2009-08-20 | 2011-02-23 | Saudi Basic Industries Corporation | Process for making polyethylene terephthalate |
US8877862B2 (en) | 2011-07-15 | 2014-11-04 | Saudi Basic Industries Corporation | Method for color stabilization of poly(butylene-co-adipate terephthalate |
US8933162B2 (en) | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
US8969506B2 (en) | 2012-02-15 | 2015-03-03 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8901273B2 (en) | 2012-02-15 | 2014-12-02 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8889820B2 (en) | 2012-02-15 | 2014-11-18 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8895660B2 (en) | 2012-03-01 | 2014-11-25 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof |
US9034983B2 (en) | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
US8901243B2 (en) | 2012-03-30 | 2014-12-02 | Saudi Basic Industries Corporation | Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
EP2725048B1 (de) * | 2012-10-29 | 2016-07-20 | Uhde Inventa-Fischer GmbH | Verfahren zur Herstellung eines hochmolekularen Polyesters oder Copolyesters sowie diese enthaltende Polymerblends |
PL2765149T3 (pl) * | 2013-02-06 | 2019-06-28 | Uhde Inventa-Fischer Gmbh | Sposób wytwarzania katalizatora zawierającego tytan, katalizator zawierający tytan, sposób wytwarzania poliestru i poliester |
CN105237393B (zh) * | 2015-09-06 | 2017-06-30 | 浙江皇马科技股份有限公司 | 一种癸二酸脂肪醇酯的制备方法 |
EP3687969B1 (en) * | 2017-09-26 | 2023-08-02 | Public Joint Stock Company "Sibur Holding" | Method of preparing esters of terephthalic acid |
TWI670291B (zh) * | 2018-08-02 | 2019-09-01 | 遠東新世紀股份有限公司 | 低黏度聚酯多元醇的製法 |
CN111087583B (zh) * | 2018-10-23 | 2022-11-04 | 中国石油化工股份有限公司 | 低端羧基pbt树脂的制备方法 |
Family Cites Families (17)
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US3056818A (en) * | 1955-10-13 | 1962-10-02 | Goodrich Co B F | Titanium and zirconium esterification catalysts |
GB811425A (en) * | 1955-10-31 | 1959-04-08 | Nat Lead Co | Organic titanium complex and method of making same |
US3047515A (en) * | 1956-07-09 | 1962-07-31 | Goodyear Tire & Rubber | Preparation of polyesters using titanium-containing catalysts |
DE1142868B (de) * | 1960-08-23 | 1963-01-31 | Wachker Chemie G M B H | Verfahren zur diskontinuierlichen oder kontinuierlichen Herstellung von Carbonsaeureestern |
CH398538A (de) * | 1960-08-23 | 1966-03-15 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Estern |
GB991020A (en) * | 1960-11-29 | 1965-05-05 | Martin Marietta Corp | Esterification of iso- and terephthalic acids |
GB970431A (zh) * | 1961-02-04 | 1900-01-01 | ||
JPS5133890B2 (zh) * | 1971-09-10 | 1976-09-22 | ||
GB1514361A (en) * | 1976-03-13 | 1978-06-14 | Tioxide Group Ltd | Titanium chelates |
JPS5398393A (en) * | 1977-02-09 | 1978-08-28 | Teijin Ltd | Production of polyester |
DD144674A1 (de) * | 1979-06-28 | 1980-10-29 | Rema S Barshtein | Verfahren zur herstellung der polyestern |
JPS59157058A (ja) * | 1983-02-28 | 1984-09-06 | Ueno Seiyaku Oyo Kenkyusho:Kk | 芳香族ヒドロキシカルボン酸ベンジルエステル類の製造法 |
US4452969A (en) * | 1983-06-09 | 1984-06-05 | General Electric Company | Poly(alkylene dicarboxylate) process and catalysts for use therein |
US4780527A (en) * | 1987-05-06 | 1988-10-25 | Industrial Technology Research Institute | Preparation of polyesters from terephthalic acid |
GB8717667D0 (en) * | 1987-07-25 | 1987-09-03 | Tioxide Group Plc | Titanium compounds |
DE3850672T2 (de) * | 1987-09-29 | 1995-03-02 | John Wentworth Bucknell | Krafterzeuger. |
JP3341430B2 (ja) * | 1994-01-07 | 2002-11-05 | 三菱化学株式会社 | チタン触媒組成液 |
-
1996
- 1996-06-11 GB GBGB9612161.1A patent/GB9612161D0/en active Pending
-
1997
- 1997-05-27 AU AU23635/97A patent/AU730131B2/en not_active Ceased
- 1997-06-02 MX MX9704069A patent/MX9704069A/es unknown
- 1997-06-03 AT AT97303744T patent/ATE207866T1/de not_active IP Right Cessation
- 1997-06-03 PT PT97303744T patent/PT812818E/pt unknown
- 1997-06-03 EP EP97303744A patent/EP0812818B1/en not_active Expired - Lifetime
- 1997-06-03 PT PT01105564T patent/PT1120392E/pt unknown
- 1997-06-03 AT AT01105564T patent/ATE254096T1/de not_active IP Right Cessation
- 1997-06-03 DK DK97303744T patent/DK0812818T3/da active
- 1997-06-03 DE DE69726200T patent/DE69726200T2/de not_active Expired - Lifetime
- 1997-06-03 ES ES01105564T patent/ES2211678T3/es not_active Expired - Lifetime
- 1997-06-03 EP EP01105564A patent/EP1120392B1/en not_active Expired - Lifetime
- 1997-06-03 DE DE69707757T patent/DE69707757T2/de not_active Expired - Lifetime
- 1997-06-03 ES ES97303744T patent/ES2166505T3/es not_active Expired - Lifetime
- 1997-06-05 US US08/869,629 patent/US5866710A/en not_active Expired - Lifetime
- 1997-06-06 CA CA002207111A patent/CA2207111A1/en not_active Abandoned
- 1997-06-09 HU HU9701024A patent/HU218143B/hu not_active IP Right Cessation
- 1997-06-09 NO NO972645A patent/NO307961B1/no unknown
- 1997-06-09 MY MYPI97002555A patent/MY115541A/en unknown
- 1997-06-09 CZ CZ971762A patent/CZ176297A3/cs unknown
- 1997-06-10 AR ARP970102514A patent/AR007540A1/es active IP Right Grant
- 1997-06-10 BR BR9703577A patent/BR9703577A/pt not_active IP Right Cessation
- 1997-06-10 CN CN97113609A patent/CN1068864C/zh not_active Expired - Lifetime
- 1997-06-10 CO CO97031854A patent/CO4810331A1/es unknown
- 1997-06-10 JP JP15229797A patent/JP4354541B2/ja not_active Expired - Lifetime
- 1997-06-10 RU RU97109363/04A patent/RU2178783C2/ru not_active IP Right Cessation
- 1997-06-10 PL PL320469A patent/PL194313B1/pl unknown
- 1997-06-11 KR KR1019970024054A patent/KR100567476B1/ko not_active IP Right Cessation
- 1997-06-11 TR TR97/00487A patent/TR199700487A3/tr unknown
- 1997-06-13 TW TW086108209A patent/TW349937B/zh not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI466863B (zh) * | 2013-03-21 | 2015-01-01 | Chang Chun Plastics Co Ltd | 對苯二甲酸二(2-乙基己酯)之製造方法 |
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Legal Events
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MK4A | Expiration of patent term of an invention patent |