KR960007532A - 아민류의 제조방법 - Google Patents

아민류의 제조방법 Download PDF

Info

Publication number
KR960007532A
KR960007532A KR1019950024756A KR19950024756A KR960007532A KR 960007532 A KR960007532 A KR 960007532A KR 1019950024756 A KR1019950024756 A KR 1019950024756A KR 19950024756 A KR19950024756 A KR 19950024756A KR 960007532 A KR960007532 A KR 960007532A
Authority
KR
South Korea
Prior art keywords
amine
oxygen
hydrogen
calculated
weight
Prior art date
Application number
KR1019950024756A
Other languages
English (en)
Other versions
KR100376641B1 (ko
Inventor
라이프 볼프강
프란쯔 로타르
스톱스 페터
멩거 폴크마르
베커 라이너
쿰머 루돌프
빈데를 지그프리드
Original Assignee
랑핑어, 슈타인호프
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 랑핑어, 슈타인호프, 바스프 악티엔게젤샤프트 filed Critical 랑핑어, 슈타인호프
Publication of KR960007532A publication Critical patent/KR960007532A/ko
Application granted granted Critical
Publication of KR100376641B1 publication Critical patent/KR100376641B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/03—Monoamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/18—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Steroid Compounds (AREA)

Abstract

본 발명은 80 내지 250℃의 온도에서 수소를 이용한 1 내지 400bar의 압력하에, 촉매적 활성 물질에 ZrO2로 계산하여 20 내지 85 중량%의 산소-함유 지르코늄 화합물, CuO로 계산하여 1 내지 30 중량%의 산소-함유 구리 화합물, NiO로 계산하여 30 내지 70 중량%%의 산호- 함유 니켈 화합물, MoO3로 계산하여 0.1 내지 5중량%의 산소-함유 몰리브덴 화합물, 그리고 Al2O3또는 MnO2를 기준으로 각각 알루미늄 및/또는 망간의 산소-함유 화합물이 0 내지 10 중량% 함유되어 있는 지르코늄/구리/니켈 촉매의 존재 상태에서, 암모니아와 1차 및 2차 아민류로 이루어진 군으로부터 선택된 1차 또는 2차 알코올류 및 질소 화합물로부터 아민류를 제조하는 신규하고도 개선된 방법에 관한 것이다.
본 발명에 따르면, 다음의 일반식(ⅱ)의 1차 또는 2차 알코올과
R4-CHR3-OH (ⅱ)
다음의 일반식(ⅲ)의 질소 화합물로부터
(ⅲ)
다음의 일반식 (ⅰ)의 아민류를 제조하는 바람직한 방법이 제공되는데,
(ⅰ)
상기 식들에서, R1및 R2는 수소, C1-C20알킬, C3-C12시클로알킬, 아릴, C7-C20아르알킬 및 C7-C20알킬아릴이거나, 함께 (CH2)l-X-(CH2)m을 형성하고, R3및 R4는 수소, C1-C20알킬, C3-C12시클로알킬, C1-C20히드록시알킬, 아미노 및/또는 히드록시로 치환된 C1-C20알킬, C2-C30알콕시알킬, R5-(OCR6R7CR8R9)n-(OCR6R7), 아릴, C7-C2아르알킬, C7-C20알킬아릴, (R5)2N-(CH2)q및 Y-(CH2)m-NR5-(CH2)q이거나, 함께 (CH2)l-X(CH2)m을 형성하거나, R2및 R4는 함께 (CH2)l-X-(CH2)m을 형성하고, R5는 수소, C1-C4알킬, C12-C40알킬페닐을 나타내고, R6, R7, R8, 및 R9는 수소, 메틸 또는 에틸을 나타내고, R10은 수소 또는 C1-C4알킬을 나타내고, X는 CH2, 산소 또는 N-R6를 나타내고, Y는 (R5)2, 히드록시, C2-C20알킬아미노알킬 또는 C3-C20디알킬아미노알킬을 나타내고, n은 1 내지 30의 정수이고, 1은 2내지 4의 정수이고, m과 q는 1 내지 4의 정수이다.

Description

아민류의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 아민의 제조 방법으로서, 80 내지 250℃의 온도에서 수소를 이용한 1 내지 400bar의 압력하에, 촉매적 활성 물질에 ZrO2로 계산하여 20 내지 85 중량%의 산소-함유 지르코늄 화합물, CuO로 계산하여 1 내지 30 중량%의 산소-함유 구리 화합물, NiO로 계산하여 30 내지 70 중량%%의 산호- 함유 니켈 화합물, MoO3로 계산하여 0.1 내지 5중량%의 산소-함유 몰리브덴 화합물, 그리고 Al2O3또는 MnO2를 기준으로 각각 알루미늄 및/또는 망간의 산소-함유 화합물이 0 내지 10 중량% 함유되어 있는 지르코늄/구리/니켈 촉매의 존재 상태에서, 암모니아와 1차 및 2차 아민류로 이루어진 군으로부터 선택된 1차 또는 2차 알코올류 및 질소 화합물로부터 아민류를 제조하는 방법.
  2. 아민의 제조방법으로서, 다음의 일반식(ⅱ)의 1차 또는 2차 알코올과
    R4-CHR3-OH (ⅱ)
    다음의 일반식(ⅲ)의 질소 화합물로부터
    (ⅲ)
    80 내지 250℃의 온도에서 수소를 이용한 1 내지 400bar의 압력하에, 촉매적 활성 물질에 ZrO2로 계산하여 20 내지 85 중량%의 산소-함유 지르코늄 화합물, CuO로 계산하여 1 내지 30 중량%의 산소-함유 구리 화합물, NiO로 계산하여 30 내지 70 중량%%의 산호- 함유 니켈 화합물, MoO3로 계산하여 0.1 내지 5중량%의 산소-함유 몰리브덴 화합물, 그리고 Al2O3또는 MnO2를 기준으로 각각 알루미늄 및/또는 망간의 산소-함유 화합물이 0 내지 10 중량% 함유되어 있는 지르코늄/구리/니켈 촉매의 존재 상태에서, 다음의 일반식(i)의 아민류를 제조하는 방법.
    (i)
    상기 식들에서, R1및 R2는 수소, C1-C20알킬, C3-C12시클로알킬, 아릴, C7-C20아르알킬 및 C7-C20알킬아릴이거나, 함께 (CH2)l-X-(CH2)m을 형성하고, R3및 R4는 수소, C1-C20알킬, C3-C12시클로알킬, C1-C20히드록시알킬, 아미노 및/또는 히드록시로 치환된 C1-C20알킬, C2-C30알콕시알킬, R5-(OCR6R7CR8R9)n-(OCR6R7), 아릴, C7-C2아르알킬, C7-C20알킬아릴, (R5)2N-(CH2)q및 Y-(CH2)m-NR5-(CH2)q이거나, 함께 (CH2)l-X(CH2)m을 형성하거나, R2및 R4는 함께 (CH2)l-X-(CH2)m을 형성하고, R5는 수소, C1-C4알킬, C12-C40알킬페닐을 나타내고, R6, R7, R8, 및 R9는 수소, 메틸 또는 에틸을 나타내고, R10은 수소 또는 C1-C4알킬을 나타내고, X는 CH2, 산소 또는 N-R6를 나타내고, Y는 (R5)2, 히드록시, C2-C20알킬아미노알킬 또는 C3-C20디알킬아미노알킬을 나타내고, n은 1 내지 30의 정수이고, 1은 2내지 4의 정수이고, m과 q는 1 내지 4의 정수이다.
  3. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 촉매적 활성물질에 NiO를 기준으로 계산하여 40 내지 70 중량%의 산소-함유 니켈 화합물이 함유되어 있는 것을 특징으로 하는 아민의 제조방법.
  4. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 촉매적 활성물질에 NiO를 기준으로 계산하여 45 내지 60 중량%의 산소-함유 니켈 화합물이 함유되어 있는 것을 특징으로 하는 아민의 제조방법.
  5. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 촉매적 활성물질에 MoO3를 기준으로 계산하여 0.5 내지 3.5 중량%의 산소-함유 니켈 화합물이 함유되어 있는 것을 특징으로 하는 아민의 제조방법.
  6. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 촉매적 활성물질에 ZrO2를 기준으로 계산하여 25 내지 60 중량%의 산소-함유 니켈 화합물이 함유되어 있는 것을 특징으로 하는 아민의 제조방법.
  7. 제 1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 촉매적 활성물질에 CuO를 기준으로 계산하여 10 내지 25 중량%의 산소-함유 니켈 화합물이 함유되어 있는 것을 특징으로 하는 아민의 제조방법.
  8. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 반응을 120° 내지 230°의 온도에서 수행하는 것을 특징으로 하는 아민의 제조방법.
  9. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 반응을 10 내지 250bar의 압력에서 수행하는 것을 특징으로 하는 아민의 제조방법.
  10. 제1항에서 정의된 지르코늄/구리/니켈 촉매의 존재하에 수소를 사용하여 알코올 및 질소 화합물로 부터 아민을 제조하는 방법에 있어서, 반응을 30 내지 220bar의 압력하에 수행하는 것을 특징으로 하는 아민의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950024756A 1994-08-08 1995-08-08 아민의제조방법 KR100376641B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4428004A DE4428004A1 (de) 1994-08-08 1994-08-08 Verfahren zur Herstellung von Aminen
DEP4428004.1 1994-08-08

Publications (2)

Publication Number Publication Date
KR960007532A true KR960007532A (ko) 1996-03-22
KR100376641B1 KR100376641B1 (ko) 2003-05-22

Family

ID=6525167

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950024756A KR100376641B1 (ko) 1994-08-08 1995-08-08 아민의제조방법

Country Status (11)

Country Link
US (1) US5530127A (ko)
EP (1) EP0696572B1 (ko)
JP (1) JP3809963B2 (ko)
KR (1) KR100376641B1 (ko)
CN (1) CN1078200C (ko)
AT (1) ATE158788T1 (ko)
CA (1) CA2155171C (ko)
DE (2) DE4428004A1 (ko)
DK (1) DK0696572T3 (ko)
ES (1) ES2107885T3 (ko)
ZA (1) ZA956574B (ko)

Families Citing this family (174)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4429547A1 (de) * 1994-08-19 1996-02-22 Basf Ag Verfahren zur Herstellung von Aminen
DE19516940A1 (de) * 1995-05-09 1996-11-14 Rwe Dea Ag Herstellung von primären Guerbetaminen
JP3361414B2 (ja) * 1995-09-22 2003-01-07 花王株式会社 Ｎ，ｎ−ジメチル−ｎ−アルキルもしくはアルケニルアミンの製造方法
US5679862A (en) * 1996-03-25 1997-10-21 Chemical Research & Licensing Company Amination process
DE19645430A1 (de) * 1996-11-04 1998-05-07 Basf Ag Polyolefine und deren funktionalisierte Derivate
DE19742911A1 (de) * 1997-09-29 1999-04-01 Basf Ag Verfahren zur Herstellung von Aminen
DE19905837A1 (de) * 1999-02-12 2000-08-17 Basf Ag Verfahren zur Racemisierung von optisch aktiven Aminen
DE19910960A1 (de) * 1999-03-12 2000-09-14 Basf Ag Verfahren zur Herstellung von Aminen
DE19916512A1 (de) * 1999-04-13 2000-10-19 Basf Ag Polyalkenalkohol-Polyetheramine und deren Verwendung in Kraft- und Schmierstoffen
EP1106601B1 (de) * 1999-12-06 2004-02-25 Basf Aktiengesellschaft Verfahren zur Herstellung von Monoisopropylamin
DE50007278D1 (de) 1999-12-06 2004-09-09 Basf Ag Verfahren zur Herstellung von Aminen
DE10145119A1 (de) 2001-09-13 2003-04-03 Basf Ag Verfahren zur Herstellung von Aminen
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
DE10211101A1 (de) * 2002-03-14 2003-09-25 Basf Ag Katalysatoren und Verfahren zur Herstellung von Aminen
DE10261193A1 (de) 2002-12-20 2004-07-01 Basf Ag Verfahren zur Herstellung eines Armins
DE10261195A1 (de) * 2002-12-20 2004-07-01 Basf Ag Verfahren zur Herstellung eines symmetrischen sekundären Amins
DE502004005974D1 (de) 2003-09-10 2008-03-06 Basf Ag Verfahren zur herstellung von xylylendiamin durch kontinuierliche hydrierung von flüssigem phthalodinitril
DE10361503A1 (de) 2003-12-23 2005-07-28 Basf Ag Verfahren zur Herstellung eines Ethylamins
DE102004062253A1 (de) * 2004-12-23 2006-07-06 Basf Ag Direktaminierung von Kohlenwasserstoffen
DE102005029932A1 (de) 2005-06-28 2007-01-11 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung von Polyetheraminen
US7728174B2 (en) 2005-08-02 2010-06-01 Basf Se Continuous hydrogenation processes for the preparation of xylylenediamines
DE102005043440A1 (de) * 2005-09-13 2007-03-15 Basf Ag Verfahren zur Herstellung eines Ethylamins aus vergälltem Ethanol
JP4989888B2 (ja) * 2005-12-28 2012-08-01 花王株式会社 含窒素化合物の製造方法
JP4989889B2 (ja) * 2005-12-28 2012-08-01 花王株式会社 含窒素化合物の製造方法
WO2007128803A1 (de) 2006-05-09 2007-11-15 Basf Se Verfahren zur herstellung von aminoalkylnitrilen und diaminen aus solchen nitrilen
WO2008006749A1 (de) * 2006-07-14 2008-01-17 Basf Se Verfahren zur herstellung eines amins
WO2008006754A1 (de) * 2006-07-14 2008-01-17 Basf Se Verfahren zur herstellung eines amins
RU2009104982A (ru) * 2006-07-14 2010-08-27 Басф Се (De) Способ получения амина
CN101489981B (zh) * 2006-07-14 2013-03-20 巴斯夫欧洲公司 生产胺的方法
CN101489979B (zh) 2006-07-14 2015-04-08 巴斯夫欧洲公司 生产胺的方法
PL2043576T3 (pl) * 2006-07-20 2013-03-29 Essity Hygiene & Health Ab Urządzenie i sposób formowania nakładanych powietrznie wkładów chłonnych
DE102006036220A1 (de) 2006-08-03 2008-02-07 Clariant International Limited Polyetheramin-Makromonomere mit zwei benachbarten Hydroxylgruppen und ihre Verwendung zur Herstellung von Polyurethanen
EP2077990B1 (de) * 2006-09-28 2013-08-07 Basf Se Verfahren zur kontinuierlichen destillativen auftrennung von gemischen enthaltend morpholin (mo), monoaminodiglykol (adg), ammoniak und wasser
DE502007003425D1 (de) * 2006-09-28 2010-05-20 Basf Se Verfahren zur kontinuierlichen destillativen auftrennung von gemischen enthaltend morpholin (mo), monoaminodiglykol (adg), ammoniak und wasser
JP5200023B2 (ja) 2006-09-28 2013-05-15 ビーエーエスエフ ソシエタス・ヨーロピア モルホリン（ｍｏ）、モノアミノジグリコール（ａｄｇ）、アンモニア及び水を含有する混合物を連続的に蒸留により分離するための方法
CN101522607B (zh) 2006-12-06 2014-03-12 科莱恩金融(Bvi)有限公司 聚醚胺的制备方法
CN101622222A (zh) 2007-03-01 2010-01-06 巴斯夫欧洲公司 由未处理的aan制备亚乙基胺的方法
WO2008104551A1 (de) 2007-03-01 2008-09-04 Basf Se Verfahren zur herstellung von tetraethylenpentaamin
EP2537835B1 (de) 2007-03-01 2014-04-30 Basf Se Neues Verfahren zur Herstellung von TETA über EDDN
US7880036B2 (en) 2007-03-01 2011-02-01 Basf Se Production method for ethyleneamine mixtures
EP2132165B1 (de) 2007-03-01 2014-04-23 Basf Se Verfahren zur herstellung von ethylendiamin
RU2470009C2 (ru) 2007-03-01 2012-12-20 Басф Се Способ получения триэтилентетраамина
RU2473537C2 (ru) 2007-03-01 2013-01-27 Басф Се Способ получения смеси этиленаминов
ES2545271T3 (es) 2007-07-23 2015-09-09 Basf Se Procedimiento para la preparación de mentol mediante hidrogenación de isopulegol
US20100240894A1 (en) * 2007-08-29 2010-09-23 Basf Se Method for producing amines from glycerin
CN101842346B (zh) 2007-08-29 2013-05-15 巴斯夫欧洲公司 由糖醇生产胺的方法
JP5599716B2 (ja) 2007-11-30 2014-10-01 ビーエーエスエフ ソシエタス・ヨーロピア 光学活性ラセミメントールを製造するための方法
KR20100108393A (ko) 2007-12-21 2010-10-06 바스프 에스이 키랄 이민의 부분입체 선택적 전환 방법
CA2708315A1 (en) 2007-12-21 2009-07-02 Basf Se One-stage reductive amination
CN101903097A (zh) * 2007-12-21 2010-12-01 巴斯夫欧洲公司 制备胺的方法
WO2009080506A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
WO2009080508A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
CN101903095B (zh) 2007-12-21 2013-07-10 巴斯夫欧洲公司 制备胺的方法
WO2009080510A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
CN102105435B (zh) 2008-07-25 2014-07-23 巴斯夫欧洲公司 5-异丙基-3-氨基甲基-2-甲基-1-氨基环己烷(香芹酮二胺)及其制备方法
JP2011529027A (ja) * 2008-07-25 2011-12-01 ビーエーエスエフ ソシエタス・ヨーロピア ３−アミノメチル−１−シクロヘキシルアミン、及びその製造方法
EP2352719B1 (de) 2008-11-05 2016-06-08 Basf Se Verfahren zur herstellung von n,n-substituierten 3-aminopropan-1-olen
US20110313187A1 (en) 2009-02-09 2011-12-22 Christof Wilhelm Wigbers Method for improving the catalytic activity of monolithic catalysts
WO2010089346A2 (de) 2009-02-09 2010-08-12 Basf Se Verfahren zur verbesserung der katalytischen aktivität von monolithischen katalysatoren
JP2012517331A (ja) 2009-02-09 2012-08-02 ビーエーエスエフ ソシエタス・ヨーロピア 水素化触媒、その製造方法およびその使用
CN102348676B (zh) * 2009-03-12 2016-02-10 巴斯夫欧洲公司 制备氢氧化1-金刚烷基三甲基铵的方法
EP2443088B1 (de) 2009-06-18 2013-08-14 Basf Se Methyl-substituierte teta-verbindungen
CN102029166B (zh) * 2009-09-27 2012-07-18 上海焦化有限公司 一种合成气制取低碳混合醇的催化剂及其制备方法
EP2506965B1 (de) 2009-12-03 2016-11-09 Basf Se Katalysator und verfahren zur herstellung eines amins
EP2506966B1 (de) 2009-12-03 2017-08-16 Basf Se Katalysator und verfahren zur herstellung eines amins
US8742174B2 (en) 2009-12-17 2014-06-03 Basf Se Method for preparing higher ethanolamines
CN102711456B (zh) 2010-01-18 2015-05-13 巴斯夫欧洲公司 包含农药和2-丙基庚胺的烷氧基化物的组合物
US8618179B2 (en) 2010-01-18 2013-12-31 Basf Se Composition comprising a pesticide and an alkoxylate of 2-propylheptylamine
WO2011101303A2 (de) 2010-02-16 2011-08-25 Basf Se Zusammensetzung umfassend ein pestizid und ein alkoxylat von iso-heptadecylamin
US20110201497A1 (en) * 2010-02-16 2011-08-18 Basf Se Composition Comprising A Pesticide and an Alkoxylate of Iso-Heptadecylamine
US20110218295A1 (en) * 2010-03-02 2011-09-08 Basf Se Anionic associative rheology modifiers
KR20130036188A (ko) 2010-03-02 2013-04-11 바스프 에스이 블록 공중합체 및 이의 용도
US8673275B2 (en) 2010-03-02 2014-03-18 Basf Se Block copolymers and their use
WO2011113786A2 (de) 2010-03-17 2011-09-22 Basf Se Zusammensetzung umfassend ein pestizid und ein alkoxylat von verzweigtem nonylamin
US9258996B2 (en) 2010-03-17 2016-02-16 Basf Se Composition comprising a pesticide and an alkoxylate of iso-nonylamine
US8779169B2 (en) 2010-05-27 2014-07-15 Basf Se Process for the preparation of 2 substituted tetrahydropyranols
ES2660768T3 (es) 2010-05-27 2018-03-26 Basf Se Procedimiento para la preparación de tetrahidropiranoles sustituidos en posición 2
US8791276B2 (en) 2010-06-10 2014-07-29 Basf Se Process for the preparation and isolation of 2-substituted tetrahydropyranols
US8637668B2 (en) 2010-06-15 2014-01-28 Basf Se Process for preparing a cyclic tertiary methylamine
EP2588442B1 (de) 2010-06-30 2014-04-16 Basf Se Verfahren zur herstellung von tri-n-propylamin (tpa)
US8466322B2 (en) 2010-06-30 2013-06-18 Basf Se Process for preparing tri-n-propylamine (TPA)
DE102010040427A1 (de) 2010-09-08 2012-03-08 Basf Se Verfahren zur Herstellung von Mono-n-Octylamin (MOA)
DE102011004465A1 (de) * 2010-09-10 2012-03-15 Evonik Degussa Gmbh Verfahren zur direkten Aminierung sekundärer Alkohole mit Ammoniak zu primären Aminen
CN101948394A (zh) * 2010-09-20 2011-01-19 浙江博华化学有限公司 三（3，6-二氧杂庚基）胺的合成方法
US8933223B2 (en) 2010-10-14 2015-01-13 Basf Se Process for preparing a cyclic tertiary amine
MX2013004872A (es) 2010-11-02 2013-05-22 Basf Se Procesos para preparar un fenilciclohexano.
US8653313B2 (en) 2010-11-02 2014-02-18 Basf Se Process for preparing a phenylcyclohexane
EP4112727A3 (de) 2010-11-17 2023-03-15 Basf Se Verfahren zur biokatalytischen cyclisierung von terpenen und darin einsetzbare cyclase-mutanten
DE102011075162A1 (de) 2010-12-08 2012-06-14 Evonik Degussa Gmbh Verfahren zur homogen-katalysierte, hochselektiven direkten Aminierung von primären Alkoholen mit Ammoniak zu primären Aminen bei hohem Volumenverhältnis von Flüssig- zu Gasphase und/oder hohen Drücken
EP2468712A1 (de) 2010-12-14 2012-06-27 Basf Se Verfahren zur Herstellung und Aufreinigung von 3-Aminopropanol
EP2678306B1 (de) 2011-02-21 2017-06-21 Evonik Degussa GmbH Verfahren zur direkten aminierung von alkoholen mit ammoniak zu primären aminen mittels eines xantphos katalysatorsystems
EA022869B1 (ru) 2011-02-28 2016-03-31 Басф Се Композиция, содержащая пестицид, сурфактант и алкоксилат 2-пропилгептиламина
RU2013144822A (ru) 2011-03-08 2015-04-20 Басф Се Способ получения ди-, три- и полиаминов аминированием спиртов при гомогенном катализе
MX2013010218A (es) 2011-03-08 2013-10-25 Basf Se Proceso para la preparacion de aminas primarias por aminacion del alcohol homogeneamente catalizado.
US8785693B2 (en) 2011-03-08 2014-07-22 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8637709B2 (en) 2011-03-08 2014-01-28 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8912361B2 (en) 2011-03-08 2014-12-16 Basf Se Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination
WO2012119927A1 (de) 2011-03-08 2012-09-13 Basf Se Verfahren zur herstellung von primären aminen durch homogen-katalysierte alkoholaminierung
EP2688862A1 (de) 2011-03-22 2014-01-29 Basf Se Verfahren zur hydrierung von nitrilen
WO2012126956A1 (de) 2011-03-22 2012-09-27 Basf Se Verfahren zur hydrierung von nitrilen
WO2013030254A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von teta und/oder deta
JP2014534164A (ja) 2011-08-31 2014-12-18 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｅｄｄｎないしｅｄｍｎの水素化から生ずる反応生成物を精製する方法
US8946459B2 (en) 2011-08-31 2015-02-03 Basf Se Process for preparing EDDN and/or EDMN by reacting EDFA and/or EDMFA with HCN
EP2751069B1 (de) 2011-08-31 2017-10-11 Basf Se Verfahren zur herstellung von eddn und/oder edmn
US9096497B2 (en) 2011-08-31 2015-08-04 Basf Se Process for preparing EDDN and EDMN
US9012638B2 (en) 2011-08-31 2015-04-21 Basf Se Process for preparing EDDN and/or EDMN by conversion of FACH and EDA
WO2013030259A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von teta
WO2013030287A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von fach und eda
EP2751066A1 (de) 2011-08-31 2014-07-09 Basf Se Verfahren zur herstellung von edfa und/oder edmfa und deta und/oder teta
EP2751065B1 (de) 2011-08-31 2016-11-16 Basf Se Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von edfa und/oder edmfa mit hcn
WO2013030023A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von eddn und/oder edmn sowie ein verfahren zur herstellung von deta und/oder teta
WO2013030144A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von eddn, edmn, teta und deta
WO2013030249A1 (de) 2011-08-31 2013-03-07 Basf Se Verfahren zur herstellung von aminen durch hydrierung von nitrilen
US8952156B2 (en) 2011-08-31 2015-02-10 Basf Se Process for working up reaction outputs from the hydrogenation of EDDN or EDMN
WO2013075974A1 (de) 2011-11-21 2013-05-30 Basf Se Verfahren zur herstellung von ethylaminen und mono-iso-propylamin (mipa)
US8766009B2 (en) 2011-11-21 2014-07-01 Basf Se Process for preparing ethylamines and monoisopropylamine (MIPA)
EP2855443B1 (de) 2012-06-01 2016-03-30 Basf Se Verfahren zur herstellung eines mono-n-alkyl-piperazins
US8884015B2 (en) 2012-06-01 2014-11-11 Basf Se Process for the preparation of a mono-N-alkypiperazine
WO2013182465A1 (de) 2012-06-06 2013-12-12 Basf Se Verfahren zur herstellung von piperazin
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
US20130331574A1 (en) * 2012-06-06 2013-12-12 Basf Se Process for Preparing Piperazine
DE102012014395B3 (de) * 2012-07-13 2013-08-22 Oxea Gmbh Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
CN105073712B (zh) 2013-01-30 2017-09-22 巴斯夫欧洲公司 2,6‑双(氨基甲基)哌啶衍生物
JP2016514178A (ja) 2013-02-28 2016-05-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ポリアミン及びその製造方法
JP2016508522A (ja) 2013-02-28 2016-03-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｓｏ２不含のシアン化水素を使用したｅｄａの製造法
US8987518B2 (en) 2013-02-28 2015-03-24 Basf Se Polyamines and process for preparation thereof
WO2014131674A2 (en) 2013-03-01 2014-09-04 Basf Se Amine composition
EP2970166A4 (en) 2013-03-15 2016-11-23 Gfbiochemicals Ltd PROCESS FOR PRODUCING OCTANE DIOIC ACID, PRECURSORS AND DERIVATIVES
EP2978740B1 (en) 2013-03-28 2020-05-13 Basf Se Polyetheramines based on 1,3-dialcohols
HUE043499T2 (hu) 2013-03-28 2019-09-30 Procter & Gamble Poliéteramin-tartalmú tiszítószerek
WO2014184039A1 (de) 2013-05-16 2014-11-20 Basf Se Verfahren zur herstellung von n-alkyl-piperazinen
CN103420843A (zh) * 2013-07-30 2013-12-04 苏州环科新材料有限公司 二异十三胺的合成方法
EP2842936A1 (en) * 2013-08-26 2015-03-04 Basf Se Etheramines based on alkoxylated glycerine or trimethylolpropane.
EP2883862A1 (de) 2013-12-10 2015-06-17 Basf Se Verfahren zur Herstellung von Aminen
US9884805B2 (en) 2014-02-18 2018-02-06 Basf Antwerpen Nv Method for producing N-ethyl-diisopropylamine
CN105992788A (zh) 2014-02-26 2016-10-05 巴斯夫欧洲公司 制备聚胺的方法
MX2016012563A (es) 2014-03-27 2016-12-14 Procter & Gamble Composiciones de limpieza que contienen una polieteramina.
KR101903976B1 (ko) 2014-03-27 2018-10-04 바스프 에스이 1,2-디알코올 기재의 에테르아민
KR101903977B1 (ko) * 2014-03-27 2018-10-04 바스프 에스이 디알코올 기반 에테르아민
JP6275864B2 (ja) 2014-03-27 2018-02-07 ザ プロクター アンド ギャンブル カンパニー ポリエーテルアミンを含有する洗浄組成物
US20150275143A1 (en) 2014-03-27 2015-10-01 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
EP2940116B1 (en) 2014-04-30 2018-10-17 The Procter and Gamble Company Detergent
EP2940117B1 (en) 2014-04-30 2020-08-19 The Procter and Gamble Company Cleaning composition containing a polyetheramine
US9974985B2 (en) 2014-05-15 2018-05-22 Basf Se Etheramines based on 1,2-dialcohols
US9617502B2 (en) 2014-09-15 2017-04-11 The Procter & Gamble Company Detergent compositions containing salts of polyetheramines and polymeric acid
RU2017113008A (ru) 2014-09-15 2018-10-17 Басф Се Соли простых эфираминов и полимерной кислоты
EP3197862B1 (en) 2014-09-25 2020-06-10 Basf Se Polyetheramines based on 1,3-dialcohols
CA2959431C (en) 2014-09-25 2019-10-22 The Procter & Gamble Company Fabric care compositions containing a polyetheramine
US9752101B2 (en) 2014-09-25 2017-09-05 The Procter & Gamble Company Liquid laundry detergent composition
US9631163B2 (en) 2014-09-25 2017-04-25 The Procter & Gamble Company Liquid laundry detergent composition
JP6396583B2 (ja) 2014-09-25 2018-09-26 ザ プロクター アンド ギャンブル カンパニー ポリエーテルアミンを含有する洗浄組成物
US20160090552A1 (en) 2014-09-25 2016-03-31 The Procter & Gamble Company Detergent compositions containing a polyetheramine and an anionic soil release polymer
US9388368B2 (en) 2014-09-26 2016-07-12 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
HUE047041T2 (hu) * 2014-12-12 2020-04-28 Basf Se Eljárás poliéteraminok elõállítására
KR101754833B1 (ko) 2015-01-13 2017-07-07 한국화학연구원 2급 디알킬아민 제조용 촉매 및 이의 이용
EP3061743A1 (de) 2015-02-25 2016-08-31 Basf Se Verfahren zur Herstellung von primären Aminen unter Verwendung eines Nickel-Festbettkatalysators
CN105254508A (zh) * 2015-10-26 2016-01-20 安徽广信农化股份有限公司 正丁基异氰酸酯中间体的精制方法
EP3162880A1 (en) 2015-10-29 2017-05-03 The Procter and Gamble Company Liquid detergent composition
ES2689048T3 (es) 2015-10-29 2018-11-08 The Procter & Gamble Company Composición detergente líquida
US20170275565A1 (en) 2016-03-24 2017-09-28 The Procter & Gamble Company Compositions containing an etheramine
EP3257924A1 (en) 2016-06-17 2017-12-20 The Procter and Gamble Company Liquid detergent composition
EP3279301A1 (en) 2016-08-04 2018-02-07 The Procter & Gamble Company Water-soluble unit dose article comprising a cleaning amine
EP3293246A1 (en) 2016-09-13 2018-03-14 Basf Se Lubricant compositions containing diurea compounds
WO2018050555A1 (de) 2016-09-19 2018-03-22 Basf Se Verfahren zur herstellung von polyaminen ausgehend von dinitrilen und/oder aminonitrilen
WO2018050554A1 (de) 2016-09-19 2018-03-22 Basf Se Cyanethylierte methylcylohexandiamin- (mcda) und toluoldiamin- (tda) derivate
WO2018085957A1 (en) 2016-11-09 2018-05-17 Rhodia Operations Process for production of aromatic compounds comprising at least two amine functions
CN106866435A (zh) * 2017-03-01 2017-06-20 无锡阿科力科技股份有限公司 一种含有桥环结构的聚醚胺及其制备方法
WO2018157395A1 (en) * 2017-03-03 2018-09-07 Rhodia Operations Process for preparing an amine via a direct amination reaction
WO2019162120A1 (de) 2018-02-22 2019-08-29 Basf Se Verfahren zur abreicherung von 2-methoxyethanol (moe)
US11518749B2 (en) 2018-02-22 2022-12-06 Basf Se Method for the continuous separation by distillation of mixtures that contain morpholine (MO), monoaminodiglycol (ADG), ammonia, water and methoxyethanol (MOE)
EP4097205A1 (en) 2020-01-29 2022-12-07 The Procter & Gamble Company A cleaning composition
WO2022179864A1 (en) 2021-02-25 2022-09-01 Basf Se Process for the production of polyalkylene-polyamines by condensation of alkylene-diamines
KR20240072249A (ko) 2021-10-07 2024-05-23 바스프 에스이 액체 상에서의 비스(피롤리디노)부탄의 제조 방법
WO2023135035A1 (en) 2022-01-14 2023-07-20 Basf Se Method for the manufacture or conversion of alkanolamines

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE757840A (fr) 1969-10-23 1971-04-22 Basf Ag Procede de preparation d'amines a partir d'alcools
US4014933A (en) * 1969-10-23 1977-03-29 Basf Aktiengesellschaft Production of amines from alcohols
US4151204A (en) 1975-06-27 1979-04-24 Teijin Limited Process for preparing amino alcohols
SE457608B (sv) 1986-07-11 1989-01-16 Berol Kemi Ab Foerfarande foer framstaellning av en ruteniumdopad nickel- och/eller koboltkatalysator paa en poroes metalloxidbaerare samt anvaendning av katalysatorn i en hydrerings- och/eller dehydreringsreaktion
DE3903367A1 (de) 1989-02-04 1990-08-16 Basf Ag Katalysator und verfahren zur hydrierenden aminierung von alkoholen
US5166433A (en) * 1989-02-04 1992-11-24 Basf Aktiengesellschaft Catalyst and the amination of alcohols under hydrogenating conditions
DE4116367A1 (de) * 1991-05-18 1992-11-19 Basf Ag Verfahren zur herstellung von aminen

Also Published As

Publication number Publication date
DE59500748D1 (de) 1997-11-06
EP0696572B1 (de) 1997-10-01
ES2107885T3 (es) 1997-12-01
KR100376641B1 (ko) 2003-05-22
US5530127A (en) 1996-06-25
JPH08176074A (ja) 1996-07-09
DE4428004A1 (de) 1996-02-15
ATE158788T1 (de) 1997-10-15
CA2155171C (en) 2006-03-14
ZA956574B (en) 1997-02-07
CN1123789A (zh) 1996-06-05
EP0696572A1 (de) 1996-02-14
DK0696572T3 (da) 1997-10-27
CN1078200C (zh) 2002-01-23
CA2155171A1 (en) 1996-02-09
JP3809963B2 (ja) 2006-08-16

Similar Documents

Publication Publication Date Title
KR960007532A (ko) 아민류의 제조방법
DE50007278D1 (de) Verfahren zur Herstellung von Aminen
CA2478858A1 (en) Catalysts and method for the production of amines
DE60201456D1 (de) Säureblockierte Amin-Katalysatoren für die Herstellung von Polyurethanen
GB1422263A (en) 4-phenyl-piperidine compounds
ATE69813T1 (de) Als antiemetika oder antipsychotika nuetzliche carboxamide.
SU648097A3 (ru) Способ получени производных мочевины
ES318019A1 (es) Procedimiento para la fabricaciën de derivados de alcanolamina
GB1492457A (en) 1,2-alkylene-4-substituted urazole derivative
IE39574L (en) 1, 2, 4- triazinediones.
ATE62686T1 (de) Neue 3-oxadiazol- und 3-carbonsaeure-betacarbolinderivate, ihre herstellung und ihre verwendung als arzneimittel.
DK378685D0 (da) 1-(aminophenyl)-2-aminopropanonderivater
DK0945166T3 (da) Katalysator til reduktion af NOx i forbrændingsgasser
RO81681B (ro) Procedeu pentru prepararea unor 1, 2, 3-tiadiazol-3-in-5-ilidenuree
SU778710A3 (ru) Способ получени производных аминоалкоксибензофурана
GB1170561A (en) 5-Nitrothiazole Derivatives and their production
NL194699B (nl) Bereiding van gesubstitueerde ethenen en daarvan afgeleide ranitidine.
ATE80162T1 (de) Antibiotisch wirkende isoxazolderivate, ihre herstellung und verwendung.
ATE918T1 (de) Tensioaktive polypode, verfahren zu ihrer herstellung und diese enthaltende praeparate.
GB1422230A (en) Use of o,n-and n,n-acetals in the preparation of polyurethanes ureas
DE69512786T2 (de) Verfahren zur herstellung von o-(2-hydroxy)oximen
IT1122376B (it) Prodotti diuretici
ES430457A1 (es) Procedimiento para la preparacion de acidos 2-alcoxi-ben- zoicos sustituidos con sulfamoilo en la posicion 5.
GB1038339A (en) 4-benzenesulphonyl-thiosemicarbazides and their manufacture and use
DE3570877D1 (en) 3-amino-2,3-dihydro-1-benzoxepine compounds, process for their preparation and medicaments containing these compounds

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20100223

Year of fee payment: 8

LAPS Lapse due to unpaid annual fee