KR920014794A - 히드라진 유도체 및 상기 유도체를 유효성분으로서 포함하는 살충 조성물 - Google Patents

히드라진 유도체 및 상기 유도체를 유효성분으로서 포함하는 살충 조성물 Download PDF

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KR920014794A
KR920014794A KR1019920000922A KR920000922A KR920014794A KR 920014794 A KR920014794 A KR 920014794A KR 1019920000922 A KR1019920000922 A KR 1019920000922A KR 920000922 A KR920000922 A KR 920000922A KR 920014794 A KR920014794 A KR 920014794A
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hydrogen atom
hydrazine
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alkoxy
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미끼오 야나기
히로야스 스기자끼
데쯔야 도야
야스히또 가또
히데또시 시라꾸라
데쯔오 와따나베
요시미 야지마
세이찌로우 고다마
아끼오 마스이
도시아끼 야나이
요시히사 쯔가모또
요시히로 사와다
신지 요꼬이
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니뽕 가야꾸 가부시끼가이샤
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Abstract

내용 없음

Description

히드라진 유도체 및 상기 유도체를 유효성분으로서 포함하는 살충 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 하기 일반식(Ⅰ)의 히드라진 유도체 :
    상기 식에서,
    A 및 B는 각각 독립적으로NR'이고,
    A 및 B가 각각 독립적으로또는 NR'인 경우, A, B 또는 A와 B 모두는 임의적으로는 인접한 탄소 원자와 함께 이중 결합을 형성하며, R은 수소 원자, (C1-C4)알킬기 또는 (C1-C4)알콕시기이고, R'은 수소원자, (C1-C4)알킬기, (C2-C4)아실기 또는 p-플루오로벤질기이거나, 또는 R과 R'은 합쳐져서 R과 R'이 결합되어 있는 탄소 원자와 함께 디옥솔란 고리를 형성할 수 있으며, R1, R2, R3및 R4는 각각 독립적으로 수소 원자, 할로겐 원자, (C1-C4)알킬기, (C1-C4)알콕시, (C1-C4)알킬기 또는 벤질옥시(C1-C4)알킬기이며, R5, R6및 R7은 각각 독립적으로 수소 원자, 할로겐 원자, (C1-C4)알킬기, 니트로기, 아미노기, 시아노기, 히드록시기, 포르밀기, (C1-C4)할로알킬기, (C2-C4)알켄일기, (C1-C|4)알콕시기, (C1-C4)알콕시 (C1-C4)알킬기, (C1-C4)알킬티오 (C1-C4)알킬기 또는 (C1-C|4)알콕시 (C1-C4)알콕시기이며, R8, R9및 R10은 각각 독립적으로 수소 원자, 할로겐 원자, (C1-C4)알킬기, 트리(C1-C4)알킬실릴옥시(C1-C4)알킬기, 니트로기, (C1-C4)할로알킬기, 히드록시(C|1-C4)알킬기, 포르밀기, (C1-C4)알콕시기, (C2-C4)알켄일옥시기, (C2-C|4)알킨일옥시기, (C2-C4)알켄일기, (C2-C4)알킨일기, (C1-C4)할로알콕시기, (C1-C|4)할로알킬티오기, (C1-C4)알콕시 (C1-C4)알콕시기, 할로겐 원자에 의해 임의적으로 치환되 페닐기를 갖는 (C1-C|4)알콕시기, 또는 CF3, 할로겐 원자 또는 (C1-C2)알킬기에 의해 임의적으로 치환된 페녹시기를 갖는 (C1-C4)알콕시기이고, R11은 수소 원자, 시아노기, (C1-C|4)할로알킬티오기, (C2-C5)아실기, 디(C1-C4)알킬카르바모일기, (C1-C|4)알콕시카르보닐기, (C1-C4)알콕시카르보닐카르보닐기, (C2-C4)알켄일기 또는 할로겐 원자, (C1-C4)알콕시기, (C1-C6)알킬카르보닐옥시기 또는 (C1-C4)알콕시카르보닐기에 의해 임의적으로 치환된 (C1-C4)알킬기이고, R12는 측쇄(C3-C10)알킬기이고, n은 0 또는 1이고, 단 A 및 B가 각각 독립적으로 -O- 또는(여기에서, R 및 R'은 각각 독립적으로 수소 원자 또는 (C1-C4)알킬기임)인 경우, R5, R6및 R7중 적어도 하나는 수소 원자가 아니다.
  2. 제1항에 있어서, A가 -O- 또는 -CH2-이고, B가 -O- 또는 -CH2-이며, R1, R2, R3및 R4가 각각 독립적으로 수소 원자 또는 메틸기이고, R5가 (C1-C4)알킬기, (C1-C4)할로알킬기 또는 할로겐 원자이고, R6이 수소 원자, (C1-C4)알킬기 또는 할로겐 원자이며, R7이 수소 원자 또는 할로겐 원자이며, R8, R9및 R10이 각각 독립적으로 수소 원자, (C1-C4)알킬기, (C1-C4)할로알킬기, 할로겐 원자, 니트로기, (C1-C4)알콕시기, (C2-C4)알켄일옥시기, (C2-C4)알킨일옥시기, (C2-C4)알켄일기, (C1-C4)할로알콕시기, 페닐 잔기가 할로겐 원자에 의해 임의적으로 치환된 페닐(C1-C4)알콕시기, 또는 페닐 잔기가 (C1-C2)알킬기, CF3또는 할로겐 원자에 의해 임의적으로 치환된 페녹시(C1-C4)알콕시기이며, R11이 수소 원자, 시아노기, (C1-C4)할로알킬티오기, (C1-C4)알콕시카르보닐카르보닐기 또는 (C1-C4)알킬카르보닐옥시메틸기이며, R12가 측쇄(C4-C8)알킬기이고; 또 n이 0인 히드라진 유도체.
  3. 제1항에 있어서, A가 -O- 또는 -CH2-이고, B가 -O- 이고, R1, R2, R3및 R4가 각각 수소 원자이고, R5가 (C1-C2)알킬기, (C1-C2)할로알킬기 또는 할로겐 원자이고, R6이 수소 원자이며, R7이 수소 원자이고, R8, R9및 R10이 각각 독립적으로 수소 원자, (C1-C2)알킬기, (C1-C2)할로알킬기, 할로게 원자, 니트로기 또는 (C1-C2)알콕시기이며, R11이 수소 원자, 시아노기, 트리클로로메틸티오기, 에톡시카르보닐카르보닐기 또는 피발로일옥시메틸기이며, R12가 측쇄 (C4-C6)알킬기이며, 또 n이 0인 히드라진 유도체.
  4. 제1항에 있어서, A가 -O- 또는 -CH2-이고, B가 -O- 이고, R1, R2, R3및 R4가 각각 수소 원자이고, R5가 (C1-C2)알킬기이며, R6이 수소 원자이고, R7이 수소 원자이고, R8, R9및 R10이 각각 독립적으로 수소 원자, 메틸기, 모노-, 디- 또는 트리플루오로 메틸기, 염소 원자, 플루오르 원자, 니트로기 또는 메톡시기이며, R11이 수소 원자, 시아노기, 트리클로로메틸티오기, 에톡시카르보닐카르보닐기 또는 피발로일옥시메틸기이고, R12가 측쇄 (C4-C6)알킬기이며, 또 n이 0인 히드라진 유도체.
  5. 제1항에 있어서, A가 -O- 또는 -CH2-이고, B가 -O- 이며, R1, R2, R3및 R4가 각각 수소 원자이며, R5가 (C1-C2)알킬기이며, R6이 수소 원자이고, R7이 수소 원자이고, R8, R9및 R10이 자신들이 결합되어 있는 페닐기와 함께 3,5-디메틸페닐기, 3,5-디클로로페닐기, 2,4-디클로로페닐기, 3-플루오로메틸-5-메틸페닐기, 3-디플루오로메틸-5-메틸펠기 또는 3,5-디메틸-4-플루오로페닐기이며, R11이 수소 원자, 시아노기 또는 트리클로로메틸티오기이며, R12가 3차부틸기, 2,2-디메틸프로필기 또는 1,2,2-트리메틸프로필기이고, 또 n이 0인 히드라진 유도체.
  6. 제1항에 있어서, N-(5-메틸크로만-6-카르보)-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-시아노-N-(5-메틸크로만-6-카르보)-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-(5-메틸크로만-6-카르보)-N'-3차부틸-N'-(3,5-디메틸-4-플루오로벤조일)히드라진, N-(5-메틸크로만-6-카르보)-N-트리클로로메틸티오-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-(2,2-디메틸프로필)-N'-(3,5-디메틸벤조일)히드라진, N-시아노-N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N-트리클로로메틸티오-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-3차부틸-N'-(3,5-디메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-3차부틸-N'-(3-디플루오로메틸-5메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-3차부틸-N'-(3-디플루오로메틸-5-메틸벤조일)히드라진, N-(5-메틸-1,4-벤조디옥산-6-카르보)-N'-3차부틸-N'-(3.5-디메틸벤조일)히드라진으로부터 선정되는 히드라진 유도체.
  7. 유효성분으로서 제1항 내지 제6항중 어느 하나에 따른 히드라진 유도체 살충 유효량 및 살충제에서 허용가능하 보조제를 포함하는 살충 조성물.
  8. 제1항 내지 제6항중 어느 하나에 따른 히드라진 유도체를 해충에게 투여하는 것을 포함하는, 해충 방제법.
  9. 염기의 존재하에 불활성 용매중에서 하기 일반식(Ⅱ)의 히드라지드를 하기 일반식(Ⅲ)의 벤조일 할라이드와 반응시키는 것을 포함하는, 하기 일반식(Ⅰ)의 히드라진 유도체의 제조방법 :
    상기 식에서, R1내지 R12및, A, B 및 n은 제1항에서 정의한 바와 같고, X는 할로겐 원자이다.
  10. 염기의 존재하에 불활성 용매 중에서 하기 일반식(Ⅰa)의 히드라진 유도체를 하기 일반식(Ⅱa)의 할라이드와 반응시키는 것을 포함하는, 하기 일반식(Ⅰ)의 히드라진 유도체의 제조방법 :
    상기 식에서, R1내지 R10R12, A, B 및 n은 제1항에서 정의한 바와 같고, R11은 시아노기, (C1-C4)할로알킬티오기, (C2-C5)아실기, 디(C1-C4)아킬카르바모일기, (C1-C4)알콕시카르보닐기, (C1-C4)알콕시카르보닐카르보닐기; 할로겐 원자, (C1-C4)알콕시기, (C1-C6)알킬카르보닐옥시기 또는 (C1-C4)알콕시카르보닐기에 의해 임의적으로 치환된 (C1-C4)알킬기; 또는 (C2-C4)알켄일기이며, X는 할로겐 원자이다.
  11. 염기의 존재하에 불활성 용매 중에서 하기 일반식(Ⅳ)의 벤조일 할라이드를 하기 일반식(Ⅸ)의 히드라지드와 반응시키는 것을 포함하는, 하기 일반식(Ⅰa)의 히드라진 유도체의 제조방법 :
    상기 식에서, R1내지 R10, R12, A, B 및 n은 제1항에서 정의한 바와 같고, X는 할로겐 원자이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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EP0496342A1 (en) 1992-07-29
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AU684340B2 (en) 1997-12-11
JPH05163266A (ja) 1993-06-29
DE69215393T3 (de) 2002-11-28
EP0496342B2 (en) 2002-07-24
GR3021792T3 (en) 1997-02-28
AU646918B2 (en) 1994-03-10
ES2094241T5 (es) 2002-12-01
UA27744C2 (uk) 2000-10-16
CA2059787C (en) 2002-04-30
EP0496342B1 (en) 1996-11-27
JP2577189B2 (ja) 1997-01-29
ATE145646T1 (de) 1996-12-15
IL100643A0 (en) 1992-09-06
RU2041220C1 (ru) 1995-08-09
DK0496342T4 (da) 2002-11-11
DE69215393T2 (de) 1997-03-27
JPH06340654A (ja) 1994-12-13
JP2577154B2 (ja) 1997-01-29
IL100643A (en) 1996-10-31
DE69215393D1 (de) 1997-01-09
KR0159047B1 (ko) 1998-12-01
ES2094241T3 (es) 1997-01-16
CN1063488A (zh) 1992-08-12
CN1035539C (zh) 1997-08-06
AU1781695A (en) 1995-08-17
DK0496342T3 (ko) 1997-03-03
AU1031792A (en) 1992-09-17
US5378726A (en) 1995-01-03

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