KR940014359A - 살충제 및 진드기 구충제로서 n-아릴히드라진 유도체 - Google Patents

살충제 및 진드기 구충제로서 n-아릴히드라진 유도체 Download PDF

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KR940014359A
KR940014359A KR1019930030416A KR930030416A KR940014359A KR 940014359 A KR940014359 A KR 940014359A KR 1019930030416 A KR1019930030416 A KR 1019930030416A KR 930030416 A KR930030416 A KR 930030416A KR 940014359 A KR940014359 A KR 940014359A
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alkyl
halogen
haloalkyl
alkoxy
haloalkoxy
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KR100314220B1 (ko
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아우구스투스 퍼어치 조오지프
조오지 쿠운 데이빗
앨런 헌트 데이빗
치에 류우 앨버트
엠마 그로노스타예스키 신씨아
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알퐁스 아아르 노에
아메리칸 사이아나밋드 캄파니
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  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

일반식 Ⅰ의 N-아릴히드라진 유도체
곤충 및 진드기 페스트의 방체를 위한 이들의 사용 및 상기 페스트로 인한 손해 및 손실로부터 작물을 보호하기 위한 방법 및 조성물이 제공된다.

Description

살충제 및 진드기 구충제로서 N-아릴히드라진 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 곤충 또는 진드기 페스트 또는 그들의 먹이원, 번식지 또는 서식지를 살충제로 효과적인 양이 하기 일반식을 갖는 화합물 또는 이들의 산 부가염과 접촉시키는 것으로 구성되는 상기 페스트들의 방제 방법
    상기 식에서, A는 C-R4또는 N이고 ; B는 C-R5또는 N 이고 ; W는 C-R 또는 N이나 단 A, B 또는 W중 적어도 하나는 N이외의 것이어야만 하고 ; Y는 할로겐, CN, NO2, C1-C6알킬, C1-C6할로알킬, C1-C6알콕시 또는 C1-C6할로알콕시이고 ; n은 정수 0,1 또는 2이고 ; Q는
    R은 수소, 하나 이상의 할로겐, C3-C6시클로알킬, C1-C4알콕시, C1-C4할로알콕시, (C1-C4알킬)SOx, SOx( C1-C4할로알킬)SOx, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, (C1-C4알킬)SOx,( C1-C4할로알킬)SOx, NO2또는 CN기로 임의 치환된 페닐, 또는 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, ( C1-C4알킬)SOx, ( C1-C4할로알킬)SOx, NO2또는 CN기로 임의 치환된 페녹시로 임의 치환된 C1-C10알킬, 하나이상의 할로겐, C1-C6알킬, C1-C6할로알킬, C1-C4알콕시, C1-C4할로알콕시, ( C1-C4알킬)SOx, ( C1-C4할로알킬)SOx, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 페닐, 또는 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 페녹시로 임의 치환된 C3-C12시클로알킬, 또는 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 페닐이고 ; R1및 R2는 각각 독립적으로 수소 또는 C1-C4알킬이고 ; R3및 R16은 각각 독립적으로 수소, 하나 이상의 할로겐, 히드록시, C1-C4알콕시, ( C1-C4알킬)SOx, CONR7, R8, CO2R9, R10, R11, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 C3-C6시클로알킬 하나 이상의 할로겐 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, CO2또는 CN기로 임의 치환된 페닐, 또는 하나이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 피리딜로 임의 치환된 C1-C10알킬, 하나 이상의 할로겐, 히드록시, C1-C4알콕시, (C1-C4알킬)SOx, CONR7R8, C02R9, R10, R11, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 C3-C6시클로알킬, 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, CO2또는 CN기로 임의 치환된 페닐, 또는 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 피리딜로 임의 치환된 C3-C10알케닐, 하나 이상의 할로겐, 히드록시, C1-C4알콕시, (C1-C4알킬)SOx, CONR7R8, C02R9, R10, R11, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 C3-C6시클로알킬, 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, CO2또는 CN기로 임의 치환된 페닐, 또는 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 피리딜로 임의 치환된 C3-C10알케닐, 하나 이상의 할로겐, 히드록시, C1-C4알콕시, (C1-C4알킬)SOx, CONR7R8, C02R9, R10, R11, 1-3개의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 C3-C6시클로알킬, 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, CO2또는 CN기로 임의 치환된 페닐, 또는 하나 이상의 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4할로알콕시, NO2또는 CN기로 임의 치환된 페리딜로 임의 치환된 피리딜로 임의 치환된 C3-C12시클로알킬이거나 R3및 R16은 함께 취해져서 하기 구조식으로 나타내어진 고리를 형성할 수 있고
    R4, R5및 R6는 각각 독립적으로 수소, 할로겐, CN, NO2, (C1-C4알킬)SOx, (C1-C4할로알킬)SOx, C1-C6알킬, C1-C6할로알킬, C1-C6알콕시 또는 C1-C6할로알콕시이고 ; R7, R8및 R0는 각각 독립적으로 수소 또는 C1-C4알킬이고 ; R10은 NR12R13,
    이고 ; R12, R13, R14및 R15는 각각 독립적으로 수소 또는 C1-C4알킬기이고 ; X는 O, S 또는 NR14이고 ; X1는 염소, 브롬, 또는 불소이고 ; r은 정수 0 또는 1이고 ; P 및 m은 각각 독립적으로 정수 0, 1, 2 또는 3이며 p, m 또는 r중 하나 만이 0일 수 있고 또한 단 p+m+r의 합은 4, 5 또는 6이어야만 하고 ; X는 점수 0, 1 또는 2이며 ; 단 Q가
    R이 C1-C5알킬이며 X1이 염소이면, A, B 또는 W중 적어도 하나는 N이어야만 하거나 R4, R5, R6및 Y는 수소이외의 것이어야만 하며 n은 0이어야만 하고 또한 단 Q가
    R이 페닐 또는 치환 페닐이며 X1이 염소이면, A, B 또는 W 적어도 하나는 N이어야만 한다.
  2. 제 1 항에 있어서, Q가
    인 방법.
  3. 제 2 항에 있어서, A가 C-R4이고, B가 CH이고, W가 C-R6이고, Y가 할로겐이고, n이 1이고, R1이 수소이고, R4및 R6이 각각 독립적으로 할로겐 또는 하나 이상의 할로겐으로 치환된 C1-C6알킬이며, R, R3및 R16은 각각 독립적으로 수소 또는 C1-C10알킬인 방법.
  4. 제 1 항에 있어서, Q가
    인 방법.
  5. 제 4 항에 있어서, R1및 R2가 수소이고, R이 C1-C6알킬이고, A가 C-R3이고, B가 C-R4이고, W가 C-R5이고, Y가 할로겐이고, n이 1이고, R3가 할로겐이고, R4가 수소이며 R5는 하나 이상의 할로겐으로 치환된 C1-C6알킬인 방법.
  6. 제 5 항에 있어서, 화합물이 2,2-디메틸프로피온산, 2-(2,6-디클로로-α,α,α-트리플루오로-p-톨릴) 히드라지드인 방법.
  7. 하기 구조식을 갖는 화합물
    상기 식에서 A, B, W, Y, n, R, R1, R3및 R16은 제 1 항에 서술되고 단 A, B 및 W 모두 N이 아니라면, R 및 R3또는 R16중 하나는 수소이외의 것이며 또한 단 A, B 또는 W중 하나가 N이면, Y, R4, R5또는 R6은 C1-C10알킬이외의 것이어야만 한다.
  8. 제 7 항에 있어서 하기 구조식을 갖는 화합물
    상기 식에서 R은 C1-C10알킬이고 ; R1은 수소 또는 C-C4알킬이고 ; R3는 C1-C10알킬이고 ; R16은 수소 또는 C1-C10알킬이며 ; R4, R6및 Y는 각각 독립적으로 수소, 할로겐, CN, NO2, C1-C6알킬, C1-C6할로알킬, C1-C6알콕시 또는 C1-C6할로알콕시이다.
  9. 제 8 항에 있어서, N-에틸-2,2-디메틸프로피온아미드, 2-(2,6-디클로로-α, α, α-트리플루오로-p-톨릴)히드라존인 화합물.
  10. 하기 구조식
    을 갖는 화합물을 적어도 1몰 당량의 아민 화합물, HNR3R16과 반응시키는 것으로 이루어지는 하기 구조식 ;
    (상기 식에서 A, B, W, Y, n, R, R1, R3및 R16은 제 1 항에 서술됨)을 갖는 화합물의 제조방법.
  11. 불활성 액체 또는 고체 부형제 및 살충제로 효과적인 양의 하기 일반식 Ⅰ의 화합물로 이루어지는 곤충 또는 진드기 페스트를 방제하기 위한 조성물
    (상기 식에서 A, B, W, Y, n, R1 및 Q는 제 1 항에 서술된다.
  12. 제 11항에 있어서, 일반식 Ⅰ 화합물이 하기 구조식
    을 갖고 R이 C1-C10알킬이고 ; R1이 수소 또는 C1-C4알킬이고 ; R3가 C1-C10알킬이고 ; R16이 수소 또는 C1-C10알킬이며 ; R4, R6및 Y는 각각 독립적으로 수소, 할로겐, CN, NO2, C1-C6알킬, C1-C6할로알킬, C1-C6알콕시 또는 C1-C6할로알콕시인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930030416A 1992-12-29 1993-12-28 살충제및 진드기 구충제로서 n-아릴히드라진 유도체 KR100314220B1 (ko)

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Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6306798B1 (en) 1996-07-24 2001-10-23 Syngenta Crop Protection, Inc. Compounds for controlling insects and representatives of the order acarina
US6492527B1 (en) * 1999-10-13 2002-12-10 Fmc Corporation Process to prepare aryltriazolinones and novel intermediates thereto
UA79571C2 (en) * 2003-12-04 2007-06-25 Basf Ag Metod for the protection of seeds from soil pests comprising
DE602005026291D1 (de) 2004-07-06 2011-03-24 Basf Se Flüssige pestizidzusammensetzungen
WO2006073973A2 (en) 2004-12-31 2006-07-13 Reddy Us Therapeutics, Inc. Novel benzylamine derivatives as cetp inhibitors
US8604055B2 (en) 2004-12-31 2013-12-10 Dr. Reddy's Laboratories Ltd. Substituted benzylamino quinolines as cholesterol ester-transfer protein inhibitors
AP2007004296A0 (en) * 2005-06-03 2007-12-31 Basf Ag Pesticidal mixture
EA200702537A1 (ru) * 2005-06-03 2008-06-30 Басф Акциенгезельшафт Композиция для пропитки нитей, тканей и сетчатых материалов, обеспечивающая защиту от вредителей
EP1895839A1 (en) * 2005-06-03 2008-03-12 Basf Se Method of combating bugs
DE602006012669D1 (de) 2005-06-03 2010-04-15 Basf Se Derivate eines 1-phenyltriazols als antiparasitika
WO2007051756A1 (en) * 2005-11-04 2007-05-10 Basf Se Crystalline modification of n-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro- alpha,alpha,alpha -trifluoro-p-tolyl)hydrazone
JP2009545552A (ja) * 2006-08-03 2009-12-24 ビーエーエスエフ ソシエタス・ヨーロピア アミドラゾンの調製方法
AR062844A1 (es) 2006-09-14 2008-12-10 Basf Ag Composicion pesticida
US20100099774A1 (en) * 2007-02-01 2010-04-22 Basf Se Method for Controlling Harmful Fungi
WO2008092818A2 (en) * 2007-02-01 2008-08-07 Basf Se Pesticidal mixtures
EP2618661A2 (de) 2010-09-23 2013-07-31 Basf Se Verfahren zum schutz von lebenden pflanzen vor schadinsekten mit einem flächengebilde
CN103827105B (zh) 2011-08-18 2016-08-17 雷迪博士实验室有限公司 作为胆固醇酯转移蛋白(cetp)抑制剂的取代的杂环胺化合物
CN103958511A (zh) 2011-09-27 2014-07-30 雷迪博士实验室有限公司 作为胆固醇酯转移蛋白(CETP)抑制剂用于治疗动脉粥样硬化的5-苄基氨基甲基-6-氨基吡唑并[3,4-b]吡啶衍生物
MY187947A (en) 2015-04-17 2021-10-31 Basf Agrochemical Products Bv Method for controlling non-crop pests
WO2019175712A1 (en) 2018-03-14 2019-09-19 Basf Corporation New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways
WO2019175713A1 (en) 2018-03-14 2019-09-19 Basf Corporation New catechol molecules and their use as inhibitors to p450 related metabolic pathways

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB736473A (en) * 1952-09-25 1955-09-07 Bataafsche Petroleum Compositions for combating parasites
US3505403A (en) * 1963-12-27 1970-04-07 Union Carbide Corp Amidoximes and amidhydrazones and method of preparation
DE1199540B (de) * 1963-12-27 1965-08-26 Schering Ag Mittel mit Wirkung gegen echten Mehltau
US3745215A (en) * 1969-11-07 1973-07-10 Upjohn Co Methods of combatting insects and mites using alkanoyl chloride phenylhydrazones
FR2105698A5 (ko) * 1970-09-17 1972-04-28 Roussel Uclaf
DE2223936A1 (de) * 1972-05-17 1973-12-06 Bayer Ag Fungizide mittel
US3917849A (en) * 1972-05-26 1975-11-04 Rhone Poulenc Sa Insecticidal and acaricidal phenylhydrazone derivatives
US3935315A (en) * 1972-05-26 1976-01-27 Rhone-Poulenc S.A. Insecticidal and acaricidal phenylhydrazone derivatives
US3879542A (en) * 1972-10-16 1975-04-22 Upjohn Co Anti-arthropodal formulation and method
DE3869167D1 (de) * 1987-03-27 1992-04-23 Kumiai Chemical Industry Co Phenyltriazol-derivate und insectizid.
DE3802175A1 (de) * 1988-01-26 1989-08-03 Hoechst Ag N-phenylbenzamide und n-phenylbenzamidoxime, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung als schaedlingsbekaempfungsmittel
DE4200591A1 (de) * 1992-01-13 1993-07-15 Bayer Ag Herbizide, insektizide und akarizide mittel enthaltend fluorsubstituierte benzhydrazidoylhalogenide

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SK281733B6 (sk) 2001-07-10
JP3816543B2 (ja) 2006-08-30
BG98338A (bg) 1994-07-29
BR9305254A (pt) 1994-11-01
DE69331600D1 (de) 2002-03-28

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