KR880012561A - 피라졸 유도체, 이를 유효성분으로서 함유하는 살충제 또는 살비제 조성물 - Google Patents

피라졸 유도체, 이를 유효성분으로서 함유하는 살충제 또는 살비제 조성물 Download PDF

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KR880012561A
KR880012561A KR1019880004707A KR880004707A KR880012561A KR 880012561 A KR880012561 A KR 880012561A KR 1019880004707 A KR1019880004707 A KR 1019880004707A KR 880004707 A KR880004707 A KR 880004707A KR 880012561 A KR880012561 A KR 880012561A
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이따루 오까다
스꼬 오꾸이
요지 다까하시
도시끼 후꾸찌
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시바따 마쓰지로
미쓰비시 가세이 고교 가부시끼가이샤
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
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    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D—HETEROCYCLIC COMPOUNDS
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
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    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/38—Nitrogen atoms
    • C07D231/40—Acylated on said nitrogen atom
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    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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Abstract

내용 없음

Description

피라졸 유도체, 이들 유효성분으로서 함유하는 살충제 또는 살비제 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 일반식(Ⅰ)로 표시되는 피라졸 유도체:
    상기식에서, R1은 수소원자, C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 어느 하나는또는를 나타내며; 여기서, R4는
    를 나타내고; 또 여기에서, R5,R6, 및 R7은 각각 수소원자, C1-C|4알킬기, 또는 페닐기를 나타내며, R8및 R9는 각각 수소원자, 할로겐원자, C1-C8알킬기, C3-C5알켄일기, C3-C5알킨일기, C3-C6시클로알킬기, C2-C|4알콕시알킬기, C1-C4알콕시기, 니트로기, 트리플루오로메틸기, 페닐기, 벤질기, 페녹시기, 벤질옥시기, 아미노기, C1-C4알킬아미노기, C2-C8디알킬아미노기, 시아노기, 카르복시기, C2-C5알콕시카르보닐기, C4-C7시클로알콕시카르보닐기, C3-C9알콕시알콕시카르보닐기, C2-C6알킬아미노카르보닐기, 알아미노카르보닐기, C3-C11디알키아미노카르보닐기, 피페리디노카르보닐기, 모르폴리노르보닐기, 트리메틸실릴기, C1-C4알킬티오기, C1-C|4알킬술피닐기, C1-C4또는 C1-C4알킬술포닐기를 나타내고; R6,R|7,R8및 R9모두가 수소원자를 나타내는 경우, R1은 C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2,R3중 나머지 하나는 수소원자, C1-C4알킬기, C1-C4할로알킬기, C3-C6시클로알킬기 또는 페닐기를 나타내며; X는 수소원자, 할로겐 원자, C1-C4알킬기, 니트로기, 사아노기, C1-C5알킬아미노기, C2-C10디알킬아미노기 및 C2-C7아실아미노기를 나타낸다.
  2. 제1항에 있어서, R1이 C1-C4알킬기, 페닐기 또는 벤질기이고; R2가 수소원자, C1-C4알킬기, C3-C8실클로알킬기 또는 C1-C4할로알킬기이며; R3가또는이고; 여기서, R4는
    이고, 또 여기서,R5,R6,R7,R8및 R9는 제1항에 정의한 바와 동일한 의미를 가지며; 또 X가 수소원자, 할로겐 원자, C1-C4알킬기, 시아노기 또는 C1-C|4알킬아미노기인 피라졸 유도체.
  3. 제2항에 있어서, R1이 C1-C4알킬기이고; 또 R5및 R9가 수소원자인 피라졸 유도체.
  4. 유효성분으로서, 살충 및 살비 유효량의 하기 일반식(Ⅰ)로 표시되는 피라졸 유도체를 함유하고 또 살충제 및 살비제를 허용되는 보조제(들)를 함유하는 살충제 및 살비제 조성물:
    상기식에서 R1은 수소원자, C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 어느 하나는또는를 나타내며; 여기서, R4는
    또는를 나타내고; 또 여기에서, R5,R6및 R7은 각각 수소원 자, C1-C4일킬기, 또는 페닐기를 나타내며; R8및 R9는 각각 수소원자, 할로겐원자, C1-C8알킬기, C3-C5알켄일기, C3-C|5알킨일기, C3-C6시클로알킬기, C2-C4알콕시알킬기, C3-C6시클로알킬기, C1-C4할로알콕시기, 니트로기, 트리플루오로메틸기, 페닐기, 벤질기, 페녹시기, 벤질옥시기, 아미노기, C1-C4알킬아미노기, C2-C8디알킬아미노기, 시아노기, 카르복시기, C2-C5알콕시카르보닐기, C4-C7시클로알콕시카르보닐기, C3-C9알콕시알콕시카르보닐기, C2-C6알킬아미노카르보닐기, C3-C11디알킬아미노카르보닐기,피페리디노카르보닐기,모르폴리노카르보닐기,트리메틸실릴기, C1-C4알킬티오기, C1-C4알킬술피닐기, 또는 C1-C4알킬술포닐기를 나타내고; R6,R7,R8및 R9모두가 수소원자를 나타내는 경우, R1은 C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 나머지 하나는 수소원자, C1-C4알킬기, C1-C4할로알킬기, C3-C6시클로알킬기 또는 페닐기를 나타내며; X는 수소원자, 할로겐 원자, C1-C4알킬기, 니트로기, 사아노기, C1-C5알킬아미노기, C2-C10디알킬아미노기 및 C2-C7아실아미노기를 나타낸다.
  5. 제4항에 있어서, R1은 C1-C4알킬기, 페닐기 또는 벤질기이고; R2가 수소원자, C1-C4알킬기, C3-C3-C8시클로알킬기 또는 C1-C4할로알킬기이며, R3가또는를 나타내며; 여기서, R4는
    이며, 또 여기에서, R5,R6,R7,R8및 R9는 제1항에서 정의한 바와 같이 동일한 의미를 가지고; 또 X가 수소원자, 할로겐 원자, C1-C4알킬기, 시아노기 또는 C1-C4알킬아미노기인 살충제 및 살비제 조성물.
  6. 제5항에 있어서, R1이 C1-C4알킬기이고, 또 R5및 R9가 수소원자인 살충제 및 살비제 조성물.
  7. 하기 일반식(Ⅰ)로 표시되는 피라졸 유도체를 살충 및 살비 유효량으로 상기 해충 또는 진드기의 알 또는 유충에 투여하는 것을 특징으로 하여 및 진드기를 방제하는 방법.
    상기식에서 R1은 수소원자, C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 어느 하나는또는를 나타내며; 여기서, R4는
    또는를 내타내고;또 여기에서, R5,R6및 R7은 각각 수소원 자, C1-C4일킬기, 또는 페닐기를 나타내며; R8및 R9는 각각 수소원자, 할로겐원자, C1-C8알킬기, C3-C5알켄일기, C3-C|5알킨일기, C3-C6시클로알킬기, C2-C4알콕시알킬기, C1-C4알콕시기, C1-C4할로알콕시기, 니트로기, 트리플루오로메틸기, 페닐기, 벤질기, 페녹시기, 벤질옥시기, 아미노기, C1-C4알킬아미노기, C2-C8디알킬아미노기, 시아노기, 카르복시기, C2-C5알콕시카르보닐기, C4-C7시클로알콕시카르보닐기, C3-C9알콕시알콕시카르보닐기, C2-C6알킬아미노카르보닐기, C3-C11디알킬아미노카르보닐기, 페페리디노카르보닐기, 모르폴리노카르보닐기, 트리메틸실릴기, C1-C4알킬티오기, C1-C4알킬술피닐기, 또는 C1-C|4알킬술포닐기를 나타내고; R6,R7,R8및 R9모두가 수소원자를 나타내는 경우, R1은 C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 나머지 하나는 수소원자, C1-C4알킬기, C1-C4할로알킬기, C3-C6시클로알킬기 또는 페닐기를 나타내며; X는 수소원자, 할로겐 원자, C1-C4알킬기, 니트로기, 사아노기, C1-C5알킬아미노기, C2-C10디알킬아미노기 및 C2-C7아실아미노기를 나타낸다.
  8. 하기 일반식(Ⅱ)로 표시되는 화합물을 하기 일반식(Ⅲ)으로 표시되는 화합물과 반응시키는 것을 포함하는, 하기 일반식(Ⅰ)로 표시되는 피라졸 유도체의 제조방법:
    상기식에서 R1은 수소원자, C1-C4알킬기, C1-C4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 어느 하나는또는를 나타내며; 여기서, R4는
    또는를 내타내고;또 여기에서, R5,R6및 R7은 각각 수소원 자, C1-C4일킬기, 또는 페닐기를 나타내며; R8및 R9는 각각 수소원자, 할로겐원자, C1-C8알킬기, C3-C5알켄일기, C3-C5알킨일기, C3-C6시클로알킬기, C2-C4알콕시알킬기, C1-C4알콕시기, C1-C4할로알콕시기, 니트로기, 트리플루오로메틸기, 페닐기, 벤질기, 페녹시기, 벤질옥시기, 아미노기, C1-C4알킬아미노기, C2-C|8디알킬아미노기, 시아노기, 카르복시기, C2-C5알콕시카르보닐기, C4-C7시클로알콕시카르보닐기, C3-C9알콕시알콕시카르보닐기, C2-C6알킬아미노카르보닐기, C3-C11디알킬아미노카르보닐기, 페페리디노카르보닐기, 모르폴리노카르보닐기, 트리메틸실릴기, C1-C4알킬티오기, C1-C4알킬술피닐기, 또는 C1-C4알킬술포닐기를 나타내고; R6,R7,R8및 R9모두가 수소원자를 나타내는 경우, R1은 C1-C4알킬기, C1-C|4할로알킬기, 페닐기 또는 벤질기를 나타내고; R2및 R3중 나머지 하나는 수소원자, C1-C4알킬기, C1-C4할로알킬기, C3-C6시클로알킬기 또는 페닐기를 나타내고; X는 수소원자, 할로겐 원자, C1-C4알킬기, 니트로기, 사아노기, C1-C5알킬아미노기, C2-C10디알킬아미노기 및 C2-C7아실아미노기를 나타내며, R10및 R11중 어느 하나는 |또는(여기서, Z는 염소원자, 브롬원자, 히드록시기, 메톡시기, 에톡시기 또는 프로폭시기임)이고, R10및 R11중 나머지 하나는 수소원자,
    C1-C4알킬기, C1-C4할로알킬기, C3-C6시클로알킬기 또는 페닐기이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004707A 1987-04-24 1988-04-23 피라졸 유도체, 이를 유효성분으로서 함유하는 살충제 또는 살비제 조성물 KR950009363B1 (ko)

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JP10137287 1987-04-24
JP101372/87 1987-04-24
JP62-101372 1987-04-24

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