KR870011095A - 5위가 황으로 치환된 피리딘 모노카르복시 제초제 - Google Patents

5위가 황으로 치환된 피리딘 모노카르복시 제초제 Download PDF

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KR870011095A
KR870011095A KR870004601A KR870004601A KR870011095A KR 870011095 A KR870011095 A KR 870011095A KR 870004601 A KR870004601 A KR 870004601A KR 870004601 A KR870004601 A KR 870004601A KR 870011095 A KR870011095 A KR 870011095A
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integer
methyl
alkylthio
alkoxy
composition
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KR870004601A
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KR890003836B1 (ko
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글렌 돌슨 마크
렌팡리
레이그 스페어 케리
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아놀드 하베이 콜
몬산토캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/46—Oxygen atoms
    • C07D213/48—Aldehydo radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/80—Acids; Esters in position 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/83—Thioacids; Thioesters; Thioamides; Thioimides

Abstract

내용 없음

Description

5위가 황으로 치환된 피리딘 모노카르복시 제초제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 다음과 같은 구조식으로 표현되는 화합물.
    여기에서 n은 0 내지 2의 정수; X는 할로겐, 하이드록시, 저급알콕시, 저급알켄옥시, 저급알킨옥시, 할로알콕시, 할로알켄옥시와 알킬티오로 구성된 군으로부터 선택된 것이고; R1과 R2는 플루오로화메틸과 클로로플루오르화메틸로부터 간간 선택된 것으로 R1과 R2중 하나는 반드시 플루오르화메틸이어야 하며; R4는 저급알킬, 할로겐, 시클로알킬아릴과 치환된 아릴, 아르알킬시아노, 아미노와 알킬아미노로부터 선택되며; R3는 하이드록시, 알콕시, 알킬티오, 알킬설포닐, 저급알킬, 시클로알킬, 시클로알킬알킬로부터 선택되며; n이 0 또는 2일 경우에 R4는 아릴이 아니어야 하며, R3가 메틸이고 R4가 메틸, 에틸 또는 t-부틸일 경우에는 n은 1 또는 2의 정수가 아니어야 한다.
  2. 제1항에 있어서, R1과 R2중의 하나는 트릴플루오로메틸이고 그 다른 하나는 디플루오로메틸임을 특징으로 하는 화합물.
  3. 제2항에 있어서, X는 알콕시와 알킬티오로부터 선택된 것임을 특징으로 하는 화합물.
  4. 제3항에 있어서, R4는 저급알킬임을 특징으로 하는 화합물.
  5. 제4항에 있어서, R3는 시클로부틸, 2-메틸프로필과 n-프로필로부터 선택된 것임을 특징으로 하는 화합물.
  6. 제5항에 있어서, n은 0임을 특징으로 하는 화합물.
  7. 제5항에 있어서, n은 1인 정수임을 특징으로 하는 화합물.
  8. 제5항에 있어서, n은 2인 정수임을 특징으로 하는 화합물.
  9. 다음과 같은 구조식으로 표현되는 화합물을 활성성분으로 포함함을 특징으로 하는 제초제 조성물.
    여기에서 n은 0 내지 2의 정수; X는 할로겐, 하이드록시, 저급알콕시, 저급알켄옥시, 할로알콕시, 할로알켄옥시와 알킬티오로 구성된 군으로부터 선택된 것이고; R1과 R2는 플루오로화메틸과 클로로플루오르화메틸로부터 각각 선택된 것으로 R1과 R2중 하나는 반드시 플루오르화메틸이어야 하며; R4는 저급알킬, 할로겐, 시클로알킬아릴과 치환된 아릴, 아르알킬, 시아노, 아미노와 알킬아미노로부터 선택되며; R3는 하이드록시, 알콕시, 알킬티오, 알킬설포닐, 저급알킬, 시클로알킬, 시클로알킬알킬로부터 선택되며; n이 0 또는 2일 경우에 R4는 아릴이 아니어야 하며, R3가 메틸이고 R4가 메틸, 에틸 또는 t-부틸일 경우에는 n은 1 또는 2의 정수가 아니어야 한다.
  10. 제9항에 있어서, R1과 R2중 하나는 트리플루오로메틸이고 그 다른 하나는 디플루오로메틸임을 특징으로 하는 조성물.
  11. 제10항에 있어서, X는 알콕시와 알킬티오로부터 선택된 것임을 특징으로 하는 조성물.
  12. 제11항에 있어서, R4는 저급알킬임을 특징으로 하는 조성물.
  13. 제12항에 있어서, R3는 시클로부틸, 2-메틸프로필과 n-프로필로부터 선택된 것임을 특징으로 하는 조성물.
  14. 제13항에 있어서, n은 0임을 특징으로 하는 조성물.
  15. 제13항에 있어서, n은 1인 정수임을 특징으로 하는 조성물.
  16. 제13항에 있어서, n은 2인 정수임을 특징으로 하는 조성물.
  17. 다음과 같은 구조식으로 표현되는 화합물의 유효량을 식물이 있는 장소에 사용함을 특징으로 하는 바람직하지 않은 식물체를 제어하는 방법.
    여기에서 n은 0 내지 2의 정수; X는 할로겐, 하이드록시, 저급알콕시, 저급알켄옥시, 저급알킨옥시, 할로알콕시, 할로알켄옥시와 알킬티오로 구성된 군으로부터 선택된 것이고; R1과 R2는 플루오로화메틸과 클로로플루오르화메틸로부터 각각 선택된 것으로 R1과 R2중 하나는 반드시 플루오르화메틸이어야 하며; R4는 저급알킬, 할로겐, 시클로알킬아릴과 치환된 아릴, 아르알킬, 시아노, 아미노와 알킬아미노로부터 선택되며; R3는 하이드록시, 알콕시, 알킬티오, 알킬설포닐, 저급알킬, 시클로알킬, 시클로알킬알킬로부터 선택되며; n이 0 또는 2일 경우에 R4는 아릴이 아니어야 하며, R3가 메틸이고 R4가 메틸, 에틸 또는 t-부틸일 경우에는 n은 1 또는 2의 정수가 아니어야 한다.
  18. 제17항에 있어서, R1과 R2중 하나는 트리플루오로메틸이고 그 다른 하나는 디플루오로메틸임을 특징으로 하는 방법.
  19. 제18항에 있어서, X는 알콕시와 알킬티오로부터 선택된 것임을 특징으로 하는 방법.
  20. 제19항에 있어서, R4는 저급알킬임을 특징으로 하는 방법.
  21. 제19항에 있어서, R3는 시클로부틸, 2-메틸프로필과 n-프로필로부터 선택된 것임을 특징으로 하는 방법.
  22. 제21항에 있어서, n은 0임을 특징으로 하는 방법.
  23. 제21항에 있어서, n은 1인 정수임을 특징으로 하는 방법.
  24. 제21항에 있어서, n은 2인 정수임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870004601A 1986-05-12 1987-05-11 5위가 황으로 치환된 피리딘 모노카르복시 제초제 KR890003836B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/862,340 US4789395A (en) 1986-05-12 1986-05-12 5-sulfur substituted pyridine monocarboxylic herbicides
US862.340 1986-05-12
US862340 1986-05-12

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KR870011095A true KR870011095A (ko) 1987-12-19
KR890003836B1 KR890003836B1 (ko) 1989-10-05

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US (1) US4789395A (ko)
EP (1) EP0258201A1 (ko)
JP (1) JPS62273955A (ko)
KR (1) KR890003836B1 (ko)
CN (1) CN87103523A (ko)
AU (1) AU590708B2 (ko)
HU (1) HUT44126A (ko)
IL (1) IL82487A0 (ko)
ZA (1) ZA873348B (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4936905A (en) * 1986-05-09 1990-06-26 Monsanto Company Substituted 2,6-substituted pyridine compounds having herbicidal activity
US4885026A (en) * 1986-05-12 1989-12-05 Monsanto Company Certain 3-amino-5-carboxy (or thio carboxy) pyridine herbicides
US5019153A (en) * 1986-05-12 1991-05-28 Monsanto Company Substituted pyridine herbicides
US5196045A (en) * 1986-05-12 1993-03-23 Monsanto Company Substituted pyridine herbicides
US5228897A (en) * 1991-02-25 1993-07-20 Monsanto Company Substituted pyridine compounds
US5125956A (en) * 1991-02-25 1992-06-30 Monsanto Company Substituted pyridine compounds
AU3285499A (en) 1998-02-13 1999-08-30 G.D. Searle & Co. Substituted pyridines useful for inhibiting cholesteryl ester transfer protein activity
CN101289422B (zh) * 2008-06-06 2011-11-30 华中师范大学 具有杀菌、除草活性的2,3,5,6-四取代-4-氨基吡啶及制备

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3534056A (en) * 1967-03-02 1970-10-13 Pennwalt Corp Fluoro-alkyl pyridines and their preparation
US3748334A (en) * 1972-04-12 1973-07-24 Dow Chemical Co 2,6-bis(trifluoromethyl)-4-pyridinols
ES8506627A1 (es) * 1983-08-11 1985-08-01 Monsanto Co Un procedimiento para preparar derivados de piridina sustituidos en las posiciones 2 y 6
US4698093A (en) * 1984-11-06 1987-10-06 Monsanto Company Herbicidal (2 or 6)-fluoroalkyl-4-amino pyridine derivatives
US4609399A (en) * 1984-11-06 1986-09-02 Monsanto Company Substituted 4,6-alkoxy pyridinecarboxylate compounds and herbicidal use
US4655816A (en) * 1984-11-06 1987-04-07 Monsanto Company Herbicidal 2-trifluoromethyl 3-pyridine carboxylic acid derivatives

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HUT44126A (en) 1988-02-29
EP0258201A1 (en) 1988-03-02
AU7268587A (en) 1987-11-19
ZA873348B (en) 1987-11-30
CN87103523A (zh) 1987-12-09
KR890003836B1 (ko) 1989-10-05
JPS62273955A (ja) 1987-11-28
IL82487A0 (en) 1987-11-30
AU590708B2 (en) 1989-11-09
US4789395A (en) 1988-12-06

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