KR102286107B1 - 감광성 수지 조성물 - Google Patents
감광성 수지 조성물 Download PDFInfo
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- KR102286107B1 KR102286107B1 KR1020197012465A KR20197012465A KR102286107B1 KR 102286107 B1 KR102286107 B1 KR 102286107B1 KR 1020197012465 A KR1020197012465 A KR 1020197012465A KR 20197012465 A KR20197012465 A KR 20197012465A KR 102286107 B1 KR102286107 B1 KR 102286107B1
- Authority
- KR
- South Korea
- Prior art keywords
- photosensitive resin
- compound
- resin composition
- ethylenically unsaturated
- unsaturated bond
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 132
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- 238000011161 development Methods 0.000 claims abstract description 27
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 29
- 125000002947 alkylene group Chemical group 0.000 claims description 28
- 230000018109 developmental process Effects 0.000 claims description 26
- 125000003118 aryl group Chemical group 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 24
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical group OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 21
- 239000004020 conductor Substances 0.000 claims description 18
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- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 14
- 238000007747 plating Methods 0.000 claims description 14
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- 239000002253 acid Substances 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
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- 239000011241 protective layer Substances 0.000 description 11
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 9
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- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
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- 238000005227 gel permeation chromatography Methods 0.000 description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 4
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- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Chemical compound C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 2
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- KFJDQPJLANOOOB-UHFFFAOYSA-N 2h-benzotriazole-4-carboxylic acid Chemical class OC(=O)C1=CC=CC2=NNN=C12 KFJDQPJLANOOOB-UHFFFAOYSA-N 0.000 description 2
- GUOVBFFLXKJFEE-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid Chemical compound C1=C(C(=O)O)C=CC2=NNN=C21 GUOVBFFLXKJFEE-UHFFFAOYSA-N 0.000 description 2
- IRQWEODKXLDORP-UHFFFAOYSA-N 4-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=C)C=C1 IRQWEODKXLDORP-UHFFFAOYSA-N 0.000 description 2
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- 125000003884 phenylalkyl group Chemical group 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
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- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
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- XOHZHMUQBFJTNH-UHFFFAOYSA-N 1-methyl-2h-tetrazole-5-thione Chemical compound CN1N=NN=C1S XOHZHMUQBFJTNH-UHFFFAOYSA-N 0.000 description 1
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- JFWOLMRNYJBCCJ-UHFFFAOYSA-N 2,4-bis(2-chlorophenyl)-2-[2-(2-chlorophenyl)-4,5-diphenylimidazol-2-yl]-5-(3,4-dimethoxyphenyl)imidazole Chemical compound C1=C(OC)C(OC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC=CC=2)C=2C=CC=CC=2)C=2C(=CC=CC=2)Cl)(C=2C(=CC=CC=2)Cl)N=C1C1=CC=CC=C1Cl JFWOLMRNYJBCCJ-UHFFFAOYSA-N 0.000 description 1
- RKFITYIZOSRLCV-UHFFFAOYSA-N 2-(2,4-difluorophenyl)-2-[2-(2,4-difluorophenyl)-4,5-bis(3-methoxyphenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)imidazole Chemical compound COC1=CC=CC(C=2C(=NC(N=2)(C=2C(=CC(F)=CC=2)F)C2(N=C(C(=N2)C=2C=C(OC)C=CC=2)C=2C=C(OC)C=CC=2)C=2C(=CC(F)=CC=2)F)C=2C=C(OC)C=CC=2)=C1 RKFITYIZOSRLCV-UHFFFAOYSA-N 0.000 description 1
- JCYHWKVBYDDNKD-UHFFFAOYSA-N 2-(2,5-difluorophenyl)-2-[2-(2,5-difluorophenyl)-4,5-bis(3-methoxyphenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)imidazole Chemical compound COC1=CC=CC(C=2C(=NC(N=2)(C=2C(=CC=C(F)C=2)F)C2(N=C(C(=N2)C=2C=C(OC)C=CC=2)C=2C=C(OC)C=CC=2)C=2C(=CC=C(F)C=2)F)C=2C=C(OC)C=CC=2)=C1 JCYHWKVBYDDNKD-UHFFFAOYSA-N 0.000 description 1
- LVXWJQRVXVFARN-UHFFFAOYSA-N 2-(2,6-difluorophenyl)-2-[2-(2,6-difluorophenyl)-4,5-bis(3-methoxyphenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)imidazole Chemical compound COC1=CC=CC(C=2C(=NC(N=2)(C=2C(=CC=CC=2F)F)C2(N=C(C(=N2)C=2C=C(OC)C=CC=2)C=2C=C(OC)C=CC=2)C=2C(=CC=CC=2F)F)C=2C=C(OC)C=CC=2)=C1 LVXWJQRVXVFARN-UHFFFAOYSA-N 0.000 description 1
- NSWNXQGJAPQOID-UHFFFAOYSA-N 2-(2-chlorophenyl)-4,5-diphenyl-1h-imidazole Chemical class ClC1=CC=CC=C1C1=NC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)N1 NSWNXQGJAPQOID-UHFFFAOYSA-N 0.000 description 1
- TVIPVNDJQQUGOQ-UHFFFAOYSA-N 2-(2-fluorophenyl)-2-[2-(2-fluorophenyl)-4,5-bis(3-methoxyphenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)imidazole Chemical compound COC1=CC=CC(C=2C(=NC(N=2)(C=2C(=CC=CC=2)F)C2(N=C(C(=N2)C=2C=C(OC)C=CC=2)C=2C=C(OC)C=CC=2)C=2C(=CC=CC=2)F)C=2C=C(OC)C=CC=2)=C1 TVIPVNDJQQUGOQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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- JQMPYPZEZKHJTJ-UHFFFAOYSA-N 2-[2,3-bis(fluoromethyl)phenyl]-2-[2-[2,3-bis(fluoromethyl)phenyl]-4,5-bis(3-methoxyphenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)imidazole Chemical compound FCC1=C(C=CC=C1CF)C1(N=C(C(=N1)C1=CC(=CC=C1)OC)C1=CC(=CC=C1)OC)C1(N=C(C(=N1)C1=CC(=CC=C1)OC)C1=CC(=CC=C1)OC)C1=C(C(=CC=C1)CF)CF JQMPYPZEZKHJTJ-UHFFFAOYSA-N 0.000 description 1
- XOLNSMTWLSOUQY-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]-1-(4-nonylphenoxy)ethanol;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCCCCCCC1=CC=C(OC(O)COCCOCCOCCOCCOCCOCCOCCO)C=C1 XOLNSMTWLSOUQY-UHFFFAOYSA-N 0.000 description 1
- AIYITDGPHANYCA-UHFFFAOYSA-N 2-[4,5-bis(3-methoxyphenyl)-2-(2,3,4,5,6-pentafluorophenyl)imidazol-2-yl]-4,5-bis(3-methoxyphenyl)-2-(2,3,4,5,6-pentafluorophenyl)imidazole Chemical compound COC1=CC=CC(C=2C(=NC(N=2)(C=2C(=C(F)C(F)=C(F)C=2F)F)C2(N=C(C(=N2)C=2C=C(OC)C=CC=2)C=2C=C(OC)C=CC=2)C=2C(=C(F)C(F)=C(F)C=2F)F)C=2C=C(OC)C=CC=2)=C1 AIYITDGPHANYCA-UHFFFAOYSA-N 0.000 description 1
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- 238000005498 polishing Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
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- 239000004926 polymethyl methacrylate Substances 0.000 description 1
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- 239000004800 polyvinyl chloride Substances 0.000 description 1
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- 238000003918 potentiometric titration Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
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- 230000001681 protective effect Effects 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
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- 229910010271 silicon carbide Inorganic materials 0.000 description 1
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- 238000005507 spraying Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- DWWMSEANWMWMCB-UHFFFAOYSA-N tribromomethylsulfonylbenzene Chemical compound BrC(Br)(Br)S(=O)(=O)C1=CC=CC=C1 DWWMSEANWMWMCB-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
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- 229920002554 vinyl polymer Polymers 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
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- G—PHYSICS
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- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
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- G—PHYSICS
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
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- G—PHYSICS
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/40—Treatment after imagewise removal, e.g. baking
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/42—Stripping or agents therefor
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/18—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials For Photolithography (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (6)
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JPJP-P-2015-079381 | 2015-04-08 | ||
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JPJP-P-2015-166570 | 2015-08-26 | ||
JP2015166570 | 2015-08-26 | ||
KR1020177020557A KR101990230B1 (ko) | 2015-04-08 | 2016-04-08 | 감광성 수지 조성물 |
PCT/JP2016/061610 WO2016163540A1 (ja) | 2015-04-08 | 2016-04-08 | 感光性樹脂組成物 |
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KR1020197012465A KR102286107B1 (ko) | 2015-04-08 | 2016-04-08 | 감광성 수지 조성물 |
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KR (2) | KR101990230B1 (ja) |
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MY (1) | MY187481A (ja) |
TW (3) | TWI620017B (ja) |
WO (1) | WO2016163540A1 (ja) |
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TWI666518B (zh) * | 2016-12-30 | 2019-07-21 | 奇美實業股份有限公司 | 感光性樹脂組成物及其應用 |
JP6981864B2 (ja) * | 2017-01-30 | 2021-12-17 | 旭化成株式会社 | 感光性樹脂組成物、感光性樹脂積層体、レジストパターンが形成された基板および回路基板の製造方法 |
WO2018159629A1 (ja) * | 2017-03-01 | 2018-09-07 | 旭化成株式会社 | 感光性樹脂組成物 |
JP6783381B2 (ja) * | 2017-03-29 | 2020-11-11 | 旭化成株式会社 | 感光性樹脂組成物 |
CN109976092B (zh) * | 2017-12-27 | 2022-04-01 | 太阳油墨(苏州)有限公司 | 固化性树脂组合物、干膜、固化物、及印刷电路板 |
WO2019244898A1 (ja) * | 2018-06-22 | 2019-12-26 | 旭化成株式会社 | 感光性樹脂組成物およびレジストパターンの形成方法 |
CN118778362A (zh) * | 2018-06-22 | 2024-10-15 | 旭化成株式会社 | 感光性树脂组合物和抗蚀图案的形成方法 |
CN112400139B (zh) * | 2018-07-11 | 2024-04-23 | 富士胶片株式会社 | 药液、药液收容体 |
JP7422664B2 (ja) * | 2018-08-09 | 2024-01-26 | 旭化成株式会社 | 感光性樹脂組成物及びレジストパターンの形成方法 |
JP7300619B2 (ja) * | 2019-01-11 | 2023-06-30 | 太陽ホールディングス株式会社 | 積層構造体、ドライフィルム、その硬化物および電子部品 |
WO2021054457A1 (ja) * | 2019-09-19 | 2021-03-25 | クラレノリタケデンタル株式会社 | 歯科用硬化性組成物 |
US20230041025A1 (en) * | 2019-10-08 | 2023-02-09 | Tokyo Ohka Kogyo Co., Ltd. | Negative-working photosensitive resin composition, photosensitive resist film, pattern formation method, cured film, cured film production method, and rolled body |
US20220390843A1 (en) * | 2019-11-11 | 2022-12-08 | Asahi Kasei Kabushiki Kaisha | Photosensitive resin composition and photosensitive resin multilayer body |
CN116209571A (zh) * | 2020-08-07 | 2023-06-02 | 株式会社力森诺科 | 感光性树脂组合物、感光性元件、抗蚀剂图案的形成方法及印刷线路板的制造方法 |
JPWO2022181485A1 (ja) * | 2021-02-26 | 2022-09-01 | ||
WO2022181764A1 (ja) * | 2021-02-26 | 2022-09-01 | 太陽インキ製造株式会社 | 積層構造体およびフレキシブルプリント配線板 |
KR20240031514A (ko) * | 2022-08-30 | 2024-03-08 | 삼성에스디아이 주식회사 | 감광성 수지 조성물, 이를 이용하여 제조된 감광성 수지막 및 컬러 필터 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013156369A (ja) * | 2012-01-27 | 2013-08-15 | Asahi Kasei E-Materials Corp | 感光性樹脂組成物 |
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JP3619852B2 (ja) * | 1999-06-08 | 2005-02-16 | ニチゴー・モートン株式会社 | 感光性樹脂組成物及びこれを用いたドライフィルムレジスト |
CN1273867C (zh) * | 2001-11-12 | 2006-09-06 | 旭化成电子材料元件株式会社 | 感光性树脂组合物及其用途 |
US20070269738A1 (en) * | 2004-07-30 | 2007-11-22 | Hitachi Chemical Company, Ltd. | Photosensitive Film, Photosensitive Film Laminate and Photosensitive Film Roll |
JP4535851B2 (ja) * | 2004-11-19 | 2010-09-01 | 旭化成イーマテリアルズ株式会社 | 光重合性樹脂組成物 |
JP4646759B2 (ja) | 2005-09-20 | 2011-03-09 | 旭化成イーマテリアルズ株式会社 | パターン形成材料、並びにパターン形成装置及びパターン形成方法 |
JP2007133349A (ja) * | 2005-10-14 | 2007-05-31 | Hitachi Chem Co Ltd | 感光性フィルムロール |
JP4936848B2 (ja) * | 2006-10-16 | 2012-05-23 | 旭化成イーマテリアルズ株式会社 | 感光性樹脂組成物およびその積層体 |
CN102707571A (zh) * | 2006-12-19 | 2012-10-03 | 日立化成工业株式会社 | 感光性元件 |
JP2008202022A (ja) * | 2007-01-23 | 2008-09-04 | Fujifilm Corp | 光ナノインプリントリソグラフィ用硬化性組成物およびそれを用いたパターン形成方法 |
KR20090122343A (ko) * | 2007-06-18 | 2009-11-27 | 아사히 가세이 이-매터리얼즈 가부시키가이샤 | 감광성 수지 조성물, 플렉소 인쇄판 및 플렉소 인쇄판의 제조 방법 |
KR101175079B1 (ko) * | 2007-12-18 | 2012-08-21 | 아사히 가세이 이-매터리얼즈 가부시키가이샤 | 네거티브형 감광성 수지 적층체를 사용한 레지스트 경화물의 제조 방법, 네거티브형 감광성 수지 적층체, 및 네거티브형 감광성 수지 적층체의 사용 방법 |
TWI536094B (zh) * | 2007-12-25 | 2016-06-01 | Asahi Kasei Emd Corp | Photosensitive resin laminate |
JP5396833B2 (ja) * | 2008-11-28 | 2014-01-22 | Jsr株式会社 | 感放射線性樹脂組成物、液晶表示素子のスペーサーおよび保護膜ならびにそれらの形成方法 |
CN104111585A (zh) * | 2009-07-29 | 2014-10-22 | 旭化成电子材料株式会社 | 感光性树脂组合物、感光性树脂层压体和抗蚀图案形成方法 |
TWI413859B (zh) * | 2009-09-25 | 2013-11-01 | Asahi Kasei E Materials Corp | A photosensitive resin composition for a resist material, and a photosensitive resin laminate |
JP5526868B2 (ja) * | 2010-03-03 | 2014-06-18 | Jsr株式会社 | 感放射線性樹脂組成物、表示素子のスペーサーおよび保護膜ならびにそれらの形成方法 |
JP5570275B2 (ja) * | 2010-03-31 | 2014-08-13 | 旭化成イーマテリアルズ株式会社 | ドライフィルムレジストロール |
KR20120002864A (ko) * | 2010-07-01 | 2012-01-09 | 동우 화인켐 주식회사 | 흑색 감광성 수지 조성물, 컬러 필터 및 이를 구비한 액정 표시 장치 |
CN102331684A (zh) * | 2010-07-13 | 2012-01-25 | 日立化成工业株式会社 | 感光性元件、抗蚀图案的形成方法、印刷电路布线板的制造方法及印刷电路布线板 |
JP6022749B2 (ja) * | 2010-07-30 | 2016-11-09 | 日立化成株式会社 | 感光性樹脂組成物、感光性エレメント、レジストパターンの製造方法、リードフレームの製造方法及びプリント配線板の製造方法 |
JP5771944B2 (ja) * | 2010-10-18 | 2015-09-02 | Jsr株式会社 | カラーフィルタの製造方法 |
KR20130098406A (ko) * | 2010-12-24 | 2013-09-04 | 아사히 가세이 이-매터리얼즈 가부시키가이샤 | 감광성 수지 조성물 |
JP5835014B2 (ja) * | 2011-03-31 | 2015-12-24 | Jsr株式会社 | 画素パターンの形成方法及びカラーフィルタの製造方法 |
KR20130047656A (ko) * | 2011-10-31 | 2013-05-08 | 히타치가세이가부시끼가이샤 | 감광성 수지 조성물, 감광성 엘리먼트, 레지스트 패턴의 형성 방법 및 인쇄 배선판의 제조 방법 |
JP6229256B2 (ja) | 2011-10-31 | 2017-11-15 | 日立化成株式会社 | 感光性エレメント、レジストパターンの形成方法及びプリント配線板の製造方法 |
JP2013195681A (ja) * | 2012-03-19 | 2013-09-30 | Mitsubishi Chemicals Corp | 感光性樹脂組成物、カラーフィルタ、液晶表示装置、及び有機elディスプレイ |
JP5853806B2 (ja) * | 2012-03-23 | 2016-02-09 | Jsr株式会社 | 感放射線性樹脂組成物、硬化膜及び硬化膜の形成方法 |
JP6019791B2 (ja) * | 2012-06-19 | 2016-11-02 | 日立化成株式会社 | 隔壁形成材料、これを用いた感光性エレメント、隔壁の形成方法及び画像表示装置の製造方法 |
JP5826135B2 (ja) * | 2012-08-23 | 2015-12-02 | 富士フイルム株式会社 | 着色感放射線性組成物、これを用いたカラーフィルタ |
JP6063200B2 (ja) | 2012-10-15 | 2017-01-18 | 旭化成株式会社 | 感光性樹脂組成物 |
JP6135314B2 (ja) * | 2012-12-26 | 2017-05-31 | Jsr株式会社 | 着色組成物、カラーフィルタ及び表示素子 |
JP6120560B2 (ja) * | 2012-12-26 | 2017-04-26 | 第一工業製薬株式会社 | カラーフィルター、ブラックマトリックス、又は回路形成用の硬化性樹脂組成物 |
JP6257164B2 (ja) | 2013-03-28 | 2018-01-10 | 旭化成株式会社 | レジストパターンの形成方法 |
WO2014192716A1 (ja) * | 2013-05-27 | 2014-12-04 | 富士フイルム株式会社 | カラーフィルタの製造方法、下地層形成用組成物、有機el表示装置 |
KR102394595B1 (ko) | 2013-07-23 | 2022-05-04 | 쇼와덴코머티리얼즈가부시끼가이샤 | 투영 노광용 감광성 수지 조성물, 감광성 엘리먼트, 레지스트 패턴의 형성 방법, 프린트 배선판의 제조 방법 및 리드 프레임의 제조 방법 |
TWI623814B (zh) * | 2014-05-21 | 2018-05-11 | Asahi Kasei E Mat Corporation | 感光性樹脂組合物及電路圖案之形成方法 |
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