KR100766755B1 - 반도체 소자에서의 투명 비결정질 탄소 구조체 - Google Patents
반도체 소자에서의 투명 비결정질 탄소 구조체 Download PDFInfo
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- KR100766755B1 KR100766755B1 KR1020067005057A KR20067005057A KR100766755B1 KR 100766755 B1 KR100766755 B1 KR 100766755B1 KR 1020067005057 A KR1020067005057 A KR 1020067005057A KR 20067005057 A KR20067005057 A KR 20067005057A KR 100766755 B1 KR100766755 B1 KR 100766755B1
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- 229910003481 amorphous carbon Inorganic materials 0.000 title claims abstract description 166
- 239000004065 semiconductor Substances 0.000 title claims abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 94
- 238000010521 absorption reaction Methods 0.000 claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 230000000873 masking effect Effects 0.000 claims description 31
- 229920002120 photoresistant polymer Polymers 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 26
- 239000007789 gas Substances 0.000 claims description 17
- 238000000059 patterning Methods 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 8
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 7
- 230000003667 anti-reflective effect Effects 0.000 claims description 6
- 239000001307 helium Substances 0.000 claims description 6
- 229910052734 helium Inorganic materials 0.000 claims description 6
- PBZHKWVYRQRZQC-UHFFFAOYSA-N [Si+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound [Si+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PBZHKWVYRQRZQC-UHFFFAOYSA-N 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 5
- 230000005670 electromagnetic radiation Effects 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 239000000615 nonconductor Substances 0.000 claims 1
- 238000005530 etching Methods 0.000 abstract description 13
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000003990 capacitor Substances 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 10
- 238000000151 deposition Methods 0.000 description 9
- 230000008021 deposition Effects 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 4
- 239000005368 silicate glass Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000012811 non-conductive material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000001360 synchronised effect Effects 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 102100035964 Gastrokine-2 Human genes 0.000 description 1
- 101001075215 Homo sapiens Gastrokine-2 Proteins 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GDFCWFBWQUEQIJ-UHFFFAOYSA-N [B].[P] Chemical compound [B].[P] GDFCWFBWQUEQIJ-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000005380 borophosphosilicate glass Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- -1 titanium silicide Chemical compound 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 description 1
- 229910021342 tungsten silicide Inorganic materials 0.000 description 1
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Abstract
Description
Claims (112)
- 하나 이상의 정렬 마크를 포함하는 기판;상기 기판 위에 형성되는 소자 구조체; 및상기 소자 구조체 위에 형성되며, 가시광선 영역에서 상기 정렬 마크의 판독을 허용하기 위해, 상기 가시광선 영역에서 투명한 비결정질 탄소층을 포함하는 마스킹 구조체를 포함하는, 반도체 소자.
- 제 1 항에 있어서,상기 비결정질 탄소층은 633 나노미터의 파장에서 약 0.15 와 약 0.001 사이의 흡수 계수를 갖는, 반도체 소자.
- 제 1 항에 있어서,상기 가시광선 영역은 400 나노미터와 700 나노미터 사이의 파장을 갖는 전자기 복사를 포함하는, 반도체 소자.
- 제 1 항에 있어서,상기 비결정질 탄소층은 4000 옹스트롬보다 큰 두께를 갖는, 반도체 소자.
- 제 4 항에 있어서,상기 소자 구조체는 40000 옹스트롬보다 큰 두께를 갖는, 반도체 소자.
- 제 1 항에 있어서,상기 마스킹 구조체는 상기 비결정질 탄소층 위에 형성되는 실리콘 질산화물 층을 더 포함하는, 반도체 소자.
- 제 1 항에 있어서,상기 마스킹 구조체는 포토레지스트 층을 더 포함하는, 반도체 소자.
- 제 7 항에 있어서,상기 마스킹 구조체는 무반사성 층을 더 포함하는, 반도체 소자.
- 제 7 항에 있어서,상기 포토레지스트 층은 적어도 하나의 개구부를 포함하는, 반도체 소자.
- 제 9 항에 있어서,상기 비결정질 탄소층은 상기 포토레지스트 층의 적어도 하나의 개구부와 연속되는 적어도 하나의 개구부를 포함하는, 반도체 소자.
- 제 1 항에 있어서,상기 소자 구조체는 도체 재료, 부도체 재료, 및 반도체 재료로 구성되는 그룹의 재료로부터 선택되는 층을 포함하는, 반도체 소자.
- 제 11 항에 있어서,상기 소자 구조체는 비결정 탄소층을 더 포함하며,상기 소자 구조체의 상기 비결정질 탄소층은 가시광선 영역에서 투명한, 반도체 소자.
- 제 1 항에 있어서,상기 기판은 복수의 도핑된 영역을 포함하고,상기 소자 구조체는 복수의 게이트 구조체, 복수의 컨택트, 및 상기 게이트와 컨택트 위에 형성되는 절연층을 포함하며,상기 컨택트의 각각은 2 개의 게이트 구조체 사이에 위치 되고 상기 도핑된 영역 중 하나에 접촉하는, 반도체 소자.
- 기판 위에 소자 구조체를 형성하는 단계; 및비결정질 탄소층의 형성을 포함하는, 상기 기판 위에 마스킹 구조체를 형성하는 단계를 포함하고,상기 기판은 하나 이상의 정렬 마크를 포함하며,가시광선 영역에서 상기 정렬 마크의 판독을 허용하기 위해, 상기 비결정질 탄소층은 가시광선 영역에서 투명한, 방법.
- 제 14 항에 있어서,상기 비결정질 탄소층은 형성하는 단계는,적어도 4000 옹스트롬의 두께를 갖는 상기 비결정질 탄소층의 형성을 포함하는, 방법.
- 제 15 항에 있어서,상기 소자 구조체를 형성하는 단계는,적어도 40000 옹스트롬의 두께를 갖는 상기 소자 구조체의 형성을 포함하는, 방법.
- 제 14 항에 있어서,상기 마스킹 구조체를 형성하는 단계는,상기 비결정질 탄소층 위에 실리콘 질산화물 층을 형성하는 단계를 더 포함하는, 방법.
- 제 17 항에 있어서,상기 실리콘 질산화물 층은 상기 비결정질 탄소층과 함께 인-시추 (in situ) 증착되는, 방법.
- 제 14 항에 있어서,상기 비결정질 탄소층을 형성하는 단계는,패터닝된 비결정질 탄소층을 형성하도록 비결정질 탄소층을 패터닝하는 단계를 포함하는, 방법.
- 제 19 항에 있어서,상기 소자 구조체를 형성하는 단계는,상기 패터닝된 비결정질 탄소층을 마스크로 사용하여 상기 소자 구조체를 패터닝하는 단계를 포함하는, 방법.
- 제 14 항에 있어서,상기 마스킹 구조체를 형성하는 단계는,패터닝된 포토레지스트 층을 형성하는 단계를 더 포함하는, 방법.
- 제 21 항에 있어서,상기 마스킹 구조체를 형성하는 단계는,상기 패터닝된 포토레지스트 층을 마스크로 사용하여 패터닝된 비결정질 탄소층을 제공하기 위하여, 상기 비결정질 탄소층을 패터닝하는 단계를 더 포함하는, 방법.
- 제 22 항에 있어서,상기 소자 구조체를 형성하는 단계는,상기 패터닝된 비결정질 탄소층을 마스크로 사용하여 상기 소자 구조체를 패터닝하는 단계를 포함하는, 방법.
- 제 14 항에 있어서,상기 비결정질 탄소층은 633 나노미터의 파장에서 약 0.15 와 약 0.001 사이의 흡수 계수를 갖는, 방법.
- 제 24 항에 있어서,상기 비결정질 탄소층은 약 200 ℃ 내지 약 500 ℃ 의 온도 범위에서 형성되는, 방법.
- 제 14 항에 있어서,상기 가시광선 영역은,400 나노미터와 700 나노미터 사이의 파장을 갖는 전자기 복사를 포함하는, 방법.
- 제 14 항에 있어서,상기 비결정질 탄소층을 형성하는 단계는,약 200 ℃ 로부터 약 300 ℃ 이하까지의 온도에서 상기 비결정질 탄소층을 형성하는 단계를 포함하는, 방법.
- 제 27 항에 있어서,상기 비결정질 탄소층을 형성하는 단계는,약 4 토르 내지 약 6.5 토르 범위의 압력, 약 450 와트 내지 약 1000 와트 범위의 무선 주파수 전력 범위, 및 프로필렌을 포함하는 혼합 기체 조건 하의 챔버에서 수행되는, 방법.
- 제 28 항에 있어서,상기 혼합 기체는 헬륨을 더 포함하는, 방법.
- 제 29 항에 있어서,상기 프로필렌은 분당 500 표준 세제곱 센티미터 (sccm) 와 3000 sccm 사이의 유량으로 챔버로 주입되는, 방법.
- 제 30 항에 있어서,상기 헬륨은 250 sccm 과 1000 sccm 사이의 유량으로 챔버로 주입되는, 방법.
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US10/661,379 | 2003-09-12 |
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CN1879201A (zh) | 2006-12-13 |
US20050056835A1 (en) | 2005-03-17 |
JP2007505497A (ja) | 2007-03-08 |
TWI262551B (en) | 2006-09-21 |
KR20060057010A (ko) | 2006-05-25 |
US20060022247A1 (en) | 2006-02-02 |
CN100530561C (zh) | 2009-08-19 |
US7298024B2 (en) | 2007-11-20 |
US20060003237A1 (en) | 2006-01-05 |
WO2005034229A1 (en) | 2005-04-14 |
US20050059262A1 (en) | 2005-03-17 |
US20060244086A1 (en) | 2006-11-02 |
US20060008741A1 (en) | 2006-01-12 |
TW200518209A (en) | 2005-06-01 |
US7220683B2 (en) | 2007-05-22 |
US7132201B2 (en) | 2006-11-07 |
EP1668684A1 (en) | 2006-06-14 |
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