JPWO2019104543A5 - - Google Patents
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- JPWO2019104543A5 JPWO2019104543A5 JP2020529328A JP2020529328A JPWO2019104543A5 JP WO2019104543 A5 JPWO2019104543 A5 JP WO2019104543A5 JP 2020529328 A JP2020529328 A JP 2020529328A JP 2020529328 A JP2020529328 A JP 2020529328A JP WO2019104543 A5 JPWO2019104543 A5 JP WO2019104543A5
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- molecular sieve
- type molecular
- modified
- dealuminum
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- 239000002808 molecular sieve Substances 0.000 claims description 253
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 88
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 76
- 238000006243 chemical reaction Methods 0.000 claims description 70
- 239000003054 catalyst Substances 0.000 claims description 66
- 239000002253 acid Substances 0.000 claims description 55
- 239000011734 sodium Substances 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 43
- 238000004566 IR spectroscopy Methods 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 32
- ADSOSINJPNKUJK-UHFFFAOYSA-N 2-butylpyridine Chemical compound CCCCC1=CC=CC=N1 ADSOSINJPNKUJK-UHFFFAOYSA-N 0.000 claims description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 29
- 238000000354 decomposition reaction Methods 0.000 claims description 29
- 239000000969 carrier Substances 0.000 claims description 28
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims description 25
- 229910052708 sodium Inorganic materials 0.000 claims description 25
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 24
- 238000005342 ion exchange Methods 0.000 claims description 23
- 239000011148 porous material Substances 0.000 claims description 21
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 21
- 150000003863 ammonium salts Chemical class 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 229910001415 sodium ion Inorganic materials 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000012266 salt solution Substances 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 238000005984 hydrogenation reaction Methods 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 11
- -1 benzyl quaternary ammonium salt Chemical class 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229940104869 Fluorosilicate Drugs 0.000 claims description 9
- OHORFAFFMDIQRR-UHFFFAOYSA-N hexafluorosilicate(2-) Chemical compound F[Si-2](F)(F)(F)(F)F OHORFAFFMDIQRR-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 238000006011 modification reaction Methods 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 8
- FKNQFGJONOIPTF-UHFFFAOYSA-N sodium cation Chemical group [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 7
- DVARTQFDIMZBAA-UHFFFAOYSA-O Ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- ITHIMUMYFVCXSL-UHFFFAOYSA-P Ammonium fluorosilicate Chemical compound [NH4+].[NH4+].F[Si-2](F)(F)(F)(F)F ITHIMUMYFVCXSL-UHFFFAOYSA-P 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- UDYGXWPMSJPFDG-UHFFFAOYSA-M benzyl(tributyl)azanium;bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1 UDYGXWPMSJPFDG-UHFFFAOYSA-M 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000005712 crystallization Effects 0.000 claims description 4
- KLGZELKXQMTEMM-UHFFFAOYSA-N hydride Chemical compound [H-] KLGZELKXQMTEMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052987 metal hydride Inorganic materials 0.000 claims description 4
- 150000004681 metal hydrides Chemical class 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000011959 amorphous silica alumina Substances 0.000 claims description 3
- VJGNLOIQCWLBJR-UHFFFAOYSA-M benzyl(tributyl)azanium;chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1 VJGNLOIQCWLBJR-UHFFFAOYSA-M 0.000 claims description 3
- OSPKGDDLQQVQSG-UHFFFAOYSA-M benzyl(tripropyl)azanium;bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CC1=CC=CC=C1 OSPKGDDLQQVQSG-UHFFFAOYSA-M 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- QDHHCQZDFGDHMP-UHFFFAOYSA-N monochloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- 239000005695 Ammonium acetate Substances 0.000 claims description 2
- VBIXEXWLHSRNKB-UHFFFAOYSA-N Ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 2
- 229940043376 ammonium acetate Drugs 0.000 claims description 2
- 235000019257 ammonium acetate Nutrition 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- YTRIOKYQEVFKGU-UHFFFAOYSA-M benzyl(tripropyl)azanium;chloride Chemical compound [Cl-].CCC[N+](CCC)(CCC)CC1=CC=CC=C1 YTRIOKYQEVFKGU-UHFFFAOYSA-M 0.000 claims description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- 230000002378 acidificating Effects 0.000 description 45
- 239000000047 product Substances 0.000 description 44
- 239000003921 oil Substances 0.000 description 39
- 239000007787 solid Substances 0.000 description 18
- 239000000523 sample Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- 239000002994 raw material Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 7
- 238000002715 modification method Methods 0.000 description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000012263 liquid product Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000000875 corresponding Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 4
- 229920002521 Macromolecule Polymers 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000005039 chemical industry Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052904 quartz Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- JLDSOYXADOWAKB-UHFFFAOYSA-N Aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 1
- QGAVSDVURUSLQK-UHFFFAOYSA-N Ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N Cobalt(II) nitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N Nickel(II) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N Picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000003009 desulfurizing Effects 0.000 description 1
- 230000002542 deteriorative Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 230000002349 favourable Effects 0.000 description 1
- 238000002795 fluorescence method Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000607 poisoning Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000004642 transportation engineering Methods 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2017/113629 WO2019104543A1 (zh) | 2017-11-29 | 2017-11-29 | 改性y型分子筛及制备方法、加氢裂化催化剂及制备方法和烃油加氢裂化的方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2021504281A JP2021504281A (ja) | 2021-02-15 |
| JPWO2019104543A5 true JPWO2019104543A5 (de) | 2022-02-28 |
| JP7169354B2 JP7169354B2 (ja) | 2022-11-10 |
Family
ID=66663729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020529328A Active JP7169354B2 (ja) | 2017-11-29 | 2017-11-29 | 変性ｙ型分子篩及び製造方法、水素化分解触媒及び製造方法、並びに、炭化水素油の水素化分解方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11179705B2 (de) |
| EP (1) | EP3718629A4 (de) |
| JP (1) | JP7169354B2 (de) |
| KR (1) | KR102428229B1 (de) |
| CA (1) | CA3083830C (de) |
| RU (1) | RU2744001C1 (de) |
| SG (1) | SG11202005027XA (de) |
| WO (1) | WO2019104543A1 (de) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112403507B (zh) * | 2019-08-20 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种多产石脑油型加氢裂化催化剂及其应用 |
| CN112723370B (zh) * | 2019-10-28 | 2022-08-12 | 中国石油化工股份有限公司 | 一种高酸量改性y型分子筛及其制备方法与应用 |
| CN112717981B (zh) * | 2019-10-28 | 2022-04-08 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法和应用 |
| CN112723372B (zh) * | 2019-10-28 | 2022-08-12 | 中国石油化工股份有限公司 | 一种富含中强酸的改性y型分子筛及其制备方法与应用 |
| CN110862096A (zh) * | 2019-11-19 | 2020-03-06 | 上海绿强新材料有限公司 | 一种高硅NaY分子筛及其制备方法和应用 |
| CN114433204B (zh) * | 2020-10-19 | 2023-09-01 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法 |
| CN113441169B (zh) * | 2020-10-19 | 2022-11-15 | 宁波中科远东催化工程技术有限公司 | 一种可除硫类杂质的催化剂及其制备方法 |
| CN114433184B (zh) * | 2020-10-19 | 2024-05-07 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法和应用 |
| CN114477215B (zh) * | 2020-10-23 | 2023-07-14 | 中国石油化工股份有限公司 | 一种低钠含量y型分子筛及其制备方法 |
| CN114471687B (zh) * | 2020-10-26 | 2023-10-10 | 中国石油化工股份有限公司 | 体相加氢裂化催化剂的制备方法 |
| CN114471742A (zh) * | 2020-10-27 | 2022-05-13 | 中国石油化工股份有限公司 | 一种改性y型分子筛及其制备方法和应用 |
| CN114471675B (zh) * | 2020-10-27 | 2023-09-01 | 中国石油化工股份有限公司 | 一种用于临氢降凝的改性zsm-5分子筛及其制备方法 |
| CN114534773A (zh) * | 2020-11-24 | 2022-05-27 | 中国石油天然气股份有限公司 | Usy型分子筛改性方法及其应用 |
| CN116060117B (zh) * | 2021-10-29 | 2024-04-05 | 中国石油化工股份有限公司 | 一种催化柴油加氢裂化催化剂及其制备方法 |
| CN116062766B (zh) * | 2021-10-29 | 2024-05-07 | 中国石油化工股份有限公司 | 一种改性zsm-5分子筛及其制备方法和应用 |
| CN116060091A (zh) * | 2021-10-29 | 2023-05-05 | 中国石油化工股份有限公司 | 一种改性y型分子筛及其制备方法和应用 |
| CN116062768B (zh) * | 2021-10-29 | 2024-05-03 | 中国石油化工股份有限公司 | 改性zsm-5分子筛及其制法和应用 |
| CN114956956B (zh) * | 2022-05-07 | 2023-12-19 | 万华化学集团股份有限公司 | 一种生产新戊二醇的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4036739A (en) | 1971-10-20 | 1977-07-19 | Union Oil Company Of America | Catalytic cracking process using ammonia-stable zeolite catalyst |
| US4503023A (en) | 1979-08-14 | 1985-03-05 | Union Carbide Corporation | Silicon substituted zeolite compositions and process for preparing same |
| CN1055063C (zh) | 1996-09-27 | 2000-08-02 | 中国石油化工总公司 | 一种改性y沸石及其制备方法 |
| CN1064929C (zh) | 1996-10-09 | 2001-04-25 | 中国石油化工集团公司抚顺石油化工研究院 | 一种高硅高结晶度y型分子筛及其制备方法 |
| CN100422081C (zh) | 2005-10-19 | 2008-10-01 | 中国石油化工股份有限公司 | 一种改性y沸石及其制备方法 |
| RU2310509C1 (ru) * | 2006-09-18 | 2007-11-20 | ООО "Компания Катахим" | Способ получения катализатора гидрокрекинга нефтяного сырья |
| JP5417969B2 (ja) | 2008-12-17 | 2014-02-19 | 東ソー株式会社 | Ｎ，ｎ，ｎ−トリメチル−ベンジルアンモニウムイオンを用いたチャバザイトの製造方法 |
| FR2951193B1 (fr) | 2009-10-13 | 2011-12-09 | Inst Francais Du Petrole | Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee |
| FR2952380B1 (fr) * | 2009-11-10 | 2012-05-18 | Inst Francais Du Petrole | Procede de production de distillat moyen a partir de cires fischer tropsch mettant en oeuvre un catalyseur a base de zeolithe modifiee par un traitement basique |
| CN103447069B (zh) * | 2012-06-01 | 2016-04-06 | 中国石油天然气股份有限公司 | 一种包含y型分子筛的催化裂化催化剂及其制备方法 |
| BR102014002154A2 (pt) * | 2014-01-28 | 2015-10-27 | Whirlpool Sa | processo de produção de composto alquilaromático, processo de transalquilação de polialquilaromáticos para produção seletiva de composto monoalquilaromático, e, processo de alquilação e transalquilação de compostos aromáticos e/ou poliaromáticos |
| CN105621444B (zh) | 2014-11-03 | 2018-02-09 | 中国石油化工股份有限公司 | 一种改性y分子筛及其制备方法 |
| CN106669786B (zh) * | 2015-11-11 | 2019-04-12 | 中国石油化工股份有限公司 | 一种催化柴油加氢裂化催化剂及其制备方法 |
| CN107304373B (zh) | 2016-04-22 | 2019-03-19 | 中国石油化工股份有限公司 | 一种催化柴油加氢转化工艺 |
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2017
- 2017-11-29 JP JP2020529328A patent/JP7169354B2/ja active Active
- 2017-11-29 KR KR1020207018583A patent/KR102428229B1/ko active IP Right Grant
- 2017-11-29 RU RU2020119436A patent/RU2744001C1/ru active
- 2017-11-29 CA CA3083830A patent/CA3083830C/en active Active
- 2017-11-29 EP EP17933464.4A patent/EP3718629A4/de active Pending
- 2017-11-29 SG SG11202005027XA patent/SG11202005027XA/en unknown
- 2017-11-29 WO PCT/CN2017/113629 patent/WO2019104543A1/zh unknown
- 2017-11-29 US US16/768,070 patent/US11179705B2/en active Active
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