JPS59191723A - ビス−トリアルコキシシラン化合物の製造方法 - Google Patents

ビス−トリアルコキシシラン化合物の製造方法

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Publication number
JPS59191723A
JPS59191723A JP59067333A JP6733384A JPS59191723A JP S59191723 A JPS59191723 A JP S59191723A JP 59067333 A JP59067333 A JP 59067333A JP 6733384 A JP6733384 A JP 6733384A JP S59191723 A JPS59191723 A JP S59191723A
Authority
JP
Japan
Prior art keywords
bis
terminated
backbone
manufacture
trialkoxysilane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59067333A
Other languages
English (en)
Inventor
ロナルド・アレン・ミツチユ
ジヨゼフ・ラマ−ル・ゾ−リンガ−
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US00070540A external-priority patent/US3810874A/en
Priority claimed from CA120,659A external-priority patent/CA960400A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of JPS59191723A publication Critical patent/JPS59191723A/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C265/00—Derivatives of isocyanic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
    • C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D271/10—1,3,4-Oxadiazoles; Hydrogenated 1,3,4-oxadiazoles
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    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
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    • C10N2040/18—Electric or magnetic purposes in connection with recordings on magnetic tape or disc
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/185—Magnetic fluids

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 本発明はポリ（パーフルオロアルキレンオキサイド）背
骨を有するビス−トリアルコキシシランの製造法に関す
る。
航空工業において、密閉剤、ガスケット、〇−リング、
固体発射薬結合剤、等は低温度可撓性、高温度安定性、
耐溶媒性、および熱および酸化安定性を持たなければな
らない。若干の上記性質を示す最近の先行技術の物質が
述べられているけれども、今まで、上記要求事項を満足
させかつさらに望ましい低温度可撓性を有する重合体は
提供されていない。
本発明は、極めて低いガラス転移湿度を有しかつ低温度
において可撓性であり、そして耐溶媒性および良好な加
水分解、熱および酸化安定性を有する新規な重合体の製
造のため極めて有用である新規な多官能末端ポリ（パー
フルオロアルキレンオキサイド）の背骨を有するビス−
トリアルコキシシランを提供する。
本発明に゛よるビス−トリアルコキシシランは式％式％
（） （式中ｍおよびｎは各々、不規則に分布されているノぐ
−フルオ四エチレンオキシおよびノぐ−フルオロメチレ
ンオキシ背骨反復側単位の数を示し、しかも比率ｒｌｌ
　／　ｎはＯ０２／１ないし５／１、好ましくは０．５
　／　１ないし２／１である）の背骨を有するエステル
末端またはアシル末端ポリパーフルオロアルキレンオキ
サイＰをアミノプロピルアルコキシシランと反応させる
ことにより得られる。
本発明によるビス−トリアルコキシシラン化合物は５０
０ないし２０，０００またはより高い、好ましくは８０
０ないし１５．０００の範囲の数平均分子量醜を有し熱
安定性、耐溶媒性のポリシロキサンの製造のためホモ重
合または共重合される。
この♂スートリアルコキシシラン化合物のガラス転移温
度（Ｔｇ　）は一般に一７８°Ｃより低く、好ましくは
一１００°Ｃより低く、そして−１２５°Ｃまたはさら
に低く、例えば−１３０°Ｃでありうる。
これらの有利に低いガラス転移温度はまたこの化合物か
ら造られた重合体の特性であり、そして化合物中の酸素
／弗素含有率を増加させることによりまたはポリ（パー
フルオロアルキレンオキサイド）セグメントの長さを増
加させることによりさらに下げることができる。
セグメント−末端基は通常かつ好ましくは一０Ｆ２−で
あるけれども、−Ｃ２Ｆじ、−Ｃ３Ｆ６−または類似の
パーフルオロアルキレン基を含有するセグメントをつく
ることができ、それは−０Ｆ２−末端セグメントと同一
の性質を本質的に有する。
本式（Ｉ）の背骨は、パーフルオロメチレン基を末端と
し、この末端基は非芳香族二重結合を含まない二価基に
よりパーフルオロメチレン基に結合された重合反応性基
を有する。
原料物質として用いられるエステル末端またはアシル末
端ポリパーフルオロアルキレンオキサイドの例としては
、−Ｃ０００Ｈ３末端・化合物が包含され、これらの化
合物は、たとえばイタリー国特許第８１７，８０９号明
細書にその製造方法とともに記載されている。
本発明による代表的ビス−トリアルコキシシラン末端ポ
リパーフルオロアルキレンオキサイＰには一００１７Ｈ
（ＯＨ２）３８１１（ＯＣＨ３）３末端ポリパーフルオ
ロアルキレンオキサイドがあり、これは−００００Ｈ３
末端先駆化合物をＨ２Ｎ（ＯＨ２）　３Ｓｉ（ＯＣＨ３
）　３と反応させることにより得ることができる。
代理人　浅　村　　　皓 手続補正書 昭和５９年　４月ｊＯ日 特許庁長官殿 １、事件の表示 ２・発明の名称　　２．、、、−）ＩＪアヤ、ヤッッ、
２イ、８１つ製造方法 ３、補正をする者 事件との関係　特許出願人 ４、代理人 ５、補正命令の日付 昭和　　年　　月　　日 ６、補正により増加する発明の数 ７、補正の対象 明細書の発明の詳細な説明の欄 （１）明細書第３頁７行「得られる。」の次に「アルコ
キシ基は好ましくはメトキシ基またはエトキシ基である
。」を加入する。
＝１４５−

Claims (1)

  1. 【特許請求の範囲】 式 ％式％） （式中ｍおよびｎは各々、不規則に分布されたパーフル
    オロエチレンオキシおよびパーフルオロメチレンオキシ
    背骨反復側単位の数を示し、しかも比率ｍ　／　ｎは０
    ．２／１ないし５／１である）ノ背骨を有するエステル
    末端またはアシル末端ポリパーフルオロアルキレンオキ
    サイドを、アミノプロピルアルコキシシランと反応させ
    ることを特徴とする、式 ％式％ （式中ｍおよびｎは上記のとおりである）の背骨を有す
    るビス−トリアルコキシシランの製造方法。
JP59067333A 1970-09-08 1984-04-04 ビス−トリアルコキシシラン化合物の製造方法 Pending JPS59191723A (ja)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US00070540A US3810874A (en) 1969-03-10 1970-09-08 Polymers prepared from poly(perfluoro-alkylene oxide) compounds
US70540 1970-09-08
US00108623A US3845051A (en) 1970-09-08 1971-01-21 Alpha,omega-di-s-triazinyl perfluoropolyoxa-alkanes
CA120,658A CA960221A (en) 1970-09-08 1971-08-16 Dis-"alpha, omega-di-s-triazinyl perfluoropoly-oxaalkanes"
CA120,659A CA960400A (en) 1970-09-08 1971-08-16 Poly(perfluoroalkylene oxide) derivatives
CA190,722A CA960222A (en) 1970-09-08 1974-01-21 Polyfunctional poly(perfluoroalkylene oxide) compounds

Publications (1)

Publication Number Publication Date
JPS59191723A true JPS59191723A (ja) 1984-10-30

Family

ID=27507950

Family Applications (5)

Application Number Title Priority Date Filing Date
JP59067335A Expired JPS6050823B2 (ja) 1970-09-08 1984-04-04 ジヒドロキシ末端ポリパ−フルオロアルキレンオキサイドの製造方法
JP59067334A Granted JPS59191724A (ja) 1970-09-08 1984-04-04 ビス−トリフルオロメタンスルホネ−ト化合物の製造方法
JP59067331A Granted JPS59191722A (ja) 1970-09-08 1984-04-04 ジエポキシド化合物の製造方法
JP59067333A Pending JPS59191723A (ja) 1970-09-08 1984-04-04 ビス−トリアルコキシシラン化合物の製造方法
JP59067330A Granted JPS59191721A (ja) 1970-09-08 1984-04-04 ジアクリレ−ト化合物の製造方法

Family Applications Before (3)

Application Number Title Priority Date Filing Date
JP59067335A Expired JPS6050823B2 (ja) 1970-09-08 1984-04-04 ジヒドロキシ末端ポリパ−フルオロアルキレンオキサイドの製造方法
JP59067334A Granted JPS59191724A (ja) 1970-09-08 1984-04-04 ビス−トリフルオロメタンスルホネ−ト化合物の製造方法
JP59067331A Granted JPS59191722A (ja) 1970-09-08 1984-04-04 ジエポキシド化合物の製造方法

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Application Number Title Priority Date Filing Date
JP59067330A Granted JPS59191721A (ja) 1970-09-08 1984-04-04 ジアクリレ−ト化合物の製造方法

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Country Link
US (1) US3845051A (ja)
JP (5) JPS6050823B2 (ja)
AU (2) AU469118B2 (ja)
BE (2) BE772308A (ja)
CA (2) CA960221A (ja)
DE (2) DE2145176C2 (ja)
FR (2) FR2106375B1 (ja)
GB (2) GB1373932A (ja)
NL (2) NL7111865A (ja)

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DE3929164A1 (de) * 1989-09-02 1991-03-07 Basf Ag Magnetische aufzeichnungstraeger
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WO1994019433A1 (en) * 1993-02-24 1994-09-01 Hitachi Maxell, Ltd. Lubricant
WO2016084746A1 (ja) * 2014-11-28 2016-06-02 ダイキン工業株式会社 フルオロオキシメチレン基含有パーフルオロポリエーテル変性体
JP2016138240A (ja) * 2014-11-28 2016-08-04 ダイキン工業株式会社 フルオロオキシメチレン基含有パーフルオロポリエーテル変性体
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Also Published As

Publication number Publication date
JPS59191722A (ja) 1984-10-30
BE772308A (fr) 1972-03-07
FR2116364A1 (ja) 1972-07-13
DE2145176A1 (de) 1972-03-16
JPS6050823B2 (ja) 1985-11-11
FR2106375B1 (ja) 1976-04-30
DE2145174C3 (de) 1979-05-31
JPS59191721A (ja) 1984-10-30
NL157596B (nl) 1978-08-15
CA960222A (en) 1974-12-31
DE2145176C2 (de) 1983-05-26
AU3317471A (en) 1973-03-15
GB1373932A (en) 1974-11-13
JPS59191724A (ja) 1984-10-30
AU462798B2 (en) 1975-07-10
DE2145174B2 (de) 1978-10-05
DE2145174A1 (de) 1972-03-23
JPS6214169B2 (ja) 1987-04-01
AU469118B2 (en) 1976-02-05
JPS59191725A (ja) 1984-10-30
NL7112315A (ja) 1972-03-10
GB1373931A (en) 1974-11-13
FR2106375A1 (ja) 1972-05-05
JPS6214171B2 (ja) 1987-04-01
CA960221A (en) 1974-12-31
FR2116364B1 (ja) 1976-08-20
AU3317671A (en) 1973-03-15
BE772309A (fr) 1972-03-07
US3845051A (en) 1974-10-29
NL7111865A (ja) 1972-03-10
JPS6214170B2 (ja) 1987-04-01

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