JPS6214170B2 - - Google Patents

Info

Publication number
JPS6214170B2
JPS6214170B2 JP59067331A JP6733184A JPS6214170B2 JP S6214170 B2 JPS6214170 B2 JP S6214170B2 JP 59067331 A JP59067331 A JP 59067331A JP 6733184 A JP6733184 A JP 6733184A JP S6214170 B2 JPS6214170 B2 JP S6214170B2
Authority
JP
Japan
Prior art keywords
terminated
added
formula
perfluoroalkylene
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP59067331A
Other languages
English (en)
Other versions
JPS59191722A (ja
Inventor
Joseph Lamar Zollinger
Ronald Allen Mitsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US00070540A external-priority patent/US3810874A/en
Priority claimed from CA120,659A external-priority patent/CA960400A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of JPS59191722A publication Critical patent/JPS59191722A/ja
Publication of JPS6214170B2 publication Critical patent/JPS6214170B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C265/00—Derivatives of isocyanic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
    • C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D271/10—1,3,4-Oxadiazoles; Hydrogenated 1,3,4-oxadiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5015—Polyethers having heteroatoms other than oxygen having halogens having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/773—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/42—Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/16—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C10M2215/222—Triazines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/02—Esters of silicic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/175—Pantographs, i.e. printing devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/18—Electric or magnetic purposes in connection with recordings on magnetic tape or disc
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/185—Magnetic fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Lubricants (AREA)
  • Laminated Bodies (AREA)

Description

【発明の詳細な説明】
本発明はポリ（パーフルオロアルキレンオキサ
イド）の背骨を有するジエポキシドの製造方法に
関する。 航空工業において、密閉剤、ガスケツト、Ｏ−
リング、固体発射薬結合剤、等は低温度可撓性、
高温度安定性、耐溶媒性、および熱および酸化安
定性を持たなければならない。若干の上記性質を
示す最近の先行技術の物質が述べられているけれ
ども、今まで、上記要求事項を満足させかつさら
に望ましい低温度可撓性を有する重合体は提供さ
れていない。 本発明は、極めて低いガラス転移温度を有しか
つ低温度において可撓性であり、そして耐溶媒性
および良好な加水分解、熱および酸化安定性を有
する新規な重合体の製造のため極めて有用である
新規な二官能末端ポリ（パーフルオロアルキレン
オキサイド）の背骨を有するジエポキシドを提供
する。 本発明のジエポキシドは式 Ａ−CF2O（CF2CF2O）n（CF2O）oCF2−A′ （式中、ＡおよびA′は−CH2OH、−CH2OCH2CH
（OH）CH2OH、−CONHCH2CH2OHまたは−
CON（CH3）CH2CH2OH、であり、ｍおよびｎ
は各々不規則に分布されたパーフルオロエチレン
オキシおよびパーフルオロメチレンオキシ背骨反
復副単位の数を示し、しかも比率ｍ／ｎは0.2／
１〜５／１である。）を有するヒドロキシ末端ポ
リパーフルオルアルキレンオキサイドをエピクロ
ルヒドリンまたはエピブロモヒドリンと反応させ
ることにより得られる。 本発明によるジエポキシド化合物は500ないし
20000またはより高い、好ましくは800ないし
15000の範囲の数平均分子量oを有し、熱安定
性、耐溶媒性のエラストマーの製造のためホモ重
合または共重合される。本発明のジエポキシド化
合物のガラス転移温度（Tg）は一般に−78℃よ
り低く、好ましくは−100℃より低く、そして−
125℃またはさらに低く、例えば−130℃でありう
る。これらの有利に低いガラス転移温度はまたこ
の化合物から造られた重合体の特性であり、そし
て化合物中の酸素／弗素含有率を増加させること
によりまたはポリ（パーフルオロアルキレンオキ
サイド）セグメントの長さを増加させることによ
りさらに下げることができる。 セグメント−末端基は通常かつ好ましくは−
CF2−であるけれども、−C2F4−、−C3F6−また
は類似のパーフルオロアルキレン基を含有するセ
グメントをつくることができ、それは−CF2−末
端セグメントと同一の性質を本質的に有する。 原料物質として用いられる線状ヒドロキシ−末
端ポリ（パーフルオロアルキレンオキサイド）は
それ自身新規な材料であり、またそれらは−78℃
より低い例外的に低いガラス転移点を有す。それ
らは、例えば、それらの公知のエステル−、カル
ボキシ−、またはアシルハライド−末端プレカー
サーの還元により、または上記エステル−または
アシルハライド−末端プレカーサーとアミレアル
コールとの反応（列えばイタリヤ特許第817809参
照）により製造することができる。ヒドロキシ−
末端プレポリマーは普通ヒドロキシ官能性２を有
す。このような官能性は、プレポリマーを通常化
学量論量以下で２・３−エポキシ−１−プロパノ
ールのようなヒドロキシ−含有エポキサイドと反
応させることにより例えば３まで増加させること
ができる。 たとえば−COOCH3末端先駆化合物をLiAlH4
で還元することにより−CH2OH末端ポリパーフ
ルオロアルキレンオキサイドを生成し、次いで
【式】と反応させると、− CH2OCH2CH（OH）CH2OH末端化合物が得られ
る。アミノアルコールの例としてはエタノールア
ミンはプロパノールアミンがあり、この場合には
それぞれ−OCHNCH2CH2OH末端および−CON
（CH3）CH2CH2OH末端生成物が得られる。 線状ヒドロキシ−末端ポリ（パーフルオロアル
キレンオキサイド）の数平均分子量oは500ない
し10000好ましくは800ないし5000の範囲である。
こらのプレポリマーのガラス転移温度Tgは一般
に−78℃より低く、好ましくは−90℃より低く、
更に−125℃程度であることができ、プレポリマ
ー中の酸素対フツ素が高ければ高い程ガラス転移
点は低い。（重合体の“ガラス転移温度”はそれ
以上では重合体が軟らかくゴム状、即ち柔軟であ
り、それ以下では固いもろいガラスである温度で
ある；このような温度は一般に示差分析、DTA
または膨張係数の変化により測定される。）この
プレポリマーは一般に室温で透明で無色の液体で
あり、低い容積粘度（例えば27℃で125センチポ
イズ）を有し、その性質はこれらの材料を用いる
のに有利である。 一般に、ヒドロキシ−末端プレポリマーは異つ
た骨格または鎖長を有する化合物の混合物であ
る。 実施例 エポキシ末端ポリ（パーフルオロアルキレンオ
キサイド）の製造100mlのガラスフラスコに、式 HOCH2−CF2O（CF2CF2O）n（CF2O）oCF2−CH2OH で示されるジカルビノール（o＝1800）10ｇ
（0.0055モル）と、１・１・２−トリクロロトリ
フルオロエタン25mlと、１・２−ジメトキシエタ
ン15mlと、ナトリウムハイドライド（鉱油中50
％）0.64ｇ（0.013モル）とを入れた。この混合
物を１時間加熱還流した。この還流している混合
物に、１・２−ジメトキシエタン５ml中の１−ブ
ロモ−２・３−エポキシプロパン2.4ｇを５分間
にわたつて添加した。この混合物は透明になり始
めそして２時間の還流時間の間に、フラスコ壁上
に固体が形成し始めた。冷却した透明溶液を固体
から傾斜除去し、水で３回洗浄し、減圧下で濃縮
して淡黄色液体（ｎ２４ Ｄ＝1.3133）５ｇ（収率約50
％）を得た。プロトン原子核磁気共鳴吸収ピーク
は次の通りである：8.2τ、6.4τ、7.0τ、7.4
τ。これらのデータは構造 （Ｒfpは−CF2O（CF2CF2O）n（CF2O）o（CF2−
である）に一致する。このジエポキシサイドは、
８時間、約100℃で１−５％トリエチレンジアミ
ンまたは（CF3SO3）2znと共に加熱して重合させ
ると、低温ガスケツトに有用な耐溶媒性エラスト
マーが得られる。140℃で16時間、５％トリス−
ジメチルアミノメチルフエノールと等モル量の式 H2NCH2CF2O（CF2CF2O）n（CF2O）oCF2CH2H2 で示されるジアミンと共にこのジエポキサイドを
加熱すると、低温密閉用物質として適する交サ結
合エラストマーが得られる。 参考例 １ ヒドロキシ末端ポリ（パーフルオロアルキレン
オキサイド）の製造 粉末のリチウムアルミニウムハイドライド
（1.9ｇ、0.05モル）を、機械的撹拌機、硫酸カル
シウム乾燥用管を具備する還流コンデンサー、お
よびガス注入管の設けられている500mlの三ツ首
フラスコ中の乾燥ジエチルエーテル120mlに添加
し、混合物を乾燥窒素下で４時間撹拌した。式 CH3O2COF2O（CF2CF2O）n（CF2O）oCF2CO2CH3 で示されるメチルジエステル（o＝1800および
ｍ／ｎ＝1.4／１）のエーテル溶液50mlを、緩慢
な還流を維持するに十分な速度でリチウムアルミ
ニウムハイドライドの撹拌溶液に添加した。すべ
てのエステルを添加した後、得られた混合物を一
夜にわたり加熱還流した。無水メチルアルコール
（20ml）を添加して過剰のハイドライドを分解
し、ついで稀硫酸（水100ml中の36NH2SO437
ｇ）を添加した。水性相および有機相を分離し、
水性層をジエチルエーテルで４回抽出し、得られ
たエーテル部分と有機相とを混合し、硫酸カルシ
ウム上で乾燥した。硫酸カルシウムとエーテルと
を混合エーテル部分から除去して透明白色液体の
メチロール−末端ポリ（パーフルオロアルキレン
オキサイド）、 HOCH2−CF2O（CF2CF2O）n（CF2O）oCF2−CH2OH を得た。この生成物は約18000のo、975±50の
ヒドロキシル当量および−107℃のTgを有するこ
とが判明した。 参考例 ２ 各末端基上に一個より多いヒドロキシル基を含
有する他のタイプのヒドロキシ−末端ポリ（パ
ーフルオロアルキレンオキサイド）の製造 500mlの丸底ガラスフラスコに、参考例１で得
られたメチロール末端ポリ（パーフルオロアルキ
レンオキサイド）化合物（o＝2000、ｍ／ｎ＝
0.6）105ｇを仕込んだ。この系を脱気し、N2で覆
い、次に、メタノール中のNaOCH3（4.85meq／
ｇ）溶液5.25mlを磁気的に撹拌しながら注射器を
通じて添加した。この混合物を65℃に加熱しなが
ら、減圧下でメタノールを除去した。この系を再
びN2で覆い、45℃に冷却し、次いでグリシドー
ル1.85ｇを添加した。この混合物を１1/2時間90
℃で撹拌した後、これを冷却し、
CF2ClCFCl2150mlで稀釈し、次いで10％水性
H2SO410mlで洗浄した。この溶液を乾燥し、ろ過
し、次いで濃縮した。0.8mmHgで95℃に最終的に
加熱した後、生成物を焼結ガラスろう斗を通じて
ろ過して微量の汚染物を除去した。式 HOCH2CF2O（CF2CF2O）n（CF2O）oCF2CH2 −OCH2CH（OH）CH2OH を有する化合物の未反応原料ジオール中の50％溶
液である黄色透明生成物（98.5ｇ、92.5％）を得
た。上記１：0.5の代りに、グリシドール対ジオ
ールのモル比を２：１にすることにより、完全に
二置換された生成物を得た。この生成物それ自体
は、ウレタンまたはポリエステル重合体のための
交サ結合剤として有用である。 参考例 ３ エチロール置換アミド末端ポリ（パーフルオロ
アルキレンオキサイド）の製造 式 CH3O2CCF2O（CF2CF2O）n（CF2O）oCF2CO2CH3 で示されるメチルジエステル化合物（o＝1400
およびｍ／ｎ＝1.55）10.2ｇにエタノールアミン
0.9ｇを徐々に添加し、撹拌する。この混合物を
１時間撹拌した後に、赤外線スペクトルは、ジエ
ステル化合物が、エチロール置換アミド末端プレ
ポリマーに完全に変換されたことを示した。反応
混合物をジエチルエーテル125ml中に溶解し、各
回10mlの水で３回洗浄し、硫酸カルシウム上で乾
燥した。硫酸カルシウムおよびエーテルを除去す
ると赤外線スペクトルにより確認される構造 HOCH2CH2NHC（Ｏ）CF2O
（CF2CF2O）n（CF2O）o −CF2CONHCH2CH2OH を有する淡黄色プレポリマー9.5ｇが得られた。

Claims (1)

  1. 【特許請求の範囲】 １ 式 Ａ−CF2O（CF2CF2O）n（CF2O）oCF2 −A′ （式中、ＡおよびＡは−CH2OH、−CH2OCH2CH
    （OH）CH2OH、−CONHCH2CH2OHまたは−
    CON（CH3）CH2CH2OH、でありｍおよびｎは
    各々不規則に分布されたパーフルオロエチレンオ
    キシおよびパーフルオロメチレンオキシ背骨反復
    副単位の数を示し、しかも比率ｍ／ｎは0.2／１
    〜５／１である。） を有するヒドロキシ末端ポリ（パーフルオロアル
    キレンオキサイド）をエピハロヒドリンと反応さ
    せることを特徴とする、式 −CF2O（CF2CF2O）n（CF2O）oCF− （式中ｍおよびｎは上記のとおりである。） の背骨を有するジエポキシドの製造方法。
JP59067331A 1970-09-08 1984-04-04 ジエポキシド化合物の製造方法 Granted JPS59191722A (ja)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US70540 1970-09-08
US00070540A US3810874A (en) 1969-03-10 1970-09-08 Polymers prepared from poly(perfluoro-alkylene oxide) compounds
US00108623A US3845051A (en) 1970-09-08 1971-01-21 Alpha,omega-di-s-triazinyl perfluoropolyoxa-alkanes
CA120,659A CA960400A (en) 1970-09-08 1971-08-16 Poly(perfluoroalkylene oxide) derivatives
CA120,658A CA960221A (en) 1970-09-08 1971-08-16 Dis-"alpha, omega-di-s-triazinyl perfluoropoly-oxaalkanes"
CA190,722A CA960222A (en) 1970-09-08 1974-01-21 Polyfunctional poly(perfluoroalkylene oxide) compounds

Publications (2)

Publication Number Publication Date
JPS59191722A JPS59191722A (ja) 1984-10-30
JPS6214170B2 true JPS6214170B2 (ja) 1987-04-01

Family

ID=27507950

Family Applications (5)

Application Number Title Priority Date Filing Date
JP59067335A Expired JPS6050823B2 (ja) 1970-09-08 1984-04-04 ジヒドロキシ末端ポリパ−フルオロアルキレンオキサイドの製造方法
JP59067330A Granted JPS59191721A (ja) 1970-09-08 1984-04-04 ジアクリレ−ト化合物の製造方法
JP59067331A Granted JPS59191722A (ja) 1970-09-08 1984-04-04 ジエポキシド化合物の製造方法
JP59067333A Pending JPS59191723A (ja) 1970-09-08 1984-04-04 ビス−トリアルコキシシラン化合物の製造方法
JP59067334A Granted JPS59191724A (ja) 1970-09-08 1984-04-04 ビス−トリフルオロメタンスルホネ−ト化合物の製造方法

Family Applications Before (2)

Application Number Title Priority Date Filing Date
JP59067335A Expired JPS6050823B2 (ja) 1970-09-08 1984-04-04 ジヒドロキシ末端ポリパ−フルオロアルキレンオキサイドの製造方法
JP59067330A Granted JPS59191721A (ja) 1970-09-08 1984-04-04 ジアクリレ−ト化合物の製造方法

Family Applications After (2)

Application Number Title Priority Date Filing Date
JP59067333A Pending JPS59191723A (ja) 1970-09-08 1984-04-04 ビス−トリアルコキシシラン化合物の製造方法
JP59067334A Granted JPS59191724A (ja) 1970-09-08 1984-04-04 ビス−トリフルオロメタンスルホネ−ト化合物の製造方法

Country Status (9)

Country Link
US (1) US3845051A (ja)
JP (5) JPS6050823B2 (ja)
AU (2) AU462798B2 (ja)
BE (2) BE772308A (ja)
CA (2) CA960221A (ja)
DE (2) DE2145174C3 (ja)
FR (2) FR2116364B1 (ja)
GB (2) GB1373931A (ja)
NL (2) NL7111865A (ja)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE411763B (sv) * 1971-08-05 1980-02-04 Montedison Spa Amorf, mycket viskos polymer sampolyeter med hog molekylvikt vars makromolekyler er bildade av monomerenheterna -cf?712cf?712o- och -cf?712o- samt sett for dess framstellning
US3888854A (en) * 1971-11-18 1975-06-10 Pcr Bis-triazine compounds
IT956237B (it) * 1972-04-26 1973-10-10 Montedison Spa Poliammidi elastomeriche contenen ti fluoro
IT963296B (it) * 1972-07-24 1974-01-10 Montedison Spa Copoliimmidi elastomeriche conte nenti fluoro e procedimento per la loro preparazione
US4647413A (en) * 1983-12-27 1987-03-03 Minnesota Mining And Manufacturing Company Perfluoropolyether oligomers and polymers
IT1188202B (it) * 1985-11-15 1988-01-07 Ausimont Spa Composizioni elastomeriche vulcanizzabili di fluoroelastomeri
IT1209669B (it) * 1985-11-15 1989-08-30 Ausimont Spa Composizioni vulcanizzabili fluoroelastomeri aventi migliorate caratteristiche di processabilita'e di stabilita' chimica.
FR2599378B1 (fr) * 1986-05-30 1988-07-29 Atochem Lubrifiants et nouveaux composes polyfluores utilisables comme additifs
US4820588A (en) * 1986-08-29 1989-04-11 Minnesota Mining And Manufacturing Company Shaped articles of polyfluoropolyethers having pendant perfluoroalkoxy groups
US4981727A (en) * 1986-08-29 1991-01-01 Minnesota Mining And Manufacturing Company Polyfluoropolyethers having pendant perfluoroalkoxy groups
US4743300A (en) * 1986-08-29 1988-05-10 Minnesota Mining And Manufacturing Company Polyfluoropolyethers having pendant perfluoroalkoxy groups
IT1231758B (it) * 1989-04-20 1991-12-21 Ausimont Srl Fluoropolieteri funzionalizzati
US5693748A (en) * 1989-02-01 1997-12-02 Asahi Kasei Kogyo Kabushiki Kaisha High molecular weight polyimidoylamidine and a polytriazine derived therefrom
KR930008206B1 (ko) * 1989-06-05 1993-08-26 아사히가세이고오교 가부시끼가이샤 냉매조성물
DE3929164A1 (de) * 1989-09-02 1991-03-07 Basf Ag Magnetische aufzeichnungstraeger
US5032301A (en) * 1990-04-06 1991-07-16 The Dow Chemical Company High performance lubricants comprising triazine derivatives
IT1244751B (it) * 1991-02-15 1994-08-08 Ausimont Spa Coloranti per perfluoropoliossialchileni e composizioni a base di perfluoropoliossialchileni contenenti tali coloranti
JP2554412B2 (ja) * 1991-06-03 1996-11-13 信越化学工業株式会社 シラン架橋性アルキレンオキシド重合体の製造方法
DE4490958T1 (de) * 1993-02-24 1995-04-27 Hitachi Maxell Schmiermittel
RU2045544C1 (ru) * 1994-02-04 1995-10-10 Акционерное общество "Автоконинвест" Амиды и эфиры перфторполиоксаалкиленсульфо- или перфторполиоксаалкиленкарбоновых кислот и способ их получения
US6496637B2 (en) * 2000-12-21 2002-12-17 Corning Incorporated Low optical loss polymers
ITMI20011034A1 (it) * 2001-05-18 2002-11-18 Ausimont Spa Processo per la preprazione di fluoropoliossoalchileni aventi un terminale -ch 2oh e l'altro terminale contenente cloro
EP1399417B1 (de) * 2001-06-01 2009-08-12 MERCK PATENT GmbH Verfahren zur herstellung von perfluoralkansulfonsäureestern
RU2380384C2 (ru) * 2003-01-29 2010-01-27 Грин, Твид Оф Делавэр, Инк. Вулканизирующие агенты на основе бисаминофенила и вулканизирующие агенты и ускорители вулканизации на основе амидина для перфторэластомерных композиций
WO2004069900A2 (en) 2003-01-29 2004-08-19 Greene, Tweed Of Delaware, Inc. Bisaminophenyl-based curatives and amidine-based curatives and cure accelerators for perfluoroelastomeric compositions
US7514506B2 (en) * 2004-03-31 2009-04-07 Greene, Tweed Of Delaware, Inc. Fast curing fluoroelastomeric compositions, adhesive fluoroelastomeric compositions and methods for bonding fluoroelastomeric compositions
JP4828114B2 (ja) * 2004-11-15 2011-11-30 富士通株式会社 組成物を含む潤滑剤、磁気記録媒体、ヘッドスライダおよび磁気記録装置
JP4974208B2 (ja) * 2005-12-28 2012-07-11 信越化学工業株式会社 室温硬化性含フッ素組成物
US7615283B2 (en) * 2006-06-13 2009-11-10 3M Innovative Properties Company Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film
WO2011099131A1 (ja) * 2010-02-10 2011-08-18 株式会社Moresco パーフルオロポリエーテル化合物、その製造方法、該化合物を含有する潤滑剤、および磁気ディスク
JP5830848B2 (ja) * 2010-10-29 2015-12-09 ダイキン工業株式会社 表面処理剤と組成物、その処理加工品
CN107001619B (zh) * 2014-11-28 2019-07-19 大金工业株式会社 含氟氧亚甲基的全氟聚醚改性体
US10053538B2 (en) * 2014-12-12 2018-08-21 Moresco Corporation Method for producing fluoropolyether
EP3426705B1 (en) * 2016-03-11 2019-12-18 Solvay Specialty Polymers Italy S.p.A. Polyunsaturated compound for curing fluoroelastomer compositions
CN114957042A (zh) * 2022-07-01 2022-08-30 苏州莱克施德药业有限公司 一种2,2,2-三氟乙脒的合成工艺

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3566835A (en) * 1968-10-28 1971-03-02 Dow Corning Perfluoroalkylene ether and thioether triazine compounds

Also Published As

Publication number Publication date
AU462798B2 (en) 1975-07-10
AU3317471A (en) 1973-03-15
BE772309A (fr) 1972-03-07
DE2145174A1 (de) 1972-03-23
CA960221A (en) 1974-12-31
FR2116364A1 (ja) 1972-07-13
JPS6214169B2 (ja) 1987-04-01
JPS6050823B2 (ja) 1985-11-11
AU3317671A (en) 1973-03-15
DE2145174B2 (de) 1978-10-05
FR2106375A1 (ja) 1972-05-05
JPS59191724A (ja) 1984-10-30
DE2145174C3 (de) 1979-05-31
GB1373931A (en) 1974-11-13
CA960222A (en) 1974-12-31
JPS59191721A (ja) 1984-10-30
US3845051A (en) 1974-10-29
JPS6214171B2 (ja) 1987-04-01
NL157596B (nl) 1978-08-15
DE2145176A1 (de) 1972-03-16
NL7111865A (ja) 1972-03-10
JPS59191722A (ja) 1984-10-30
GB1373932A (en) 1974-11-13
BE772308A (fr) 1972-03-07
AU469118B2 (en) 1976-02-05
FR2106375B1 (ja) 1976-04-30
DE2145176C2 (de) 1983-05-26
JPS59191725A (ja) 1984-10-30
NL7112315A (ja) 1972-03-10
FR2116364B1 (ja) 1976-08-20
JPS59191723A (ja) 1984-10-30

Similar Documents

Publication Publication Date Title
JPS6214170B2 (ja)
US3278496A (en) Thiol terminated liquid polymers
US6509509B2 (en) Process for the preparation of perfluoropolyoxyalkylenes with hydroxyl end groups
US3849504A (en) Perfluoropolyethers and process for making
US3733349A (en) Fluorocarbon cyanates
JPS6361336B2 (ja)
JPH0768336B2 (ja) オリゴオキシエチレン側鎖を有するポリエーテル共重合体の製法
EP0422231B1 (en) High-molecular polytriazine
US5426174A (en) Hydroxy-functionalized polyoxyalkylene ether compositions derived from mixtures of C4 epoxides
EP0621296B1 (en) Thermoplastic polyesters containing perfluoropolyoxyalkylene sequences
EP2280037A1 (en) Fluorine-containing polyether compound and method for producing the same
US3472913A (en) Polythiol composition and preparation thereof
US2883395A (en) Epoxy-substituted organosilicon compounds and method for preparing the same
US4064109A (en) Perfluoroalkylene ether bibenzoxazole polymers
US3846376A (en) Thermally stable perfluoroalkylene ether bibenzoxazole polymers
US3714265A (en) Hydroxy alkylene ethers of divinyl glycol
EP0215543B1 (en) A new process for making polyesters, polyamides and polyketones
Relles et al. Dichloromaleimide chemistry. IV. Preparation of poly (maleimide–ethers) from the reaction of bisdichloromaleimides with bisphenols
US3261819A (en) Preparation and polymerization of 1,2-divinyl ethylene oxide
JPH04209627A (ja) オリゴオキシエチレン側鎖を有するポリエーテルポリマー
US3354119A (en) Cyclic siloxane-contaioning silicone polymers
US3496120A (en) Halogen containing polyether epoxide composition of matter and process of preparing same
JP2681597B2 (ja) 高官能ポリアルキレンエーテルポリオールの製造方法
CN117069949A (zh) 一种具有交替多嵌段结构的缩水甘油叠氮聚醚-四氢呋喃含能共聚醚及其合成方法
USRE28387E (en) Hydroxy alkylene ethers of divinyl glycol