JPH08511543A - 第四級アンモニウム及び防水/防腐剤組成物 - Google Patents
第四級アンモニウム及び防水/防腐剤組成物Info
- Publication number
- JPH08511543A JPH08511543A JP7502177A JP50217795A JPH08511543A JP H08511543 A JPH08511543 A JP H08511543A JP 7502177 A JP7502177 A JP 7502177A JP 50217795 A JP50217795 A JP 50217795A JP H08511543 A JPH08511543 A JP H08511543A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- quaternary ammonium
- formula
- hydroxide
- wood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 221
- 125000001453 quaternary ammonium group Chemical group 0.000 title claims description 103
- 239000003755 preservative agent Substances 0.000 title claims description 30
- 230000002335 preservative effect Effects 0.000 title claims description 16
- 238000004078 waterproofing Methods 0.000 claims abstract description 87
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 154
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 130
- 239000003171 wood protecting agent Substances 0.000 claims description 106
- 125000000217 alkyl group Chemical group 0.000 claims description 92
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 87
- 239000002904 solvent Substances 0.000 claims description 86
- 239000002023 wood Substances 0.000 claims description 85
- 239000003795 chemical substances by application Substances 0.000 claims description 74
- 229910052751 metal Inorganic materials 0.000 claims description 67
- 239000002184 metal Substances 0.000 claims description 67
- -1 didecyldimethylammonium compound Chemical class 0.000 claims description 62
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 59
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims description 57
- 239000000758 substrate Substances 0.000 claims description 57
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 claims description 51
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 50
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 50
- 150000004692 metal hydroxides Chemical class 0.000 claims description 50
- 238000006243 chemical reaction Methods 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 41
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 40
- 230000003115 biocidal effect Effects 0.000 claims description 33
- 239000000376 reactant Substances 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 31
- 229940078672 didecyldimethylammonium Drugs 0.000 claims description 29
- 239000001569 carbon dioxide Substances 0.000 claims description 28
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 28
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 25
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 22
- 229920006395 saturated elastomer Polymers 0.000 claims description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 15
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 14
- 239000004327 boric acid Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 13
- 239000003125 aqueous solvent Substances 0.000 claims description 13
- 239000000908 ammonium hydroxide Substances 0.000 claims description 12
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- FAEUZVNNXJDELC-UHFFFAOYSA-M didecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC FAEUZVNNXJDELC-UHFFFAOYSA-M 0.000 claims description 10
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 150000007942 carboxylates Chemical class 0.000 claims description 9
- 229910001510 metal chloride Inorganic materials 0.000 claims description 9
- 239000001099 ammonium carbonate Substances 0.000 claims description 8
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- OYEOMXKDDUASEI-UHFFFAOYSA-N carbonic acid;carboxy hydrogen carbonate Chemical compound OC(O)=O.OC(=O)OC(O)=O OYEOMXKDDUASEI-UHFFFAOYSA-N 0.000 claims description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 169
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 102
- 235000019441 ethanol Nutrition 0.000 description 48
- 238000011282 treatment Methods 0.000 description 35
- 230000000052 comparative effect Effects 0.000 description 33
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 31
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 28
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 24
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 24
- 239000000243 solution Substances 0.000 description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 description 20
- 239000011707 mineral Substances 0.000 description 20
- 235000010755 mineral Nutrition 0.000 description 19
- 239000000047 product Substances 0.000 description 19
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 18
- 239000002585 base Substances 0.000 description 18
- 235000015096 spirit Nutrition 0.000 description 18
- 239000000543 intermediate Substances 0.000 description 17
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 16
- 239000007787 solid Substances 0.000 description 16
- 238000003786 synthesis reaction Methods 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 15
- 235000011613 Pinus brutia Nutrition 0.000 description 15
- 241000018646 Pinus brutia Species 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 235000011114 ammonium hydroxide Nutrition 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 15
- 239000001103 potassium chloride Substances 0.000 description 15
- 235000011164 potassium chloride Nutrition 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 241000446313 Lamella Species 0.000 description 14
- 238000005260 corrosion Methods 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 230000004584 weight gain Effects 0.000 description 14
- 235000019786 weight gain Nutrition 0.000 description 14
- JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical compound CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 13
- 238000002386 leaching Methods 0.000 description 13
- 239000002244 precipitate Substances 0.000 description 13
- 125000004122 cyclic group Chemical group 0.000 description 12
- 235000019260 propionic acid Nutrition 0.000 description 12
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 10
- 238000011109 contamination Methods 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 238000006467 substitution reaction Methods 0.000 description 10
- HUCAMSNMGAEXCX-UHFFFAOYSA-M 6-hydroxyhexyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCCO HUCAMSNMGAEXCX-UHFFFAOYSA-M 0.000 description 9
- 244000060011 Cocos nucifera Species 0.000 description 9
- 235000013162 Cocos nucifera Nutrition 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- 125000002015 acyclic group Chemical group 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- XPZLPHAUBUNMEN-UHFFFAOYSA-M didecyl(dimethyl)azanium;acetate Chemical compound CC([O-])=O.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC XPZLPHAUBUNMEN-UHFFFAOYSA-M 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000008188 pellet Substances 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 8
- 235000011054 acetic acid Nutrition 0.000 description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- 229940050410 gluconate Drugs 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- MACIVYPRPJBSDB-UHFFFAOYSA-N 13-chlorotridecylbenzene Chemical compound C(C1=CC=CC=C1)CCCCCCCCCCCCCl MACIVYPRPJBSDB-UHFFFAOYSA-N 0.000 description 6
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 6
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 6
- BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 6
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 6
- 230000001680 brushing effect Effects 0.000 description 6
- 238000007598 dipping method Methods 0.000 description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 6
- 239000001589 sorbitan tristearate Substances 0.000 description 6
- 235000011078 sorbitan tristearate Nutrition 0.000 description 6
- 229960004129 sorbitan tristearate Drugs 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical compound CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 241000233866 Fungi Species 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 150000004679 hydroxides Chemical class 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- 229920001278 polyethylene glycol distearate Polymers 0.000 description 5
- 229910000027 potassium carbonate Inorganic materials 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000010454 slate Substances 0.000 description 5
- 239000001587 sorbitan monostearate Substances 0.000 description 5
- 235000011076 sorbitan monostearate Nutrition 0.000 description 5
- 229940035048 sorbitan monostearate Drugs 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- MAUMSNABMVEOGP-UHFFFAOYSA-N (methyl-$l^{2}-azanyl)methane Chemical compound C[N]C MAUMSNABMVEOGP-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910052785 arsenic Inorganic materials 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000003139 biocide Substances 0.000 description 4
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- TXOJCSIIFFMREV-UHFFFAOYSA-L didecyl(dimethyl)azanium;carbonate Chemical compound [O-]C([O-])=O.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC TXOJCSIIFFMREV-UHFFFAOYSA-L 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000006053 organic reaction Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 239000011877 solvent mixture Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 3
- 241001529936 Murinae Species 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- UBNVDFUEPGQZQS-UHFFFAOYSA-N acetic acid;n,n-dimethyldodecan-1-amine Chemical compound CC([O-])=O.CCCCCCCCCCCC[NH+](C)C UBNVDFUEPGQZQS-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 description 3
- 150000001805 chlorine compounds Chemical group 0.000 description 3
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 3
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- ACSHVUWFODGJQR-UHFFFAOYSA-M didecyl(dimethyl)azanium;2-ethylhexanoate Chemical compound CCCCC(CC)C([O-])=O.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC ACSHVUWFODGJQR-UHFFFAOYSA-M 0.000 description 3
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- 239000003112 inhibitor Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000005679 long-chain carbonates Chemical class 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- ATBNMWWDBWBAHM-UHFFFAOYSA-N n-decyl-n-methyldecan-1-amine Chemical compound CCCCCCCCCCN(C)CCCCCCCCCC ATBNMWWDBWBAHM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000059 polyethylene glycol stearate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- BWILYWWHXDGKQA-UHFFFAOYSA-M potassium propanoate Chemical compound [K+].CCC([O-])=O BWILYWWHXDGKQA-UHFFFAOYSA-M 0.000 description 1
- 239000004331 potassium propionate Substances 0.000 description 1
- 235000010332 potassium propionate Nutrition 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- CMDGQTVYVAKDNA-UHFFFAOYSA-N propane-1,2,3-triol;hydrate Chemical compound O.OCC(O)CO CMDGQTVYVAKDNA-UHFFFAOYSA-N 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000036280 sedation Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- VYPDUQYOLCLEGS-UHFFFAOYSA-M sodium;2-ethylhexanoate Chemical compound [Na+].CCCCC(CC)C([O-])=O VYPDUQYOLCLEGS-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- IJJNTMLAAKKCML-UHFFFAOYSA-N tribenzyl borate Chemical compound C=1C=CC=CC=1COB(OCC=1C=CC=CC=1)OCC1=CC=CC=C1 IJJNTMLAAKKCML-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/62—Quaternary ammonium compounds
- C07C211/63—Quaternary ammonium compounds having quaternised nitrogen atoms bound to acyclic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/14—Boron; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/62—Quaternary ammonium compounds
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/70—Hydrophobation treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/20—Compounds of alkali metals or ammonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
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Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.水酸化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル 第四級アンモニウムの製造方法において、 (a) 塩化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキ ル第四級アンモニウム反応物(reactant)と、金属水酸化物反応物とをC1〜C4 直鎖アルコールからなる溶媒中で反応させ、然も、前記金属水酸化物が前記水酸 化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル第四級アン モニウムを生成するのに充分な量で存在する、 ことからなる製造方法。 2.C1〜C20アルキル又はアリール置換アルキルが、メチル、C8〜C16アル キル、及びベンジル基からなる群から選択され、C8〜C20アルキル基がC10〜 C16アルキルである、請求項1に記載の方法。 3.アルキル基がジC8〜C12である、請求項1に記載の方法。 4.第四級アンモニウム化合物がジデシルジメチルアンモニウム化合物である 、請求項1に記載の方法。 5.金属水酸化物が水酸化カリウムからなる、請求項1〜4のいずれか1項に 記載の方法。 6.C1〜C4直鎖アルコールがエタノールからなる、請求項1〜5のいずれか 1項に記載の方法。 7.(a) 塩化ジデシルジメチルアンモニウムと水酸化カリウムとをエタノ ール中で反応させ、然も、前記水酸化カリウムが、前記塩化ジデシルジメチルア ンモニウムに対し少なくとも化学量論的量で存在する、 ことからなる水酸化ジデシルジメチルアンモニウムの製造方法。 8.請求項1〜7のいずれか1項に記載の方法により製造された組成物。 9.(a)殺生物に有効な量の少なくとも一種類の水酸化ジC8〜C12アルキ ル第四級アンモニウム、及び(b)溶媒からなり、然も、金属を含まない木材防 腐剤組成物。 10.水酸化ジC8〜C12アルキル第四級アンモニウムが水酸化ジデシルジメチ ルアンモニウムである、請求項13に記載の木材防腐剤組成物。 11.溶媒が水性溶媒である、請求項13に記載の木材防腐剤組成物。 12.水酸化ジC8〜C12アルキル第四級アンモニウムと溶媒とを一緒にしたも のを100重量部として、約0.1〜約5重量部の水酸化ジC8〜C12アルキル 第四級アンモニウム及び約95〜99.9重量部の溶媒からなる、請求項13に 記載の木材防腐剤組成物。 13.水酸化ジC8〜C12アルキル第四級アンモニウムが水酸化ジデシルジメチ ルアンモニウムである、請求項17に記載の木材防腐剤組成物。 14.請求項3に記載の方法により製造された少なくとも一種類の水酸化ジC8 〜C12アルキル第四級アンモニウムを殺生物に有効な量で含む木材防腐剤組成物 。 15.木質基材を、請求項13に記載の木材防腐剤組成物で処理することからな る、木質基材の防腐方法。 16.(a)式: (式中、R1は、C8〜C12アルキル基である。) を有する少なくとも一種類の炭酸ジC8〜C12アルキル第四級アンモニウム;及 び (b)(1)式: (式中、R1は、(a)の場合と同じか又は異なるC8〜C12アルキル基である。 ) を有する少なくとも一種類の炭酸水素C8〜C12アルキル第四級アンモニウム; 又は (2)式: (式中、R1は、(a)又は(b)の場合と同じか又は異なるC8〜C12アルキル 基であり、Mは非カップラー金属である。) を有する少なくとも一種類の炭酸金属ジC8〜C12アルキル第四級アンモニウム ;又は (3)(b)(1)及び(b)(2)の組合せ; からなる、金属カップラーを含まない木材防腐剤組成物。 17.(A)殺生物に有効な量の、式: (式中、R1は、C8〜C12アルキル基である。) を有する少なくとも一種類の炭酸ジC8〜C12アルキル第四級アンモニウム、及 び(B)溶媒からなる、金属カップラーを含まない木材防腐剤組成物。 18.(A)殺生物に有効な量の、請求項1に記載の少なくとも一種類の組成物 、及び(B)溶媒からなる木材防腐剤組成物。 19.炭酸ジC8〜C12アルキル第四級アンモニウムと溶媒とを一緒にしたもの を100重量部として、約0.1〜約5重量部の炭酸ジC8〜C12アルキル第四 級アンモニウム及び約95〜99.9重量部の溶媒からなる、請求項3に記載の 木材防腐剤組成物。 20.式: (式中、R1は、C1〜C20アルキル又はアリール置換アルキル基であり、R2は 、C8〜C12アルキル基である。) を有する炭酸C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル 第四級アンモニウムの製造方法において、 (a) 塩化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキ ル第四級アンモニウム反応物と金属水酸化反応物とを、C1〜C4直鎖アルコール からなる溶媒中で反応させ、然も、前記金属水酸化物が、水酸化C1〜C20アル キル又はアリール置換アルキル、C8〜C20アルキル第四級アンモニウム、金属 塩化物、及び任意に未反応金属水酸化物を生ずるのに充分な量で存在し、そして (b) 前記水酸化C1〜C20アルキル又はアリール置換C8〜C20アルキル又 はアリール置換アルキル、C8〜C20アルキル第四級アンモニウム及び任意に未 反応金属水酸化物と、二酸化炭素とを反応させ、前記炭酸C1〜C20アルキル又 はアリール置換アルキル、C8〜C20アルキル第四級アンモニウム及び任意に金 属炭酸塩を生成させる、 ことからなる製造方法。 21.式: を有する炭酸第四級アンモニウム化合物中のR1が、C8〜C12アルキル基である 、請求項20に記載の方法。 22.R1がC10アルキル基である、請求項21に記載の方法。 23.請求項17に記載の木材防腐剤組成物で木質基材を処理することからなる 、木質基材を防腐する方法。 24.請求項20、21、22、又は23のいずれか1項に記載の方法により製 造された組成物。 25.(a)殺生物に有効な量の、 (i)少なくとも一種類の、式: 〔式中、R1は、C8〜C12アルキル基であり;R3は、置換又は非置換、断続(i nterrupted)又は非断続C1〜C100基であり;l及びqは、独立に1、2又は3 であり、(l)(q)は1、2、又は3であり;nは、0又は1〜50の整数で ある。〕 を有するカルボン酸ジC8〜C12アルキル第四級アンモニウム; (ii)少なくとも一種類の、式: (式中、R1は上で定義した通りであり、aは2又は3であり、aが2の時、b は0又は1であり、aが3の時、bは0、1、又は2である。) を有する硼酸ジC8〜C12アルキル第四級アンモニウム;又は (iii)(i)及び(ii)の組合せ;及び (b)溶媒; からなる、金属を含まない木材防腐剤組成物。 26.R1がC10アルキル基であり、R3がアルキル又はアルケニル基である、請 求項25に記載の木材防腐剤組成物。 27.lが1又は2である、請求項25に記載の木材防腐剤組成物。 28.nが1〜20の整数である、請求項25に記載の木材防腐剤組成物。 29.ジC8〜C12アルキル第四級アンモニウムのカルボン酸塩、硼酸塩、又は それらの組合せ及び溶媒を一緒にしたものを100重量部として、約0.1〜約 5重量部のジC8〜C12アルキル第四級アンモニウムのカルボン酸塩、硼酸塩、 又はそれらの組合せ、及び約95〜約99.9重量部の溶媒からなる、請求項2 5に記載の木材防腐剤組成物。 30.式: 〔式中、R1は、C1〜C20アルキル又はアリール置換アルキル基であり;R2は 、C8〜C12アルキル基であり;R3は、置換又は非置換、断続又は非断続C1〜 C100基であり;l及びqは、独立に1、2又は3であり、(l)(q)は1、 2、又は3であり;nは、0又は1〜50の整数である。〕 を有するカルボン酸第四級アンモニウムの製造方法において、 (a) 塩化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキ ル第四級アンモニウム反応物と金属水酸化物反応物とを、C1〜C4直鎖アルコー ルからなる溶媒中で反応させ、然も、前記金属水酸化物が水酸化C1〜C20アル キル又はアリール置換アルキル、C8〜C20アルキル第四級アンモニウム、金属 塩化物、及び任意に未反応の金属水酸化物を生ずるのに充分な量で存在し、 (b) 前記水酸化C1〜C20アルキル又はアリール置換アルキル、C8〜C20 アルキル第四級アンモニウム及び任意に未反応金属水酸化物と、二酸化炭素とを 反応させ、炭酸C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキ ル第四級アンモニウム及び任意に金属炭酸塩を生成させ、 (c) 前記炭酸C1〜C20アルキル又はアリール置換アルキル、C8〜C20ア ルキル第四級アンモニウムと、式 〔式中、R3は、置換又は非置換、断続又は非断続C1〜C100基であり;l及び qは、独立に1、2、又は3であり、(l)(q)は1、2、又は3であり;n は、0又は1〜50の整数である。〕 を有する少なくとも一種類のカルボン酸と反応させ、前記カルボン酸C1〜C20 アルキル又はアリール置換アルキル、C8〜C20アルキル第四級アンモニウムを 生成させる、 ことからなるカルボン酸第四級アンモニウムの製造方法。 31.ジC8〜C12アルキル基がデシル基である、請求項30に記載の方法。 32.式: 〔式中、R1は、C1〜C20アルキル又はアリール置換アルキル基であり;R2は 、C8〜C20アルキル基であり:R3は、置換又は非置換、断続又は非断続C1〜 C100基であり;l及びqは、独立に1、2又は3であり、(l)(q)は1、 2、又は3であり;nは0又は1〜50の整数である。〕 を有するカルボン酸第四級アンモニウムの製造方法において、 (a) 塩化C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキ ル第四級アンモニウム反応物と、式: 〔式中、R3は、置換又は非置換、断続又は非断続C1〜C20基であり;Mは、一 価、二価、又は三価の金属であり;l及びqは、独立に1、2、又は3であり; (l)(q)は、1、2、又は3であり;lは、Mが一価の時1であり、Mが二 価の時2であり、Mが三価の時3であり:nは、0又は1〜50の整数であ る。〕 を有する少なくとも一種類の金属カルボン酸塩と、C1〜C4直鎖アルコールから なる溶媒中で反応させ、前記カルボン酸第四級アンモニウムを生成させる、こと からなるカルボン酸第四級アンモニウムの製造方法。 33.R1がC8〜C12アルキル基である、請求項30、31、又は32のいずれ か1項に記載の方法。 34.請求項30に記載の木材防腐剤組成物で木質基材を処理することからなる 、木質基材の防腐方法。 35.請求項30、31、又は32のいずれか1項に記載の方法に従い製造され た組成物。 36.式: R及びR2は、独立に飽和又は不飽和、置換又は非置換、断続又は非断 続C9〜C50基であり; R1は、水素又はメチル基であり;そして nは、1〜10の整数である。) を有する防水剤組成物であって、然も任意に、殺生物に有効な量の少なくとも一 種類のC1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル第四級 アンモニウム組成物、溶媒、又はそれらの組合せを含有する防水剤組成物。 水素であり、nが1である、請求項36に記載の防水剤組成物。 38.式: Yは、置換又は非置換 置換又は非置換 置換又は非置換 R3、R4、及びR5は、独立に飽和又は不飽和、置換又は非置換、断続 又は非断続C9〜C50基であり; wは、1〜10の整数であり;そして X及びyは、独立に0、1、又は2である。) を有する防水剤組成物であって、然も任意に、殺生物に有効な量の少なくとも一 種類の、C1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル第四 級アンモニウム組成物、溶媒、又はそれらの組合せを含む防水剤組成物。 39.Xが水素であり;R3がC11〜C17アルキル基であり;nが1である、請 求項38に記載の防水剤組成物。 40.Xが水素であり;R3がC11アルキル基であり;nが1である、請求項38 に記載の防水剤組成物。 41.Xが水素であり; Yが、 R3がC17アルキル基であり; xが2である; 請求項38に記載の防水剤組成物。 Yが、 R3、R4、及びR5が、夫々C17アルキル基であり; yが1であり; 然も、任意に、殺生物に有効な量の少なくとも一種類のC1〜C20アルキル又 はアリール置換アルキル、C8〜C20アルキル第四級アンモニウム組成物、溶媒 、又はそれらの組合せを含有する、請求項4に記載の防水剤組成物。 43.式: (式中、R6は飽和又は不飽和、置換又は非置換、断続又は非断続C6〜C30基で あり; pは、1〜30の整数である。) を有する防水剤組成物であって、任意に、殺生物に有効な量の少なくとも一種類 のC1〜C20アルキル又はアリール置換アルキル、C8〜C20アルキル第四級アン モニウム組成物、溶媒、又はそれらの組合せを含有する防水剤組成物。 44.R5がC18アルキル基又はp−ノニルフェニルであり、pが4である、請 求項43に記載の防水剤組成物。
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JP2004501622A (ja) * | 2000-06-27 | 2004-01-22 | キアゲン ゲゼルシャフト ミット ベシュレンクテル ハフツング | 原核生物、菌類、原生動物もしくは藻類などの微生物中で、または微生物から核酸を安定化および/または単離するための、カチオン化合物およびプロトン供与体からなる組成物の使用 |
JP2012135317A (ja) * | 2000-06-27 | 2012-07-19 | Qiagen Gmbh | 生物材料中の核酸を安定化および/または単離するための新規な組成物 |
JP2010501469A (ja) * | 2006-04-28 | 2010-01-21 | アルベマール・コーポレーシヨン | 第四級アンモニウム化合物を含有するコーティング、コーティング配合物および組成物 |
JP2010509238A (ja) * | 2006-11-03 | 2010-03-25 | アルベマール・コーポレーシヨン | カビ、ウドンコ病菌、および菌類の被害回復における第四級アンモニウム化合物の使用 |
JP2010513537A (ja) * | 2006-12-20 | 2010-04-30 | アルベマール・コーポレーシヨン | 新築および/または現存建造物中のカビ、うどん粉菌および菌・カビ防止における第四級アンモニウム化合物の使用 |
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JP2016124849A (ja) * | 2015-01-08 | 2016-07-11 | 株式会社ザイエンス | 防カビ組成物、木質材料の防カビ処理方法、および、木質材料 |
WO2022225049A1 (ja) * | 2021-04-23 | 2022-10-27 | ミヨシ油脂株式会社 | 抗菌剤とそれを用いた抗菌性組成物及び抗ウイルス性組成物 |
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