US3666690A - Skin cleansing composition - Google Patents

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US3666690A
US3666690A US3666690DA US3666690A US 3666690 A US3666690 A US 3666690A US 3666690D A US3666690D A US 3666690DA US 3666690 A US3666690 A US 3666690A
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percent
parts
skin
mineral oil
lanolin
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Robert Francis Bann
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Wyeth Holdings LLC
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Wyeth Holdings LLC
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid, cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid, cyclodextrin etherified, e.g. CMC
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/19Cosmetics or similar toilet preparations characterised by the composition containing inorganic ingredients
    • A61K8/23Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/02Preparations for care of the skin for chemically bleaching or whitening the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0042Reducing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424Polymers characterized by specific structures/properties characterized by the charge anionic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S514/00Drug, bio-affecting and body treating compositions
    • Y10S514/937Dispersion or emulsion
    • Y10S514/938Oil-water type
    • Y10S514/939Mineral oil-water type
    • Y10S514/941Polyoxyalkylated compound containing

Abstract

A skin-cleansing composition for the removal of dye stains caused by basic triphenylmethane dyes, such as malachite green, comprising, in defined proportions, (1) a cationic surface-active quaternary ammonium salt containing a long-chain alkyl substituent, (2) mineral oil, (3) lanolin, (4) glycerine, (5) an alkali metal sulfite, (6) sodium carboxymethyl cellulose and (7) water.

Description

United States Patent Bann [54] SKIN CLEANSING COMPOSITION [72] Inventor: Robert Francis Bann, Bn'dgewater Township, Somerset County, Nd,

[73] Assignee: American Cyanamid Company, Stamford,

Conn.

[22] Filed: Nov. 12, 1970 [21] App1.No.: 89,065

2,948,686 8/1960 Gianladis ..252/ 153 [451 May 30, 1972 3,178,371 4/1965 Friedenberg ..252/153 3,207,694 9/ 1965 Gogek ..252/105 3,400,079 9/1968 Clifford et a] ..252/105 X Primary Examiner-Richard D. Lovering Attorney-John L. Sullivan [5 7] ABSTRACT A skin-cleansing composition for the removal of dye stains caused by basic triphcnylmethane dyes, such as malachite green, comprising, in defined proportions, (l) a cationic surface-active quaternary ammonium salt containing a longchain alkyl substituent, (2) mineral oil, (3) lanolin, (4) glycerine, (5) an alkali metal sulfite, (6) sodium carboxymethyl cellulose and (7) water.

4 Claims, No Drawings SKIN CLEANSING COMPOSITION This invention relates to a skin cleansing composition. More particularly, this invention relates to a hand cream for removing dye stains from the skin.

Dye stains are difficult to remove from the skin. Probably the most difficultly removable dye stains are those from basic triphenylmethane dyes such as malachite green and methyl violet. These are intensely colored materials of great tinctorial strength. The stains produced on the skin by these dyes are resistant to removal and cannot be washed off with ordinary soaps and detergents. Special hand cleaners available on the market are of little or no help. Many of these cleaners contain abrasives and are designed for the use of mechanics and others to remove grease and related stains. It has been a customary practice in many dye laboratories and manufacturing plants to remove the dye stains by application of strong bleaches, such as sodium hypochlorite and potassium permanganate. The latter requires the subsequent use of a reducing agent to remove the brown stain left by the permanganate. Strong bleaching compounds are detrimental to the skin. Therefore, a completely satisfactory cleaner has not been available for removing stains caused by basic triphenylmethane dyes from the skin without damage to the skin.

The object of this invention is to provide an effective skin cleansing agent for removal of dye stains caused by basic triphenylmethane dyes.

It is a further object of this invention to provide a cleaner which not only removes the dye stains, but does so without damage to the skin.

A stable composition has now been discovered which will remove from the skin stains caused by basic triphenylmethane dyes, particularly malachite green, fuchsine and methyl violet stains, and will not damage the skin. The components of the composition are a cationic surface active agent, a mineral oil, an alkali metal sulfite, lanolin, glycerine, water and a thickening agent. Optional components include a nonionic surface active agent and a buffering agent to maintain near neutral conditions. I

The cationic surface active agents of use in this invention are quaternary ammonium salts containing a long-chain alkyl group of from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, such as, for example, cetyl dimethyl ethyl ammonium bromide or stearyl dimethyl benzyl ammonium chloride. The salt may also contain one or two polyethoxylated groups, i.e., -(CH CH,0),,H in which n is an integer of from about 5 to about 15, such as, for example, di(polyethoxylated) stearyl methyl ammonium chloride and di(polyethoxylated) coco methyl ammonium chloride (coco" being a mixed long-chain (C -C, )-alkyl). The quaternary ammonium salts suitable for the composition of the invention will conform to the formula:

wherein R is methyl, ethyl or -(CH CH,O),,H in which n is an integer of from 5 to l5; R is lower (C,-C )alkyl, benzyl or (CH Cl-l 0bnl-l; and X is chloride or bromide.

The mineral oil of use in this invention is of the light mineral oil type and includes kerosene. A preferred white mineral oil has an SVS viscosity of 70-74 at 100F., a specific gravity at 60F. of 0.8575 and a pour point of +10"F.

The alkali metal sulfites of use include sodium sulfite, sodium bisulfite, potassium sulfite, and potassium bisulfite. Sodium bisulfite is preferred for economic reasons.

The nonionic surface active agents enhance the detergency of the cleaning composition. Representative types of nonionic surface active agents which may be used include the polyethoxylated long-chain alkylphenols, such as the reaction products of nonylphenol with from 4 to 30 moles of ethylene oxide per mole of nonylphenol, and glycol monoesters of longchain fatty acids of from 12 to 22 carbon atoms, such as propylene glycol monostearate. The preferred nonionic surface active agent is the condensation product of nonylphenol and about 9.5 moles of ethylene oxide.

The thickening agent provides a stabilized product that is a cream and is easily applied to the skin. Without the thickening agent, the product of this invention is a liquid emulsion. Suitable thickening agents include sodium carboxymethylcellulose.

The buffering agent neutralizes any residual acidity of the components of the cleanser. Obviously, the presence of strong acid in the cleansing composition is undesirable. Alkali metal salts of lower fatty acids, as represented by sodium acetate or potassium acetate, are suitable buffering agents.

The cleansing composition should contain between 3 and 12 percent, preferably between 6 and 10 percent, of the cationic surface active agent; between 5 and 20 percent, preferably between 7 and 10 percent, of the mineral oil; between 3 and 25 percent, preferably between 5 and 20 percent, of alkali metal sulfite; between 2 and 6 percent, preferably between 3 and 5 percent, of lanolin; between 5 and 18 percent, preferably between 10 and 15 percent, of glycerine; and between 30 and 50 percent, preferably between 35 and 45 percent, of water. The thickening agent should be used in an amount to provide the desired gel or cream. in the case of sodium carboxymethylcellulose, the amount is between 2 and 12 percent, normally between 5 and 8 percent. The amount of nonionic surface active agent is between 0 and I5 percent, preferably between 7 and 12 percent. The amount of bufi'ering agent, if used, is sufi'lcient to neutralize any strong acidity. For sodium acetate, the amount is between 0 and 2.5 percent, normally between 0.5 and 1 percent.

In a preferred embodiment of this invention, the composition contains about 8.3 percent of cetyl dimethyl ethyl ammonium bromide, about 8.6 percent of mineral oil, about 4.1 percent of lanolin, about 13 percent of glycerine, about 10.9 percent of the condensation product of nonylphenol and 9.5 moles of ethylene oxide, about 41 percent water, about 0.6 percent of sodium acetate, about 6.2 percent of sodium bisulfite and 6.8 percent of sodium carboxymethylcellulose.

The components of the cleansing composition can be combined in several different orders or sequences. In a particularly convenient procedure, the cationic surface active agent, mineral oil and lanolin, are melted together and to the mixture with good stirring are added the glycerine and nonionic surface active agent. The solution of the alkali metal sulfite and buffering compound in warm water is added followed by the thickening agent. The stirring is continued briefly and the mixture is then cooled.

The cleansing composition of this invention is a stable, soft cream which is easily applied to the skin. The cleansing cream is applied to the hands and the cream is worked into the skin until the stains are removed. When the stains have been removed, the excess cream can be wiped off or it can be flushed off with water.

EXAMPLE 1 A mixture of 400 parts of cetyl dimethyl ethyl ammonium bromide, 415 parts of mineral oil and 200 parts of lanolin is melted, and to the melt with good stirring there are added 630 parts of glycerine and 525 parts of the condensation product of 1 mole of nonylphenol with about 9.5 moles of ethylene oxide. With vigorous stirring, 2,000 parts of warm water, 30 parts of sodium acetate, 300 parts of sodium bisulfite and 325 parts of sodium carboxymethylcellulose are added. The mixture is stirred for about 30 minutes and is then cooled. The product removes stains of malachite green, fuchsine and methyl violet from the skin and leaves the skin soft.

EXAMPLE 2 A mixture of 50 parts of propylene glycol monostearate and 200 parts of cetyl dimethyl ethyl ammonium bromide is melted, and 210 parts of mineral oil, parts of lanolin, 315

parts of glycerine, 1,000 parts of water, 500 parts of sodium bisulfite, 50 parts of sodium acetate and 95 parts of sodium carboxymethylcellulose are added in the stated order with good stirring.

The product removes stains of methyl violet, fuchsine and malachite green from the skin and leaves the skin soft.

EXAMPLE 3 A mixture of 100 parts of propylene glycol monostearate and 100 parts of di(polyethoxylated) stearyl methyl ammonium chloride (containing a total of 15 ethylene oxide units per molecule) and 415 parts of mineral oil is melted, and while the mixture is vigorously stirred, a solution of 500 parts of sodium bisulfite in 1,000 parts of water is slowly added. The thin solution is then thickened by addition of 200 parts of sodium carboxymethylcellulose. A solution of 90 parts of lanolin in 200 parts of glycerine is then added.

The product removes stains of malachite green, fuchsine and methyl violet from the skin and leaves the skin soft.

EXAMPLE 4 To a stirred mixture of 100 parts of di(polyethoxylated) stearyl methyl ammonium chloride (containing a total of 15 ethylene oxide units per molecule) and 415 parts of mineral oil, there is added a solution of 500 parts of sodium bisulfite in 1,000 parts of water. The resulting solution is heated to 90C. and stirred with cooling. Sodium carboxymethylcellulose (200 parts) is added, followed by a solution of 90 parts of lanolin in 250 parts of glycerine.

The product removes stains of malachite green, fuchsine and methyl violet from the skin and leaves the skin soft.

I claim:

1. A hand cleansing composition consisting essentially of:

1. from about 3 to about 12 percent of a cationic quaternary ammonium salt of the formula:

wherein R is methyl, ethyl or -(CH CH O),,H in which n is an integer of from 5 to 15; R is lower alkyl, benzyl or (CH CH O),,H; and X is chloride or bromide;

2. from about 5 to about 20 percent of mineral oil;

3. from about 2 to about 6 percent of lanolin;

4. from about 5 to about 18 percent of glycerine;

5. from about 3 to about 25 percent of an alkali metal sulfite;

6. from about 2 to about 12 percent of sodium carboxymethylcellulose; and

7. from about 30 to about 50 percent of water.

2. A composition according to Claim 1 containing up to about 15 percent of a non-ionic surface active agent selected from (a) a condensation product of 1 mole proportion of nonylphenol with from 4 to 30 mole proportions of ethylene oxide and (b) a glycol monoester of a long-chain fatty acid.

3. A composition according to Claim 2 containing up to about 2.5 percent of an alkali metal acetate as buffering agent.

4. A composition according to claim 1 containing:

1. from 6 to 10 percent of cetyl dimethyl ethyl ammonium bromide;

2. from 7 to 10 percent of mineral oil;

3. from 3 to 5 percent lanolin;

4. from 10-15 percent glycerine; V

5. from 10 to 15 percent sodium bisulfite;

6. from 5 to 8 percent sodium carboxymethylcellulose;

7. from 35-45 percent of water;

8. from 7-12 percent of the condensation product of 1 mole proportion of nonylphenol and 9.5 mole proportions of ethylene oxide; and

9. from 0.5 to 1 percent of sodium acetate.

Claims (17)

  1. 2. from 7 to 10 percent of mineral oil;
  2. 2. from about 5 to about 20 percent of mineral oil;
  3. 2. A composition according to Claim 1 containing up to about 15 percent of a non-ionic surface active agent selected from (a) a condensation product of 1 mole proportion of nonylphenol with from 4 to 30 mole proportions of ethylene oxide and (b) a glycol monoester of a long-chain fatty acid.
  4. 3. A composition according to Claim 2 containing up to about 2.5 percent of an alkali metal acetate as buffering agent.
  5. 3. from about 2 to about 6 percent of lanolin;
  6. 3. from 3 to 5 percent lanolin;
  7. 4. from 10-15 percent glycerine;
  8. 4. from about 5 to about 18 percent of glycerine;
  9. 4. A composition according to claim 1 containing:
  10. 5. from about 3 to about 25 percent of an alkali metal sulfite;
  11. 5. ''from 10 to 15 percent sodium bisulfite;
  12. 6. from 5 to 8 percent sodium carboxymethylcellulose;
  13. 6. from about 2 to about 12 percent of sodium carboxymethylcellulose; and
  14. 7. from about 30 to about 50 PERCENT of water.
  15. 7. from 35-45 percent of water;
  16. 8. from 7-12 percent of the condensation product of 1 mole proportion of nonylphenol and 9.5 mole proportions of ethylene oxide; and
  17. 9. from 0.5 to 1 percent of sodium acetate.
US3666690A 1970-11-12 1970-11-12 Skin cleansing composition Expired - Lifetime US3666690A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4295985A (en) * 1979-10-25 1981-10-20 Petrow Henry G Method of removal of chlorine retained by human skin and hair after exposure to chlorinated water, and soap and shampoo compositions adapted to effect said removal
US4476044A (en) * 1982-05-13 1984-10-09 Henkel Corporation Surfactant product
US4707189A (en) * 1984-11-07 1987-11-17 Hercules Incorporated Biostable compositions and the aqueous solutions thereof as thickeners for aqueous-based systems
US4708813A (en) * 1985-08-14 1987-11-24 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
US4798682A (en) * 1985-06-18 1989-01-17 Henkel Kommanditgesellschaft Auf Aktien Oil-in-water emulsions with increased viscosity under shear stress
US4806262A (en) * 1985-08-14 1989-02-21 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
EP0318279A2 (en) * 1987-11-26 1989-05-31 Unilever Plc Machine dishwashing compositions
US4950475A (en) * 1988-07-19 1990-08-21 Imaginative Research Associates, Inc. Novel film-forming gels with high concentrations of humectants and emollients
WO1994028715A1 (en) * 1993-06-09 1994-12-22 Lonza Inc. Quaternary ammonium and waterproofing/preservative compositions
US5855817A (en) * 1993-06-09 1999-01-05 Lonza, Inc. Waterproofing and preservative compositions and preparation thereof
US6136775A (en) * 1998-12-18 2000-10-24 Kimberly-Clark Worldwide, Inc. Wet wipe with non-aqueous, oil-based solvent for industrial cleaning
US20040231070A1 (en) * 2003-05-19 2004-11-25 The Procter & Gamble Company Cosmetic compositions comprising a polymer and a colorant
US20050116198A1 (en) * 2001-11-08 2005-06-02 Douglas Ryan Stabilisation of particulate material using wool grease
WO2008058717A2 (en) * 2006-11-17 2008-05-22 Beiersdorf Ag Cosmetic preparations having a high glycerol content
WO2010125050A2 (en) * 2009-04-28 2010-11-04 Pastaclean Gmbh Cleaning paste

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948686A (en) * 1955-07-14 1960-08-09 G H Packwood Mfg Company Thixotropic and fast breaking skin cleaner emulsion and process for producing the same
US3178371A (en) * 1960-10-31 1965-04-13 David L Berman Lipstick removing methods
US3207694A (en) * 1961-05-26 1965-09-21 Colgate Palmolive Co Compositions for and processes of removing stains
US3400079A (en) * 1966-12-12 1968-09-03 Riegel Textile Corp Formaldehyde absorbent composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948686A (en) * 1955-07-14 1960-08-09 G H Packwood Mfg Company Thixotropic and fast breaking skin cleaner emulsion and process for producing the same
US3178371A (en) * 1960-10-31 1965-04-13 David L Berman Lipstick removing methods
US3207694A (en) * 1961-05-26 1965-09-21 Colgate Palmolive Co Compositions for and processes of removing stains
US3400079A (en) * 1966-12-12 1968-09-03 Riegel Textile Corp Formaldehyde absorbent composition

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4295985A (en) * 1979-10-25 1981-10-20 Petrow Henry G Method of removal of chlorine retained by human skin and hair after exposure to chlorinated water, and soap and shampoo compositions adapted to effect said removal
US4476044A (en) * 1982-05-13 1984-10-09 Henkel Corporation Surfactant product
US4707189A (en) * 1984-11-07 1987-11-17 Hercules Incorporated Biostable compositions and the aqueous solutions thereof as thickeners for aqueous-based systems
US4798682A (en) * 1985-06-18 1989-01-17 Henkel Kommanditgesellschaft Auf Aktien Oil-in-water emulsions with increased viscosity under shear stress
US4806262A (en) * 1985-08-14 1989-02-21 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
US4708813A (en) * 1985-08-14 1987-11-24 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
EP0318279A2 (en) * 1987-11-26 1989-05-31 Unilever Plc Machine dishwashing compositions
EP0318279A3 (en) * 1987-11-26 1990-04-04 Unilever Plc Machine dishwashing compositions
US4950475A (en) * 1988-07-19 1990-08-21 Imaginative Research Associates, Inc. Novel film-forming gels with high concentrations of humectants and emollients
US5855817A (en) * 1993-06-09 1999-01-05 Lonza, Inc. Waterproofing and preservative compositions and preparation thereof
WO1994028715A1 (en) * 1993-06-09 1994-12-22 Lonza Inc. Quaternary ammonium and waterproofing/preservative compositions
US6136775A (en) * 1998-12-18 2000-10-24 Kimberly-Clark Worldwide, Inc. Wet wipe with non-aqueous, oil-based solvent for industrial cleaning
US20050116198A1 (en) * 2001-11-08 2005-06-02 Douglas Ryan Stabilisation of particulate material using wool grease
US20040231070A1 (en) * 2003-05-19 2004-11-25 The Procter & Gamble Company Cosmetic compositions comprising a polymer and a colorant
US7837742B2 (en) 2003-05-19 2010-11-23 The Procter & Gamble Company Cosmetic compositions comprising a polymer and a colorant
WO2008058717A2 (en) * 2006-11-17 2008-05-22 Beiersdorf Ag Cosmetic preparations having a high glycerol content
WO2008058717A3 (en) * 2006-11-17 2009-05-22 Beiersdorf Ag Cosmetic preparations having a high glycerol content
WO2010125050A2 (en) * 2009-04-28 2010-11-04 Pastaclean Gmbh Cleaning paste
WO2010125050A3 (en) * 2009-04-28 2011-01-13 Pastaclean Gmbh Cleaning paste

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