JPH08509772A - グラフト改質した実質的に線状であるエチレンポリマー類と他の熱可塑性ポリマー類とのブレンド物 - Google Patents
グラフト改質した実質的に線状であるエチレンポリマー類と他の熱可塑性ポリマー類とのブレンド物Info
- Publication number
- JPH08509772A JPH08509772A JP6524447A JP52444794A JPH08509772A JP H08509772 A JPH08509772 A JP H08509772A JP 6524447 A JP6524447 A JP 6524447A JP 52444794 A JP52444794 A JP 52444794A JP H08509772 A JPH08509772 A JP H08509772A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- polymer
- substantially linear
- linear ethylene
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. エチレン系不飽和部位を少なくとも1つとカルボキシル基を少なくとも 1つ有する不飽和有機化合物をグラフト化エチレンポリマーの重量を基準にして 少なくとも0.01重量%の量で用いてグラフト化した少なくとも1種の実質的 に線状であるエチレンポリマーと少なくとも1種の熱可塑性ポリマーとの実質的 に均一なブレンド物を含む組成物であって、該エチレンポリマーが、 (i)メルトフロー比I10/I2が≧5.63であり、 (ii)方程式:Mw/Mn≦(I10/I2)−4.63で定義される分子量 分布Mw/Mnを有し、 (iii)0.850g/cm3以上の密度を有し、かつ (iv)表面メルトフラクチャーが起こり始める時の臨界せん断速度が、ほ ぼ同じI2とMw/Mnを有する線状オレフィンポリマーの表面メルトフラクチャ ーが起こり始める時の臨界せん断速度より、少なくとも50%大きい、 として特徴づけられる組成物。 2. 該実質的に線状であるエチレンポリマーが、重合したエチレンモノマー を約95から50重量%の範囲で含むと共に3から約20個の炭素原子を有する 少なくとも1種の重合したアルファ−オレフィンコモノマーを約5から50重量 %の範囲で含む請求の範囲第1項の組成物。 3. 該実質的に線状であるエチレンポリマーが約0.860から約0.93 5g/cm3の範囲の密度を有する請求の範囲第2項の組成物。 4. 該実質的に線状であるエチレンポリマーが約6.5から15のメルトフ ロー比を示す請求の範囲第3項の組成物。 5. 該実質的に線状であるエチレンポリマーが約0.5から200g/10 分のメルトインデックスを示す請求の範囲第4項の組成物。 6. 該実質的に線状であるエチレンポリマーがゲル浸透クロマトグラフィー で測定して約1.8から2.5の範囲の分子量分布を示す請求の範囲第5項の組 成物。 7. 該実質的に線状であるエチレンポリマーが、プロピレン、1−ブテン、 1−ヘキセン、4−メチル−1−ペンテンおよび1−オクテンから成る群から選 択される少なくとも1種のコモノマーとエチレンとのインターポリマーである請 求の範囲第6項の組成物。 8. 該実質的に線状であるエチレンポリマーが、1−ブテン、1−ヘキセン 、4−メチル−1−ペンテンまたは1−オクテンとエチレンとのコポリマーであ る請求の範囲第7項の組成物。 9. 該実質的に線状であるエチレンポリマーがエチレンと1−オクテンとの コポリマーである請求の範囲第6項の組成物。 10. 該不飽和有機化合物がマレイン酸、アクリル酸、メタアクリル酸、イ タコン酸、クロトン酸、アルファ−メチルクロトン酸および桂皮酸、それらの無 水物、エステルおよび金属塩、並びにフマル酸およびそれのエステルおよび金属 塩から成る群から選択される請求の範囲第6項の組成物。 11. 該不飽和有機化合物が無水マレイン酸である請求の範囲第7項の組成 物。 12. 該グラフト化させた不飽和有機化合物が該グラフト化したポリマーの 重量の約0.05から約10%の範囲である請求の範囲第1項の組成物。 13. 該熱可塑性ポリマーがポリウレタン、ポリカーボネート、ポリスチレ ン、ポリエステル、エポキシ、ポリアミドおよび極性基含有ポリオレフィンの少 なくとも1種を含む請求の範囲第1項の組成物。 14. グラフト化していない実質的に線状であるエチレンポリマーを更に含 む請求の範囲第13項の組成物。 15. 該熱可塑性ポリマーがポリエステルである請求の範囲第1項の組成物 。 16. 該熱可塑性ポリマーがポリアミドである請求の範囲第1項の組成物。 17. 該熱可塑性ポリマーがEAA、EVA、ECO、EPCOおよびEC OAAの少なくとも1種である請求の範囲第1項の組成物。 18. 充填材を更に含む請求の範囲第1項の組成物。 19. 該充填材がシリカ、タルク、ガラス、粘土およびカーボンブラックの 少なくとも1種である請求の範囲第18項の組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/054,376 US5346963A (en) | 1993-04-28 | 1993-04-28 | Graft-modified, substantially linear ethylene polymers and methods for their use |
US08/054,376 | 1993-04-28 | ||
PCT/US1994/004512 WO1994025526A1 (en) | 1993-04-28 | 1994-04-25 | Blends of graft-modified substantially linear ethylene polymers and other thermoplastic polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08509772A true JPH08509772A (ja) | 1996-10-15 |
JP3428649B2 JP3428649B2 (ja) | 2003-07-22 |
Family
ID=21990623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52444794A Expired - Lifetime JP3428649B2 (ja) | 1993-04-28 | 1994-04-25 | グラフト改質した実質的に線状であるエチレンポリマー類と他の熱可塑性ポリマー類とのブレンド物 |
Country Status (13)
Country | Link |
---|---|
US (2) | US5346963A (ja) |
EP (1) | EP0696303B1 (ja) |
JP (1) | JP3428649B2 (ja) |
KR (1) | KR100330606B1 (ja) |
CN (1) | CN1057550C (ja) |
AU (1) | AU6773394A (ja) |
BR (1) | BR9406669A (ja) |
DE (1) | DE69419146T2 (ja) |
ES (1) | ES2132403T3 (ja) |
FI (1) | FI955149A0 (ja) |
SI (1) | SI9420033B (ja) |
TW (1) | TW459014B (ja) |
WO (1) | WO1994025526A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1129702A (ja) * | 1997-05-16 | 1999-02-02 | Mitsui Chem Inc | ポリアミド樹脂組成物および製造方法 |
JP2015535311A (ja) * | 2012-11-05 | 2015-12-10 | ダウ グローバル テクノロジーズ エルエルシー | 官能化ポリマー組成物およびそれから形成されるフィルム |
JP2020502343A (ja) * | 2016-12-19 | 2020-01-23 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 良好な機械特性を有する熱可塑性組成物 |
WO2021131814A1 (ja) * | 2019-12-24 | 2021-07-01 | ユニチカ株式会社 | フィルムおよびそれからなる積層体 |
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US5364909A (en) * | 1992-07-23 | 1994-11-15 | Arco Chemical Technology, L.P. | Graft polymer compositions containing mono-amine functionalized polyoxyalkylene ethers |
CA2103401C (en) * | 1992-11-19 | 2002-12-17 | Mamoru Takahashi | Ethylene copolymer composition |
-
1993
- 1993-04-28 US US08/054,376 patent/US5346963A/en not_active Expired - Lifetime
-
1994
- 1994-04-25 AU AU67733/94A patent/AU6773394A/en not_active Abandoned
- 1994-04-25 CN CN94191944A patent/CN1057550C/zh not_active Expired - Lifetime
- 1994-04-25 KR KR1019950704719A patent/KR100330606B1/ko not_active IP Right Cessation
- 1994-04-25 ES ES94915876T patent/ES2132403T3/es not_active Expired - Lifetime
- 1994-04-25 WO PCT/US1994/004512 patent/WO1994025526A1/en active IP Right Grant
- 1994-04-25 SI SI9420033A patent/SI9420033B/sl unknown
- 1994-04-25 JP JP52444794A patent/JP3428649B2/ja not_active Expired - Lifetime
- 1994-04-25 BR BR9406669A patent/BR9406669A/pt not_active Application Discontinuation
- 1994-04-25 EP EP94915876A patent/EP0696303B1/en not_active Expired - Lifetime
- 1994-04-25 DE DE69419146T patent/DE69419146T2/de not_active Expired - Lifetime
- 1994-04-27 TW TW083103803A patent/TW459014B/zh not_active IP Right Cessation
- 1994-09-09 US US08/304,037 patent/US5705565A/en not_active Expired - Lifetime
-
1995
- 1995-10-27 FI FI955149A patent/FI955149A0/fi unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1129702A (ja) * | 1997-05-16 | 1999-02-02 | Mitsui Chem Inc | ポリアミド樹脂組成物および製造方法 |
JP2015535311A (ja) * | 2012-11-05 | 2015-12-10 | ダウ グローバル テクノロジーズ エルエルシー | 官能化ポリマー組成物およびそれから形成されるフィルム |
JP2020502343A (ja) * | 2016-12-19 | 2020-01-23 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 良好な機械特性を有する熱可塑性組成物 |
WO2021131814A1 (ja) * | 2019-12-24 | 2021-07-01 | ユニチカ株式会社 | フィルムおよびそれからなる積層体 |
Also Published As
Publication number | Publication date |
---|---|
JP3428649B2 (ja) | 2003-07-22 |
CN1057550C (zh) | 2000-10-18 |
DE69419146D1 (de) | 1999-07-22 |
FI955149A (fi) | 1995-10-27 |
TW459014B (en) | 2001-10-11 |
BR9406669A (pt) | 1996-01-23 |
SI9420033A (en) | 1996-08-31 |
SI9420033B (sl) | 2002-02-28 |
ES2132403T3 (es) | 1999-08-16 |
US5346963A (en) | 1994-09-13 |
DE69419146T2 (de) | 1999-10-14 |
EP0696303A1 (en) | 1996-02-14 |
AU6773394A (en) | 1994-11-21 |
EP0696303B1 (en) | 1999-06-16 |
US5705565A (en) | 1998-01-06 |
CN1122144A (zh) | 1996-05-08 |
FI955149A0 (fi) | 1995-10-27 |
KR100330606B1 (ko) | 2002-11-30 |
WO1994025526A1 (en) | 1994-11-10 |
KR960701948A (ko) | 1996-03-28 |
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