JP5877510B2 - Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池 - Google Patents

Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池 Download PDF

Info

Publication number
JP5877510B2
JP5877510B2 JP2011548934A JP2011548934A JP5877510B2 JP 5877510 B2 JP5877510 B2 JP 5877510B2 JP 2011548934 A JP2011548934 A JP 2011548934A JP 2011548934 A JP2011548934 A JP 2011548934A JP 5877510 B2 JP5877510 B2 JP 5877510B2
Authority
JP
Japan
Prior art keywords
target
alkali metal
cigs
film
absorption layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2011548934A
Other languages
English (en)
Japanese (ja)
Other versions
JPWO2011083647A1 (ja
Inventor
正克 生澤
正克 生澤
英生 高見
英生 高見
友哉 田村
友哉 田村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JX Nippon Mining and Metals Corp
Original Assignee
JX Nippon Mining and Metals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JX Nippon Mining and Metals Corp filed Critical JX Nippon Mining and Metals Corp
Priority to JP2011548934A priority Critical patent/JP5877510B2/ja
Publication of JPWO2011083647A1 publication Critical patent/JPWO2011083647A1/ja
Application granted granted Critical
Publication of JP5877510B2 publication Critical patent/JP5877510B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • C23C14/3414Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/032Inorganic materials including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312
    • H01L31/0322Inorganic materials including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312 comprising only AIBIIICVI chalcopyrite compounds, e.g. Cu In Se2, Cu Ga Se2, Cu In Ga Se2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/541CuInSe2 material PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)
  • Physical Vapour Deposition (AREA)
  • Powder Metallurgy (AREA)
JP2011548934A 2010-01-07 2010-12-03 Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池 Active JP5877510B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2011548934A JP5877510B2 (ja) 2010-01-07 2010-12-03 Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2010002058 2010-01-07
JP2010002058 2010-01-07
PCT/JP2010/071661 WO2011083647A1 (ja) 2010-01-07 2010-12-03 Cu-Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池
JP2011548934A JP5877510B2 (ja) 2010-01-07 2010-12-03 Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2014177040A Division JP5923569B2 (ja) 2010-01-07 2014-09-01 Cu−Ga系スパッタリングターゲット

Publications (2)

Publication Number Publication Date
JPWO2011083647A1 JPWO2011083647A1 (ja) 2013-05-13
JP5877510B2 true JP5877510B2 (ja) 2016-03-08

Family

ID=44305385

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2011548934A Active JP5877510B2 (ja) 2010-01-07 2010-12-03 Cu−Ga系スパッタリングターゲット、同ターゲットの製造方法、光吸収層及び該光吸収層を用いた太陽電池
JP2014177040A Active JP5923569B2 (ja) 2010-01-07 2014-09-01 Cu−Ga系スパッタリングターゲット

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2014177040A Active JP5923569B2 (ja) 2010-01-07 2014-09-01 Cu−Ga系スパッタリングターゲット

Country Status (3)

Country Link
JP (2) JP5877510B2 (zh)
TW (1) TWI583811B (zh)
WO (1) WO2011083647A1 (zh)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4831258B2 (ja) * 2010-03-18 2011-12-07 三菱マテリアル株式会社 スパッタリングターゲット及びその製造方法
JP5725610B2 (ja) * 2011-04-29 2015-05-27 三菱マテリアル株式会社 スパッタリングターゲット及びその製造方法
JP5795898B2 (ja) * 2011-07-28 2015-10-14 株式会社アルバック CuGaNa系スパッタリング用ターゲット
JP5795897B2 (ja) * 2011-07-28 2015-10-14 株式会社アルバック CuGaNa系スパッタリング用ターゲット
JP5165100B1 (ja) 2011-11-01 2013-03-21 三菱マテリアル株式会社 スパッタリングターゲット及びその製造方法
JP5999357B2 (ja) * 2012-02-24 2016-09-28 三菱マテリアル株式会社 スパッタリングターゲット及びその製造方法
CN102751388B (zh) * 2012-07-18 2015-03-11 林刘毓 一种铜铟镓硒薄膜太阳能电池的制备方法
JP5783984B2 (ja) * 2012-09-26 2015-09-24 株式会社東芝 光電変換素子と太陽電池及びこれらの製造方法
JP6311912B2 (ja) 2012-10-17 2018-04-18 三菱マテリアル株式会社 Cu−Ga二元系スパッタリングターゲット及びその製造方法
JP6365922B2 (ja) 2013-04-15 2018-08-01 三菱マテリアル株式会社 スパッタリングターゲット及びその製造方法
JP5733357B2 (ja) * 2013-08-02 2015-06-10 住友金属鉱山株式会社 Cu−Ga合金スパッタリングターゲット
JP6665428B2 (ja) * 2014-07-08 2020-03-13 三菱マテリアル株式会社 Cu−Ga合金スパッタリングターゲット及びその製造方法
JP5973041B2 (ja) * 2014-08-28 2016-08-17 三菱マテリアル株式会社 Cu−Gaスパッタリングターゲット及びCu−Gaスパッタリングターゲットの製造方法
TWI551704B (zh) * 2015-05-21 2016-10-01 China Steel Corp Copper gallium alloy composite sodium element target manufacturing method
JP6794850B2 (ja) * 2016-02-08 2020-12-02 三菱マテリアル株式会社 スパッタリングターゲット及びスパッタリングターゲットの製造方法
WO2018021105A1 (ja) 2016-07-29 2018-02-01 三菱マテリアル株式会社 Cu-Gaスパッタリングターゲット及びCu-Gaスパッタリングターゲットの製造方法
JP6531816B1 (ja) * 2017-12-22 2019-06-19 三菱マテリアル株式会社 Cu−Ga合金スパッタリングターゲット、及び、Cu−Ga合金スパッタリングターゲットの製造方法
JP2019112671A (ja) * 2017-12-22 2019-07-11 三菱マテリアル株式会社 Cu−Ga合金スパッタリングターゲット、及び、Cu−Ga合金スパッタリングターゲットの製造方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08102546A (ja) * 1994-09-30 1996-04-16 Matsushita Electric Ind Co Ltd 半導体薄膜の製造方法
JPH1074967A (ja) * 1996-08-29 1998-03-17 Moririka:Kk 薄膜太陽電池
JP2000073163A (ja) * 1998-08-28 2000-03-07 Vacuum Metallurgical Co Ltd Cu−Ga合金スパッタリングターゲット及びその製造方法
JP2002064108A (ja) * 2000-08-17 2002-02-28 Honda Motor Co Ltd 化合物半導体成膜装置
JP2007266626A (ja) * 1994-12-01 2007-10-11 Shell Solar Gmbh 基板上に太陽電池を製造する方法及びカルコパイライト吸収層を有する太陽電池
JP2009283560A (ja) * 2008-05-20 2009-12-03 Showa Shell Sekiyu Kk Cis系薄膜太陽電池の製造方法
JP2011117077A (ja) * 2009-11-06 2011-06-16 Mitsubishi Materials Corp スパッタリングターゲット及びその製造方法
WO2011083646A1 (ja) * 2010-01-07 2011-07-14 Jx日鉱日石金属株式会社 スパッタリングターゲット、化合物半導体薄膜、化合物半導体薄膜を有する太陽電池及び化合物半導体薄膜の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101521249B (zh) * 2002-09-30 2012-05-23 米亚索尔公司 薄膜太阳能电池大规模生产的制造装置与方法
JP2006186200A (ja) * 2004-12-28 2006-07-13 Showa Shell Sekiyu Kk プリカーサ膜及びその製膜方法
CN101613091B (zh) * 2009-07-27 2011-04-06 中南大学 一种cigs粉末、靶材、薄膜及其制备方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08102546A (ja) * 1994-09-30 1996-04-16 Matsushita Electric Ind Co Ltd 半導体薄膜の製造方法
JP2007266626A (ja) * 1994-12-01 2007-10-11 Shell Solar Gmbh 基板上に太陽電池を製造する方法及びカルコパイライト吸収層を有する太陽電池
JPH1074967A (ja) * 1996-08-29 1998-03-17 Moririka:Kk 薄膜太陽電池
JP2000073163A (ja) * 1998-08-28 2000-03-07 Vacuum Metallurgical Co Ltd Cu−Ga合金スパッタリングターゲット及びその製造方法
JP2002064108A (ja) * 2000-08-17 2002-02-28 Honda Motor Co Ltd 化合物半導体成膜装置
JP2009283560A (ja) * 2008-05-20 2009-12-03 Showa Shell Sekiyu Kk Cis系薄膜太陽電池の製造方法
JP2011117077A (ja) * 2009-11-06 2011-06-16 Mitsubishi Materials Corp スパッタリングターゲット及びその製造方法
WO2011083646A1 (ja) * 2010-01-07 2011-07-14 Jx日鉱日石金属株式会社 スパッタリングターゲット、化合物半導体薄膜、化合物半導体薄膜を有する太陽電池及び化合物半導体薄膜の製造方法

Also Published As

Publication number Publication date
JP5923569B2 (ja) 2016-05-24
TW201126003A (en) 2011-08-01
JP2015045091A (ja) 2015-03-12
TWI583811B (zh) 2017-05-21
JPWO2011083647A1 (ja) 2013-05-13
WO2011083647A1 (ja) 2011-07-14

Similar Documents

Publication Publication Date Title
JP5923569B2 (ja) Cu−Ga系スパッタリングターゲット
JP5730788B2 (ja) スパッタリングターゲット及びスパッタリングターゲットの製造方法
US8894826B2 (en) Copper indium gallium selenide (CIGS) thin films with composition controlled by co-sputtering
TWI617681B (zh) Cu-Ga合金濺鍍靶及其製造方法
JP2010245238A (ja) 光電変換装置およびその製造方法ならびに硫化物焼結体ターゲットの製造方法
WO2013069710A1 (ja) スパッタリングターゲットおよびその製造方法
CN104835869B (zh) 铜铟镓硒薄膜太阳能电池及其制备方法
CN105705674B (zh) Cu-Ga合金溅射靶及其制造方法
US9273389B2 (en) Cu—In—Ga—Se quaternary alloy sputtering target
Zhu et al. Direct current magnetron sputtered Cu2ZnSnS4 thin films using a ceramic quaternary target
TW201425620A (zh) 濺鍍靶及其之製造方法
WO2013129468A1 (ja) Czts半導体薄膜の製造方法及び光電変換素子
JP6217295B2 (ja) Inスパッタリングターゲット
JP2012092438A (ja) Mo系スパッタリングターゲットおよびその製造方法ならびにこれを用いたCIGS系薄膜太陽電池
Oubaki et al. One‐Step DcMS and HiPIMS Sputtered CIGS Films from a Quaternary Target
EP2182083B1 (en) Copper-gallium alloy sputtering target and method for fabricating the same
Kim et al. CIGS thin film solar cell prepared by reactive co-sputtering
Jo et al. Spatial and RF power dependence of the structural and electrical characteristics of copper zinc tin selenide thin films prepared by single elementary target sputtering
TW201344944A (zh) 一種利用硒化合物補償碇的高溫硒化技術應用於薄膜太陽能電池之黃錫礦與黃銅礦光吸收層之製作
TWI413704B (zh) 一種靶材製造方法
Murali et al. CuIn 1− x Al x Se 2 solar cells fabricated on the flexible substrates by co-sputtering and modified selenization
JP2016082120A (ja) 太陽電池用光吸収層およびその製造方法、並びに前記太陽電池用光吸収層を有する太陽電池

Legal Events

Date Code Title Description
A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130924

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131105

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20140715

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140901

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20140916

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150831

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20151113

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20160118

R150 Certificate of patent or registration of utility model

Ref document number: 5877510

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250