JP5163488B2 - 積層体 - Google Patents
積層体 Download PDFInfo
- Publication number
- JP5163488B2 JP5163488B2 JP2008508417A JP2008508417A JP5163488B2 JP 5163488 B2 JP5163488 B2 JP 5163488B2 JP 2008508417 A JP2008508417 A JP 2008508417A JP 2008508417 A JP2008508417 A JP 2008508417A JP 5163488 B2 JP5163488 B2 JP 5163488B2
- Authority
- JP
- Japan
- Prior art keywords
- gas barrier
- film
- layer
- barrier coating
- coating layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010410 layer Substances 0.000 claims description 101
- 230000004888 barrier function Effects 0.000 claims description 84
- 239000011247 coating layer Substances 0.000 claims description 59
- 239000000463 material Substances 0.000 claims description 59
- 239000000758 substrate Substances 0.000 claims description 49
- -1 polyethylene terephthalate Polymers 0.000 claims description 41
- 238000009832 plasma treatment Methods 0.000 claims description 30
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 29
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 29
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 24
- 125000000524 functional group Chemical group 0.000 claims description 23
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 18
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 18
- 229920001684 low density polyethylene Polymers 0.000 claims description 15
- 239000004702 low-density polyethylene Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 91
- 239000010408 film Substances 0.000 description 86
- 229920005992 thermoplastic resin Polymers 0.000 description 72
- 238000001020 plasma etching Methods 0.000 description 49
- 238000001125 extrusion Methods 0.000 description 40
- 238000012545 processing Methods 0.000 description 34
- 239000004743 Polypropylene Substances 0.000 description 33
- 229920001155 polypropylene Polymers 0.000 description 33
- 238000000034 method Methods 0.000 description 32
- 229920005989 resin Polymers 0.000 description 27
- 239000011347 resin Substances 0.000 description 27
- 238000007740 vapor deposition Methods 0.000 description 25
- 238000003475 lamination Methods 0.000 description 24
- 239000002985 plastic film Substances 0.000 description 21
- 229920006255 plastic film Polymers 0.000 description 21
- 238000004458 analytical method Methods 0.000 description 17
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 16
- 238000005259 measurement Methods 0.000 description 16
- 229910052809 inorganic oxide Inorganic materials 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 13
- 229920003169 water-soluble polymer Polymers 0.000 description 13
- 238000000926 separation method Methods 0.000 description 12
- 238000010030 laminating Methods 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 9
- 239000004952 Polyamide Substances 0.000 description 9
- 229920002647 polyamide Polymers 0.000 description 9
- 229910052786 argon Inorganic materials 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000003851 corona treatment Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 238000007639 printing Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000005022 packaging material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- 229920002799 BoPET Polymers 0.000 description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- 238000001771 vacuum deposition Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000002952 polymeric resin Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 238000010849 ion bombardment Methods 0.000 description 3
- 229920001179 medium density polyethylene Polymers 0.000 description 3
- 239000004701 medium-density polyethylene Substances 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000002925 chemical effect Effects 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005211 surface analysis Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007718 adhesive strength test Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000011243 crosslinked material Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/28—Multiple coating on one surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/734—Dimensional stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/3175—Next to addition polymer from unsaturated monomer[s]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Laminated Bodies (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
(ii)PET/AC/熱可塑性樹脂層/(RIE処理面)基材/AC/熱可塑性樹脂層/直鎖状低密度ポリエチレン(LLDPE)層
(iii)OPP/AC/熱可塑性樹脂層/(RIE処理面)基材/AC/熱可塑性樹脂層/低密度ポリプロピレン(CPP)層、
(iv)PET/インキ/AC/MAH−grafted PP/(処理面)PET/蒸着層/ガスバリア性被膜層(処理面)/MAH−grafted PP/CPP。
以下、本発明の積層体の実施例を具体的に説明する。なお、本発明はこれらの実施例に限定されるものではない。
厚さ12μmのポリエチレンテレフタレート(PET)フィルムの未処理面に、以下の条件でリアクティブイオンエッチング(RIE)を利用した前処理を施した。電極には周波数13.56MHzの高周波電源を用いた。
印加電力:120W
処理時間:0.1sec
処理ガス:アルゴン
処理ユニット圧力:2.0Pa。
上記例1において、RIE前処理時の処理時間を0.5secにした以外は、例1と同様の方法で積層体を作製した。自己バイアス値は450V,Ed値は430W・m−2・secであった。
上記例1において、RIE前処理時の印加電力を500Wにした以外は、例1と同様の方法で積層体を作製した。自己バイアス値は900V,Ed値は900W・m−2・secであった。
上記例1において、ポリプロピレン(PP)樹脂を押出し温度290℃で押出ラミネーションした以外は、例1と同様の方法で積層体を作製した。
上記例1において、PETフィルムに前処理を行わなかった以外は、例1と同様の方法で積層体を作製した。
上記例1において、PETフィルムにRIE前処理の代わりにコロナ処理を行った以外は、例1と同様の方法で積層体を作製した。
厚さ15μmのポリアミド(Ny)フィルムの未処理面に、以下の条件でリアクティブイオンエッチング(RIE)を利用した前処理を施した。電極には周波数13.56MHzの高周波電源を用いた。
印加電力:120W
処理時間:0.1sec
処理ガス:アルゴン
処理ユニット圧力:2.0Pa。
上記例7において、RIE前処理時の処理時間を0.5secにした以外は、例7と同様の方法で積層体を作製した。自己バイアス値は450V,Ed値は430W・m−2・secであった。
上記例7において、ポリプロピレン(PP)樹脂を押出し温度290℃で押出ラミネーションした以外は、例7と同様の方法で積層体を作製した。
上記例7において、Nyフィルムに前処理を行わなかった以外は、例7と同様の方法で積層体を作製した。
上記例7において、NyフィルムにRIE前処理の代わりにコロナ処理を行った以外は、例7と同様の方法で積層体を作製した。
厚さ20μmのポリプロピレン(PP)フィルムの未処理面に、以下の条件でリアクティブイオンエッチング(RIE)を利用した前処理を施した。電極には周波数13.56MHzの高周波電源を用いた。
印加電力:200W
処理時間:0.2sec
処理ガス:アルゴン
処理ユニット圧力:2.0Pa。
上記例12において、RIE前処理時の処理時間を0.5secにした以外は、例12と同様の方法で積層体を作製した。自己バイアス値は550V,Ed値は1800W・m−2・secであった。
上記例12において、PPフィルムに前処理を行わなかった以外は、例12と同様の方法で積層体を作製した。
上記例12において、PPフィルムにRIE前処理の代わりにコロナ処理を行った以外は、例12と同様の方法で積層体を作製した。
例1〜15において、基材に熱可塑性樹脂を押出ラミネートする前に、X線光電子分光測定によりRIEによる前処理面の表面分析を行った。測定に用いたX線光電子分光装置は日本電子株式会社製JPS−90MXVであり、X線源として非単色化MgKα(1253.6eV)を用い、出力100W(10kV−10mA)で測定した。定量分析はO1sで2.28、C1sで1.00、N1sで1.61の相対感度因子を用いて計算を行い、元素比率としてO比(O/CまたはO/(C+N))を求めた。C1s波形の波形分離解析にはガウシアン関数とローレンツ関数の混合関数を使用し、帯電補正はベンゼン環に由来するC−C結合ピークを285.0eVとして補正した。
例1〜15の積層体について、フィルム基材とラミネートした熱可塑性樹脂層との間のラミネート強度を、オリエンテック社テンシロン万能試験機RTC−1250を用いて測定した(JIS Z1707準拠)。この測定の際に、測定部位を水で湿潤させながら剥離を行った。剥離角度は180度とした。結果を表1に示す。また、このラミネート強度測定後のサンプルの剥離面が基材であるか層間であるかを、X線光電子分光測定により確認した。
厚さ12μmのポリエチレンテレフタレート(PET)フィルムの一方の面に、電子線加熱方式による真空蒸着装置により金属アルミニウムを蒸着し、これに酸素ガスを導入して厚さ15nmの酸化アルミニウムを形成した。この酸化アルミニウム上に、下記に示すA液とB液を配合比(wt%)60/40に混合した溶液をグラビアコート法により塗布して乾燥し、厚さ0.3μmのガスバリア性被膜層を形成して、ガスバリア性フィルムを作製した。
B液:ポリビニルアルコールの3wt%水/イソプロピルアルコール溶液(水:イソプロピルアルコール重量比90:10)。
上記例21において、ガスバリア性被膜層に印加電力1200W、プラズマ密度E=1700W・sec/m2の条件でイオンボンバードによるプラズマ処理を施した。処理ガスにアルゴンガスを用い、処理ユニット圧力を0.4Paとした。それ以外は、例21と同様の方法で積層体を作製した。
例21と同様に、厚さ12μmのポリエチレンテレフタレート(PET)フィルムの一方の面に、電子線加熱方式による真空蒸着装置により金属アルミニウムを蒸着し、これに酸素ガスを導入して厚さ15nmの酸化アルミニウムを形成した。この酸化アルミニウム上に、下記に示すA液とB液とC液を配合比(wt%)70/25/5に混合した溶液をグラビアコート法により塗布して乾燥し、厚さ0.3μmのガスバリア性被膜層を形成して、ガスバリア性フィルムを作製した。
B液:ポリビニルアルコールの3wt%水/イソプロピルアルコール溶液(水:イソプロピルアルコール重量比90:10)、
C液:β−(3,4−エポキシシクロヘキシル)トリメトキシシランとイソプロピルアルコール(IPA溶液)に塩酸(1N)を徐々に加え、30分間攪拌し加水分解させた後、水/IPA=1/1溶液で加水分解を行い、固形分5wt.%(R2Si(OH)3換算)に調整した加水分解溶液。
上記例23において、ガスバリア性被膜層に印加電力350W、プラズマ密度E=600W・sec/m2の条件でリアクティブイオンエッチング(RIE)によるプラズマ処理を施した。処理ガスに酸素ガスを用い、処理ユニット圧力を2.0Paとし、自己バイアス値は650Vであった。それ以外は、例23と同様の方法で積層体を作製した。
上記例21において、ガスバリア性被膜層に対してプラズマ処理を行わなかった。それ以外は、例21と同様の方法で積層体を作製した。
上記例21において、ガスバリア性被膜層に印加電力1000W、放電量500W・min/m2の条件でコロナ放電処理を行った。それ以外は、例21と同様の方法で積層体を作製した。
上記例23において、ガスバリア性被膜層に対してプラズマ処理を行わなかった。それ以外は、例23と同様の方法で積層体を作製した。
上記例23におけるプラズマ処理の代わりに、ガスバリア性被膜層に印加電力10W、プラズマ密度E=15W・sec/m2の条件でリアクティブイオンエッチング(RIE)によるプラズマ処理を施した。処理ガスにアルゴン/酸素混合ガスを用い、処理ユニット圧力を2.0Paとし、自己バイアス値は100Vであった。それ以外は、例23と同様の方法で積層体を作製した。
上記例28におけるプラズマ処理の代わりに、ガスバリア性被膜層に印加電力250W、プラズマ密度E=1300W・sec/m2の条件でリアクティブイオンエッチング(RIE)によるプラズマ処理を施した。処理ガスにアルゴン/酸素混合ガスを用い、処理ユニット圧力を2.0Paとし、自己バイアス値は650Vであった。それ以外は、例28と同様の方法で積層体を作製した。
例21〜29において、ガスバリア性被覆層に対する前処理の前後に、X線光電子分光測定によりガスバリア性被覆層の表面分析を行った。測定に用いたX線光電子分光装置は日本電子株式会社製JPS−90MXVであり、X線源として非単色化MgKα(1253.6eV)を用い、出力100W(10kV−10mA)で測定した。C1s波形の波形分離解析にはガウシアン関数とローレンツ関数の混合関数を使用し、帯電補正はC−C結合ピークを285.0eVとして補正した。波形分離解析よりC−C結合とC−OH結合のピーク強度を求めた。前処理前の官能基比D0(C−OH/C−C)と、前処理後の官能基比D(C−OH/C−C)を求めた。また、D/D0を求めた。
例21〜29の積層体について、日本工業規格JIS K6854−3:1999「接着剤−剥離接着強さ試験方法−第3部:T型剥離」に規定されている試験方法に従ってラミネート強度を測定した。試験にはオリエンテック社テンシロン万能試験機RTC−1250を用いた。
例23のガスバリア性フィルムのガスバリア性被膜層に同様にプラズマ処理を施し、更に基材のポリエチレンテレフタレート面にも、例1と同じプラズマ処理を行った。
この積層体2枚を、CPP面を対向させ、周縁部をシールし、パウチを作り、水を充填して、レトルト殺菌処理を行った。レトルト条件は、蒸気式レトルトで120℃、120分行った。
MAH−grafted PP/(処理面)PETの間では、
レトルト前:2.4N/15mm、レトルト後:1.5N/15mm、
ガスバリア性被膜層(処理面)/MAH−grafted PPの間で、
レトルト前:1.0N/15mm、レトルト後:4.1N/15mm
であった。
Claims (4)
- ポリエチレンテレフタレートフィルムからなる基材と、
前記基材の片面に設けられた酸化アルミニウム層と、
前記酸化アルミニウム層上に、A液:テトラエトキシシランの加水分解溶液と、B液:ポリビニルアルコール溶液との混合溶液を塗布し乾燥して形成され、プラズマ処理による前処理が施されたガスバリア性被膜層であって、前記ガスバリア性被膜層の表面を、X線光電子分光法(XPS)を用いて測定した時に、前記ポリビニルアルコールの炭素−炭素結合(C−C)と炭素−水酸基結合(C−OH)の官能基比D(C−OH/C−C)が0.25以上0.87以下であるガスバリア性被膜層と、
前記ガスバリア性被膜層上に直接積層された低密度ポリエチレン層と
を有することを特徴とする積層体。 - ポリエチレンテレフタレートフィルムからなる基材と、
前記基材の片面に設けられた酸化アルミニウム層と、
前記酸化アルミニウム層上に、A液:テトラエトキシシランの加水分解溶液と、B液:ポリビニルアルコール溶液と、C液:β−(3,4−エポキシシクロヘキシル)トリメトキシシランの加水分解溶液との混合溶液を塗布し乾燥して形成され、プラズマ処理による前処理が施されたガスバリア性被膜層であって、前記ガスバリア性被膜層の表面を、X線光電子分光法(XPS)を用いて測定した時に、前記ポリビニルアルコールの炭素−炭素結合(C−C)と炭素−水酸基結合(C−OH)の官能基比D(C−OH/C−C)が0.25以上0.87以下であるガスバリア性被膜層と、
前記ガスバリア性被膜層上に直接積層された低密度ポリエチレン層と
を有することを特徴とする積層体。 - 前記酸化アルミニウム層の厚さが5〜100nmであることを特徴とする請求項1または2に記載の積層体。
- 前記ガスバリア性被膜層について、前処理後の官能基比Dと前処理前の官能基比D0との比D/D0が0.30以上0.92以下であることを特徴とする請求項1ないし3のいずれか1項に記載の積層体。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008508417A JP5163488B2 (ja) | 2006-09-08 | 2007-08-31 | 積層体 |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006244513 | 2006-09-08 | ||
JP2006244513 | 2006-09-08 | ||
JP2007094833 | 2007-03-30 | ||
JP2007094833 | 2007-03-30 | ||
PCT/JP2007/067017 WO2008029733A1 (fr) | 2006-09-08 | 2007-08-31 | Corps multicouche |
JP2008508417A JP5163488B2 (ja) | 2006-09-08 | 2007-08-31 | 積層体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2008029733A1 JPWO2008029733A1 (ja) | 2010-01-21 |
JP5163488B2 true JP5163488B2 (ja) | 2013-03-13 |
Family
ID=39157163
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008508417A Active JP5163488B2 (ja) | 2006-09-08 | 2007-08-31 | 積層体 |
Country Status (7)
Country | Link |
---|---|
US (2) | US20090181244A1 (ja) |
EP (2) | EP3351377B1 (ja) |
JP (1) | JP5163488B2 (ja) |
KR (1) | KR101473021B1 (ja) |
CN (1) | CN102514336B (ja) |
TW (1) | TWI476104B (ja) |
WO (1) | WO2008029733A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8421344B2 (en) | 2010-06-28 | 2013-04-16 | Panasonic Corporation | Organic light emitting element and manufacturing method of the same, organic display panel, and organic display device |
US8519425B2 (en) | 2010-02-22 | 2013-08-27 | Panasonic Corporation | Light-emitting device and manufacturing method thereof |
US8618536B2 (en) | 2010-06-29 | 2013-12-31 | Panasonic Corporation | Organic light-emitting element, display panel, display device, and manufacturing method for organic light-emitting element |
US8664669B2 (en) | 2010-06-24 | 2014-03-04 | Panasonic Corporation | Organic EL element, display apparatus, and light-emitting apparatus |
US8717260B2 (en) | 2010-06-16 | 2014-05-06 | Panasonic Corporation | EL display panel, EL display device provided with EL display panel, organic EL display device, and method for manufacturing EL display panel |
US8729535B2 (en) | 2010-05-07 | 2014-05-20 | Panasonic Corporation | Organic EL display panel and method for producing same |
US8779453B2 (en) | 2009-09-29 | 2014-07-15 | Panasonic Corporation | Light-emitting element and display device using same |
US8791881B2 (en) | 2008-04-28 | 2014-07-29 | Panasonic Corporation | Display device and manufacturing method therefor |
US11469281B2 (en) | 2019-03-01 | 2022-10-11 | Joled Inc. | Organic EL display panel and manufacturing method of organic el display panel |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101473021B1 (ko) | 2006-09-08 | 2014-12-15 | 도판 인사츠 가부시키가이샤 | 적층체 |
WO2011013677A1 (ja) | 2009-07-31 | 2011-02-03 | 東洋紡績株式会社 | ガスバリア性積層フィルム |
JP5497789B2 (ja) * | 2009-12-10 | 2014-05-21 | 三菱樹脂株式会社 | 表面保護パネル及び液晶画像表示装置 |
JP5668459B2 (ja) * | 2009-12-24 | 2015-02-12 | 東洋紡株式会社 | ガスバリア性積層フィルム |
JP5598080B2 (ja) * | 2010-05-17 | 2014-10-01 | 大日本印刷株式会社 | ガスバリア性シートの製造方法 |
KR20150023075A (ko) * | 2010-09-24 | 2015-03-04 | 생-고뱅 퍼포먼스 플라스틱스 코포레이션 | 적층 구조체 및 그의 제조 방법 |
US8980088B2 (en) | 2011-04-19 | 2015-03-17 | Pall Corporation | Fluid treatment arrangements and methods of making fluid treatment arrangements |
JP5741232B2 (ja) * | 2011-06-09 | 2015-07-01 | 大日本印刷株式会社 | 積層体およびその製造方法 |
JP5741231B2 (ja) * | 2011-06-09 | 2015-07-01 | 大日本印刷株式会社 | 積層体およびその製造方法 |
JP5831789B2 (ja) * | 2011-07-08 | 2015-12-09 | 大日本印刷株式会社 | 積層体およびその製造方法 |
TWI590951B (zh) * | 2011-07-28 | 2017-07-11 | 凸版印刷股份有限公司 | 積層體、阻氣薄膜、積層體之製造方法及積層體製造裝置 |
EP2805975A4 (en) * | 2012-01-20 | 2015-12-09 | Toyo Ink Sc Holdings Co Ltd | STEAM BARRIER RESIN, STEAM BARRIER COATING, STEAM BARRIER FILM AND STEAM BARRIER LAMINATE |
JP6089594B2 (ja) * | 2012-10-31 | 2017-03-08 | 凸版印刷株式会社 | 化粧板用防湿シート及び化粧板 |
JP6458338B2 (ja) * | 2013-11-01 | 2019-01-30 | 凸版印刷株式会社 | 二次電池用外装材、二次電池、及び二次電池用外装材の製造方法 |
JP2015172099A (ja) * | 2014-02-21 | 2015-10-01 | Apc株式会社 | ポリプロピレン系フィルム及びその製造方法、並びに積層体 |
US10674738B2 (en) * | 2014-12-31 | 2020-06-09 | Toray Plastics (America), Inc. | Starch coated polyester film for release of canned meat products |
JP7180072B2 (ja) * | 2015-05-28 | 2022-11-30 | 凸版印刷株式会社 | 積層フィルム及び包装袋 |
US20190061331A1 (en) * | 2015-10-08 | 2019-02-28 | Basf Se | Preparation of retort packaging ink through cross-linking of polyurethane resins |
JP6724390B2 (ja) * | 2016-01-28 | 2020-07-15 | 凸版印刷株式会社 | 波長変換シート用保護フィルム |
JP2018122562A (ja) * | 2017-02-03 | 2018-08-09 | 凸版印刷株式会社 | ガスバリアフィルム積層体 |
KR102572921B1 (ko) * | 2017-03-28 | 2023-08-30 | 린텍 가부시키가이샤 | 가스 배리어성 적층체 |
JP2019031078A (ja) * | 2017-08-09 | 2019-02-28 | 旭化成株式会社 | 筒状成形体、並びに、バリア口栓、バリア口栓付容器、及びインク収容管 |
EP3747651A4 (en) * | 2018-01-31 | 2021-04-07 | Toppan Printing Co., Ltd. | LAMINATED BODY AND METHOD FOR MANUFACTURING LAYERED BODIES |
CN109263224B (zh) * | 2018-11-12 | 2020-10-30 | 浙江鸿圣纺织科技有限公司 | 一种功能性无缝墙布及其制备方法 |
WO2020196301A1 (ja) * | 2019-03-22 | 2020-10-01 | 凸版印刷株式会社 | 包装材料および包装体 |
CN113748158A (zh) * | 2019-04-29 | 2021-12-03 | Sabic环球技术有限责任公司 | 阻氧膜的制备方法 |
EP4008552A4 (en) * | 2019-08-02 | 2022-09-14 | Toppan Inc. | GAS BARRIER FILM AND METHOD OF MAKING THE GAS BARRIER FILM |
JP6936406B1 (ja) * | 2021-01-15 | 2021-09-15 | 金澤 等 | 改善された材料の表面改質 |
JPWO2022168976A1 (ja) * | 2021-02-08 | 2022-08-11 | ||
WO2024014451A1 (ja) * | 2022-07-12 | 2024-01-18 | Toppanホールディングス株式会社 | ガスバリアフィルムおよびバリア性積層体 |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS606459A (ja) * | 1983-06-27 | 1985-01-14 | 東洋インキ製造株式会社 | 積層体 |
JPS61280930A (ja) * | 1985-06-07 | 1986-12-11 | 東洋インキ製造株式会社 | 積層体 |
JPS62214941A (ja) * | 1986-03-17 | 1987-09-21 | Toppan Printing Co Ltd | ラミネ−トフイルムの製造方法 |
JPH09156043A (ja) * | 1995-12-08 | 1997-06-17 | Toppan Printing Co Ltd | 低臭低吸着性液体紙容器用積層体及びその製造方法 |
JP2001009979A (ja) * | 1999-04-28 | 2001-01-16 | Tokuyama Corp | 積層フィルム |
JP2001322201A (ja) * | 2000-05-16 | 2001-11-20 | Dainippon Printing Co Ltd | バリア性フィルムおよびそれを使用した積層材 |
JP2002265652A (ja) * | 2001-03-14 | 2002-09-18 | Toppan Printing Co Ltd | ガスバリア性積層体の製造方法 |
JP2005068236A (ja) * | 2003-08-21 | 2005-03-17 | Amt Kenkyusho:Kk | 二軸延伸飽和ポリエステル系フィルム及びその製造方法、積層体及びその製造方法 |
JP2005231039A (ja) * | 2004-02-17 | 2005-09-02 | Dainippon Printing Co Ltd | バリア性フィルムおよびそれを使用した積層材 |
JP2006142548A (ja) * | 2004-11-17 | 2006-06-08 | Toppan Printing Co Ltd | ガスバリア性透明積層体 |
JP2006142494A (ja) * | 2004-11-16 | 2006-06-08 | Toppan Printing Co Ltd | レトルト用積層体 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63242541A (ja) * | 1987-03-30 | 1988-10-07 | 凸版印刷株式会社 | 包装材料 |
JPH03114829A (ja) * | 1989-09-29 | 1991-05-16 | Shin Etsu Chem Co Ltd | 包装材 |
JP2895917B2 (ja) | 1990-06-06 | 1999-05-31 | 三菱化学株式会社 | 熱可塑性樹脂の押出ラミネート方法 |
JP3385663B2 (ja) | 1993-09-28 | 2003-03-10 | 凸版印刷株式会社 | 液体包装用ラミネートフィルム及びその製造方法 |
JP3716006B2 (ja) | 1995-03-20 | 2005-11-16 | 住友化学株式会社 | 積層フィルムの製造方法 |
JP3753832B2 (ja) * | 1997-03-11 | 2006-03-08 | 凸版印刷株式会社 | 積層包装材料 |
JP2000238195A (ja) | 1999-02-24 | 2000-09-05 | Nippon Polyolefin Kk | 積層体およびその製造方法 |
TWI225499B (en) * | 1999-04-15 | 2004-12-21 | Konishiroku Photo Ind | Protective film for polarizing plate |
JP2000318104A (ja) * | 1999-05-10 | 2000-11-21 | Toppan Printing Co Ltd | ナイロンフィルム積層体及びその製造方法 |
EP1255616B1 (en) * | 2000-02-08 | 2010-05-05 | Basf Se | Process for the production of strongly adherent surface-coatings by plasma-or coronaactivated grafting |
JP4085814B2 (ja) * | 2001-04-09 | 2008-05-14 | 凸版印刷株式会社 | 積層体 |
KR20020092812A (ko) * | 2001-06-05 | 2002-12-12 | 가부시끼가이샤 도꾸야마 | 가스 차단제, 가스 차단 필름 및 그 제조 방법 |
JP2004137419A (ja) * | 2002-10-21 | 2004-05-13 | Toppan Printing Co Ltd | ポリエチレンテレフタレートフィルム及び積層体 |
JP4385835B2 (ja) * | 2004-04-13 | 2009-12-16 | 凸版印刷株式会社 | 強密着蒸着フィルムおよびそれを用いたレトルト用包装材料 |
KR101256416B1 (ko) * | 2004-05-10 | 2013-04-19 | 미쓰이 가가쿠 토세로 가부시키가이샤 | 가스 배리어성 막, 가스 배리어성 적층체 및 그 제조방법 |
FR2873705B1 (fr) * | 2004-07-27 | 2006-12-01 | Coating Plasma Ind Soc Par Act | Procede de traitement de surface d'un substrat en polyester ou polyamide |
KR101473021B1 (ko) | 2006-09-08 | 2014-12-15 | 도판 인사츠 가부시키가이샤 | 적층체 |
-
2007
- 2007-08-31 KR KR1020097004800A patent/KR101473021B1/ko active IP Right Grant
- 2007-08-31 WO PCT/JP2007/067017 patent/WO2008029733A1/ja active Application Filing
- 2007-08-31 JP JP2008508417A patent/JP5163488B2/ja active Active
- 2007-08-31 EP EP18159213.0A patent/EP3351377B1/en active Active
- 2007-08-31 CN CN201110359351.8A patent/CN102514336B/zh active Active
- 2007-08-31 EP EP07806490.4A patent/EP2060391B1/en active Active
- 2007-09-06 TW TW096133168A patent/TWI476104B/zh active
-
2009
- 2009-03-06 US US12/382,065 patent/US20090181244A1/en not_active Abandoned
-
2011
- 2011-05-09 US US13/067,105 patent/US8628638B2/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS606459A (ja) * | 1983-06-27 | 1985-01-14 | 東洋インキ製造株式会社 | 積層体 |
JPS61280930A (ja) * | 1985-06-07 | 1986-12-11 | 東洋インキ製造株式会社 | 積層体 |
JPS62214941A (ja) * | 1986-03-17 | 1987-09-21 | Toppan Printing Co Ltd | ラミネ−トフイルムの製造方法 |
JPH09156043A (ja) * | 1995-12-08 | 1997-06-17 | Toppan Printing Co Ltd | 低臭低吸着性液体紙容器用積層体及びその製造方法 |
JP2001009979A (ja) * | 1999-04-28 | 2001-01-16 | Tokuyama Corp | 積層フィルム |
JP2001322201A (ja) * | 2000-05-16 | 2001-11-20 | Dainippon Printing Co Ltd | バリア性フィルムおよびそれを使用した積層材 |
JP2002265652A (ja) * | 2001-03-14 | 2002-09-18 | Toppan Printing Co Ltd | ガスバリア性積層体の製造方法 |
JP2005068236A (ja) * | 2003-08-21 | 2005-03-17 | Amt Kenkyusho:Kk | 二軸延伸飽和ポリエステル系フィルム及びその製造方法、積層体及びその製造方法 |
JP2005231039A (ja) * | 2004-02-17 | 2005-09-02 | Dainippon Printing Co Ltd | バリア性フィルムおよびそれを使用した積層材 |
JP2006142494A (ja) * | 2004-11-16 | 2006-06-08 | Toppan Printing Co Ltd | レトルト用積層体 |
JP2006142548A (ja) * | 2004-11-17 | 2006-06-08 | Toppan Printing Co Ltd | ガスバリア性透明積層体 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8791881B2 (en) | 2008-04-28 | 2014-07-29 | Panasonic Corporation | Display device and manufacturing method therefor |
US8779453B2 (en) | 2009-09-29 | 2014-07-15 | Panasonic Corporation | Light-emitting element and display device using same |
US8519425B2 (en) | 2010-02-22 | 2013-08-27 | Panasonic Corporation | Light-emitting device and manufacturing method thereof |
US8729535B2 (en) | 2010-05-07 | 2014-05-20 | Panasonic Corporation | Organic EL display panel and method for producing same |
US8717260B2 (en) | 2010-06-16 | 2014-05-06 | Panasonic Corporation | EL display panel, EL display device provided with EL display panel, organic EL display device, and method for manufacturing EL display panel |
US8664669B2 (en) | 2010-06-24 | 2014-03-04 | Panasonic Corporation | Organic EL element, display apparatus, and light-emitting apparatus |
US8421344B2 (en) | 2010-06-28 | 2013-04-16 | Panasonic Corporation | Organic light emitting element and manufacturing method of the same, organic display panel, and organic display device |
US8618536B2 (en) | 2010-06-29 | 2013-12-31 | Panasonic Corporation | Organic light-emitting element, display panel, display device, and manufacturing method for organic light-emitting element |
US11469281B2 (en) | 2019-03-01 | 2022-10-11 | Joled Inc. | Organic EL display panel and manufacturing method of organic el display panel |
Also Published As
Publication number | Publication date |
---|---|
EP2060391A4 (en) | 2012-03-28 |
EP2060391B1 (en) | 2020-11-04 |
KR20090047517A (ko) | 2009-05-12 |
EP3351377A1 (en) | 2018-07-25 |
TWI476104B (zh) | 2015-03-11 |
CN102514336B (zh) | 2014-09-03 |
US20110212275A1 (en) | 2011-09-01 |
KR101473021B1 (ko) | 2014-12-15 |
US20090181244A1 (en) | 2009-07-16 |
EP3351377B1 (en) | 2019-08-21 |
JPWO2008029733A1 (ja) | 2010-01-21 |
US8628638B2 (en) | 2014-01-14 |
EP2060391A1 (en) | 2009-05-20 |
CN102514336A (zh) | 2012-06-27 |
TW200823054A (en) | 2008-06-01 |
WO2008029733A1 (fr) | 2008-03-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5163488B2 (ja) | 積層体 | |
KR20070051332A (ko) | 가스 배리어성 적층 필름 및 그 제조 방법 | |
JP2018122562A (ja) | ガスバリアフィルム積層体 | |
JP2008143103A (ja) | ガスバリア性積層フィルム | |
JP2006056092A (ja) | 強密着蒸着フィルムおよびそれを用いたレトルト用包装材料 | |
JP2009255398A (ja) | ガスバリア性積層フィルム | |
JP4784040B2 (ja) | 高性能バリアフィルム | |
JP4784039B2 (ja) | 帯電防止性能を有する強密着蒸着フィルム | |
JP4626329B2 (ja) | レトルト用積層体 | |
JP5092541B2 (ja) | ガスバリア性フィルム及びガスバリア性積層体 | |
JP4946411B2 (ja) | 液体紙容器 | |
JP2008023931A (ja) | バリア性フィルムおよびそれを使用した積層材 | |
JP4978066B2 (ja) | ガスバリアフィルム積層体の製造条件の評価方法 | |
JP4461737B2 (ja) | レトルト用包装材料 | |
JP4946412B2 (ja) | 液体紙容器 | |
JP4385835B2 (ja) | 強密着蒸着フィルムおよびそれを用いたレトルト用包装材料 | |
JP2007196528A (ja) | 液体紙容器 | |
JP2005335109A (ja) | 耐熱透明バリアフィルム | |
CN101511585A (zh) | 层叠体 | |
JP4648206B2 (ja) | 液体紙容器 | |
JP4905851B2 (ja) | 蒸着フィルムの製造方法 | |
JP2008265853A (ja) | レトルト処理用紙容器およびそれを使用したレトルト処理包装体 | |
JP4811546B2 (ja) | 液体紙容器 | |
JP4811544B2 (ja) | 液体紙容器 | |
JP4811545B2 (ja) | 液体紙容器 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100726 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120529 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20120622 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120730 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120828 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121024 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20121120 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20121203 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20151228 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5163488 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |