JP5075113B2 - メタロセン化合物 - Google Patents
メタロセン化合物 Download PDFInfo
- Publication number
- JP5075113B2 JP5075113B2 JP2008501307A JP2008501307A JP5075113B2 JP 5075113 B2 JP5075113 B2 JP 5075113B2 JP 2008501307 A JP2008501307 A JP 2008501307A JP 2008501307 A JP2008501307 A JP 2008501307A JP 5075113 B2 JP5075113 B2 JP 5075113B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- group
- propylene
- alkyl
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 0 *C(C1)=Cc2c1c(*)c(*)c(*)c2* Chemical compound *C(C1)=Cc2c1c(*)c(*)c(*)c2* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05102189 | 2005-03-18 | ||
| EP05102189.7 | 2005-03-18 | ||
| PCT/EP2006/060767 WO2006097497A1 (en) | 2005-03-18 | 2006-03-15 | Metallocene compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008535799A JP2008535799A (ja) | 2008-09-04 |
| JP2008535799A5 JP2008535799A5 (https=) | 2009-04-23 |
| JP5075113B2 true JP5075113B2 (ja) | 2012-11-14 |
Family
ID=36228814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008501307A Expired - Lifetime JP5075113B2 (ja) | 2005-03-18 | 2006-03-15 | メタロセン化合物 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7842764B2 (https=) |
| EP (1) | EP1858907B1 (https=) |
| JP (1) | JP5075113B2 (https=) |
| KR (1) | KR101293405B1 (https=) |
| CN (1) | CN101142224B (https=) |
| AT (1) | ATE411330T1 (https=) |
| AU (1) | AU2006224576B2 (https=) |
| BR (1) | BRPI0611557B1 (https=) |
| DE (1) | DE602006003194D1 (https=) |
| ES (1) | ES2316050T3 (https=) |
| PL (1) | PL1858907T3 (https=) |
| RU (1) | RU2410388C2 (https=) |
| WO (1) | WO2006097497A1 (https=) |
| ZA (1) | ZA200707189B (https=) |
Families Citing this family (184)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE445650T1 (de) | 2004-05-04 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ataktischen 1- butenpolymeren |
| US7803887B2 (en) | 2005-03-18 | 2010-09-28 | Basell Polyolefine Gmbh | Metallocene compounds |
| US7799880B2 (en) | 2005-03-23 | 2010-09-21 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| CN101146836B (zh) | 2005-03-23 | 2011-06-08 | 巴塞尔聚烯烃股份有限公司 | 烯烃聚合方法 |
| WO2006117285A1 (en) | 2005-05-03 | 2006-11-09 | Basell Polyolefine Gmbh | Process for the polymerization of alpha olefins |
| ATE515533T1 (de) | 2005-05-11 | 2011-07-15 | Basell Poliolefine Srl | Polymerisationsverfahren zur herstellung von polyolefinblends |
| AU2006259143A1 (en) | 2005-06-13 | 2006-12-21 | Basell Polyolefine Gmbh | Process for the copolymerization of propylene |
| US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
| EP2010580B1 (en) | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
| US8785575B2 (en) | 2006-04-21 | 2014-07-22 | Basell Polyolefine Gmbh | Process for the preparation of ethylene propylene copolymers |
| US7812104B2 (en) | 2008-01-18 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Production of propylene-based polymers |
| EP2103634A1 (en) | 2008-03-20 | 2009-09-23 | ExxonMobil Chemical Patents Inc. | Production of propylene-based polymers |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| WO2011076780A1 (en) | 2009-12-22 | 2011-06-30 | Borealis Ag | Catalysts |
| EP2341087B1 (en) * | 2009-12-30 | 2014-04-09 | Borealis AG | New way to produce polypropylene grade in a sequential process |
| EP2738183A1 (en) | 2010-05-07 | 2014-06-04 | Borealis AG | Preparation of a solid catalyst system |
| EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
| ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
| JP5966321B2 (ja) * | 2010-11-19 | 2016-08-10 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2655431A1 (en) | 2010-12-22 | 2013-10-30 | Borealis AG | Bridged metallocene catalysts |
| EP2532687A3 (en) | 2011-06-10 | 2013-04-10 | Borealis AG | Bridged Metallocene Catalysts |
| CN103649101A (zh) | 2011-07-08 | 2014-03-19 | 博瑞立斯有限公司 | 催化剂 |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| JP5892025B2 (ja) * | 2011-10-10 | 2016-03-23 | 日本ポリプロ株式会社 | メタロセン予備重合触媒の製造方法 |
| JP5880000B2 (ja) * | 2011-12-14 | 2016-03-08 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| ES2711081T3 (es) | 2012-10-18 | 2019-04-30 | Borealis Ag | Catalizador para la polimerización de olefinas |
| EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
| EP2722344B1 (en) | 2012-10-18 | 2017-03-22 | Borealis AG | Polymerisation process |
| ES2645256T3 (es) | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| EP2746301B1 (en) | 2012-12-21 | 2018-05-30 | Borealis AG | Catalyst |
| ES2589053T3 (es) | 2013-06-10 | 2016-11-08 | Borealis Ag | Procedimiento para la preparación de un polímero de propileno |
| PL2824142T3 (pl) | 2013-07-12 | 2016-08-31 | Borealis Ag | Kopolimer heterofazowy |
| JP6216887B2 (ja) | 2013-08-14 | 2017-10-18 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | 低温における耐衝撃性が改善されたプロピレン組成物 |
| WO2015024887A1 (en) | 2013-08-21 | 2015-02-26 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| MX2016001705A (es) | 2013-08-21 | 2016-05-18 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| EP2853563B1 (en) | 2013-09-27 | 2016-06-15 | Borealis AG | Films suitable for BOPP processing from polymers with high XS and high Tm |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| US10519259B2 (en) | 2013-10-24 | 2019-12-31 | Borealis Ag | Low melting PP homopolymer with high content of regioerrors and high molecular weight |
| ES2574428T3 (es) | 2013-10-24 | 2016-06-17 | Borealis Ag | Artículo moldeado por soplado basado en copolímero al azar bimodal |
| EP3063185B9 (en) | 2013-10-29 | 2017-11-15 | Borealis AG | Solid single site catalysts with high polymerisation activity |
| CA2927448C (en) | 2013-11-22 | 2017-01-17 | Borealis Ag | Low emission propylene homopolymer with high melt flow |
| EP3077426B1 (en) | 2013-12-04 | 2022-10-05 | Borealis AG | Phthalate-free pp homopolymers for meltblown fibers |
| KR101873134B1 (ko) | 2013-12-18 | 2018-06-29 | 보레알리스 아게 | 향상된 강성/인성 균형을 가진 bopp 필름 |
| PL2891667T3 (pl) | 2014-01-07 | 2017-07-31 | Borealis Ag | Heterofazowy polimer polipropylenu |
| CN105829364B (zh) | 2014-01-17 | 2017-11-10 | 博里利斯股份公司 | 用于制备丙烯/1‑丁烯共聚物的方法 |
| BR112016017227B1 (pt) | 2014-02-06 | 2021-06-29 | Borealis Ag | Copolímero de propileno heterofásico, película não orientada, recipiente, e uso de um copolímero de propileno heterofásico |
| JP2017508032A (ja) | 2014-02-06 | 2017-03-23 | ボレアリス エージー | 高衝撃強さを有する軟質コポリマー |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| WO2015158790A2 (en) * | 2014-04-17 | 2015-10-22 | Borealis Ag | Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| CN103980396B (zh) * | 2014-04-30 | 2016-06-15 | 中国科学院化学研究所 | 一种可用于3d打印的超高分子量等规聚丙烯树脂及其制备方法和应用 |
| EP2947118B1 (en) | 2014-05-20 | 2017-11-29 | Borealis AG | Polypropylene composition for automotive interior applications |
| EP2995629B1 (en) | 2014-09-12 | 2018-03-07 | Borealis AG | Process for producing propylene copolymers in gas phase |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
| WO2016038211A1 (en) * | 2014-09-12 | 2016-03-17 | Borealis Ag | Process for the preparation of copolymers of propylene |
| KR102022686B1 (ko) * | 2015-07-17 | 2019-11-04 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
| KR102024327B1 (ko) * | 2015-07-17 | 2019-11-11 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
| KR102022685B1 (ko) * | 2015-07-17 | 2019-09-18 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
| KR102023168B1 (ko) * | 2015-07-17 | 2019-09-19 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
| EP3241611B1 (en) | 2016-05-02 | 2020-03-04 | Borealis AG | A process for feeding a polymerisation catalyst |
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| CN109328200B (zh) | 2016-06-23 | 2022-08-19 | 博里利斯股份公司 | 催化剂失活的方法 |
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| JP7130644B2 (ja) | 2016-12-15 | 2022-09-05 | ボレアリス エージー | 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系 |
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| ES2974283T3 (es) | 2017-10-25 | 2024-06-26 | Borealis Ag | Composición de polipropileno cargado con propiedades termo-mecánicas mejoradas |
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| JP7249349B2 (ja) | 2017-12-27 | 2023-03-30 | ボレアリス エージー | チーグラー・ナッタ触媒及びその調製 |
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| PL3567061T3 (pl) | 2018-05-09 | 2024-02-26 | Borealis Ag | Kompozycja polipropylenowa dla rur |
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| US20210002397A1 (en) | 2018-05-09 | 2021-01-07 | Borealis Ag | Process for preparing propylene copolymers comprising c4-c12-apha olefin comonomer units |
| KR20210027401A (ko) * | 2018-06-28 | 2021-03-10 | 보레알리스 아게 | 촉매 |
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| EP4017887A4 (en) | 2019-08-22 | 2023-01-18 | ExxonMobil Chemical Patents Inc. | ISOTACTIC PROPYLENE HOMOPOLYMERS AND COPOLYMERS MADE WITH C1-SYMMETRIC METALLOCENE CATALYSTS |
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| US12571144B2 (en) | 2019-12-04 | 2026-03-10 | Borealis Ag | Light weight melt blown webs with improved barrier properties |
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| CN116670146A (zh) | 2020-11-23 | 2023-08-29 | 埃克森美孚化学专利公司 | 使用不含芳族溶剂的载体制备的茂金属聚丙烯 |
| WO2022106710A1 (en) | 2020-11-23 | 2022-05-27 | Borealis Ag | In-situ reactor blend of ziegler-natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene |
| KR102900234B1 (ko) | 2020-12-11 | 2025-12-12 | 보레알리스 게엠베하 | 반도전성 폴리프로필렌 조성물 |
| KR20230130047A (ko) | 2021-01-21 | 2023-09-11 | 보레알리스 아게 | 개선된 여과 특성을 갖는 일렉트릿 멜트-블로운 웹 |
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- 2006-03-15 US US11/886,646 patent/US7842764B2/en active Active
- 2006-03-15 KR KR1020077021417A patent/KR101293405B1/ko not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2008535799A (ja) | 2008-09-04 |
| ZA200707189B (en) | 2008-10-29 |
| RU2410388C2 (ru) | 2011-01-27 |
| CN101142224B (zh) | 2011-10-19 |
| EP1858907A1 (en) | 2007-11-28 |
| DE602006003194D1 (de) | 2008-11-27 |
| AU2006224576A1 (en) | 2006-09-21 |
| KR101293405B1 (ko) | 2013-08-05 |
| BRPI0611557B1 (pt) | 2017-03-28 |
| US20090062491A1 (en) | 2009-03-05 |
| RU2007138560A (ru) | 2009-04-27 |
| ES2316050T3 (es) | 2009-04-01 |
| AU2006224576B2 (en) | 2011-11-03 |
| ATE411330T1 (de) | 2008-10-15 |
| EP1858907B1 (en) | 2008-10-15 |
| PL1858907T3 (pl) | 2009-04-30 |
| CN101142224A (zh) | 2008-03-12 |
| KR20070110522A (ko) | 2007-11-19 |
| BRPI0611557A2 (pt) | 2010-09-21 |
| WO2006097497A1 (en) | 2006-09-21 |
| US7842764B2 (en) | 2010-11-30 |
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