IT1264680B1 - Catalizzatori supportati per la polimerizzazione delle olefine - Google Patents
Catalizzatori supportati per la polimerizzazione delle olefineInfo
- Publication number
- IT1264680B1 IT1264680B1 IT93MI001467A ITMI931467A IT1264680B1 IT 1264680 B1 IT1264680 B1 IT 1264680B1 IT 93MI001467 A IT93MI001467 A IT 93MI001467A IT MI931467 A ITMI931467 A IT MI931467A IT 1264680 B1 IT1264680 B1 IT 1264680B1
- Authority
- IT
- Italy
- Prior art keywords
- polymerization
- supported catalysts
- olefins
- heterozous
- cyclopentadienylic
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- -1 HYDROGEN ATOMS Chemical group 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000765 intermetallic Inorganic materials 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
CATALIZZATORI SUPPORTATI PER LA POLIMERIZZAZIONE DI OLEFINE COMPRENDONO:(A) UN SUPPORTO ORGANICO POROSO FUNZIONALIZZATO CON GRUPPI FUNZIONALI AVENTI ATOMI DI IDROGENO ATTIVO;(B) UN COMPOSTO ORGANO-METALLICO DELL'ALLIUMINIO CONTENENTE ETEROATOMI SCELTI TRA OSIGENO, AZOTO, ZOLFO;(C) UNO O PIU' COMPOSTI DI UN METALLO DI TRANSIZIONE SCELTO TRA TITANIO, ZIRCONIO, AFNIO E VANADIO, CONTENENTE ALMENO UN LEGANTE DI TIPO CICLOPENTADIENILICO.QUESTI CATALIZZATORI, OTTENIBILI IN FORMA DI PARTICELLE SFERICHE, POSSONO ESSERE UTILIZZATI NELLE REAZIONI DI POLIMERIZZAZIONE DELLE OLEFINE IN FASE LIQUIDA O IN FASE GAS, PRODUCENDO POLIMERI DOTATI DI MORFOLOGIA CONTROLLATA E DI ELEVATA "BULK DENSITY".
Priority Applications (19)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001467A IT1264680B1 (it) | 1993-07-07 | 1993-07-07 | Catalizzatori supportati per la polimerizzazione delle olefine |
AT94110168T ATE158309T1 (de) | 1993-07-07 | 1994-06-30 | Geträgerte katalysatoren für die polymerisation von olefinen |
DE69405658T DE69405658T3 (de) | 1993-07-07 | 1994-06-30 | Geträgerte Katalysatoren für die Polymerisation von Olefinen |
ES94110168T ES2108339T5 (es) | 1993-07-07 | 1994-06-30 | Catalizadores soportados para la polimerizacion de olefinas. |
DK94110168.5T DK0633272T3 (da) | 1993-07-07 | 1994-06-30 | Bårne katalysatorer til polymerisation af olefiner |
EP94110168A EP0633272B2 (en) | 1993-07-07 | 1994-06-30 | Supported catalysts for the polymerization of olefins |
MYPI94001730A MY110923A (en) | 1993-07-07 | 1994-07-02 | Supported catalysts for the polymerization of olefins |
IL11021994A IL110219A (en) | 1993-07-07 | 1994-07-05 | Supported catalysts for the polymerization of olefins their preparation and use thereof |
AU66181/94A AU675711B2 (en) | 1993-07-07 | 1994-07-05 | Supported catalysts for the polymerization of olefins |
RU94023242A RU2116316C1 (ru) | 1993-07-07 | 1994-07-05 | Катализатор на носителе для полимеризации олефинов (варианты), способ его получения (варианты), способ полимеризации олефинов |
BR9402237-2A BR9402237A (pt) | 1993-07-07 | 1994-07-06 | Processo para a preparação de um catalisador suportado para a preparação de olefinas e processo para a homo-ou co-polimerização de olefinas |
FI943238A FI111080B (fi) | 1993-07-07 | 1994-07-06 | Kantajalla olevia katalysaattoreita olefiinien polymerointiin |
CA002127601A CA2127601A1 (en) | 1993-07-07 | 1994-07-07 | Supported catalysts for the polymerization of olefins |
CN94109180A CN1033860C (zh) | 1993-07-07 | 1994-07-07 | 载体型烯烃聚合催化剂、其制备方法及其用途 |
KR1019940016366A KR100335805B1 (ko) | 1993-07-07 | 1994-07-07 | 올레핀중합용담지촉매 |
JP15611694A JP3573494B2 (ja) | 1993-07-07 | 1994-07-07 | オレフィン類重合用支持触媒 |
US09/004,867 US6423660B1 (en) | 1993-07-07 | 1998-01-09 | Supported catalysts for the polymerization of olefins |
US09/589,994 US6444604B1 (en) | 1993-07-07 | 2000-06-08 | Supported catalysts for the polymerization of olefins |
US10/184,679 US6774194B2 (en) | 1993-07-07 | 2002-06-26 | Supported catalysts for the polymerization of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001467A IT1264680B1 (it) | 1993-07-07 | 1993-07-07 | Catalizzatori supportati per la polimerizzazione delle olefine |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI931467A0 ITMI931467A0 (it) | 1993-07-07 |
ITMI931467A1 ITMI931467A1 (it) | 1995-01-07 |
IT1264680B1 true IT1264680B1 (it) | 1996-10-04 |
Family
ID=11366547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT93MI001467A IT1264680B1 (it) | 1993-07-07 | 1993-07-07 | Catalizzatori supportati per la polimerizzazione delle olefine |
Country Status (17)
Country | Link |
---|---|
US (3) | US6423660B1 (it) |
EP (1) | EP0633272B2 (it) |
JP (1) | JP3573494B2 (it) |
KR (1) | KR100335805B1 (it) |
CN (1) | CN1033860C (it) |
AT (1) | ATE158309T1 (it) |
AU (1) | AU675711B2 (it) |
BR (1) | BR9402237A (it) |
CA (1) | CA2127601A1 (it) |
DE (1) | DE69405658T3 (it) |
DK (1) | DK0633272T3 (it) |
ES (1) | ES2108339T5 (it) |
FI (1) | FI111080B (it) |
IL (1) | IL110219A (it) |
IT (1) | IT1264680B1 (it) |
MY (1) | MY110923A (it) |
RU (1) | RU2116316C1 (it) |
Families Citing this family (105)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
IT1273662B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
IT1273661B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
IT1276752B1 (it) | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
US6166153A (en) * | 1995-07-18 | 2000-12-26 | Fina Technology, Inc. | Process for the syndiotactic propagation of olefins |
CA2181413A1 (en) * | 1995-07-18 | 1998-01-18 | Edwar S. Shamshoum | Process for the syndiotactic propagation of olefins |
NL1001014C2 (nl) * | 1995-08-21 | 1997-02-25 | Dsm Nv | Katalysatorsysteem voor het bereiden van een rubberachtig copolymeer. |
US6150483A (en) * | 1995-08-21 | 2000-11-21 | Dsm N.V. | Catalyst system for the preparation of a rubbery copolymer |
NO306549B1 (no) * | 1995-12-15 | 1999-11-22 | Norsk Hydro As | Fremgangsmåte ved baking eller kalsinering av formede kull-legemer i en kalsineringsovn samt pakkmateriale for bruk i samme |
US5914289A (en) * | 1996-02-19 | 1999-06-22 | Fina Research, S.A. | Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution |
DE19621969A1 (de) * | 1996-05-31 | 1997-12-04 | Basf Ag | Verfahren zur Herstellung von kristallinen Polymerisaten durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen |
PT839834E (pt) * | 1996-10-30 | 2001-11-30 | Repsol Quimica Sa | Catalisadores organometalicos e sua utilizacao para a polimerizacao e copolimerizacao de alfa-olefinas |
ES2158474T3 (es) | 1996-10-30 | 2001-09-01 | Repsol Quimica Sa | Sistemas de catalizadores para la polimerizacion y copolimerizacion de alfa-olefinas. |
US20030195109A1 (en) | 1996-10-31 | 2003-10-16 | Jose Sancho Royo | Catalytic systems for the polimerisation and copolimerisation of alpha-olefins |
CN1074771C (zh) * | 1996-12-30 | 2001-11-14 | 中国科学院长春应用化学研究所 | 聚合物载体茂金属催化剂的制备 |
US6228795B1 (en) | 1997-06-05 | 2001-05-08 | Exxon Chemical Patents, Inc. | Polymeric supported catalysts |
AU743551B2 (en) * | 1997-06-05 | 2002-01-31 | Exxonmobil Chemical Patents Inc | Polymeric supported catalysts for olefin polymerization |
JPH11292913A (ja) * | 1998-04-06 | 1999-10-26 | Sumitomo Chem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触媒、オレフィン系重合体の製造方法、並びにオレフィン重合用固体触媒成分の製造方法 |
DE69918013T2 (de) | 1998-04-21 | 2005-07-14 | Basell Polyolefine Gmbh | Verfahren zur herstellung von copolymeren aus ethylen und alpha-olefinen |
ES2211013T3 (es) | 1998-04-27 | 2004-07-01 | Repsol Quimica S.A. | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
CA2301618A1 (en) * | 1998-06-27 | 2000-01-06 | Montell Technology Company B.V. | Catalyst components for the polymerization of olefins and catalyst obtained therefrom |
HUP0100215A3 (en) | 1998-07-02 | 2001-12-28 | Montell Technology Company Bv | Process for the preparation of substantially amorphous alpha-ol |
BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
US6544921B1 (en) * | 1999-09-28 | 2003-04-08 | Sumitomo Chemical Comapny, Limited | Solid catalyst component and catalyst for olefin polymerization, process for producing olefin polymer and process for producing solid catalyst component for olefin polymerization |
JP2001163912A (ja) * | 1999-09-28 | 2001-06-19 | Sumitomo Chem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触媒、オレフィン重合体の製造方法、並びにオレフィン重合用固体触媒成分の製造方法 |
ATE508135T1 (de) | 1999-12-28 | 2011-05-15 | Basell Polyolefine Gmbh | Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren |
EP1226193B1 (en) | 1999-12-28 | 2006-07-19 | Basell Polyolefine GmbH | Process for the preparation of ethylene polymers |
EP1157046B1 (en) | 1999-12-28 | 2005-12-07 | Basell Polyolefine GmbH | Process for the preparation of ethylene polymers |
JP5122054B2 (ja) * | 2000-05-12 | 2013-01-16 | バセル テクノロジー カンパニー ビー.ブイ. | オレフィン重合用の予備重合触媒成分 |
KR20020012346A (ko) * | 2000-08-07 | 2002-02-16 | 유현식 | 신디오탁틱 폴리스티렌을 고수율로 제조하고 반응기부착물을 감소시키는 담지촉매 |
NO20013880L (no) | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matriks og fremgangsmåte for fremstilling av polyolefiner |
GB0021301D0 (en) | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
EP1392740B1 (en) | 2000-09-25 | 2008-08-20 | Basell Polyolefine GmbH | Process for the preparation of ethylene polymers with a bis-amido titanium compound |
GB0023662D0 (en) | 2000-09-27 | 2000-11-08 | Borealis Tech Oy | Supported catalyst |
US7074736B2 (en) | 2000-10-31 | 2006-07-11 | Rohm And Haas Company | Hydrozirconated matrix and process for polyolefin production |
US6720396B2 (en) | 2000-11-30 | 2004-04-13 | Univation Technologies, Llc | Polymerization process |
US20020137861A1 (en) * | 2000-12-04 | 2002-09-26 | Woo Min Song | Polymerization process |
EP1395619B1 (en) | 2001-06-12 | 2011-08-10 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
WO2002100909A1 (en) | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
EP1397371B1 (en) | 2001-06-22 | 2006-03-22 | Basell Polyolefine GmbH | Metallocenes and their use in catalyst systems for producing olefin polymers |
JP4291693B2 (ja) | 2001-11-12 | 2009-07-08 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンを重合する方法および1−ブテンポリマー |
JP2005510567A (ja) | 2001-11-30 | 2005-04-21 | バセル ポリオレフィン ジーエムビーエイチ | メタロセン化合物およびプロピレンポリマー製造方法 |
WO2003070778A1 (en) | 2002-02-25 | 2003-08-28 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
AU2003260432A1 (en) | 2002-09-06 | 2004-03-29 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
AU2003273400A1 (en) | 2002-10-10 | 2004-05-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
ATE461222T1 (de) * | 2002-11-04 | 2010-04-15 | Basell Polyolefine Gmbh | Herstellung einer katalysatorzusammensetzung mit vetbesserter aktivität |
DE10251491A1 (de) * | 2002-11-04 | 2004-05-13 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Katalysatorzusammensetzungen mit verbesserter Aktivität |
US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
EP1622948B1 (en) | 2003-05-12 | 2019-11-20 | Basell Polyolefine GmbH | Process for polymerizing 1-butene |
KR101167877B1 (ko) | 2003-07-04 | 2012-07-23 | 바젤 폴리올레핀 게엠베하 | 올레핀 중합 방법 |
EP1753792B1 (en) | 2004-05-04 | 2009-10-14 | Basell Polyolefine GmbH | Process for the preparation of atactic 1-butene polymers |
WO2006082176A1 (en) | 2005-02-03 | 2006-08-10 | Basell Polyolefine Gmbh | Process for producing thermoformed articles |
US7175444B2 (en) * | 2005-02-23 | 2007-02-13 | Molex Incorporated | Plug connector and construction therefor |
ES2316050T3 (es) | 2005-03-18 | 2009-04-01 | Basell Polyolefine Gmbh | Compuestos metalocenos. |
JP2008536813A (ja) | 2005-03-18 | 2008-09-11 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
US7728086B2 (en) | 2005-03-23 | 2010-06-01 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
EP1861435B1 (en) | 2005-03-23 | 2016-01-13 | Basell Polyolefine GmbH | Process for the polymerization of olefins |
JP2008540714A (ja) | 2005-05-03 | 2008-11-20 | バーゼル・ポリオレフィン・ゲーエムベーハー | α−オレフィンの重合方法 |
EP1879959B1 (en) | 2005-05-11 | 2011-07-06 | Basell Poliolefine Italia S.r.l. | Polymerization process for preparing polyolefin blends |
US20090234084A1 (en) * | 2005-06-30 | 2009-09-17 | Basell Polyolefine Gmbh | Metallocene Compounds |
EP1940944B1 (en) | 2005-10-21 | 2017-03-15 | Basell Polyolefine GmbH | Polypropylene for injection molding |
DE602006014708D1 (de) * | 2005-10-21 | 2010-07-15 | Basell Polyolefine Gmbh | Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen |
WO2007045603A1 (en) | 2005-10-21 | 2007-04-26 | Basell Polyolefine Gmbh | Propylene polymers |
US20090017710A1 (en) * | 2006-02-02 | 2009-01-15 | Basell Polyolefine Gmbh | Propylene Melt Blown Resins, Propylene Melt Blown Resin Fibers and Non-Woven Fabric Made From the Same, and Methods of Making the Same |
ATE461244T1 (de) | 2006-02-23 | 2010-04-15 | Basell Poliolefine Srl | Propylenpolymere für spritzgiessanwendungen |
WO2007107448A1 (en) | 2006-03-17 | 2007-09-27 | Basell Polyolefine Gmbh | Metallocene compounds |
JP2009533382A (ja) | 2006-04-12 | 2009-09-17 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
JP2010500418A (ja) | 2006-04-21 | 2010-01-07 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンプロピレンコポリマーの製造方法 |
US8742042B2 (en) | 2006-04-21 | 2014-06-03 | Basell Polyolefine Gmbh | Process for the preparation of ethylene copolymers |
CN101274968B (zh) * | 2007-03-28 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于生产宽分子量分布的聚乙烯的复合催化剂 |
EP2158235B1 (en) * | 2007-06-25 | 2010-10-20 | Basell Polyolefine GmbH | 1-butene ethylene copolymers |
JP5480148B2 (ja) | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | マグネシウム化合物担持非メタロセン触媒およびその製造 |
JP5480147B2 (ja) | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | 担持非メタロセン触媒およびその製造方法 |
EP2197871A1 (en) * | 2007-10-19 | 2010-06-23 | Basell Polyolefine GmbH | Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands |
EP2227493B1 (en) | 2007-12-20 | 2011-09-14 | Basell Polyolefine GmbH | Process for obtaining polymers of ethylene and cycloolefins |
WO2009115402A1 (en) * | 2008-03-20 | 2009-09-24 | Basell Poliolefine Italia S.R.L. | 1-butene terpolymers |
KR20100137472A (ko) * | 2008-03-20 | 2010-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 1-부텐 기재 중합체의 조성물 |
WO2009115395A1 (en) * | 2008-03-20 | 2009-09-24 | Basell Polyolefine Italia S.R.L. | 1-butene copolymers |
US20110003951A1 (en) * | 2008-03-20 | 2011-01-06 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
KR101536796B1 (ko) * | 2008-04-22 | 2015-07-14 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 1-부텐 삼원중합체 |
KR100976666B1 (ko) * | 2008-07-21 | 2010-08-18 | 대림산업 주식회사 | 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의제조방법 |
EP2358809B1 (en) | 2008-12-19 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
US8907035B2 (en) | 2009-01-13 | 2014-12-09 | Basell Polyolefine Gmbh | Polyethylene Copolymers |
JP2012515239A (ja) | 2009-01-13 | 2012-07-05 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリマー組成物 |
US20100273964A1 (en) * | 2009-04-22 | 2010-10-28 | Stewart Lewis | Heterogeneous lewis acid catalysts for cationic polymerizations |
CN102803312B (zh) | 2009-06-16 | 2015-09-30 | 切弗朗菲利浦化学公司 | 使用茂金属-SSA催化剂系统的α烯烃低聚反应以及使用得到的聚α烯烃制备润滑剂共混物 |
EP2485839A1 (en) * | 2009-10-06 | 2012-08-15 | Chevron Phillips Chemical Company LP | Oligomerization of olefin waxes using metallocene-based catalyst systems |
WO2011050565A1 (zh) | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
WO2011050566A1 (zh) | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
JP5670465B2 (ja) | 2009-11-13 | 2015-02-18 | 中國石油化工股▲分▼有限公司 | 担持型非メタロセン触媒、その製造方法およびその使用 |
WO2011057469A1 (zh) | 2009-11-13 | 2011-05-19 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
KR101824760B1 (ko) | 2011-01-14 | 2018-02-01 | 더블유.알. 그레이스 앤드 캄파니-콘. | 개질된 메탈로센 촉매 제조 방법, 제조된 촉매 및 이의 용도 |
CN102516437B (zh) * | 2011-12-14 | 2014-05-21 | 浙江大学宁波理工学院 | 一种聚苯乙烯系功能微球的制备方法 |
EP2606970A1 (en) | 2011-12-19 | 2013-06-26 | Basell Polyolefine GmbH | Monocyclopentadienyl binuclear complexes, ligands used in their preparaion, catalyst systems comprising them and olefin polymerisation process |
EP2676972A1 (en) | 2012-06-19 | 2013-12-25 | Basell Polyolefine GmbH | Process for the obtainment of a polyolefin composition |
EP2743000A1 (en) | 2012-12-13 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Catalyst system for the preparation of polyolefins |
EP2767542A1 (en) | 2013-02-18 | 2014-08-20 | Basell Polyolefine GmbH | Oligomerization catalyst |
US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
KR20220012646A (ko) | 2020-07-23 | 2022-02-04 | 한국항공우주연구원 | 가스켓 제거 도구 |
WO2023117512A1 (en) | 2021-12-23 | 2023-06-29 | Basell Poliolefine Italia S.R.L. | Soft polyolefin composition |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL241315A (it) | 1958-07-18 | |||
US4147664A (en) * | 1975-10-24 | 1979-04-03 | Pomogailo Anatoly D | Catalyst of polymerization, copolymerization and oligomerization of olefins and drolefins |
DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
US4426318A (en) | 1982-12-01 | 1984-01-17 | Northern Petrochemical Company | Supported polyethylene polymerization catalysts utilizing substituted polystyrene resins |
US4564647A (en) | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
US4632912A (en) | 1985-12-10 | 1986-12-30 | The Dow Chemical Company | Polymer supported Ziegler-Natta catalysts |
DE3609862A1 (de) * | 1986-03-22 | 1987-10-01 | Boge Gmbh | Regelbarer stossdaempfer |
GB8609803D0 (en) | 1986-04-22 | 1986-05-29 | Bp Chem Int Ltd | Silicone surfactants |
DE3782243T2 (de) | 1986-08-26 | 1993-03-04 | Mitsui Petrochemical Ind | Katalysator zur polymerisierung von alpha-olefin und verfahren. |
US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
WO1988005058A1 (en) * | 1986-12-30 | 1988-07-14 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and process for its preparation |
JP2538595B2 (ja) | 1987-05-13 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒 |
JPH072798B2 (ja) | 1987-10-28 | 1995-01-18 | 住友化学工業株式会社 | オレフィン重合用固体触媒成分 |
US5118648A (en) | 1988-10-05 | 1992-06-02 | Mobil Oil Corporation | Particulate polymer-supported olefin polymerization catalyst |
EP0420988B1 (en) | 1989-03-23 | 1998-01-07 | Nippon Shokubai Co., Ltd. | A coating composition comprising crosslinked spherical fine particles |
JP2826362B2 (ja) * | 1990-02-13 | 1998-11-18 | 三井化学株式会社 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
DE69125789T2 (de) | 1990-05-11 | 1997-08-14 | Asahi Glass Co Ltd | Verfahren zur herstellung einer polyoxyalkylenverbindungen |
KR0179033B1 (ko) | 1990-05-22 | 1999-05-15 | 에토 다케토시 | 프로필렌 공중합체의 제조방법 |
US5242955A (en) | 1990-10-30 | 1993-09-07 | Daicel Chemical Industries, Ltd. | Composition comprising polyether compounds, a process for the preparation thereof and a curable resin composition |
EP0496405A1 (en) * | 1991-01-25 | 1992-07-29 | Mitsubishi Kasei Corporation | Porous resin and process for its production |
DE4119343A1 (de) | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
DE69224600T2 (de) * | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
US5362824A (en) * | 1991-12-13 | 1994-11-08 | Mobil Oil Corporation | Olefin polymerization catalysts |
US5461017A (en) | 1991-12-13 | 1995-10-24 | Mobil Oil Corporation | Olefin polymerization catalysts |
US5198399A (en) * | 1992-01-17 | 1993-03-30 | Quantum Chemical Corporation | Polymerization catalyst and method |
FI112233B (fi) † | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
DE69307472T2 (de) † | 1992-11-10 | 1997-05-15 | Mitsubishi Chem Corp | Verfahren zur Herstellung von Alpha-Olefinpolymeren |
US5646332A (en) | 1992-12-17 | 1997-07-08 | Exxon Chemical Patents Inc. | Batch Koch carbonylation process |
US5455214A (en) | 1993-09-09 | 1995-10-03 | Mobil Oil Corporation | Metallocenes supported on ion exchange resins |
ES2116617T3 (es) | 1993-09-17 | 1998-07-16 | Exxon Research Engineering Co | Nuevos copolimeros de isoolefina/para-alquilestireno funcionalizados. |
US5670557A (en) | 1994-01-28 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Polymerized microemulsion pressure sensitive adhesive compositions and methods of preparing and using same |
CA2181259A1 (en) * | 1994-03-01 | 1995-09-08 | Allan Brent Furtek | Olefin polymerization catalysts |
WO1996001854A1 (en) | 1994-07-11 | 1996-01-25 | Exxon Chemical Patents Inc. | Lubricating oil succinimide dispersants derived from heavy polyamine |
-
1993
- 1993-07-07 IT IT93MI001467A patent/IT1264680B1/it active IP Right Grant
-
1994
- 1994-06-30 DE DE69405658T patent/DE69405658T3/de not_active Expired - Fee Related
- 1994-06-30 DK DK94110168.5T patent/DK0633272T3/da active
- 1994-06-30 EP EP94110168A patent/EP0633272B2/en not_active Expired - Lifetime
- 1994-06-30 AT AT94110168T patent/ATE158309T1/de not_active IP Right Cessation
- 1994-06-30 ES ES94110168T patent/ES2108339T5/es not_active Expired - Lifetime
- 1994-07-02 MY MYPI94001730A patent/MY110923A/en unknown
- 1994-07-05 RU RU94023242A patent/RU2116316C1/ru not_active IP Right Cessation
- 1994-07-05 IL IL11021994A patent/IL110219A/xx not_active IP Right Cessation
- 1994-07-05 AU AU66181/94A patent/AU675711B2/en not_active Ceased
- 1994-07-06 BR BR9402237-2A patent/BR9402237A/pt not_active IP Right Cessation
- 1994-07-06 FI FI943238A patent/FI111080B/fi not_active IP Right Cessation
- 1994-07-07 CN CN94109180A patent/CN1033860C/zh not_active Expired - Fee Related
- 1994-07-07 KR KR1019940016366A patent/KR100335805B1/ko not_active IP Right Cessation
- 1994-07-07 CA CA002127601A patent/CA2127601A1/en not_active Abandoned
- 1994-07-07 JP JP15611694A patent/JP3573494B2/ja not_active Expired - Lifetime
-
1998
- 1998-01-09 US US09/004,867 patent/US6423660B1/en not_active Expired - Fee Related
-
2000
- 2000-06-08 US US09/589,994 patent/US6444604B1/en not_active Expired - Fee Related
-
2002
- 2002-06-26 US US10/184,679 patent/US6774194B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20030134993A1 (en) | 2003-07-17 |
US6444604B1 (en) | 2002-09-03 |
KR100335805B1 (ko) | 2002-10-09 |
DK0633272T3 (da) | 1997-10-13 |
BR9402237A (pt) | 1996-03-19 |
US6774194B2 (en) | 2004-08-10 |
IL110219A (en) | 1999-10-28 |
ES2108339T3 (es) | 1997-12-16 |
MY110923A (en) | 1999-06-30 |
EP0633272A1 (en) | 1995-01-11 |
ITMI931467A1 (it) | 1995-01-07 |
ITMI931467A0 (it) | 1993-07-07 |
ES2108339T5 (es) | 2005-07-16 |
JPH0753623A (ja) | 1995-02-28 |
ATE158309T1 (de) | 1997-10-15 |
US6423660B1 (en) | 2002-07-23 |
KR960014162A (ko) | 1996-05-22 |
JP3573494B2 (ja) | 2004-10-06 |
RU94023242A (ru) | 1996-05-27 |
RU2116316C1 (ru) | 1998-07-27 |
FI111080B (fi) | 2003-05-30 |
EP0633272B1 (en) | 1997-09-17 |
DE69405658T2 (de) | 1998-02-12 |
CN1033860C (zh) | 1997-01-22 |
DE69405658T3 (de) | 2005-12-29 |
IL110219A0 (en) | 1994-10-21 |
CN1103069A (zh) | 1995-05-31 |
AU6618194A (en) | 1995-01-19 |
DE69405658D1 (de) | 1997-10-23 |
AU675711B2 (en) | 1997-02-13 |
FI943238A (fi) | 1995-01-08 |
CA2127601A1 (en) | 1995-01-08 |
EP0633272B2 (en) | 2005-01-12 |
FI943238A0 (fi) | 1994-07-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
IT1264680B1 (it) | Catalizzatori supportati per la polimerizzazione delle olefine | |
IT1227258B (it) | Componenti e catalizzatori per la polimerizzazione di olefine | |
WO1993020111A3 (en) | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization | |
TW230210B (it) | ||
MY131505A (en) | Catalysts for the polymerization of olefins | |
RU93047795A (ru) | Катализаторы для полимеризации олефинов, способ получения гомо- или сополимеров олефинов | |
CA2315047A1 (en) | Mixed catalyst system | |
CA2008907A1 (en) | Catalysts for the polymerization of olefins | |
NO930349D0 (no) | Katalysatorbestanddeler og katalysatorer for anvendelse ved polymerisasjon av olefiner | |
CA2215444A1 (en) | Catalyst having a ketimide ligand | |
HU9401573D0 (en) | Catalyst support and catalyst for the polymerization of alfa olefinsi processes for optaining them and polymerization of alfa olefins in presence of the catalyst | |
CA2149045A1 (en) | Catalyst composition for use in the production of lldpe resin products | |
CA2227703A1 (en) | Gas phase polymerization process | |
PT955304E (pt) | Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas | |
ATE223444T1 (de) | Hochaktive polyethylenkatalysatoren | |
IN191827B (it) | ||
EP1041086A3 (de) | Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung | |
EP1396503A4 (en) | SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFIN | |
RU93054514A (ru) | Способ получения гомополимеров и сополимеров этилена | |
Wagner et al. | Catalyst and Process for Making Ethylene Polymers | |
FI935551A0 (fi) | Foerfarande foer framstaellning av eten(ko)polymerer med bred molmassafoerdelning | |
UA37171C2 (uk) | Твердий каталітичний компонент для полімеризації олефінів та каталізатор полімеризації олефінів | |
CA2345257A1 (en) | Aluminoxane synthesis employing reduced amount of trialkylaluminum compound | |
ES2133020B1 (es) | Catalizadores de hidrogenacion heterogeneos mejorados con isomerizacion de olefinas reducida. | |
CA2115043A1 (en) | Titanium Magnesium Catalyst Precursors for the Polymerization of Olefins |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970725 |