PL2891667T3 - Heterofazowy polimer polipropylenu - Google Patents

Heterofazowy polimer polipropylenu

Info

Publication number
PL2891667T3
PL2891667T3 PL14150318T PL14150318T PL2891667T3 PL 2891667 T3 PL2891667 T3 PL 2891667T3 PL 14150318 T PL14150318 T PL 14150318T PL 14150318 T PL14150318 T PL 14150318T PL 2891667 T3 PL2891667 T3 PL 2891667T3
Authority
PL
Poland
Prior art keywords
polypropylene polymer
heterophasic polypropylene
heterophasic
polymer
polypropylene
Prior art date
Application number
PL14150318T
Other languages
English (en)
Inventor
Jingbo Wang
Petar Doshev
Luigi Resconi
Wilfried Töltsch
Original Assignee
Borealis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Ag filed Critical Borealis Ag
Publication of PL2891667T3 publication Critical patent/PL2891667T3/pl

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/20Activation energy or enthalpy
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16Ethene-propene or ethene-propene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/16Ethene-propene or ethene-propene-diene copolymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
PL14150318T 2014-01-07 2014-01-07 Heterofazowy polimer polipropylenu PL2891667T3 (pl)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14150318.5A EP2891667B1 (en) 2014-01-07 2014-01-07 Heterophasic polypropylene polymer

Publications (1)

Publication Number Publication Date
PL2891667T3 true PL2891667T3 (pl) 2017-07-31

Family

ID=49883039

Family Applications (1)

Application Number Title Priority Date Filing Date
PL14150318T PL2891667T3 (pl) 2014-01-07 2014-01-07 Heterofazowy polimer polipropylenu

Country Status (9)

Country Link
US (1) US9932469B2 (pl)
EP (1) EP2891667B1 (pl)
JP (1) JP6545703B2 (pl)
KR (1) KR20160106690A (pl)
CN (1) CN105899553B (pl)
ES (1) ES2622299T3 (pl)
PL (1) PL2891667T3 (pl)
RU (1) RU2677463C2 (pl)
WO (1) WO2015104266A1 (pl)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2622299T3 (es) 2014-01-07 2017-07-06 Borealis Ag Polímero de polipropileno heterofásico
RU2704136C1 (ru) * 2015-11-17 2019-10-24 Бореалис Аг Композиция tpo с высокой текучестью с превосходной ударной прочностью при низкой температуре
EP3330315B1 (en) * 2016-12-01 2021-10-20 Borealis AG Foamed polypropylene composition
EP3336109B1 (en) * 2016-12-15 2023-06-07 Borealis AG Polypropylene composition with excellent paint adhesion
BR112019017985B1 (pt) 2017-03-27 2023-01-10 Basell Poliolefine Italia S.R.L. Processo para polimerização em fase gasosa de olefinas
CN110770264B (zh) * 2017-07-07 2022-10-14 博里利斯股份公司 制备多相丙烯共聚物的方法
ES2765849T3 (es) * 2017-08-28 2020-06-11 Borealis Ag Composición de polipropileno con baja contracción en un intervalo amplio de temperaturas de aplicación
US10907036B2 (en) 2017-10-13 2021-02-02 Borealis Ag Multimodal random heterophasic polypropylene composition
EP3505566A1 (en) * 2017-12-28 2019-07-03 Borealis AG Cable jacket
ES2966041T3 (es) 2018-01-05 2024-04-18 Borealis Ag Copolímeros impactados a base de catalizadores de sitio único con excelentes propiedades mecánicas y ópticas
WO2019199824A1 (en) * 2018-04-12 2019-10-17 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and polymerization methods
WO2020064313A1 (en) 2018-09-26 2020-04-02 Borealis Ag Propylene random copolymer for use in film applications
CN114761449B (zh) * 2019-09-25 2023-09-08 博里利斯股份公司 催化剂
CN114728463A (zh) * 2019-11-20 2022-07-08 Sabic环球技术有限责任公司 双轴取向管材
WO2022128379A1 (en) * 2020-12-14 2022-06-23 Basell Poliolefine Italia S.R.L. Ultrasoft polyolefin composition
KR20230159581A (ko) * 2021-03-24 2023-11-21 보레알리스 아게 헤테로상 폴리프로필렌 수지의 제조 방법
CN117377704A (zh) * 2021-03-24 2024-01-09 博里利斯股份公司 共聚物
EP4083134A1 (en) 2021-04-27 2022-11-02 Borealis AG Beta nucleated heterophasic polypropylene composition
EP4380794B8 (en) * 2021-08-04 2025-08-06 Borealis GmbH Multilayer nonwoven structure

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
DE69518094T2 (de) * 1994-04-11 2001-03-22 Mitsui Chemicals, Inc. Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
ATE373692T1 (de) 2002-06-12 2007-10-15 Basell Polyolefine Gmbh Propylen copolymerzusammensetzungen mit guter tieftemperatur-schlagfestigkeit und hoher transparenz
CN1294160C (zh) 2002-07-24 2007-01-10 巴塞尔聚烯烃股份有限公司 丙烯聚合物组合物的至少两阶段制备工艺
JP2005139282A (ja) * 2003-11-06 2005-06-02 Japan Polypropylene Corp プロピレン・エチレンブロック共重合体
EP1858907B1 (en) 2005-03-18 2008-10-15 Basell Polyolefine GmbH Metallocene compounds
WO2007116034A1 (en) 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
EP2053086A4 (en) 2006-08-11 2010-12-22 Mitsui Chemicals Inc PROPYLENE RESIN COMPOSITION FOR PACKAGING MATERIAL
BRPI0722162A2 (pt) 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
EP2363433B1 (en) 2007-12-17 2018-02-07 Borealis Technology OY Heterophasic polypropylene with high flowability and excellent low temperature impact properties
PL2072546T5 (pl) * 2007-12-18 2013-05-31 Borealis Tech Oy Heterofazowy polipropylen o wysokiej udarności
US9255166B2 (en) * 2008-04-24 2016-02-09 Borealis Ag High purity heterophasic propylene copolymers
JP5147530B2 (ja) * 2008-05-14 2013-02-20 日本ポリプロ株式会社 プロピレン−エチレン共重合体
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
ES2619729T3 (es) 2008-11-07 2017-06-26 Borealis Ag Composición de catalizador sólida
WO2010052260A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2368921B1 (en) * 2010-03-26 2014-11-26 Borealis AG Process for the preparation of flowable comonomer rich polypropylene
CN102947354B (zh) 2010-04-28 2015-04-01 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
KR101618753B1 (ko) 2010-04-28 2016-05-09 보레알리스 아게 브릿지된 메탈로센을 포함하는 고체 미립자 촉매
EP2426171A1 (en) * 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
KR101918175B1 (ko) 2011-07-08 2019-01-29 보레알리스 아게 헤테로상 공중합체
EP2899077B1 (en) * 2012-09-19 2016-12-21 Mitsubishi Chemical Corporation Airbag housing cover
EP2824142B1 (en) * 2013-07-12 2016-04-13 Borealis AG Heterophasic copolymer
ES2622299T3 (es) 2014-01-07 2017-07-06 Borealis Ag Polímero de polipropileno heterofásico
BR112016021834B1 (pt) * 2014-04-04 2021-07-13 Borealis Ag Copolímero de propileno heteroplástico, processo para preparação de um copolímero de propileno heteroplástico, e, artigo
EP2947118B1 (en) * 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications

Also Published As

Publication number Publication date
ES2622299T3 (es) 2017-07-06
JP2017502163A (ja) 2017-01-19
WO2015104266A1 (en) 2015-07-16
EP2891667B1 (en) 2017-03-15
CN105899553B (zh) 2018-02-02
US9932469B2 (en) 2018-04-03
US20160333175A1 (en) 2016-11-17
CN105899553A (zh) 2016-08-24
EP2891667A1 (en) 2015-07-08
RU2016127547A3 (pl) 2018-08-22
KR20160106690A (ko) 2016-09-12
RU2016127547A (ru) 2018-02-13
JP6545703B2 (ja) 2019-07-17
RU2677463C2 (ru) 2019-01-17

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