JP4108133B2 - 貴金属担持物の製造方法 - Google Patents

貴金属担持物の製造方法 Download PDF

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Publication number
JP4108133B2
JP4108133B2 JP52753898A JP52753898A JP4108133B2 JP 4108133 B2 JP4108133 B2 JP 4108133B2 JP 52753898 A JP52753898 A JP 52753898A JP 52753898 A JP52753898 A JP 52753898A JP 4108133 B2 JP4108133 B2 JP 4108133B2
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Prior art keywords
palladium
carrier
metal
layer
earth metals
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Expired - Lifetime
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JP52753898A
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English (en)
Japanese (ja)
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辰夫 山口
節夫 山松
裕重 岡本
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Asahi Kasei Chemicals Corp
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Asahi Kasei Chemicals Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Laminated Bodies (AREA)
JP52753898A 1996-12-16 1997-12-16 貴金属担持物の製造方法 Expired - Lifetime JP4108133B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP33581796 1996-12-16
PCT/JP1997/004624 WO1998026867A1 (fr) 1996-12-16 1997-12-16 Support pour metal precieux

Related Child Applications (1)

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JP2008028372A Division JP4994258B2 (ja) 1996-12-16 2008-02-08 貴金属担持物並びにアクリル酸エステル及び/又はメタクリル酸エステルの製造方法

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JP4108133B2 true JP4108133B2 (ja) 2008-06-25

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Family Applications (2)

Application Number Title Priority Date Filing Date
JP52753898A Expired - Lifetime JP4108133B2 (ja) 1996-12-16 1997-12-16 貴金属担持物の製造方法
JP2008028372A Expired - Lifetime JP4994258B2 (ja) 1996-12-16 2008-02-08 貴金属担持物並びにアクリル酸エステル及び/又はメタクリル酸エステルの製造方法

Family Applications After (1)

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JP2008028372A Expired - Lifetime JP4994258B2 (ja) 1996-12-16 2008-02-08 貴金属担持物並びにアクリル酸エステル及び/又はメタクリル酸エステルの製造方法

Country Status (9)

Country Link
US (1) US6228800B1 (de)
JP (2) JP4108133B2 (de)
KR (1) KR100328008B1 (de)
CN (1) CN1124178C (de)
AU (1) AU5412698A (de)
DE (1) DE19782189T1 (de)
MY (1) MY118697A (de)
TW (1) TW377306B (de)
WO (1) WO1998026867A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008161869A (ja) * 1996-12-16 2008-07-17 Asahi Kasei Chemicals Corp 貴金属担持物並びにアクリル酸エステル及び/又はメタクリル酸エステルの製造方法

Families Citing this family (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070066480A1 (en) * 1999-10-25 2007-03-22 Moser William R Method of preparing compounds using cavitation and compounds formed therefrom
US20020009414A1 (en) * 1999-10-25 2002-01-24 Moser William R. Method of preparing compounds using cavitation and compounds formed therefrom
JP2001232195A (ja) * 1999-12-17 2001-08-28 Ngk Insulators Ltd 触媒体
US6534438B1 (en) * 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
CN1179788C (zh) * 2000-09-29 2004-12-15 中国石油化工股份有限公司 不饱和烃选择加氢催化剂、其制备方法及其应用
KR100411177B1 (ko) * 2001-05-02 2003-12-18 한국화학연구원 산화반응용 촉매 및 이를 이용한 탄화수소 화합물의산화물 제조방법
GB0312769D0 (en) * 2003-06-04 2003-07-09 Johnson Matthey Plc Process for selective hydrogenation of acetylenic compounds and catalyst therefor
JP2005013800A (ja) * 2003-06-24 2005-01-20 Mitsubishi Chemicals Corp 固体触媒及びこれを用いた酸化的付加生成物の製造方法
WO2005005033A2 (en) * 2003-06-30 2005-01-20 New Jersey Institute Of Technology Catalysts and methods for making same
US7033419B1 (en) * 2003-09-16 2006-04-25 The United States Of America As Represented By The United States Department Of Energy Method for high temperature mercury capture from gas streams
JP3912377B2 (ja) * 2003-12-25 2007-05-09 日産自動車株式会社 排ガス浄化用触媒粉末の製造方法
CN1327942C (zh) * 2004-01-09 2007-07-25 中国科学院大连化学物理研究所 一种复合金属钯膜或合金钯膜及其制备方法
DE102004001975A1 (de) * 2004-01-13 2005-10-06 Basf Ag Verfahren zur Herstellung von Membranen
JP4547930B2 (ja) * 2004-02-17 2010-09-22 日産自動車株式会社 触媒、触媒の調製方法及び排ガス浄化用触媒
JP4547935B2 (ja) * 2004-02-24 2010-09-22 日産自動車株式会社 排ガス浄化用触媒、排ガス浄化触媒、及び触媒の製造方法
JP4513372B2 (ja) * 2004-03-23 2010-07-28 日産自動車株式会社 排ガス浄化用触媒及び排ガス浄化触媒
JP4599868B2 (ja) * 2004-03-30 2010-12-15 三菱化学株式会社 水添触媒およびその製造方法
JP4513384B2 (ja) * 2004-03-31 2010-07-28 日産自動車株式会社 高耐熱性排ガス浄化用触媒及びその製造方法
US7605108B2 (en) * 2004-07-08 2009-10-20 Nissan Motor Co., Ltd. Catalyst, exhaust gas purification catalyst, and method for manufacturing same
US7737077B2 (en) * 2004-11-25 2010-06-15 Cataler Corporation Catalyst for purifying exhaust gases
JP5200315B2 (ja) * 2004-12-22 2013-06-05 日産自動車株式会社 排気ガス浄化触媒、及び排気ガス浄化触媒の製造方法
JP4835011B2 (ja) * 2005-03-17 2011-12-14 東ソー株式会社 シリカアルミナを含む新規な構造体、およびその製造方法。
JP5011647B2 (ja) * 2005-03-17 2012-08-29 東ソー株式会社 タングステンジルコニアを含む新規な構造体、およびその製造方法。
US20090022643A1 (en) * 2005-04-06 2009-01-22 Mitsubishi Heavy Industries, Ltd. So3 reduction catalyst for purifying an exhaust gas, preparation process thereof, and exhaust gas purifying method using the catalyst
JP4865250B2 (ja) * 2005-04-15 2012-02-01 三菱重工業株式会社 排ガス処理用触媒の製造方法
EP1762561B1 (de) * 2005-09-09 2008-12-17 Mitsubishi Gas Chemical Company, Inc. Verfahren zur Herstellung von Aminoverbindungen mit einem aromatischen Ring unter Verwendung eines Schalenkatalysators
US7453016B1 (en) * 2005-12-20 2008-11-18 Uop Llc Selective hydrogenation process using layered catalyst composition and preparation of said catalyst
EP1834939A1 (de) * 2006-03-15 2007-09-19 MPG Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Hydrierungsverfahren unter Verwendung eines geordnete intermetallische Verbindung enthaltenden Katalysators
JP4294041B2 (ja) * 2006-07-31 2009-07-08 本田技研工業株式会社 NOx浄化触媒
DE102006058800A1 (de) * 2006-12-13 2008-06-19 Wacker Chemie Ag Verfahren zur Herstellung von Katalysatoren und deren Verwendung für die Gasphasenoxidation von Olefinen
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) * 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
JP5122196B2 (ja) 2007-07-17 2013-01-16 本田技研工業株式会社 NOx浄化触媒
JP5122195B2 (ja) 2007-07-17 2013-01-16 本田技研工業株式会社 NOx浄化触媒
CN101347730B (zh) 2007-07-18 2011-07-13 中国石油化工股份有限公司 用于粗对苯二甲酸精制的加氢催化剂
BRPI0815166A8 (pt) * 2007-08-13 2016-12-20 Asahi Kasei Chemicals Corp Catalisador para uso na produção de éster de ácido carboxílico, processos para produzir o mesmo, e, para produzir éster de ácido carboxílico
US7749375B2 (en) 2007-09-07 2010-07-06 Uop Llc Hydrodesulfurization process
KR101197837B1 (ko) * 2007-10-26 2012-11-05 아사히 가세이 케미칼즈 가부시키가이샤 복합 입자 담지물, 그 복합 입자 담지물의 제조 방법, 및 그 복합 입자 담지물을 화학 합성용 촉매로서 이용한 화합물의 제조 방법
KR101048622B1 (ko) * 2008-03-07 2011-07-14 서울대학교산학협력단 연료전지 전극 소재용 백금계 합금 촉매의 제조 방법
JP2009255032A (ja) * 2008-03-27 2009-11-05 Ibiden Co Ltd ハニカム構造体
DE102008016105A1 (de) * 2008-03-28 2009-10-01 Cognis Oleochemicals Gmbh Verfahren und Vorrichtung zur katalytischen Hydrierung ungesättigter Fettsäuren und Fettsäurederivate
JP5226382B2 (ja) * 2008-05-14 2013-07-03 三菱レイヨン株式会社 ヒドロキシアルキル(メタ)アクリレート類の製造方法
EP2177256A1 (de) * 2008-10-15 2010-04-21 Linde AG Katalysator mit Platinum und Palladium zur selektiven Reduktion von NOX mit Wasserstoff (H2-SCR)
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
NZ596975A (en) 2009-06-13 2014-04-30 Rennovia Inc Production of adipic acid and derivatives from carbohydrate-containing materials
CN102803194B (zh) 2009-06-13 2016-01-20 莱诺维亚公司 由含碳水化合物的物质生产戊二酸和衍生物
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) * 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
US20140206897A1 (en) * 2013-01-22 2014-07-24 Saudi Basic Industries Corporation Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification
TW201509522A (zh) 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化催化劑
TW201509901A (zh) 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化方法
EP3002058A1 (de) * 2014-10-02 2016-04-06 Evonik Degussa GmbH Katalysatorsystem zur Herstellung von Ketonen aus Epoxiden
US9969672B2 (en) 2014-10-31 2018-05-15 Rohm And Haas Company Oxidative esterification process
EP3170558A1 (de) 2015-11-19 2017-05-24 Evonik Röhm GmbH Gold-basierten katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
KR101911475B1 (ko) 2017-03-15 2018-10-24 한국과학기술원 아크릴산 제조용 촉매 및 이를 이용한 중성수용액에서 아크릴산의 제조방법
US10822297B2 (en) 2017-07-28 2020-11-03 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN110997615A (zh) * 2017-07-28 2020-04-10 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
KR102639243B1 (ko) * 2017-07-28 2024-02-21 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법
EP3658534A1 (de) 2017-07-28 2020-06-03 Rohm and Haas Company Verfahren zur herstellung von methylmethacrylat durch oxidative veresterung unter verwendung eines heterogenen katalysators
SG11202000744UA (en) 2017-07-28 2020-02-27 Rohm & Haas A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
WO2019022889A1 (en) 2017-07-28 2019-01-31 Dow Global Technologies Llc PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST
US10800727B2 (en) 2017-07-28 2020-10-13 Rohm And Haas Company Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CA3071239A1 (en) * 2017-07-28 2019-01-31 Rohm And Haas Company Heterogeneous catalyst
JP7150815B2 (ja) * 2017-07-28 2022-10-11 ローム アンド ハース カンパニー 不均一触媒を使用した酸化的エステル化によるメタクリル酸メチルの製造方法
CA3071240A1 (en) * 2017-07-28 2019-01-31 Rohm And Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
MX2020002600A (es) * 2017-09-19 2020-07-20 Dow Global Technologies Llc Metodo para la produccion de metacrilato de metilo por esterificacion oxidativa con el uso de un catalizador heterogeneo.
MX2020012675A (es) 2018-06-28 2021-02-09 Dow Global Technologies Llc Catalizador heterogeneo.
MX2020012682A (es) 2018-06-28 2021-02-09 Dow Global Technologies Llc Catalizador heterogeneo.
KR102220225B1 (ko) * 2019-06-21 2021-02-24 희성촉매 주식회사 과산화수소 합성 및 재생 촉매 및 이의 제조방법
CA3171056A1 (en) 2020-03-17 2021-09-23 Dow Global Technologies Llc Process and catalyst for oxidative esterification with long-life catalyst
KR20240089248A (ko) 2021-10-08 2024-06-20 롬 앤드 하스 캄파니 알킬 메타크릴레이트의 생산 방법
CA3233792A1 (en) 2021-10-08 2023-04-13 Kirk W. Limbach Process for methyl methacrylate production
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WO2023059678A1 (en) 2021-10-08 2023-04-13 Rohm And Haas Company Process for methyl methacrylate production
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WO2023059679A1 (en) 2021-10-08 2023-04-13 Rohm And Haas Company Process for methyl methacrylate production from ethanol
WO2024123526A1 (en) 2022-12-08 2024-06-13 Dow Global Technologies Llc Process for preparing alkyl methacrylates
WO2024123528A1 (en) 2022-12-08 2024-06-13 Dow Global Technologies Llc Process for preparing alkyl methacrylates

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3819533A (en) * 1972-05-18 1974-06-25 American Cyanamid Co Catalyst for the elimination of pollutants in exhaust gases; catalyst resistant to sulfur poisoning; catalyst containing an even distribution of promoters
DE2601154A1 (de) * 1976-01-14 1977-07-21 Bayer Ag Neuer katalysator, seine herstellung und verwendung
US4404124A (en) * 1981-05-06 1983-09-13 Phillips Petroleum Company Selective hydrogenation catalyst
JPS58198442A (ja) * 1982-05-14 1983-11-18 Asahi Chem Ind Co Ltd メタクリル酸メチル又はアクリル酸メチルの改良製造方法
JPS59120250A (ja) * 1982-12-27 1984-07-11 Toyota Central Res & Dev Lab Inc 触媒の製造方法
JPS60202745A (ja) * 1984-03-23 1985-10-14 Kikai Syst Shinko Kyokai 高温燃焼用触媒
JPH07108982B2 (ja) * 1987-04-07 1995-11-22 三菱化学株式会社 ヒ素含有炭化水素油の水添精製法
ES2249764T3 (es) * 1994-02-22 2006-04-01 The Standard Oil Company Proceso de preparacion de un catalizador para fabricar acetato de vinilo en un lecho fluido.
EP0686615B2 (de) * 1994-06-09 2007-06-27 Institut Francais Du Petrole Verfahren zur katalytischen Hydrierung und in diesem Verfahren zu verwendender Katalysator
JP3577361B2 (ja) * 1995-06-06 2004-10-13 旭化成ケミカルズ株式会社 強度、耐腐食性に優れたカルボン酸エステル製造用触媒
FR2755378B1 (fr) * 1996-11-07 1999-01-08 Inst Francais Du Petrole Catalyseurs d'hydrogenation selective contenant du palladium et au moins un metal du groupe iva
TW377306B (en) * 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008161869A (ja) * 1996-12-16 2008-07-17 Asahi Kasei Chemicals Corp 貴金属担持物並びにアクリル酸エステル及び/又はメタクリル酸エステルの製造方法

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KR20000069461A (ko) 2000-11-25
JP4994258B2 (ja) 2012-08-08
AU5412698A (en) 1998-07-15
CN1240372A (zh) 2000-01-05
US6228800B1 (en) 2001-05-08
MY118697A (en) 2005-01-31
TW377306B (en) 1999-12-21
KR100328008B1 (ko) 2002-03-09
JP2008161869A (ja) 2008-07-17
DE19782189T1 (de) 1999-12-23
WO1998026867A1 (fr) 1998-06-25

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