JP2014528015A5 - - Google Patents
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- JP2014528015A5 JP2014528015A5 JP2014531329A JP2014531329A JP2014528015A5 JP 2014528015 A5 JP2014528015 A5 JP 2014528015A5 JP 2014531329 A JP2014531329 A JP 2014531329A JP 2014531329 A JP2014531329 A JP 2014531329A JP 2014528015 A5 JP2014528015 A5 JP 2014528015A5
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- 229920000642 polymer Polymers 0.000 description 12
- 230000001264 neutralization Effects 0.000 description 8
- 229920001400 block copolymer Polymers 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- OZAIFHULBGXAKX-VAWYXSNFSA-N Azobisisobutyronitrile Chemical compound N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- UIJKVOGFQPSFQN-UHFFFAOYSA-N 4-ethenylbicyclo[4.2.0]octa-1(6),2,4,7-tetraene Chemical compound C=CC1=CC=C2C=CC2=C1 UIJKVOGFQPSFQN-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- ODLMAHJVESYWTB-UHFFFAOYSA-N CCCc1ccccc1 Chemical compound CCCc1ccccc1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 1
- MGLHIFKMPOBWCV-UHFFFAOYSA-N CCc1ccc(C=C2)c2c1 Chemical compound CCc1ccc(C=C2)c2c1 MGLHIFKMPOBWCV-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Incidol Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001809 detectable Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000000379 polymerizing Effects 0.000 description 1
- 230000001376 precipitating Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Substances [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 1
- HADKRTWCOYPCPH-UHFFFAOYSA-M trimethylphenylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C1=CC=CC=C1 HADKRTWCOYPCPH-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
例3:中性ポリマー3の合成
0.33gのAIBN、7.81gの4−ビニルベンゾシクロブテン(0.0600モル)、10.45gのスチレン(0.100モル)及び4.0gのメチルメタクリレート(0.0399モル)を含む溶液を、マグネチックバー及び冷水流凝縮器を備えた300mlのフラスコ中で調製した。これに、52.6gの2−ブタノンを加えて、そして攪拌後に透明な溶液を得た。窒素を導通して30分間パージした後、このフラスコを80℃の油浴中に浸漬した。重合をこの温度で20時間行った。この反応溶液を室温まで放冷し、そして攪拌しながらメタノール中に注ぎ入れて粗製ポリマーを析出させた。得られた粗製ポリマーを濾過によって単離した。次いで、ポリマーを2−ブタノン中に溶解し、次いで再びメタノール中に析出することによって精製した。精製したポリマーを、一定重量(11.6g)まで50℃の減圧炉中で乾燥した。このポリマーは、17086g/モルのMw及び10005g/モルのMnを有していた。このポリマーは、自己組織化ブレンド実験のために30モル%4−ビニルベンゾシクロブテン及び20%MMAと表2中に記した。
0.33gのAIBN、7.81gの4−ビニルベンゾシクロブテン(0.0600モル)、10.45gのスチレン(0.100モル)及び4.0gのメチルメタクリレート(0.0399モル)を含む溶液を、マグネチックバー及び冷水流凝縮器を備えた300mlのフラスコ中で調製した。これに、52.6gの2−ブタノンを加えて、そして攪拌後に透明な溶液を得た。窒素を導通して30分間パージした後、このフラスコを80℃の油浴中に浸漬した。重合をこの温度で20時間行った。この反応溶液を室温まで放冷し、そして攪拌しながらメタノール中に注ぎ入れて粗製ポリマーを析出させた。得られた粗製ポリマーを濾過によって単離した。次いで、ポリマーを2−ブタノン中に溶解し、次いで再びメタノール中に析出することによって精製した。精製したポリマーを、一定重量(11.6g)まで50℃の減圧炉中で乾燥した。このポリマーは、17086g/モルのMw及び10005g/モルのMnを有していた。このポリマーは、自己組織化ブレンド実験のために30モル%4−ビニルベンゾシクロブテン及び20%MMAと表2中に記した。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/243,640 US8691925B2 (en) | 2011-09-23 | 2011-09-23 | Compositions of neutral layer for directed self assembly block copolymers and processes thereof |
US13/243,640 | 2011-09-23 | ||
PCT/IB2012/001905 WO2013041958A1 (en) | 2011-09-23 | 2012-09-21 | Compositions of neutral layer for directed self assembly block copolymers and processes thereof |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014528015A JP2014528015A (ja) | 2014-10-23 |
JP2014528015A5 true JP2014528015A5 (ja) | 2016-01-21 |
JP6077547B2 JP6077547B2 (ja) | 2017-02-08 |
Family
ID=47911640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014531329A Active JP6077547B2 (ja) | 2011-09-23 | 2012-09-21 | 誘導自己組織化ブロックコポリマーのための中性層の組成物及びそれの方法 |
Country Status (9)
Country | Link |
---|---|
US (2) | US8691925B2 (ja) |
EP (2) | EP2758469B1 (ja) |
JP (1) | JP6077547B2 (ja) |
KR (1) | KR101829955B1 (ja) |
CN (1) | CN103797066B (ja) |
MY (1) | MY193745A (ja) |
SG (1) | SG2014004667A (ja) |
TW (1) | TWI535770B (ja) |
WO (1) | WO2013041958A1 (ja) |
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