JP2006509829A - フェノール、アセトン、α−メチルスチレン及び酸化プロピレンのコプロダクション及びその触媒 - Google Patents

フェノール、アセトン、α−メチルスチレン及び酸化プロピレンのコプロダクション及びその触媒 Download PDF

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JP2006509829A
JP2006509829A JP2004563715A JP2004563715A JP2006509829A JP 2006509829 A JP2006509829 A JP 2006509829A JP 2004563715 A JP2004563715 A JP 2004563715A JP 2004563715 A JP2004563715 A JP 2004563715A JP 2006509829 A JP2006509829 A JP 2006509829A
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group
catalyst
metals
cumene hydroperoxide
acetone
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JP2006509829A5 (enExample
Inventor
レビン、ドロン
サンティエステバン、ジョーズ・グワダループ
スミス、モリス・シー
ヴァーテュリ、ジェイムス・シー
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エクソンモービル・ケミカル・パテンツ・インク
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Publication of JP2006509829A publication Critical patent/JP2006509829A/ja
Publication of JP2006509829A5 publication Critical patent/JP2006509829A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2004563715A 2002-12-16 2003-12-16 フェノール、アセトン、α−メチルスチレン及び酸化プロピレンのコプロダクション及びその触媒 Pending JP2006509829A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/320,237 US6984761B2 (en) 2002-12-16 2002-12-16 Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
PCT/US2003/040283 WO2004058672A1 (en) 2002-12-16 2003-12-16 Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor

Publications (2)

Publication Number Publication Date
JP2006509829A true JP2006509829A (ja) 2006-03-23
JP2006509829A5 JP2006509829A5 (enExample) 2007-02-08

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Family Applications (1)

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JP2004563715A Pending JP2006509829A (ja) 2002-12-16 2003-12-16 フェノール、アセトン、α−メチルスチレン及び酸化プロピレンのコプロダクション及びその触媒

Country Status (10)

Country Link
US (1) US6984761B2 (enExample)
EP (1) EP1575888B1 (enExample)
JP (1) JP2006509829A (enExample)
KR (1) KR101084379B1 (enExample)
CN (2) CN1726176A (enExample)
AT (1) ATE483674T1 (enExample)
AU (1) AU2003297321A1 (enExample)
DE (1) DE60334493D1 (enExample)
TW (1) TWI310027B (enExample)
WO (1) WO2004058672A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010517933A (ja) * 2006-08-03 2010-05-27 エクソンモービル・ケミカル・パテンツ・インク アルキル芳香族化合物の酸化法
JP2013535484A (ja) * 2010-12-01 2013-09-12 エルジー・ケム・リミテッド αメチルスチレンの製造方法
JP2014522381A (ja) * 2011-07-15 2014-09-04 エルジー・ケム・リミテッド クミルアルコールの製造方法およびフェノール、アセトン、およびアルファメチルスチレンの製造方法

Families Citing this family (19)

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US7455762B2 (en) * 2004-08-31 2008-11-25 Exxonmobil Research And Engineering Company Selective hydrodesulfurization process
US7285512B2 (en) * 2004-08-31 2007-10-23 Exxonmobile Research And Engineering Company Selective hydrodesulfurization catalyst
US8189615B2 (en) * 2004-12-23 2012-05-29 Nokia Corporation Method and apparatus for communicating scheduling information from a UE to a radio access network
ES2261080B1 (es) * 2005-04-19 2007-12-16 Universidad Politecnica De Valencia Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
US7452841B2 (en) * 2005-09-23 2008-11-18 Eastman Chemical Company Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids
WO2007137020A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US8680355B2 (en) * 2008-12-01 2014-03-25 Mitsui Chemcials, Inc. Olefin production process
WO2010106966A1 (ja) * 2009-03-16 2010-09-23 三井化学株式会社 オレフィンの製造方法
KR101403518B1 (ko) 2010-12-21 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101476376B1 (ko) * 2011-07-15 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101447255B1 (ko) * 2011-07-22 2014-10-07 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101431122B1 (ko) * 2011-08-12 2014-08-19 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101476375B1 (ko) * 2011-09-02 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
US9115105B2 (en) 2011-09-30 2015-08-25 Exxonmobil Chemical Patents Inc. Production of propylene oxide
WO2017118887A1 (en) * 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Systems and methods for the co-production of hydrogen and alkylene oxides
CN112079691A (zh) * 2020-09-17 2020-12-15 吉化集团油脂化工有限公司 提升苯酚产品质量的方法
RU2750718C1 (ru) * 2020-12-04 2021-07-01 федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") Способ разложения гидропероксида изопропилбензола с получением диметилфенилкарбинола
EP4043420B1 (en) 2020-12-21 2024-10-09 LG Chem, Ltd. Method for producing alpha-methylstyrene

Citations (12)

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US2757209A (en) * 1951-04-26 1956-07-31 Allied Chem & Dye Corp Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
JPS5832831A (ja) * 1981-06-22 1983-02-25 アライド・コ−ポレ−シヨン クメン酸化生成物の分解法
JPS60174737A (ja) * 1984-02-22 1985-09-09 Mitsui Petrochem Ind Ltd 芳香族アルコ−ルの製造法
JPH01100136A (ja) * 1987-10-13 1989-04-18 Mitsubishi Petrochem Co Ltd α−メチルスチレンの製造方法
JPH02149534A (ja) * 1988-11-30 1990-06-08 Mitsui Petrochem Ind Ltd クメンの製造方法
JPH02231442A (ja) * 1988-11-28 1990-09-13 Mitsui Petrochem Ind Ltd フェノールの製造方法
JPH06192151A (ja) * 1992-09-11 1994-07-12 Aristech Chem Corp クメンヒドロペルオキシドの二段階分解
JPH0920699A (ja) * 1995-07-07 1997-01-21 Mitsui Petrochem Ind Ltd フェノールの製造方法
JP2001511787A (ja) * 1997-02-11 2001-08-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ヒドロペルオキシドの分解法
JP2002543052A (ja) * 1999-04-22 2002-12-17 モービル・オイル・コーポレイション フェノールの製造
JP2003506342A (ja) * 1999-08-03 2003-02-18 モービル・オイル・コーポレイション フェノール及びアセトンの製造方法
JP2003518047A (ja) * 1999-12-21 2003-06-03 エクソンモービル・オイル・コーポレイション 反応性蒸留によるフェノールの製法

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US5371305A (en) * 1992-12-31 1994-12-06 Hercules Incorporated Process for producing phenol from cumene
US5463136A (en) * 1994-12-22 1995-10-31 Shell Oil Company Cumene hydroperoxide cleavage process
WO1998027030A1 (en) 1996-12-17 1998-06-25 Alliedsignal Inc. Process for the production of alpha methylstyrenes
DE69907148T2 (de) 1998-02-17 2003-10-16 Shell Internationale Research Maatschappij B.V., Den Haag Verfahren zur herstellung von styrolen
US5905178A (en) * 1998-04-20 1999-05-18 Catalytic Distillation Technologies Removal of α-methyl styrene from cumene
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Publication number Priority date Publication date Assignee Title
US2757209A (en) * 1951-04-26 1956-07-31 Allied Chem & Dye Corp Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
JPS5832831A (ja) * 1981-06-22 1983-02-25 アライド・コ−ポレ−シヨン クメン酸化生成物の分解法
JPS60174737A (ja) * 1984-02-22 1985-09-09 Mitsui Petrochem Ind Ltd 芳香族アルコ−ルの製造法
JPH01100136A (ja) * 1987-10-13 1989-04-18 Mitsubishi Petrochem Co Ltd α−メチルスチレンの製造方法
JPH02231442A (ja) * 1988-11-28 1990-09-13 Mitsui Petrochem Ind Ltd フェノールの製造方法
JPH02149534A (ja) * 1988-11-30 1990-06-08 Mitsui Petrochem Ind Ltd クメンの製造方法
JPH02172927A (ja) * 1988-12-26 1990-07-04 Mitsui Petrochem Ind Ltd クメンの製造方法
JPH06192151A (ja) * 1992-09-11 1994-07-12 Aristech Chem Corp クメンヒドロペルオキシドの二段階分解
JPH0920699A (ja) * 1995-07-07 1997-01-21 Mitsui Petrochem Ind Ltd フェノールの製造方法
JP2001511787A (ja) * 1997-02-11 2001-08-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ヒドロペルオキシドの分解法
JP2002543052A (ja) * 1999-04-22 2002-12-17 モービル・オイル・コーポレイション フェノールの製造
JP2003506342A (ja) * 1999-08-03 2003-02-18 モービル・オイル・コーポレイション フェノール及びアセトンの製造方法
JP2003518047A (ja) * 1999-12-21 2003-06-03 エクソンモービル・オイル・コーポレイション 反応性蒸留によるフェノールの製法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010517933A (ja) * 2006-08-03 2010-05-27 エクソンモービル・ケミカル・パテンツ・インク アルキル芳香族化合物の酸化法
JP2013535484A (ja) * 2010-12-01 2013-09-12 エルジー・ケム・リミテッド αメチルスチレンの製造方法
JP2014522381A (ja) * 2011-07-15 2014-09-04 エルジー・ケム・リミテッド クミルアルコールの製造方法およびフェノール、アセトン、およびアルファメチルスチレンの製造方法

Also Published As

Publication number Publication date
ATE483674T1 (de) 2010-10-15
CN102060653A (zh) 2011-05-18
CN1726176A (zh) 2006-01-25
US6984761B2 (en) 2006-01-10
TW200508186A (en) 2005-03-01
EP1575888B1 (en) 2010-10-06
EP1575888A1 (en) 2005-09-21
KR101084379B1 (ko) 2011-11-18
AU2003297321A1 (en) 2004-07-22
DE60334493D1 (de) 2010-11-18
WO2004058672A1 (en) 2004-07-15
KR20050088178A (ko) 2005-09-02
US20040116749A1 (en) 2004-06-17
TWI310027B (en) 2009-05-21

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