AU2003297321A1 - Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor - Google Patents

Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor

Info

Publication number
AU2003297321A1
AU2003297321A1 AU2003297321A AU2003297321A AU2003297321A1 AU 2003297321 A1 AU2003297321 A1 AU 2003297321A1 AU 2003297321 A AU2003297321 A AU 2003297321A AU 2003297321 A AU2003297321 A AU 2003297321A AU 2003297321 A1 AU2003297321 A1 AU 2003297321A1
Authority
AU
Australia
Prior art keywords
methylstyrene
alpha
phenol
acetone
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2003297321A
Other languages
English (en)
Inventor
Doron Levin
Jose Guadalupe Santiesteban
Morris C. Smith
James C. Vartuli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of AU2003297321A1 publication Critical patent/AU2003297321A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AU2003297321A 2002-12-16 2003-12-16 Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor Abandoned AU2003297321A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/320,237 2002-12-16
US10/320,237 US6984761B2 (en) 2002-12-16 2002-12-16 Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
PCT/US2003/040283 WO2004058672A1 (en) 2002-12-16 2003-12-16 Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor

Publications (1)

Publication Number Publication Date
AU2003297321A1 true AU2003297321A1 (en) 2004-07-22

Family

ID=32506828

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2003297321A Abandoned AU2003297321A1 (en) 2002-12-16 2003-12-16 Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor

Country Status (10)

Country Link
US (1) US6984761B2 (enExample)
EP (1) EP1575888B1 (enExample)
JP (1) JP2006509829A (enExample)
KR (1) KR101084379B1 (enExample)
CN (2) CN1726176A (enExample)
AT (1) ATE483674T1 (enExample)
AU (1) AU2003297321A1 (enExample)
DE (1) DE60334493D1 (enExample)
TW (1) TWI310027B (enExample)
WO (1) WO2004058672A1 (enExample)

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US7285512B2 (en) * 2004-08-31 2007-10-23 Exxonmobile Research And Engineering Company Selective hydrodesulfurization catalyst
US7455762B2 (en) * 2004-08-31 2008-11-25 Exxonmobil Research And Engineering Company Selective hydrodesulfurization process
US8189615B2 (en) * 2004-12-23 2012-05-29 Nokia Corporation Method and apparatus for communicating scheduling information from a UE to a radio access network
ES2261080B1 (es) * 2005-04-19 2007-12-16 Universidad Politecnica De Valencia Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
US7452841B2 (en) * 2005-09-23 2008-11-18 Eastman Chemical Company Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids
US20100063329A1 (en) * 2006-05-16 2010-03-11 John Charles Saukaitis Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
JP2010517933A (ja) * 2006-08-03 2010-05-27 エクソンモービル・ケミカル・パテンツ・インク アルキル芳香族化合物の酸化法
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
CN102227393B (zh) * 2008-12-01 2015-02-18 三井化学株式会社 烯烃的制造方法
SG174387A1 (en) * 2009-03-16 2011-11-28 Mitsui Chemicals Inc Process for production of olefins
KR101403517B1 (ko) * 2010-12-01 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101403518B1 (ko) 2010-12-21 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101447255B1 (ko) * 2011-07-22 2014-10-07 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101476376B1 (ko) * 2011-07-15 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
WO2013012203A2 (ko) * 2011-07-15 2013-01-24 주식회사 엘지화학 쿠밀 알코올의 제조 방법 및 페놀, 아세톤, 및 알파 메틸 스티렌의 제조방법
KR101431122B1 (ko) * 2011-08-12 2014-08-19 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101476375B1 (ko) * 2011-09-02 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
WO2013058877A1 (en) 2011-10-18 2013-04-25 Exxonmobil Chemical Patents Inc. Process for co-producing of propylene oxide and phenol
WO2017118887A1 (en) * 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Systems and methods for the co-production of hydrogen and alkylene oxides
CN112079691A (zh) * 2020-09-17 2020-12-15 吉化集团油脂化工有限公司 提升苯酚产品质量的方法
RU2750718C1 (ru) * 2020-12-04 2021-07-01 федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") Способ разложения гидропероксида изопропилбензола с получением диметилфенилкарбинола
US11858874B2 (en) 2020-12-21 2024-01-02 Lg Chem, Ltd. Method for preparing alpha-methylstyrene

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US2757209A (en) * 1951-04-26 1956-07-31 Allied Chem & Dye Corp Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
US2854487A (en) * 1955-04-12 1958-09-30 Distillers Co Yeast Ltd Process for the manufacture of carbinols
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US3403193A (en) * 1965-06-28 1968-09-24 Halcon International Inc Process for the co-production of a styrene and a di-olefin
SU462812A1 (ru) * 1972-03-28 1975-03-05 Предприятие П/Я Р-6235 Способ совместного получени фенола, ацетона и -метилстирола
JPS56140935A (en) 1980-04-03 1981-11-04 Sumitomo Chem Co Ltd Preparation of styrene compound
US4358618A (en) * 1981-06-22 1982-11-09 Allied Corporation Decomposition of cumene oxidation product
JPS5916843A (ja) 1982-07-20 1984-01-28 Mitsui Toatsu Chem Inc 芳香族アルコ−ルの連続製造法
JPS60174737A (ja) * 1984-02-22 1985-09-09 Mitsui Petrochem Ind Ltd 芳香族アルコ−ルの製造法
US4853197A (en) * 1987-06-04 1989-08-01 Uop Crystalline metal aluminophosphates
JP2544745B2 (ja) * 1987-10-13 1996-10-16 三菱化学株式会社 α−メチルスチレンの製造方法
JPH02231442A (ja) * 1988-11-28 1990-09-13 Mitsui Petrochem Ind Ltd フェノールの製造方法
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CA2003925C (en) * 1988-11-28 1999-11-23 Shintaro Araki Preparation of cumene through alkylation of an aromatic compound and preparation of phenol through cumene
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Also Published As

Publication number Publication date
US20040116749A1 (en) 2004-06-17
CN1726176A (zh) 2006-01-25
WO2004058672A1 (en) 2004-07-15
ATE483674T1 (de) 2010-10-15
KR20050088178A (ko) 2005-09-02
TWI310027B (en) 2009-05-21
JP2006509829A (ja) 2006-03-23
DE60334493D1 (de) 2010-11-18
KR101084379B1 (ko) 2011-11-18
EP1575888A1 (en) 2005-09-21
US6984761B2 (en) 2006-01-10
CN102060653A (zh) 2011-05-18
EP1575888B1 (en) 2010-10-06
TW200508186A (en) 2005-03-01

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Legal Events

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MK6 Application lapsed section 142(2)(f)/reg. 8.3(3) - pct applic. not entering national phase