CN1726176A - 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂 - Google Patents

共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂 Download PDF

Info

Publication number
CN1726176A
CN1726176A CNA2003801061712A CN200380106171A CN1726176A CN 1726176 A CN1726176 A CN 1726176A CN A2003801061712 A CNA2003801061712 A CN A2003801061712A CN 200380106171 A CN200380106171 A CN 200380106171A CN 1726176 A CN1726176 A CN 1726176A
Authority
CN
China
Prior art keywords
group
catalyst
metals
stream
containing stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2003801061712A
Other languages
English (en)
Chinese (zh)
Inventor
D·莱文
J·G·桑铁斯特万
C·M·史密斯
J·C·瓦尔图利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CN1726176A publication Critical patent/CN1726176A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/02Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08Compounds containing six-membered aromatic rings
    • C07C409/10Cumene hydroperoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/185Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00Preparation of peroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054Sulfuric acid or other acids with the formula H2Sn03n+1
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNA2003801061712A 2002-12-16 2003-12-16 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂 Pending CN1726176A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/320,237 2002-12-16
US10/320,237 US6984761B2 (en) 2002-12-16 2002-12-16 Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN2010105394660A Division CN102060653A (zh) 2002-12-16 2003-12-16 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂

Publications (1)

Publication Number Publication Date
CN1726176A true CN1726176A (zh) 2006-01-25

Family

ID=32506828

Family Applications (2)

Application Number Title Priority Date Filing Date
CNA2003801061712A Pending CN1726176A (zh) 2002-12-16 2003-12-16 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂
CN2010105394660A Pending CN102060653A (zh) 2002-12-16 2003-12-16 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2010105394660A Pending CN102060653A (zh) 2002-12-16 2003-12-16 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂

Country Status (10)

Country Link
US (1) US6984761B2 (enExample)
EP (1) EP1575888B1 (enExample)
JP (1) JP2006509829A (enExample)
KR (1) KR101084379B1 (enExample)
CN (2) CN1726176A (enExample)
AT (1) ATE483674T1 (enExample)
AU (1) AU2003297321A1 (enExample)
DE (1) DE60334493D1 (enExample)
TW (1) TWI310027B (enExample)
WO (1) WO2004058672A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103052611A (zh) * 2010-12-01 2013-04-17 Lg化学株式会社 α-甲基苯乙烯的制备方法
CN103562168A (zh) * 2011-07-15 2014-02-05 Lg化学株式会社 异丙苯醇的制备方法和苯酚、丙酮及α-甲基苯乙烯的制备方法

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7455762B2 (en) * 2004-08-31 2008-11-25 Exxonmobil Research And Engineering Company Selective hydrodesulfurization process
US7285512B2 (en) * 2004-08-31 2007-10-23 Exxonmobile Research And Engineering Company Selective hydrodesulfurization catalyst
US8189615B2 (en) * 2004-12-23 2012-05-29 Nokia Corporation Method and apparatus for communicating scheduling information from a UE to a radio access network
ES2261080B1 (es) * 2005-04-19 2007-12-16 Universidad Politecnica De Valencia Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
US7452841B2 (en) * 2005-09-23 2008-11-18 Eastman Chemical Company Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids
WO2007137020A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
CN101511784A (zh) * 2006-08-03 2009-08-19 埃克森美孚化学专利公司 烷基芳族化合物的氧化方法
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US8680355B2 (en) * 2008-12-01 2014-03-25 Mitsui Chemcials, Inc. Olefin production process
WO2010106966A1 (ja) * 2009-03-16 2010-09-23 三井化学株式会社 オレフィンの製造方法
KR101403518B1 (ko) 2010-12-21 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101476376B1 (ko) * 2011-07-15 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101447255B1 (ko) * 2011-07-22 2014-10-07 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101431122B1 (ko) * 2011-08-12 2014-08-19 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101476375B1 (ko) * 2011-09-02 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
US9115105B2 (en) 2011-09-30 2015-08-25 Exxonmobil Chemical Patents Inc. Production of propylene oxide
WO2017118887A1 (en) * 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Systems and methods for the co-production of hydrogen and alkylene oxides
CN112079691A (zh) * 2020-09-17 2020-12-15 吉化集团油脂化工有限公司 提升苯酚产品质量的方法
RU2750718C1 (ru) * 2020-12-04 2021-07-01 федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") Способ разложения гидропероксида изопропилбензола с получением диметилфенилкарбинола
EP4043420B1 (en) 2020-12-21 2024-10-09 LG Chem, Ltd. Method for producing alpha-methylstyrene

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2757209A (en) * 1951-04-26 1956-07-31 Allied Chem & Dye Corp Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
US2854487A (en) * 1955-04-12 1958-09-30 Distillers Co Yeast Ltd Process for the manufacture of carbinols
BE657838A (enExample) 1964-01-07 1965-06-30
US3403193A (en) * 1965-06-28 1968-09-24 Halcon International Inc Process for the co-production of a styrene and a di-olefin
SU462812A1 (ru) * 1972-03-28 1975-03-05 Предприятие П/Я Р-6235 Способ совместного получени фенола, ацетона и -метилстирола
JPS56140935A (en) 1980-04-03 1981-11-04 Sumitomo Chem Co Ltd Preparation of styrene compound
US4358618A (en) * 1981-06-22 1982-11-09 Allied Corporation Decomposition of cumene oxidation product
JPS5916843A (ja) 1982-07-20 1984-01-28 Mitsui Toatsu Chem Inc 芳香族アルコ−ルの連続製造法
JPS60174737A (ja) * 1984-02-22 1985-09-09 Mitsui Petrochem Ind Ltd 芳香族アルコ−ルの製造法
US4853197A (en) * 1987-06-04 1989-08-01 Uop Crystalline metal aluminophosphates
JP2544745B2 (ja) * 1987-10-13 1996-10-16 三菱化学株式会社 α−メチルスチレンの製造方法
JP2593212B2 (ja) * 1988-11-30 1997-03-26 三井石油化学工業株式会社 クメンの製造方法
JPH02231442A (ja) * 1988-11-28 1990-09-13 Mitsui Petrochem Ind Ltd フェノールの製造方法
RU1839668C (ru) * 1988-11-28 1993-12-30 МИЦУИ ПЕТРОКЕМИКАЛ ИНДАСТРИЗ, Лтд (JP) Способ получени фенола
US5245090A (en) * 1992-09-11 1993-09-14 Aristech Chemical Corporation Two-stage cleavage of cumene hydroperoxide
US5371305A (en) * 1992-12-31 1994-12-06 Hercules Incorporated Process for producing phenol from cumene
US5463136A (en) * 1994-12-22 1995-10-31 Shell Oil Company Cumene hydroperoxide cleavage process
JP3769050B2 (ja) * 1995-07-07 2006-04-19 三井化学株式会社 フェノールの製造方法
WO1998027030A1 (en) 1996-12-17 1998-06-25 Alliedsignal Inc. Process for the production of alpha methylstyrenes
JP3976793B2 (ja) * 1997-02-11 2007-09-19 インヴィスタ テクノロジー エスアエルエル ヒドロペルオキシドの分解法
DE69907148T2 (de) 1998-02-17 2003-10-16 Shell Internationale Research Maatschappij B.V., Den Haag Verfahren zur herstellung von styrolen
US5905178A (en) * 1998-04-20 1999-05-18 Catalytic Distillation Technologies Removal of α-methyl styrene from cumene
US5932751A (en) * 1998-06-23 1999-08-03 Arco Chemical Technology, L.P. Epoxidation catalyst and process
US6169215B1 (en) * 1999-03-25 2001-01-02 Mobil Oil Corporation Production of phenol
US6169216B1 (en) * 1999-04-22 2001-01-02 Mobil Oil Corporation Production of phenol
US6297406B1 (en) * 1999-08-03 2001-10-02 Mobil Oil Corporation Production of phenol
US6114551A (en) * 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
US6410804B1 (en) * 1999-12-21 2002-06-25 Exxon Mobil Oil Corporation Production of phenol using reactive distillation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103052611A (zh) * 2010-12-01 2013-04-17 Lg化学株式会社 α-甲基苯乙烯的制备方法
CN103052611B (zh) * 2010-12-01 2016-02-10 Lg化学株式会社 α-甲基苯乙烯的制备方法
CN103562168A (zh) * 2011-07-15 2014-02-05 Lg化学株式会社 异丙苯醇的制备方法和苯酚、丙酮及α-甲基苯乙烯的制备方法
CN103562168B (zh) * 2011-07-15 2016-08-17 Lg化学株式会社 异丙苯醇的制备方法和苯酚、丙酮及α-甲基苯乙烯的制备方法

Also Published As

Publication number Publication date
ATE483674T1 (de) 2010-10-15
CN102060653A (zh) 2011-05-18
JP2006509829A (ja) 2006-03-23
US6984761B2 (en) 2006-01-10
TW200508186A (en) 2005-03-01
EP1575888B1 (en) 2010-10-06
EP1575888A1 (en) 2005-09-21
KR101084379B1 (ko) 2011-11-18
AU2003297321A1 (en) 2004-07-22
DE60334493D1 (de) 2010-11-18
WO2004058672A1 (en) 2004-07-15
KR20050088178A (ko) 2005-09-02
US20040116749A1 (en) 2004-06-17
TWI310027B (en) 2009-05-21

Similar Documents

Publication Publication Date Title
CN1726176A (zh) 共同生产苯酚、丙酮、α-甲基苯乙烯和环氧丙烷的方法及其催化剂
US6455712B1 (en) Preparation of oxirane compounds
JP2951510B2 (ja) クメンヒドロペルオキシドの二段階分解
US6297406B1 (en) Production of phenol
CN1109883A (zh) 制备环氧化物的集中方法
EP2207762A1 (en) Process for the production of iso-propanol by liquid phase hydrogenation
WO2000058250A1 (en) Hydroperoxide decomposition process
JP4744697B2 (ja) フェノールの製造
JP2774607B2 (ja) フェノールの製造方法およびその製造時の副生アセトンからプロピレンを得る方法
CN114436794B (zh) 一种合成甲基异戊基酮的方法
JP2005097206A (ja) プロピレンオキサイドの製造方法
JP5642314B2 (ja) クミルアルコールの製造方法およびフェノール、アセトン、およびアルファメチルスチレンの製造方法
CN114478440B (zh) 一种环氧丙烷的制备方法及得到的环氧丙烷
CN113651664B (zh) 苄醇转化的方法
CN114436756B (zh) 一种制备异丙苯的方法、系统与应用
CN117917386A (zh) 一种α,α-二甲基苄醇氢解方法及其在环氧丙烷制备中的应用
EP1893330A1 (en) Process for alcohol production by selective ether decomposition
CN1856482A (zh) 生产环氧丙烷的方法
JP2005097208A (ja) プロピレンオキサイドの製造方法
CN116848076A (zh) 丙烯的制造方法
KR101403518B1 (ko) 알파 메틸 스티렌의 제조방법
CN121198162A (zh) 一种联产环己酮和环氧环己烷的生产系统及方法
WO2005030743A1 (ja) プロピレンオキサイドの製造方法
JP2005097209A (ja) プロピレンオキサイドの製造方法
JP2005097211A (ja) プロピレンオキサイドの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Open date: 20060125