KR101084379B1 - 페놀, 아세톤, α-메틸스타이렌 및 프로필렌 옥사이드의동시 제조방법, 및 이를 위한 촉매 - Google Patents

페놀, 아세톤, α-메틸스타이렌 및 프로필렌 옥사이드의동시 제조방법, 및 이를 위한 촉매 Download PDF

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KR101084379B1
KR101084379B1 KR1020057010980A KR20057010980A KR101084379B1 KR 101084379 B1 KR101084379 B1 KR 101084379B1 KR 1020057010980 A KR1020057010980 A KR 1020057010980A KR 20057010980 A KR20057010980 A KR 20057010980A KR 101084379 B1 KR101084379 B1 KR 101084379B1
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acetone
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도론 레빈
조스 구아달루페 산티스테반
모리스 씨 스미스
제임스 씨 바툴리
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엑손모빌 케미칼 패턴츠 인코포레이티드
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/02Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08Compounds containing six-membered aromatic rings
    • C07C409/10Cumene hydroperoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/185Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00Preparation of peroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054Sulfuric acid or other acids with the formula H2Sn03n+1
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020057010980A 2002-12-16 2003-12-16 페놀, 아세톤, α-메틸스타이렌 및 프로필렌 옥사이드의동시 제조방법, 및 이를 위한 촉매 Expired - Fee Related KR101084379B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/320,237 2002-12-16
US10/320,237 US6984761B2 (en) 2002-12-16 2002-12-16 Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
PCT/US2003/040283 WO2004058672A1 (en) 2002-12-16 2003-12-16 Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor

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KR20050088178A KR20050088178A (ko) 2005-09-02
KR101084379B1 true KR101084379B1 (ko) 2011-11-18

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US (1) US6984761B2 (enExample)
EP (1) EP1575888B1 (enExample)
JP (1) JP2006509829A (enExample)
KR (1) KR101084379B1 (enExample)
CN (2) CN1726176A (enExample)
AT (1) ATE483674T1 (enExample)
AU (1) AU2003297321A1 (enExample)
DE (1) DE60334493D1 (enExample)
TW (1) TWI310027B (enExample)
WO (1) WO2004058672A1 (enExample)

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US7455762B2 (en) * 2004-08-31 2008-11-25 Exxonmobil Research And Engineering Company Selective hydrodesulfurization process
US7285512B2 (en) * 2004-08-31 2007-10-23 Exxonmobile Research And Engineering Company Selective hydrodesulfurization catalyst
US8189615B2 (en) * 2004-12-23 2012-05-29 Nokia Corporation Method and apparatus for communicating scheduling information from a UE to a radio access network
ES2261080B1 (es) * 2005-04-19 2007-12-16 Universidad Politecnica De Valencia Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
US7452841B2 (en) * 2005-09-23 2008-11-18 Eastman Chemical Company Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids
WO2007137020A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
CN101511784A (zh) * 2006-08-03 2009-08-19 埃克森美孚化学专利公司 烷基芳族化合物的氧化方法
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US8680355B2 (en) * 2008-12-01 2014-03-25 Mitsui Chemcials, Inc. Olefin production process
WO2010106966A1 (ja) * 2009-03-16 2010-09-23 三井化学株式会社 オレフィンの製造方法
KR101403517B1 (ko) * 2010-12-01 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101403518B1 (ko) 2010-12-21 2014-06-10 주식회사 엘지화학 알파 메틸 스티렌의 제조방법
KR101476376B1 (ko) * 2011-07-15 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101447255B1 (ko) * 2011-07-22 2014-10-07 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
WO2013012203A2 (ko) * 2011-07-15 2013-01-24 주식회사 엘지화학 쿠밀 알코올의 제조 방법 및 페놀, 아세톤, 및 알파 메틸 스티렌의 제조방법
KR101431122B1 (ko) * 2011-08-12 2014-08-19 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
KR101476375B1 (ko) * 2011-09-02 2014-12-26 주식회사 엘지화학 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법
US9115105B2 (en) 2011-09-30 2015-08-25 Exxonmobil Chemical Patents Inc. Production of propylene oxide
WO2017118887A1 (en) * 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Systems and methods for the co-production of hydrogen and alkylene oxides
CN112079691A (zh) * 2020-09-17 2020-12-15 吉化集团油脂化工有限公司 提升苯酚产品质量的方法
RU2750718C1 (ru) * 2020-12-04 2021-07-01 федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") Способ разложения гидропероксида изопропилбензола с получением диметилфенилкарбинола
EP4043420B1 (en) 2020-12-21 2024-10-09 LG Chem, Ltd. Method for producing alpha-methylstyrene

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Publication number Publication date
ATE483674T1 (de) 2010-10-15
CN102060653A (zh) 2011-05-18
JP2006509829A (ja) 2006-03-23
CN1726176A (zh) 2006-01-25
US6984761B2 (en) 2006-01-10
TW200508186A (en) 2005-03-01
EP1575888B1 (en) 2010-10-06
EP1575888A1 (en) 2005-09-21
AU2003297321A1 (en) 2004-07-22
DE60334493D1 (de) 2010-11-18
WO2004058672A1 (en) 2004-07-15
KR20050088178A (ko) 2005-09-02
US20040116749A1 (en) 2004-06-17
TWI310027B (en) 2009-05-21

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