DE60334493D1 - Gleichzeitige herstellung von phenol, aceton und alpha-methylstyren - Google Patents
Gleichzeitige herstellung von phenol, aceton und alpha-methylstyrenInfo
- Publication number
- DE60334493D1 DE60334493D1 DE60334493T DE60334493T DE60334493D1 DE 60334493 D1 DE60334493 D1 DE 60334493D1 DE 60334493 T DE60334493 T DE 60334493T DE 60334493 T DE60334493 T DE 60334493T DE 60334493 D1 DE60334493 D1 DE 60334493D1
- Authority
- DE
- Germany
- Prior art keywords
- alpha
- methylstyrene
- phenol
- acetone
- produced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 title abstract 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 6
- BDCFWIDZNLCTMF-UHFFFAOYSA-N 2-phenylpropan-2-ol Chemical compound CC(C)(O)C1=CC=CC=C1 BDCFWIDZNLCTMF-UHFFFAOYSA-N 0.000 abstract 3
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000003776 cleavage reaction Methods 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000007017 scission Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
- C07C409/10—Cumene hydroperoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
- C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/320,237 US6984761B2 (en) | 2002-12-16 | 2002-12-16 | Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor |
| PCT/US2003/040283 WO2004058672A1 (en) | 2002-12-16 | 2003-12-16 | Co-production of phenol, acetone, alpha-methylstyrene and propylene oxide, and catalyst therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60334493D1 true DE60334493D1 (de) | 2010-11-18 |
Family
ID=32506828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60334493T Expired - Lifetime DE60334493D1 (de) | 2002-12-16 | 2003-12-16 | Gleichzeitige herstellung von phenol, aceton und alpha-methylstyren |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6984761B2 (enExample) |
| EP (1) | EP1575888B1 (enExample) |
| JP (1) | JP2006509829A (enExample) |
| KR (1) | KR101084379B1 (enExample) |
| CN (2) | CN1726176A (enExample) |
| AT (1) | ATE483674T1 (enExample) |
| AU (1) | AU2003297321A1 (enExample) |
| DE (1) | DE60334493D1 (enExample) |
| TW (1) | TWI310027B (enExample) |
| WO (1) | WO2004058672A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7455762B2 (en) * | 2004-08-31 | 2008-11-25 | Exxonmobil Research And Engineering Company | Selective hydrodesulfurization process |
| US7285512B2 (en) * | 2004-08-31 | 2007-10-23 | Exxonmobile Research And Engineering Company | Selective hydrodesulfurization catalyst |
| US8189615B2 (en) * | 2004-12-23 | 2012-05-29 | Nokia Corporation | Method and apparatus for communicating scheduling information from a UE to a radio access network |
| ES2261080B1 (es) * | 2005-04-19 | 2007-12-16 | Universidad Politecnica De Valencia | Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno. |
| US7452841B2 (en) * | 2005-09-23 | 2008-11-18 | Eastman Chemical Company | Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids |
| WO2007137020A2 (en) * | 2006-05-16 | 2007-11-29 | Shell Oil Company | Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts |
| CN101511784A (zh) * | 2006-08-03 | 2009-08-19 | 埃克森美孚化学专利公司 | 烷基芳族化合物的氧化方法 |
| US7417003B2 (en) * | 2006-12-29 | 2008-08-26 | Uop Llc | Solid acid catalyst and process for decomposition of cumene hydroperoxide |
| US8680355B2 (en) * | 2008-12-01 | 2014-03-25 | Mitsui Chemcials, Inc. | Olefin production process |
| WO2010106966A1 (ja) * | 2009-03-16 | 2010-09-23 | 三井化学株式会社 | オレフィンの製造方法 |
| KR101403517B1 (ko) * | 2010-12-01 | 2014-06-10 | 주식회사 엘지화학 | 알파 메틸 스티렌의 제조방법 |
| KR101403518B1 (ko) | 2010-12-21 | 2014-06-10 | 주식회사 엘지화학 | 알파 메틸 스티렌의 제조방법 |
| KR101476376B1 (ko) * | 2011-07-15 | 2014-12-26 | 주식회사 엘지화학 | 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법 |
| KR101447255B1 (ko) * | 2011-07-22 | 2014-10-07 | 주식회사 엘지화학 | 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법 |
| WO2013012203A2 (ko) * | 2011-07-15 | 2013-01-24 | 주식회사 엘지화학 | 쿠밀 알코올의 제조 방법 및 페놀, 아세톤, 및 알파 메틸 스티렌의 제조방법 |
| KR101431122B1 (ko) * | 2011-08-12 | 2014-08-19 | 주식회사 엘지화학 | 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법 |
| KR101476375B1 (ko) * | 2011-09-02 | 2014-12-26 | 주식회사 엘지화학 | 페놀, 아세톤 및 알파 메틸 스티렌의 제조방법 |
| US9115105B2 (en) | 2011-09-30 | 2015-08-25 | Exxonmobil Chemical Patents Inc. | Production of propylene oxide |
| WO2017118887A1 (en) * | 2016-01-05 | 2017-07-13 | Sabic Global Technologies B.V. | Systems and methods for the co-production of hydrogen and alkylene oxides |
| CN112079691A (zh) * | 2020-09-17 | 2020-12-15 | 吉化集团油脂化工有限公司 | 提升苯酚产品质量的方法 |
| RU2750718C1 (ru) * | 2020-12-04 | 2021-07-01 | федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") | Способ разложения гидропероксида изопропилбензола с получением диметилфенилкарбинола |
| EP4043420B1 (en) | 2020-12-21 | 2024-10-09 | LG Chem, Ltd. | Method for producing alpha-methylstyrene |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2757209A (en) * | 1951-04-26 | 1956-07-31 | Allied Chem & Dye Corp | Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures |
| US2854487A (en) * | 1955-04-12 | 1958-09-30 | Distillers Co Yeast Ltd | Process for the manufacture of carbinols |
| BE657838A (enExample) | 1964-01-07 | 1965-06-30 | ||
| US3403193A (en) * | 1965-06-28 | 1968-09-24 | Halcon International Inc | Process for the co-production of a styrene and a di-olefin |
| SU462812A1 (ru) * | 1972-03-28 | 1975-03-05 | Предприятие П/Я Р-6235 | Способ совместного получени фенола, ацетона и -метилстирола |
| JPS56140935A (en) | 1980-04-03 | 1981-11-04 | Sumitomo Chem Co Ltd | Preparation of styrene compound |
| US4358618A (en) * | 1981-06-22 | 1982-11-09 | Allied Corporation | Decomposition of cumene oxidation product |
| JPS5916843A (ja) | 1982-07-20 | 1984-01-28 | Mitsui Toatsu Chem Inc | 芳香族アルコ−ルの連続製造法 |
| JPS60174737A (ja) * | 1984-02-22 | 1985-09-09 | Mitsui Petrochem Ind Ltd | 芳香族アルコ−ルの製造法 |
| US4853197A (en) * | 1987-06-04 | 1989-08-01 | Uop | Crystalline metal aluminophosphates |
| JP2544745B2 (ja) * | 1987-10-13 | 1996-10-16 | 三菱化学株式会社 | α−メチルスチレンの製造方法 |
| JP2593212B2 (ja) * | 1988-11-30 | 1997-03-26 | 三井石油化学工業株式会社 | クメンの製造方法 |
| JPH02231442A (ja) * | 1988-11-28 | 1990-09-13 | Mitsui Petrochem Ind Ltd | フェノールの製造方法 |
| RU1839668C (ru) * | 1988-11-28 | 1993-12-30 | МИЦУИ ПЕТРОКЕМИКАЛ ИНДАСТРИЗ, Лтд (JP) | Способ получени фенола |
| US5245090A (en) * | 1992-09-11 | 1993-09-14 | Aristech Chemical Corporation | Two-stage cleavage of cumene hydroperoxide |
| US5371305A (en) * | 1992-12-31 | 1994-12-06 | Hercules Incorporated | Process for producing phenol from cumene |
| US5463136A (en) * | 1994-12-22 | 1995-10-31 | Shell Oil Company | Cumene hydroperoxide cleavage process |
| JP3769050B2 (ja) * | 1995-07-07 | 2006-04-19 | 三井化学株式会社 | フェノールの製造方法 |
| WO1998027030A1 (en) | 1996-12-17 | 1998-06-25 | Alliedsignal Inc. | Process for the production of alpha methylstyrenes |
| JP3976793B2 (ja) * | 1997-02-11 | 2007-09-19 | インヴィスタ テクノロジー エスアエルエル | ヒドロペルオキシドの分解法 |
| DE69907148T2 (de) | 1998-02-17 | 2003-10-16 | Shell Internationale Research Maatschappij B.V., Den Haag | Verfahren zur herstellung von styrolen |
| US5905178A (en) * | 1998-04-20 | 1999-05-18 | Catalytic Distillation Technologies | Removal of α-methyl styrene from cumene |
| US5932751A (en) * | 1998-06-23 | 1999-08-03 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
| US6169215B1 (en) * | 1999-03-25 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6169216B1 (en) * | 1999-04-22 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6297406B1 (en) * | 1999-08-03 | 2001-10-02 | Mobil Oil Corporation | Production of phenol |
| US6114551A (en) * | 1999-10-04 | 2000-09-05 | Mobil Oil Corporation | Olefin epoxidation catalysts |
| US6410804B1 (en) * | 1999-12-21 | 2002-06-25 | Exxon Mobil Oil Corporation | Production of phenol using reactive distillation |
-
2002
- 2002-12-16 US US10/320,237 patent/US6984761B2/en not_active Expired - Fee Related
-
2003
- 2003-12-16 CN CNA2003801061712A patent/CN1726176A/zh active Pending
- 2003-12-16 CN CN2010105394660A patent/CN102060653A/zh active Pending
- 2003-12-16 TW TW092135625A patent/TWI310027B/zh not_active IP Right Cessation
- 2003-12-16 AU AU2003297321A patent/AU2003297321A1/en not_active Abandoned
- 2003-12-16 JP JP2004563715A patent/JP2006509829A/ja active Pending
- 2003-12-16 DE DE60334493T patent/DE60334493D1/de not_active Expired - Lifetime
- 2003-12-16 AT AT03814132T patent/ATE483674T1/de not_active IP Right Cessation
- 2003-12-16 KR KR1020057010980A patent/KR101084379B1/ko not_active Expired - Fee Related
- 2003-12-16 WO PCT/US2003/040283 patent/WO2004058672A1/en not_active Ceased
- 2003-12-16 EP EP03814132A patent/EP1575888B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE483674T1 (de) | 2010-10-15 |
| CN102060653A (zh) | 2011-05-18 |
| JP2006509829A (ja) | 2006-03-23 |
| CN1726176A (zh) | 2006-01-25 |
| US6984761B2 (en) | 2006-01-10 |
| TW200508186A (en) | 2005-03-01 |
| EP1575888B1 (en) | 2010-10-06 |
| EP1575888A1 (en) | 2005-09-21 |
| KR101084379B1 (ko) | 2011-11-18 |
| AU2003297321A1 (en) | 2004-07-22 |
| WO2004058672A1 (en) | 2004-07-15 |
| KR20050088178A (ko) | 2005-09-02 |
| US20040116749A1 (en) | 2004-06-17 |
| TWI310027B (en) | 2009-05-21 |
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