JP2005179613A - ハードコート剤組成物及びこれを用いた光情報媒体 - Google Patents
ハードコート剤組成物及びこれを用いた光情報媒体 Download PDFInfo
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- JP2005179613A JP2005179613A JP2003426434A JP2003426434A JP2005179613A JP 2005179613 A JP2005179613 A JP 2005179613A JP 2003426434 A JP2003426434 A JP 2003426434A JP 2003426434 A JP2003426434 A JP 2003426434A JP 2005179613 A JP2005179613 A JP 2005179613A
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- hard coat
- fluorine
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- coat agent
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 109
- 230000003287 optical effect Effects 0.000 title claims abstract description 89
- 239000011248 coating agent Substances 0.000 title abstract description 15
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 115
- 239000011737 fluorine Substances 0.000 claims abstract description 115
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 110
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 99
- 150000001875 compounds Chemical class 0.000 claims abstract description 91
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 50
- 229920000570 polyether Polymers 0.000 claims abstract description 50
- 229920001400 block copolymer Polymers 0.000 claims abstract description 44
- 239000000758 substrate Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims description 51
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- 230000005540 biological transmission Effects 0.000 claims description 27
- -1 silane compound Chemical class 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 12
- 229910052752 metalloid Inorganic materials 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 7
- 150000002738 metalloids Chemical class 0.000 claims description 7
- 239000010702 perfluoropolyether Substances 0.000 claims description 7
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- 229910052782 aluminium Inorganic materials 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
- 230000001678 irradiating effect Effects 0.000 description 4
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 4
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
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- 239000003085 diluting agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
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- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- 239000002685 polymerization catalyst Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
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- 229910052714 tellurium Inorganic materials 0.000 description 3
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- 229910052720 vanadium Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 2
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- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- BNDRWEVUODOUDW-UHFFFAOYSA-N 3-Hydroxy-3-methylbutan-2-one Chemical compound CC(=O)C(C)(C)O BNDRWEVUODOUDW-UHFFFAOYSA-N 0.000 description 2
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- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
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- HBZFBSFGXQBQTB-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HBZFBSFGXQBQTB-UHFFFAOYSA-N 0.000 description 1
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Abstract
【解決手段】 含フッ素ブロック共重合体(A1)と、活性エネルギー線反応性基を有するフッ素含有ポリエーテル化合物(A2)と、活性エネルギー線硬化性化合物(B)とを含むハードコート剤組成物。支持基体20上に、少なくとも記録層4又は反射層を含む、1層又は複数層から構成される膜体を有する光情報媒体であって、支持基体20側表面及び前記膜体側表面のうちの少なくとも一方の表面が、前記ハードコート剤組成物の硬化物を含むハードコート層8によって形成されている光情報媒体。
【選択図】 図1
Description
(1) 含フッ素ブロック共重合体(A1)と、活性エネルギー線反応性基を有するフッ素含有ポリエーテル化合物(A2)と、活性エネルギー線硬化性化合物(B)とを含むハードコート剤組成物。
不揮発分には、含フッ素ブロック共重合体(A1)、フッ素含有ポリエーテル化合物(A2)及び活性エネルギー線硬化性化合物(B)の他、後述する無機微粒子(C)、光重合開始剤、各種添加剤等の任意成分が含まれる。
前記支持基体の前記膜体が形成された側とは反対側の面上、及び前記膜体面上のうちの少なくとも一方に、(1) 〜(18)のうちのいずれかに記載のハードコート剤組成物を塗布し、活性エネルギー線の照射によって硬化させハードコート層を形成することを含む、光情報媒体の製造方法。
式中、R1は、水素原子又はメチル基を表し、
R2は、-Cp H2P -, -C(Cp H2P+1)H-, -CH2C(Cp H2p+1)H-, 又は -CH2CH2O-を表し、
Rfは、-Cn F2n+1,-(CF2)n H,-(CF2) pOCn H2n C i F2i+1,-(CF2)p OCm H2m C i F2i H,
-N(Cp H2p+1)CO Cn F2n+1, 又は-N(Cp H2p+1)SO2Cn F2n+1 を表す。
但し、p は1〜10、nは1〜16、mは0〜10、iは0〜16の整数である。
CF3(CF2)7CH2CH2OCOCH=CH2, CF3CH2OCOCH=CH2, CF3(CF2)4CH2CH2OCOC(CH3)=CH2,
C7F15CON(C2H5)CH2OCOC(CH3)=CH2, CF3(CF2)7SO2N(CH3)CH2CH2OCOCH=CH2,
C2F5SO2N(C3H7)CH2CH2OCOC(CH3)=CH2, (CF3)2CF(CF2)6(CH2)3OCOCH=CH2,
(CF3)2CF(CF2)10(CH2)3OCOC(CH3)=CH2, CF3(CF2)4CH(CH3)OCOC(CH3)=CH2,
CF3CH2OCH2CH2OCOCH=CH2, C2F5(CH2CH2O)2CH2OCOC=CH2, (CF3)2CFO(CH2)5OCOCH=CH2,
CF3(CF2)4OCH2CH2OCOC(CH3)=CH2, C2F5CON(C2H5)CH2OCOCH=CH2,
CF3(CF2)2CON(CH3)CH(CH3)CH2OCOCH=CH2, H(CF2)6C(C2H5)OCOC(CH3)=CH2,
H(CF2)8CH2OCOCH=CH2, H(CF2)4CH2OCOCH=CH2, H(CF2)6CH2OCOC(CH3)=CH2,
CF3(CF2)7SO2N(CH3)CH2CH2OCOC(CH3)=CH2, CF3(CF2)7SO2N(CH3)(CH2)10OCOCH=CH2,
C2F5SO2N(C2H5)CH2CH2OCOC(CH3)=CH2, CF3(CF2)7SO2N(CH3)(CH2)4OCOCH=CH2,
C2F5SO2N(C2H5)C(C2H5)HCH2OCOCH=CH2
等が挙げられる。これらの単量体のうちから、1種又は2種以上が適宜選択して使用される。
メチル(メタ)アクリレート、エチル(メタ)アクリレート、プロピル(メタ)アクリレート、ブチル(メタ)アクリレート、シクロヘキシル(メタ)アクリレート、ステアリル(メタ)アクリレート、ラウリル(メタ)アクリレート、メトキシエチル(メタ)アクリレート、エトキシエチル(メタ)アクリレート、N,N-ジエチルアミノエチル(メタ)アクリレート、N,N-ジメチルアミノエチル(メタ)アクリレート、テトラヒドロフルフリル(メタ)アクリレート等が挙げられる。これらの単量体のうちから、1種又は2種以上が適宜選択して使用される。
F-[CF2CF2CF2O]l-CF2CF2CH2OH (Demnum-SA)
F-[CF(CF3)CF2O]l-CF(CF3)CH2OH (Krytox-OH)
HO(CH2CH2O)n-CH2-CF2O-[CF2CF2O]l-[CF2O]m-CF2CH2(OCH2CH2)nOH (Zdol-TX)
HOCH2CH(OH)CH2O-CH2-CF2O-[CF2CF2O]l-[CF2O]m-CF2CH2OCH2CH(OH)CH2OH (Z-Tetraol)
・分子量1000当たりに1つ以上の活性エネルギー線反応性基を有するものとして、Fomblin Z DOL diacrylate〔Fomblin Z DOL (アウジモント社製)の末端ヒドロキシル基をアクリレート変性したもの〕や、フルオライトART4(共栄社化学)、
・分子量1000当たりに2つ以上の活性エネルギー線反応性基を有するものとして、フルオライトART3(共栄社化学)、
・分子量1000当たりに4つ以上の活性エネルギー線反応性基を有するものとして、Fomblin Z-Tetraol (アウジモント社製)の4つの末端ヒドロキシル基をアクリレート変性したもの、
等が挙げられる。
まず、膜体側表面が記録/再生ビーム入射側表面とされる光情報媒体について説明する。
図2は、本発明の光ディスクの層構成の一例を示す概略断面図である。図2において、光ディスクは、支持基体(20)の情報ピットやプリグルーブ等の微細凹凸が形成されている側の面上に、反射層(3) 、第2誘電体層(52)、相変化記録材料層(4) 及び第1誘電体層(51)をこの順で有し、第1誘電体層(51)上に光透過層(7) を有し、光透過層(7) 上にハードコート層(8) を有する。この例では、反射層(3) 、第2誘電体層(52)、相変化記録材料層(4) 及び第1誘電体層(51)が情報記録層を構成する。また、前記情報記録層及び光透過層(7) が、記録又は再生のために必要な膜体を構成する。この光ディスクは、ハードコート層(8) 及び光透過層(7) を通して、すなわち膜体側から、記録又は再生のためのレーザー光が入射するように使用される。
次に、支持基体側表面が記録/再生ビーム入射側表面とされる光情報媒体について説明する。
攪拌機付丸型フラスコに、フッ素アクリルブロックコポリマー(製品名:モディパーF600、日本油脂(株)製)20重量部とプロピレングリコール−1−モノメチルエーテル−2−アセテート80重量部を仕込み、ゆっくりと攪拌した。
図2に示す層構成の光記録ディスクサンプルNo.1〜14を次のように作製した。
情報記録のためにグルーブが形成されたディスク状支持基体(20)(ポリカーボネート製、直径120mm、厚さ1.1mm)のグルーブが形成された面上に、Al98Pd1 Cu1 (原子比)からなる厚さ100nmの反射層(3) をスパッタリング法により形成した。前記グルーブの深さは、波長λ=405nmにおける光路長で表してλ/6とした。グルーブ記録方式における記録トラックピッチは、0.32μmとした。
ウレタンアクリレートオリゴマー 50重量部
(三菱レイヨン(株)製、ダイヤビームUK6035)
イソシアヌル酸EO変性トリアクリレート 10重量部
(東亜合成(株)製、アロニックスM315)
イソシアヌル酸EO変性ジアクリレート 5重量部
(東亜合成(株)製、アロニックスM215)
テトラヒドロフルフリルアクリレート 25重量部
光重合開始剤(1−ヒドロキシシクロヘキシルフェニルケトン) 3重量部
反応性基修飾コロイダルシリカ(分散媒:プロピレングリコールモノメチルエーテルアセテート、不揮発分:40重量%) 100重量部
ジペンタエリスリトールヘキサアクリレート 48重量部
テトラヒドロフルフリルアクリレート 12重量部
プロピレングリコールモノメチルエーテルアセテート 40重量部
(非反応性希釈溶剤)
A1成分:前記含フッ素ブロック共重合体(不揮発分として) 表1に記載の重量部
A2成分:Fombrin Z-Tetraol (アウジモント社製)の4つの末端ヒドロキシル基をアクリレート変性したもの(分子量Mw約1,000 ) 表1に記載の重量部
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、フッ素系非架橋型界面活性剤フロラードFC−4430〔フッ素化アルキルエステル(フッ素化脂肪族系)、住友スリーエム製〕0.5重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.15を作製した。
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、フッ素系架橋型界面活性剤M−1820(2−(パーフルオロオクチル)エチルメタアクリレート、ダイキン化成品販売(株))3重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.16を作製した。
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、フッ素系非架橋型界面活性剤フロラードFC−4430(住友スリーエム製)0.5重量部及びフッ素系架橋型界面活性剤ビスコート8F(オクタフルオロペンチルアクリレート、大阪有機化学工業製)2重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.17を作製した。
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、フッ素系非架橋型界面活性剤フロラードFC−4430(住友スリーエム製)10重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.18を作製した。
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、フッ素系架橋型界面活性剤M−1820(ダイキン化成品販売(株))10重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.19を作製した。
ハードコート剤の組成におけるA1成分及びA2成分を用いないで、Demnum-SY (パーフルオロポリエーテル(ダイキン工業(株)製,末端に1つのヒドロキシル基のみを有する,分子量Mw約3,600 )0.3重量部を用いた以外は、上記ディスクサンプルの作製と同様にしてディスクサンプルNo.20を作製した。
上記のように作製した各ディスクサンプルNo.1〜20について、以下に示す性能試験を行った。
各ディスクサンプルのハードコート表面の塗布欠陥が存在するか否かを目視で判断した。
各ディスクサンプルのハードコート表面の接触角を測定した。測定液として純水を用い、協和界面科学(株)製の接触角計 FACE CONTACT-ANGLEMETER を用いて、静止接触角を測定した。測定環境は、温度20℃、相対湿度60%であった。まず、初期の接触角(a) を測定した。
ディスクサンプルNo.1〜14で用いたのと同じ支持基体上に、直接、ディスクサンプルNo.1〜14における各光透過層及び各ハードコート層の形成と全く同じ条件で、光透過層及びハードコート層をそれぞれ形成した。得られたハードコート層付き透明基板のハードコート層表面を、JIS K7204:1994に準拠したテーパー摩耗試験装置を用いて荷重4.9Nで100回摩耗させた。摩耗輪としてはCS−10Fを用いた。摩耗後のハードコート層表面の曇価をヘイズメーターTC−HIII DPK((株)東京電色技術センター製)で測定した。摩耗後のハードコート層表面の曇価は、いずれも2.3%以内であり、ハードコートとして十分な硬さを有していた。
(3) :反射層
(52):第2誘電体層
(4) :記録層
(51):第1誘電体層
(7) :光透過層
(8) :ハードコート層
Claims (23)
- 含フッ素ブロック共重合体(A1)と、活性エネルギー線反応性基を有するフッ素含有ポリエーテル化合物(A2)と、活性エネルギー線硬化性化合物(B)とを含むハードコート剤組成物。
- 組成物中の不揮発分100重量部に対して、含フッ素ブロック共重合体(A1)0.05重量部以上5重量部以下と、フッ素含有ポリエーテル化合物(A2)0.01重量部以上3重量部以下とを含む、請求項1に記載のハードコート剤組成物。
- 含フッ素ブロック共重合体(A1)は、フッ素含有セグメントと、ヒドロキシル基含有セグメントとを含むものである、請求項1又は2に記載のハードコート剤組成物。
- 含フッ素ブロック共重合体(A1)は、ヒドロキシル基含有セグメントに活性エネルギー線反応性基が導入されたものである、請求項3に記載のハードコート剤組成物。
- 含フッ素ブロック共重合体(A1)は、ヒドロキシル基含有セグメントにウレタン結合を介して活性エネルギー線反応性基が導入されたものである、請求項3に記載のハードコート剤組成物。
- 含フッ素ブロック共重合体(A1)は、ヒドロキシル基含有セグメントに、分子中に1つのエチレン性不飽和二重結合及び1つのイソシアネート基を有するモノマーが、前記ヒドロキシル基及び前記イソシアネート基由来のウレタン結合を介して導入されたものである、請求項3に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、分子内に2つ以上の活性エネルギー線反応性基を有する、請求項1〜6のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、分子の両末端に活性エネルギー線反応性基を有する、請求項7に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、式量1000当たりに1つ以上の活性エネルギー線反応性基を有する、請求項1〜8のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、式量1000当たりに2つ以上の活性エネルギー線反応性基を有する、請求項1〜9のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、式量1000当たりに4つ以上の活性エネルギー線反応性基を有する、請求項1〜10のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)が有する活性エネルギー線反応性基は、(メタ)アクリロイル基及びビニル基からなる群から選ばれる、請求項1〜11のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、末端にヒドロキシル基を有するフッ素含有ポリエーテル化合物のヒドロキシル基に、(メタ)アクリロイル基が導入されたものである、請求項1〜12のうちのいずれか1項に記載のハードコート剤組成物。
- フッ素含有ポリエーテル化合物(A2)は、パーフルオロポリエーテル部位を有するものである、請求項1〜13のうちのいずれか1項に記載のハードコート剤組成物。
- さらに平均粒子径100nm以下の無機微粒子(C)を含む、請求項1〜14のうちのいずれか1項に記載のハードコート剤組成物。
- 活性エネルギー線硬化性化合物(B)100重量部に対して、無機微粒子(C)5重量部以上500重量部以下を含む、請求項12に記載のハードコート剤組成物。
- 無機微粒子(C)が、金属(又は半金属)酸化物の微粒子、又は金属(又は半金属)硫化物の微粒子である、請求項15又は16に記載のハードコート剤組成物。
- 無機微粒子(C)が、シリカ微粒子である、請求項15〜17のうちのいずれか1項に記載のハードコート剤組成物。
- 無機微粒子(C)が、活性エネルギー線反応性基を有する加水分解性シラン化合物によって表面修飾されたものである、請求項15〜18のうちのいずれか1項に記載のハードコート剤組成物。
- 請求項1〜19のうちのいずれか1項に記載のハードコート剤組成物の硬化物を含むハードコート層が表面に付与された物体。
- 支持基体上に、少なくとも記録層又は反射層を含む、1層又は複数層から構成される膜体を有する光情報媒体であって、前記支持基体側表面及び前記膜体側表面のうちの少なくとも一方の表面が、請求項1〜19のうちのいずれか1項に記載のハードコート剤組成物の硬化物を含むハードコート層によって形成されている光情報媒体。
- 前記支持基体側表面及び前記膜体側表面のうちの光入射側とされる表面が、前記ハードコート層によって形成されている、請求項21に記載の光情報媒体。
- 支持基体上に情報記録層と、情報記録層上の光透過層とを有し、光透過層上に、請求項1〜19のうちのいずれか1項に記載のハードコート剤組成物の硬化物を含むハードコート層を有する光情報媒体。
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JP2003426434A JP4784723B2 (ja) | 2003-12-24 | 2003-12-24 | ハードコート剤組成物及びこれを用いた光情報媒体 |
PCT/JP2004/019718 WO2005061633A1 (ja) | 2003-12-24 | 2004-12-22 | ハードコート剤組成物及びこれを用いた光情報媒体 |
US11/018,376 US7090909B2 (en) | 2003-12-24 | 2004-12-22 | Hard coat agent composition and optical information medium using the same |
DE112004002275T DE112004002275T5 (de) | 2003-12-24 | 2004-12-22 | Hartbeschichtungsmittel-Zusammensetzung und diese verwendendes optisches Informationsmedium |
CN2004800383535A CN1898342B (zh) | 2003-12-24 | 2004-12-22 | 硬膜剂组合物和采用该组合物的光信息介质 |
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Also Published As
Publication number | Publication date |
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DE112004002275T5 (de) | 2006-11-09 |
CN1898342B (zh) | 2011-06-08 |
CN1898342A (zh) | 2007-01-17 |
WO2005061633A1 (ja) | 2005-07-07 |
JP4784723B2 (ja) | 2011-10-05 |
US20050158504A1 (en) | 2005-07-21 |
US7090909B2 (en) | 2006-08-15 |
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