JP2004525518A - Hvpe技術を使用したサブミクロンiii属窒化物構造を成長させる方法および装置 - Google Patents
Hvpe技術を使用したサブミクロンiii属窒化物構造を成長させる方法および装置 Download PDFInfo
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- JP2004525518A JP2004525518A JP2002578542A JP2002578542A JP2004525518A JP 2004525518 A JP2004525518 A JP 2004525518A JP 2002578542 A JP2002578542 A JP 2002578542A JP 2002578542 A JP2002578542 A JP 2002578542A JP 2004525518 A JP2004525518 A JP 2004525518A
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- group iii
- zone
- iii metal
- source
- growth
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- 238000000034 method Methods 0.000 title claims abstract description 158
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 title claims abstract description 60
- 150000004767 nitrides Chemical group 0.000 title claims description 25
- 238000005516 engineering process Methods 0.000 title claims description 10
- 239000000758 substrate Substances 0.000 claims abstract description 110
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 38
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052751 metal Inorganic materials 0.000 claims description 195
- 239000002184 metal Substances 0.000 claims description 195
- 239000007789 gas Substances 0.000 claims description 157
- -1 metal halide compound Chemical class 0.000 claims description 99
- 229910001507 metal halide Inorganic materials 0.000 claims description 95
- 239000011261 inert gas Substances 0.000 claims description 65
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 54
- 238000010438 heat treatment Methods 0.000 claims description 52
- 239000012535 impurity Substances 0.000 claims description 52
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims description 49
- 239000012495 reaction gas Substances 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 38
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 21
- 229910052738 indium Inorganic materials 0.000 claims description 21
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 20
- 229910052796 boron Inorganic materials 0.000 claims description 20
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 20
- 239000011777 magnesium Substances 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 15
- 239000010453 quartz Substances 0.000 claims description 13
- 239000004065 semiconductor Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 150000002367 halogens Chemical class 0.000 claims description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 150000005309 metal halides Chemical class 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 6
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 238000012546 transfer Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims 37
- 239000000376 reactant Substances 0.000 claims 28
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 claims 10
- 230000032258 transport Effects 0.000 claims 8
- 230000000087 stabilizing effect Effects 0.000 claims 7
- 239000007795 chemical reaction product Substances 0.000 claims 6
- 239000000956 alloy Substances 0.000 claims 5
- 229910045601 alloy Inorganic materials 0.000 claims 5
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims 5
- 239000000725 suspension Substances 0.000 claims 2
- QEBYEVQKHRUYPE-UHFFFAOYSA-N 2-(2-chlorophenyl)-5-[(1-methylpyrazol-3-yl)methyl]-4-[[methyl(pyridin-3-ylmethyl)amino]methyl]-1h-pyrazolo[4,3-c]pyridine-3,6-dione Chemical compound C1=CN(C)N=C1CN1C(=O)C=C2NN(C=3C(=CC=CC=3)Cl)C(=O)C2=C1CN(C)CC1=CC=CN=C1 QEBYEVQKHRUYPE-UHFFFAOYSA-N 0.000 claims 1
- 229940125782 compound 2 Drugs 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 91
- 238000010586 diagram Methods 0.000 abstract description 2
- 239000011229 interlayer Substances 0.000 abstract description 2
- BIXHRBFZLLFBFL-UHFFFAOYSA-N germanium nitride Chemical compound N#[Ge]N([Ge]#N)[Ge]#N BIXHRBFZLLFBFL-UHFFFAOYSA-N 0.000 description 22
- 229910002704 AlGaN Inorganic materials 0.000 description 17
- 230000009036 growth inhibition Effects 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- 238000002485 combustion reaction Methods 0.000 description 8
- 238000000137 annealing Methods 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- QBJCZLXULXFYCK-UHFFFAOYSA-N magnesium;cyclopenta-1,3-diene Chemical compound [Mg+2].C1C=CC=[C-]1.C1C=CC=[C-]1 QBJCZLXULXFYCK-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910017706 MgZn Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000000407 epitaxy Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/0262—Reduction or decomposition of gaseous compounds, e.g. CVD
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/02631—Physical deposition at reduced pressure, e.g. MBE, sputtering, evaporation
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| US28060401P | 2001-03-30 | 2001-03-30 | |
| US28374301P | 2001-04-13 | 2001-04-13 | |
| PCT/US2002/010158 WO2002080225A2 (en) | 2001-03-30 | 2002-03-28 | Method and apparatus for growing submicron group iii nitride structures utilizing hvpe techniques |
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| JP2004525518A true JP2004525518A (ja) | 2004-08-19 |
| JP2004525518A5 JP2004525518A5 (enExample) | 2005-12-22 |
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| EP (2) | EP1381718A4 (enExample) |
| JP (1) | JP2004525518A (enExample) |
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-
2002
- 2002-03-28 US US10/109,317 patent/US6706119B2/en not_active Expired - Lifetime
- 2002-03-28 US US10/113,222 patent/US7670435B2/en not_active Expired - Lifetime
- 2002-03-28 AU AU2002252566A patent/AU2002252566A1/en not_active Abandoned
- 2002-03-28 EP EP02721646A patent/EP1381718A4/en not_active Ceased
- 2002-03-28 US US10/113,692 patent/US6660083B2/en not_active Expired - Lifetime
- 2002-03-28 US US10/112,277 patent/US6656272B2/en not_active Expired - Lifetime
- 2002-03-28 US US10/109,988 patent/US6573164B2/en not_active Expired - Lifetime
- 2002-03-28 EP EP11181998A patent/EP2400046A1/en not_active Withdrawn
- 2002-03-28 JP JP2002578542A patent/JP2004525518A/ja active Pending
- 2002-03-28 WO PCT/US2002/010158 patent/WO2002080225A2/en not_active Ceased
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2003
- 2003-07-18 US US10/623,375 patent/US6955719B2/en not_active Expired - Lifetime
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| Publication number | Publication date |
|---|---|
| US20020155683A1 (en) | 2002-10-24 |
| US20020177312A1 (en) | 2002-11-28 |
| US6660083B2 (en) | 2003-12-09 |
| US6656272B2 (en) | 2003-12-02 |
| US20040137657A1 (en) | 2004-07-15 |
| US20020155713A1 (en) | 2002-10-24 |
| US6573164B2 (en) | 2003-06-03 |
| AU2002252566A1 (en) | 2002-10-15 |
| EP2400046A1 (en) | 2011-12-28 |
| WO2002080225A3 (en) | 2003-02-27 |
| EP1381718A4 (en) | 2008-05-21 |
| US7670435B2 (en) | 2010-03-02 |
| EP1381718A2 (en) | 2004-01-21 |
| US6706119B2 (en) | 2004-03-16 |
| US20020174833A1 (en) | 2002-11-28 |
| US6955719B2 (en) | 2005-10-18 |
| WO2002080225A2 (en) | 2002-10-10 |
| US20020152951A1 (en) | 2002-10-24 |
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