JP2004512650A5 - - Google Patents
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- JP2004512650A5 JP2004512650A5 JP2002538498A JP2002538498A JP2004512650A5 JP 2004512650 A5 JP2004512650 A5 JP 2004512650A5 JP 2002538498 A JP2002538498 A JP 2002538498A JP 2002538498 A JP2002538498 A JP 2002538498A JP 2004512650 A5 JP2004512650 A5 JP 2004512650A5
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- Prior art keywords
- hydrogen
- gas stream
- containing gas
- fuel cell
- adsorbent
- Prior art date
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- 239000007789 gas Substances 0.000 claims 39
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 39
- 239000001257 hydrogen Substances 0.000 claims 29
- 229910052739 hydrogen Inorganic materials 0.000 claims 29
- 239000000446 fuel Substances 0.000 claims 28
- 239000003463 adsorbent Substances 0.000 claims 18
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 11
- 239000002826 coolant Substances 0.000 claims 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 8
- 239000000463 material Substances 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- 239000001301 oxygen Substances 0.000 claims 7
- 229910052760 oxygen Inorganic materials 0.000 claims 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 7
- 239000000356 contaminant Substances 0.000 claims 6
- 239000012530 fluid Substances 0.000 claims 6
- 238000007599 discharging Methods 0.000 claims 4
- 238000000926 separation method Methods 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 238000002453 autothermal reforming Methods 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910002090 carbon oxide Inorganic materials 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000007809 chemical reaction catalyst Substances 0.000 claims 2
- 238000002485 combustion reaction Methods 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 238000000629 steam reforming Methods 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
Claims (18)
- 少なくとも1つの燃料電池陽極に水素含有ガス流を供給する方法であって、
少なくとも1つの汚染物質を含む水素含有供給ガス流を供給する段階と、
少なくとも1つの第1の吸着体と、第2の吸着体、蒸気改質触媒、および水性ガス転化反応触媒から選択される少なくとも1つの第2の材料とを有し、第1の吸着体と第2の材料は化学的に異なる吸着体であり、第1の吸着体または第2の材料の少なくとも一方が、水素含有供給ガス流中の汚染物質を優先的に吸着して浄化された水素含有ガス流を発生させる吸着モジュールに水素含有供給ガス流を導入する段階と、
浄化された水素ガス含有ガス流を燃料電池陽極に導入する段階とを含む方法。 - 汚染物質が一酸化炭素を含み、かつ第1の吸着体または第2の材料の少なくとも一方が一酸化炭素選択吸着体を含む、請求項1記載の方法。
- 汚染物質が一酸化炭素を含み、かつ第1の吸着体または第2の材料の少なくとも一方が一酸化炭素選択吸着体を含む、請求項1記載の方法であって、吸着モジュールが、水分を吸収する少なくとも1つの吸着体と少なくとも追加の吸着材料とをさらに含む方法。
- 吸着モジュールが、ロータリ圧力スウィング吸着モジュールである、請求項1記載の方法。
- 一酸化炭素選択吸着体が、Cu(I)含有材料、Ag(I)含有材料、またはそれらの混合物から選択される、請求項2記載の方法。
- 少なくとも1つの燃料電池陽極に水素含有ガス流を供給する方法であって、
一酸化炭素を含む水素含有ガス流を供給する段階と、
少なくとも1つの一酸化炭素選択吸着体を含む圧力スウィング吸着モジュールに水素含有ガス流を導入し、浄化された水素含有ガス流を発生させる段階と、
浄化された水素含有ガス流を燃料電池陽極に導入する段階とを含む方法。 - 少なくとも1つの燃料電池陽極に水素含有ガス流を供給する方法であって、
酸素濃縮ガス流を供給する段階と、
酸素濃縮ガス流と燃料との混合物を自熱改質反応炉または部分酸化反応炉に入れ、少なくとも1つの酸化炭素汚染物質を含む水素含有ガス流を発生させる段階と、
水素含有ガス流から酸化炭素汚染物質の少なくとも一部を分離する段階と、
結果として得られる浄化された水素含有ガス流を燃料電池陽極に導入する段階とを含む方法。 - 電流発生システムであって、
水素含有ガス供給源と、
水素含有ガスを少なくとも部分的に浄化することができ、少なくとも1つの第1の吸着体と、第2の吸着体、蒸気改質触媒、および水性ガス転化反応触媒から選択される少なくとも1つの第2の材料とを含み、第1の吸着体と第2の吸着体は化学的に異なる吸着体である、少なくとも1つの吸着モジュールと、
浄化された水素含有ガス流を吸着モジュールから受け入れることのできる陽極入口を形成している少なくとも1つの燃料電池とを含むシステム。 - 吸着モジュールが、ロータリ圧力スウィング吸着モジュールを含む、請求項8記載のシステム。
- 電流発生システムであって、
水素含有ガス供給源と、
水素含有ガス供給源に流体連結され、少なくとも1つの一酸化炭素選択吸着体を含む、少なくとも1つの圧力スウィング吸着モジュールと、
圧力スウィング吸着モジュールに流体連結された少なくとも1つの燃料電池陽極とを含むシステム。 - 吸着モジュールが、ロータリ圧力スウィング吸着モジュールを含む、請求項10記載のシステム。
- 電流発生システムであって、
酸素濃縮ガス流を排出する出口を有する少なくとも1つの第1の圧力スウィング吸着モジュールと、
燃料および酸素濃縮ガス流を燃焼させて水素含有ガスを発生させることのできる自熱改質反応炉または部分酸化反応炉と、
水素含有ガスを少なくとも部分的に浄化することのできる少なくとも1つの第2の圧力スウィング吸着モジュールと、
浄化された水素含有ガスを第2の圧力スウィング吸着モジュールから受け入れることのできる陽極入口を有する少なくとも1つの燃料電池とを含むシステム。 - 水素含有ガス流および酸素濃縮ガス流を燃料電池に供給する方法であって、
酸素濃縮ガス流を発生させ、第1の圧縮器または第1の真空ポンプから選択された少なくとも1つの装置を含む、少なくとも1つの第1の圧力スウィング吸着モジュールを設ける段階と、
浄化された水素ガス流および分離排気ガス流を発生させ、第2の圧縮器または第2の真空ポンプから選択された少なくとも1つの装置を含む、少なくとも1つの第2の圧力スウィング吸着モジュールを設ける段階と、
酸素濃縮ガス流および浄化された水素ガス流を燃料電池に導入する段階と、
第1の圧縮器、第1の真空ポンプ、第2の圧縮器、第2の真空ポンプ、または発電機から選択された少なくとも1つの装置を駆動するための燃焼エンジンに、燃料として分離排気ガス流を導入する段階とを含む方法。 - 水素含有ガス流を燃料電池に供給する方法であって、
冷却剤通路、および水素含有ガス流を受け入れる陽極入口を形成する燃料電池を設ける段階と、
液体の水と炭化水素燃料流とを混合して冷却剤混合物を得る段階と、
冷却剤混合物を燃料電池の冷却剤通路に導入する段階と、
冷却剤混合物を蒸発させて蒸気/燃料の蒸気混合物を形成する段階と、
水素含有ガス流を発生させるのに十分な反応条件に蒸気/燃料蒸気混合物をさらす段階と、
水素含有ガス流を燃料電池陽極入口に導入する段階とを含む方法。 - 電流発生システムであって、
浄化された水素ガスを排出する第1の出口、および分離排気ガスを排出する第2の出口を含む、少なくとも1つの水素ガス分離モジュールと
水素ガス分離モジュールの第1の出口と流体連通する陽極入口を形成する少なくとも1つの燃料電池と、
水素ガス分離モジュールの第2の出口と流体連通する燃料入口を形成する燃焼エンジンとを含むシステム。 - 水素ガス分離モジュールが圧力スウィング吸着モジュールを含む、請求項15記載のシステム。
- 電流発生システムであって、
水素含有ガス流を受け入れる陽極入口、および冷却剤入口と冷却剤出口とを有する冷却剤通路を形成する燃料電池、
冷却剤入口と流体連通する水供給源、
冷却剤入口と流体連通する炭化水素燃料供給源、
水素含有ガス流を排出する出口、および冷却剤出口と流体連通する燃料入口を含む水素ガス発生モジュール、ならびに
水素ガス発生モジュール出口と燃料電池陽極入口との間を流体連通させる第1の導管を含むシステム。 - 炭化水素燃料がメタノール、エタノール、またはそれらの混合物を含む、請求項17記載のシステム。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002324702A CA2324702A1 (en) | 2000-10-27 | 2000-10-27 | Reformate purification and heat recovery for fuel cell |
CA002324699A CA2324699A1 (en) | 2000-10-27 | 2000-10-27 | Carbon monoxide removal from hydrogen feed to fuel cell |
PCT/CA2001/001523 WO2002035623A2 (en) | 2000-10-27 | 2001-10-26 | Systems and processes for providing hydrogen to fuel cells |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2004512650A JP2004512650A (ja) | 2004-04-22 |
JP2004512650A5 true JP2004512650A5 (ja) | 2005-04-28 |
Family
ID=25682196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002538498A Pending JP2004512650A (ja) | 2000-10-27 | 2001-10-26 | 燃料電池に水素を供給するシステムおよび方法 |
Country Status (6)
Country | Link |
---|---|
US (2) | US7041272B2 (ja) |
EP (1) | EP1344270B1 (ja) |
JP (1) | JP2004512650A (ja) |
AU (1) | AU2002214858A1 (ja) |
ES (1) | ES2640910T3 (ja) |
WO (1) | WO2002035623A2 (ja) |
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- 2001-10-26 AU AU2002214858A patent/AU2002214858A1/en not_active Abandoned
- 2001-10-26 ES ES01983346.6T patent/ES2640910T3/es not_active Expired - Lifetime
- 2001-10-26 WO PCT/CA2001/001523 patent/WO2002035623A2/en active Application Filing
- 2001-10-26 US US10/039,552 patent/US7041272B2/en not_active Expired - Lifetime
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2006
- 2006-04-12 US US11/403,407 patent/US7674539B2/en not_active Expired - Lifetime
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