JP2002519181A - ２種の触媒活性金属を使用した接触部分酸化 - Google Patents

２種の触媒活性金属を使用した接触部分酸化

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Publication number
JP2002519181A
JP2002519181A JP2000556988A JP2000556988A JP2002519181A JP 2002519181 A JP2002519181 A JP 2002519181A JP 2000556988 A JP2000556988 A JP 2000556988A JP 2000556988 A JP2000556988 A JP 2000556988A JP 2002519181 A JP2002519181 A JP 2002519181A
Authority
JP
Japan
Prior art keywords
catalyst
precursor
layer
catalytically active
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000556988A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002519181A5 (enExample
Inventor
ゲリット・ヤン・バレント・アッシンク
ハンス・ミヒェル・ヒュイスマン
ゲルト・ヤン・クラマー
ロナルド・ヤン・スクーネビーク
ヴィム・ヴィルドラーイヤー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of JP2002519181A publication Critical patent/JP2002519181A/ja
Publication of JP2002519181A5 publication Critical patent/JP2002519181A5/ja
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
JP2000556988A 1998-06-30 1999-06-23 ２種の触媒活性金属を使用した接触部分酸化 Pending JP2002519181A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98305179 1998-06-30
EP98305179.8 1998-06-30
PCT/EP1999/004348 WO2000000425A1 (en) 1998-06-30 1999-06-23 Catalytic partial oxidation with two catalytically-active metals

Publications (2)

Publication Number Publication Date
JP2002519181A true JP2002519181A (ja) 2002-07-02
JP2002519181A5 JP2002519181A5 (enExample) 2006-07-06

Family

ID=8234902

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2000556988A Pending JP2002519181A (ja) 1998-06-30 1999-06-23 ２種の触媒活性金属を使用した接触部分酸化
JP2000556989A Pending JP2002519182A (ja) 1998-06-30 1999-06-24 ロジウム−イリジウム合金触媒を用いた接触部分酸化

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2000556989A Pending JP2002519182A (ja) 1998-06-30 1999-06-24 ロジウム−イリジウム合金触媒を用いた接触部分酸化

Country Status (19)

Country Link
US (1) US6702960B1 (enExample)
EP (2) EP1098840B1 (enExample)
JP (2) JP2002519181A (enExample)
KR (2) KR20010053268A (enExample)
CN (2) CN1307539A (enExample)
AT (2) ATE222214T1 (enExample)
AU (2) AU746783B2 (enExample)
BR (2) BR9911654A (enExample)
CA (2) CA2335970C (enExample)
CZ (1) CZ20004900A3 (enExample)
DE (2) DE69902547T2 (enExample)
DK (1) DK1098840T3 (enExample)
ES (1) ES2182544T3 (enExample)
ID (2) ID28037A (enExample)
NO (2) NO20006579L (enExample)
PL (2) PL345190A1 (enExample)
PT (1) PT1098840E (enExample)
WO (2) WO2000000425A1 (enExample)
ZA (2) ZA200100316B (enExample)

Cited By (1)

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US7115236B2 (en) 2001-12-27 2006-10-03 Nissan Motor Co., Ltd. Exhaust gas purifying method and system for fuel cell vehicle

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US6436363B1 (en) 2000-08-31 2002-08-20 Engelhard Corporation Process for generating hydrogen-rich gas
CA2470344A1 (en) * 2001-12-18 2003-06-26 Conocophillips Company Catalyst for spoc-enhanced synthesis gas production
WO2004043852A1 (en) 2002-11-11 2004-05-27 Conocophillips Company Stabilized alumina supports, catalysts made therefrom, and their use in partial oxidation
EP1567446A1 (en) * 2002-11-11 2005-08-31 Conocophillips Company Improved supports for high surface area catalysts
ITMI20031739A1 (it) * 2003-09-11 2005-03-12 Enitecnologie Spa Procedimento di ossidazione parziale catalitica per
DE102004024026A1 (de) * 2004-03-11 2005-09-29 W.C. Heraeus Gmbh Katalysator zur N2O-Zersetzung beim Ostwaldprozess
US20050202966A1 (en) * 2004-03-11 2005-09-15 W.C. Heraeus Gmbh Catalyst for the decomposition of N2O in the Ostwald process
JP4589682B2 (ja) * 2004-08-25 2010-12-01 千代田化工建設株式会社 合成ガス製造用触媒の調製方法
US7569512B2 (en) * 2004-11-10 2009-08-04 Umicore Ag & Co. Kg Zirconia support and zirconia supported catalyst
US20070111884A1 (en) * 2005-11-14 2007-05-17 Laiyuan Chen Catalyst support, supported catalyst, and methods of making and using the same
US20070238610A1 (en) * 2006-04-05 2007-10-11 Laiyuan Chen Fuel reformer catalyst
EP2081866A1 (en) 2006-10-31 2009-07-29 Shell Internationale Research Maatschappij B.V. Process for the production of hydrogen and the use thereof and a process for the operation of a internal combustion engine
US20080260631A1 (en) * 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
WO2009140317A1 (en) * 2008-05-15 2009-11-19 Shell Oil Company Method for recovering a natural gas contaminated with high levels of co2
TR201905563T4 (tr) 2011-06-23 2019-05-21 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Hidrojen üretimine yönelik olarak uygun bir sentez gazı aracının üretilmesine yönelik proses.
US9598290B2 (en) 2011-06-23 2017-03-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
CN103889891B (zh) 2011-10-26 2016-09-14 代表Mt创新中心的斯塔米卡邦有限公司 生产用于生产甲醇的合成气的方法
NO2771274T3 (enExample) 2011-10-26 2018-06-30
CN107021450B (zh) 2011-12-19 2019-12-27 代表Mt创新中心的斯塔米卡邦有限公司 用于制备氨和尿素的方法
KR20150028329A (ko) * 2012-06-29 2015-03-13 바스프 에스이 이리듐-함유 활성 물질의 존재 하에서 탄화수소의 이산화탄소 개질을 위한 고압 공정
WO2015069762A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto
WO2015069842A2 (en) 2013-11-06 2015-05-14 WATT Fuel Cell Corp Integrated gaseous fuel cpox reformer and fuel cell systems, and methods of producing electricity
CA2929136C (en) 2013-11-06 2018-03-13 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
JP6231697B2 (ja) 2013-11-06 2017-11-15 ワット・フューエル・セル・コーポレイションＷａｔｔ Ｆｕｅｌ Ｃｅｌｌ Ｃｏｒｐ． 液体燃料ｃｐｏｘ改質器及びｃｐｏｘ改質の方法
KR101865032B1 (ko) 2013-11-06 2018-06-07 와트 퓨얼 셀 코퍼레이션 액체 연료 cpox 개질장치-연료 전지 시스템, 및 전기 생산 방법
MX352220B (es) 2013-11-06 2017-11-15 WATT Fuel Cell Corp Reformadores de cpox de combustible gaseoso y métodos de reformación de cpox.
EP2886514A1 (de) * 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
JP5994808B2 (ja) 2014-03-05 2016-09-21 トヨタ自動車株式会社 排ガス浄化用触媒及びその製造方法
WO2016010416A1 (en) 2014-07-15 2016-01-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Method for revamping a urea production complex
PT3362405T (pt) 2015-10-15 2022-11-17 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Processo e unidade de produção para a produção de metanol
EP4021630A4 (en) 2019-08-29 2023-04-26 Watt Fuel Cell Corp. MULTITUBULAR CHEMICAL REACTOR WITH IGNITOR TO INTRODUCE GAS PHASE REDUCED EXOTHERMAL REACTIONS

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JPH0459049A (ja) * 1990-06-20 1992-02-25 Nippon Shokubai Co Ltd ディーゼルエンジン排ガス浄化用触媒および浄化方法
GB2274284A (en) * 1992-12-23 1994-07-20 Snam Progetti Catalytic process for producing synthesis gas
EP0640559A1 (en) * 1993-08-27 1995-03-01 SNAMPROGETTI S.p.A. Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde

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IT1238676B (it) * 1990-01-26 1993-09-01 Snam Progetti Sistema catalitico e procedimento per la produzione di gas di sintesi mediante reazione di reforming di idrocarubri leggeri con co2
NZ260621A (en) * 1993-06-18 1996-03-26 Shell Int Research Process for catalytic partial oxidation of hydrocarbon feedstock
US5658497A (en) * 1995-12-05 1997-08-19 Shell Oil Company Process for the catalytic partial oxidation of hydrocarbons using a certain catalyst support
US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
JPH0459049A (ja) * 1990-06-20 1992-02-25 Nippon Shokubai Co Ltd ディーゼルエンジン排ガス浄化用触媒および浄化方法
GB2274284A (en) * 1992-12-23 1994-07-20 Snam Progetti Catalytic process for producing synthesis gas
EP0640559A1 (en) * 1993-08-27 1995-03-01 SNAMPROGETTI S.p.A. Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7115236B2 (en) 2001-12-27 2006-10-03 Nissan Motor Co., Ltd. Exhaust gas purifying method and system for fuel cell vehicle
US7572422B2 (en) 2001-12-27 2009-08-11 Nissan Motor Co., Ltd. Exhaust gas purifying method for fuel cell vehicle and exhaust gas purifying system for fuel cell vehicle

Also Published As

Publication number Publication date
WO2000000425A1 (en) 2000-01-06
DE69905467T2 (de) 2003-09-11
ZA200100317B (en) 2001-07-23
DE69905467D1 (de) 2003-03-27
DK1098840T3 (da) 2002-12-09
JP2002519182A (ja) 2002-07-02
KR20010053267A (ko) 2001-06-25
NO20006579D0 (no) 2000-12-21
ATE222214T1 (de) 2002-08-15
AU4776299A (en) 2000-01-17
NO20006580L (no) 2000-12-21
AU4777699A (en) 2000-01-17
EP1093439A1 (en) 2001-04-25
CA2335970C (en) 2009-01-06
BR9911654A (pt) 2001-03-20
DE69902547T2 (de) 2003-05-22
WO2000000426A1 (en) 2000-01-06
CN1307539A (zh) 2001-08-08
ZA200100316B (en) 2001-08-29
ES2182544T3 (es) 2003-03-01
US6702960B1 (en) 2004-03-09
PT1098840E (pt) 2002-11-29
AU743727B2 (en) 2002-01-31
CZ20004900A3 (cs) 2001-08-15
CN1307538A (zh) 2001-08-08
CA2335970A1 (en) 2000-01-06
EP1098840A1 (en) 2001-05-16
NO20006580D0 (no) 2000-12-21
ID27777A (id) 2001-04-26
PL345190A1 (en) 2001-12-03
EP1093439B1 (en) 2003-02-19
AU746783B2 (en) 2002-05-02
ID28037A (id) 2001-05-03
ATE232836T1 (de) 2003-03-15
NO20006579L (no) 2000-12-21
EP1098840B1 (en) 2002-08-14
BR9911739A (pt) 2001-04-03
PL345181A1 (en) 2001-12-03
CA2335983A1 (en) 2000-01-06
DE69902547D1 (de) 2002-09-19
KR20010053268A (ko) 2001-06-25

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