DE69902547T2 - Katalytische teiloxidation mit zwei katalytisch-aktiven metallen - Google Patents

Katalytische teiloxidation mit zwei katalytisch-aktiven metallen

Info

Publication number
DE69902547T2
DE69902547T2 DE69902547T DE69902547T DE69902547T2 DE 69902547 T2 DE69902547 T2 DE 69902547T2 DE 69902547 T DE69902547 T DE 69902547T DE 69902547 T DE69902547 T DE 69902547T DE 69902547 T2 DE69902547 T2 DE 69902547T2
Authority
DE
Germany
Prior art keywords
catalyst
layer
precursor
catalytically active
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69902547T
Other languages
German (de)
English (en)
Other versions
DE69902547D1 (de
Inventor
Jan Assink
Michiel Huisman
Jan Kramer
Jan Schoonebeek
Wim Wieldraaijer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of DE69902547D1 publication Critical patent/DE69902547D1/de
Publication of DE69902547T2 publication Critical patent/DE69902547T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/464Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/468Iridium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1011Packed bed of catalytic structures, e.g. particles, packing elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1023Catalysts in the form of a monolith or honeycomb
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • C01B2203/107Platinum catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1247Higher hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
DE69902547T 1998-06-30 1999-06-23 Katalytische teiloxidation mit zwei katalytisch-aktiven metallen Expired - Fee Related DE69902547T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98305179 1998-06-30
PCT/EP1999/004348 WO2000000425A1 (en) 1998-06-30 1999-06-23 Catalytic partial oxidation with two catalytically-active metals

Publications (2)

Publication Number Publication Date
DE69902547D1 DE69902547D1 (de) 2002-09-19
DE69902547T2 true DE69902547T2 (de) 2003-05-22

Family

ID=8234902

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69902547T Expired - Fee Related DE69902547T2 (de) 1998-06-30 1999-06-23 Katalytische teiloxidation mit zwei katalytisch-aktiven metallen
DE69905467T Expired - Fee Related DE69905467T2 (de) 1998-06-30 1999-06-24 Katalytische teiloxidation mit einem rhodium-iridium legierungskatalysator

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69905467T Expired - Fee Related DE69905467T2 (de) 1998-06-30 1999-06-24 Katalytische teiloxidation mit einem rhodium-iridium legierungskatalysator

Country Status (19)

Country Link
US (1) US6702960B1 (enExample)
EP (2) EP1098840B1 (enExample)
JP (2) JP2002519181A (enExample)
KR (2) KR20010053268A (enExample)
CN (2) CN1307539A (enExample)
AT (2) ATE222214T1 (enExample)
AU (2) AU746783B2 (enExample)
BR (2) BR9911654A (enExample)
CA (2) CA2335970C (enExample)
CZ (1) CZ20004900A3 (enExample)
DE (2) DE69902547T2 (enExample)
DK (1) DK1098840T3 (enExample)
ES (1) ES2182544T3 (enExample)
ID (2) ID28037A (enExample)
NO (2) NO20006579L (enExample)
PL (2) PL345190A1 (enExample)
PT (1) PT1098840E (enExample)
WO (2) WO2000000425A1 (enExample)
ZA (2) ZA200100316B (enExample)

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WO2004043852A1 (en) 2002-11-11 2004-05-27 Conocophillips Company Stabilized alumina supports, catalysts made therefrom, and their use in partial oxidation
EP1567446A1 (en) * 2002-11-11 2005-08-31 Conocophillips Company Improved supports for high surface area catalysts
ITMI20031739A1 (it) * 2003-09-11 2005-03-12 Enitecnologie Spa Procedimento di ossidazione parziale catalitica per
DE102004024026A1 (de) * 2004-03-11 2005-09-29 W.C. Heraeus Gmbh Katalysator zur N2O-Zersetzung beim Ostwaldprozess
US20050202966A1 (en) * 2004-03-11 2005-09-15 W.C. Heraeus Gmbh Catalyst for the decomposition of N2O in the Ostwald process
JP4589682B2 (ja) * 2004-08-25 2010-12-01 千代田化工建設株式会社 合成ガス製造用触媒の調製方法
US7569512B2 (en) * 2004-11-10 2009-08-04 Umicore Ag & Co. Kg Zirconia support and zirconia supported catalyst
US20070111884A1 (en) * 2005-11-14 2007-05-17 Laiyuan Chen Catalyst support, supported catalyst, and methods of making and using the same
US20070238610A1 (en) * 2006-04-05 2007-10-11 Laiyuan Chen Fuel reformer catalyst
EP2081866A1 (en) 2006-10-31 2009-07-29 Shell Internationale Research Maatschappij B.V. Process for the production of hydrogen and the use thereof and a process for the operation of a internal combustion engine
US20080260631A1 (en) * 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
WO2009140317A1 (en) * 2008-05-15 2009-11-19 Shell Oil Company Method for recovering a natural gas contaminated with high levels of co2
TR201905563T4 (tr) 2011-06-23 2019-05-21 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Hidrojen üretimine yönelik olarak uygun bir sentez gazı aracının üretilmesine yönelik proses.
US9598290B2 (en) 2011-06-23 2017-03-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
CN103889891B (zh) 2011-10-26 2016-09-14 代表Mt创新中心的斯塔米卡邦有限公司 生产用于生产甲醇的合成气的方法
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CN107021450B (zh) 2011-12-19 2019-12-27 代表Mt创新中心的斯塔米卡邦有限公司 用于制备氨和尿素的方法
KR20150028329A (ko) * 2012-06-29 2015-03-13 바스프 에스이 이리듐-함유 활성 물질의 존재 하에서 탄화수소의 이산화탄소 개질을 위한 고압 공정
WO2015069762A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto
WO2015069842A2 (en) 2013-11-06 2015-05-14 WATT Fuel Cell Corp Integrated gaseous fuel cpox reformer and fuel cell systems, and methods of producing electricity
CA2929136C (en) 2013-11-06 2018-03-13 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
JP6231697B2 (ja) 2013-11-06 2017-11-15 ワット・フューエル・セル・コーポレイションWatt Fuel Cell Corp. 液体燃料cpox改質器及びcpox改質の方法
KR101865032B1 (ko) 2013-11-06 2018-06-07 와트 퓨얼 셀 코퍼레이션 액체 연료 cpox 개질장치-연료 전지 시스템, 및 전기 생산 방법
MX352220B (es) 2013-11-06 2017-11-15 WATT Fuel Cell Corp Reformadores de cpox de combustible gaseoso y métodos de reformación de cpox.
EP2886514A1 (de) * 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
JP5994808B2 (ja) 2014-03-05 2016-09-21 トヨタ自動車株式会社 排ガス浄化用触媒及びその製造方法
WO2016010416A1 (en) 2014-07-15 2016-01-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Method for revamping a urea production complex
PT3362405T (pt) 2015-10-15 2022-11-17 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Processo e unidade de produção para a produção de metanol
EP4021630A4 (en) 2019-08-29 2023-04-26 Watt Fuel Cell Corp. MULTITUBULAR CHEMICAL REACTOR WITH IGNITOR TO INTRODUCE GAS PHASE REDUCED EXOTHERMAL REACTIONS

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IT1272532B (it) * 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
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US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)

Also Published As

Publication number Publication date
WO2000000425A1 (en) 2000-01-06
DE69905467T2 (de) 2003-09-11
ZA200100317B (en) 2001-07-23
DE69905467D1 (de) 2003-03-27
DK1098840T3 (da) 2002-12-09
JP2002519182A (ja) 2002-07-02
KR20010053267A (ko) 2001-06-25
NO20006579D0 (no) 2000-12-21
ATE222214T1 (de) 2002-08-15
AU4776299A (en) 2000-01-17
NO20006580L (no) 2000-12-21
AU4777699A (en) 2000-01-17
EP1093439A1 (en) 2001-04-25
CA2335970C (en) 2009-01-06
BR9911654A (pt) 2001-03-20
WO2000000426A1 (en) 2000-01-06
CN1307539A (zh) 2001-08-08
ZA200100316B (en) 2001-08-29
ES2182544T3 (es) 2003-03-01
US6702960B1 (en) 2004-03-09
PT1098840E (pt) 2002-11-29
AU743727B2 (en) 2002-01-31
CZ20004900A3 (cs) 2001-08-15
CN1307538A (zh) 2001-08-08
CA2335970A1 (en) 2000-01-06
EP1098840A1 (en) 2001-05-16
NO20006580D0 (no) 2000-12-21
ID27777A (id) 2001-04-26
PL345190A1 (en) 2001-12-03
EP1093439B1 (en) 2003-02-19
AU746783B2 (en) 2002-05-02
ID28037A (id) 2001-05-03
ATE232836T1 (de) 2003-03-15
NO20006579L (no) 2000-12-21
EP1098840B1 (en) 2002-08-14
BR9911739A (pt) 2001-04-03
PL345181A1 (en) 2001-12-03
JP2002519181A (ja) 2002-07-02
CA2335983A1 (en) 2000-01-06
DE69902547D1 (de) 2002-09-19
KR20010053268A (ko) 2001-06-25

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