DE69902547T2 - Katalytische teiloxidation mit zwei katalytisch-aktiven metallen - Google Patents
Katalytische teiloxidation mit zwei katalytisch-aktiven metallenInfo
- Publication number
- DE69902547T2 DE69902547T2 DE69902547T DE69902547T DE69902547T2 DE 69902547 T2 DE69902547 T2 DE 69902547T2 DE 69902547 T DE69902547 T DE 69902547T DE 69902547 T DE69902547 T DE 69902547T DE 69902547 T2 DE69902547 T2 DE 69902547T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- layer
- precursor
- catalytically active
- rhodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 62
- 239000002184 metal Substances 0.000 title claims abstract description 62
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 29
- 230000003647 oxidation Effects 0.000 title claims abstract description 28
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 25
- 150000002739 metals Chemical class 0.000 title abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 100
- 238000000034 method Methods 0.000 claims abstract description 41
- 239000010948 rhodium Substances 0.000 claims abstract description 34
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 33
- 239000007789 gas Substances 0.000 claims abstract description 31
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 22
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- 230000000737 periodic effect Effects 0.000 claims abstract description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 45
- 239000002243 precursor Substances 0.000 claims description 34
- 239000002245 particle Substances 0.000 claims description 29
- 229910052697 platinum Inorganic materials 0.000 claims description 23
- 229930195733 hydrocarbon Natural products 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 150000001768 cations Chemical class 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229910052726 zirconium Inorganic materials 0.000 claims description 10
- 229910052762 osmium Inorganic materials 0.000 claims description 9
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 9
- 150000003284 rhodium compounds Chemical class 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 150000002504 iridium compounds Chemical class 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 150000003058 platinum compounds Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 72
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 30
- 239000000203 mixture Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 239000006260 foam Substances 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 239000000919 ceramic Substances 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 8
- 229910001928 zirconium oxide Inorganic materials 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 229910052707 ruthenium Inorganic materials 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241000264877 Hippospongia communis Species 0.000 description 3
- 229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 description 3
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000344110 Erysimum rhodium Species 0.000 description 1
- 101100311330 Schizosaccharomyces pombe (strain 972 / ATCC 24843) uap56 gene Proteins 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- -1 methane Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 101150018444 sub2 gene Proteins 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C01B2203/107—Platinum catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98305179 | 1998-06-30 | ||
| PCT/EP1999/004348 WO2000000425A1 (en) | 1998-06-30 | 1999-06-23 | Catalytic partial oxidation with two catalytically-active metals |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69902547D1 DE69902547D1 (de) | 2002-09-19 |
| DE69902547T2 true DE69902547T2 (de) | 2003-05-22 |
Family
ID=8234902
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69902547T Expired - Fee Related DE69902547T2 (de) | 1998-06-30 | 1999-06-23 | Katalytische teiloxidation mit zwei katalytisch-aktiven metallen |
| DE69905467T Expired - Fee Related DE69905467T2 (de) | 1998-06-30 | 1999-06-24 | Katalytische teiloxidation mit einem rhodium-iridium legierungskatalysator |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69905467T Expired - Fee Related DE69905467T2 (de) | 1998-06-30 | 1999-06-24 | Katalytische teiloxidation mit einem rhodium-iridium legierungskatalysator |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US6702960B1 (enExample) |
| EP (2) | EP1098840B1 (enExample) |
| JP (2) | JP2002519181A (enExample) |
| KR (2) | KR20010053268A (enExample) |
| CN (2) | CN1307539A (enExample) |
| AT (2) | ATE222214T1 (enExample) |
| AU (2) | AU746783B2 (enExample) |
| BR (2) | BR9911654A (enExample) |
| CA (2) | CA2335970C (enExample) |
| CZ (1) | CZ20004900A3 (enExample) |
| DE (2) | DE69902547T2 (enExample) |
| DK (1) | DK1098840T3 (enExample) |
| ES (1) | ES2182544T3 (enExample) |
| ID (2) | ID28037A (enExample) |
| NO (2) | NO20006579L (enExample) |
| PL (2) | PL345190A1 (enExample) |
| PT (1) | PT1098840E (enExample) |
| WO (2) | WO2000000425A1 (enExample) |
| ZA (2) | ZA200100316B (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2405927A1 (en) | 2000-04-17 | 2001-10-25 | Shell Internationale Research Maatschappij B.V. | Fuel processor |
| US6436363B1 (en) | 2000-08-31 | 2002-08-20 | Engelhard Corporation | Process for generating hydrogen-rich gas |
| CA2470344A1 (en) * | 2001-12-18 | 2003-06-26 | Conocophillips Company | Catalyst for spoc-enhanced synthesis gas production |
| JP3870783B2 (ja) | 2001-12-27 | 2007-01-24 | 日産自動車株式会社 | 燃料電池自動車用排ガス浄化システムおよび燃料電池自動車の排ガスの浄化方法 |
| WO2004043852A1 (en) | 2002-11-11 | 2004-05-27 | Conocophillips Company | Stabilized alumina supports, catalysts made therefrom, and their use in partial oxidation |
| EP1567446A1 (en) * | 2002-11-11 | 2005-08-31 | Conocophillips Company | Improved supports for high surface area catalysts |
| ITMI20031739A1 (it) * | 2003-09-11 | 2005-03-12 | Enitecnologie Spa | Procedimento di ossidazione parziale catalitica per |
| DE102004024026A1 (de) * | 2004-03-11 | 2005-09-29 | W.C. Heraeus Gmbh | Katalysator zur N2O-Zersetzung beim Ostwaldprozess |
| US20050202966A1 (en) * | 2004-03-11 | 2005-09-15 | W.C. Heraeus Gmbh | Catalyst for the decomposition of N2O in the Ostwald process |
| JP4589682B2 (ja) * | 2004-08-25 | 2010-12-01 | 千代田化工建設株式会社 | 合成ガス製造用触媒の調製方法 |
| US7569512B2 (en) * | 2004-11-10 | 2009-08-04 | Umicore Ag & Co. Kg | Zirconia support and zirconia supported catalyst |
| US20070111884A1 (en) * | 2005-11-14 | 2007-05-17 | Laiyuan Chen | Catalyst support, supported catalyst, and methods of making and using the same |
| US20070238610A1 (en) * | 2006-04-05 | 2007-10-11 | Laiyuan Chen | Fuel reformer catalyst |
| EP2081866A1 (en) | 2006-10-31 | 2009-07-29 | Shell Internationale Research Maatschappij B.V. | Process for the production of hydrogen and the use thereof and a process for the operation of a internal combustion engine |
| US20080260631A1 (en) * | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| WO2009140317A1 (en) * | 2008-05-15 | 2009-11-19 | Shell Oil Company | Method for recovering a natural gas contaminated with high levels of co2 |
| TR201905563T4 (tr) | 2011-06-23 | 2019-05-21 | Stamicarbon B V Acting Under The Name Of Mt Innovation Center | Hidrojen üretimine yönelik olarak uygun bir sentez gazı aracının üretilmesine yönelik proses. |
| US9598290B2 (en) | 2011-06-23 | 2017-03-21 | Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center | Process for producing ammonia and urea |
| CN103889891B (zh) | 2011-10-26 | 2016-09-14 | 代表Mt创新中心的斯塔米卡邦有限公司 | 生产用于生产甲醇的合成气的方法 |
| NO2771274T3 (enExample) | 2011-10-26 | 2018-06-30 | ||
| CN107021450B (zh) | 2011-12-19 | 2019-12-27 | 代表Mt创新中心的斯塔米卡邦有限公司 | 用于制备氨和尿素的方法 |
| KR20150028329A (ko) * | 2012-06-29 | 2015-03-13 | 바스프 에스이 | 이리듐-함유 활성 물질의 존재 하에서 탄화수소의 이산화탄소 개질을 위한 고압 공정 |
| WO2015069762A2 (en) | 2013-11-06 | 2015-05-14 | Watt Fuel Cell Corp. | Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto |
| WO2015069842A2 (en) | 2013-11-06 | 2015-05-14 | WATT Fuel Cell Corp | Integrated gaseous fuel cpox reformer and fuel cell systems, and methods of producing electricity |
| CA2929136C (en) | 2013-11-06 | 2018-03-13 | Watt Fuel Cell Corp. | Reformer with perovskite as structural component thereof |
| JP6231697B2 (ja) | 2013-11-06 | 2017-11-15 | ワット・フューエル・セル・コーポレイションWatt Fuel Cell Corp. | 液体燃料cpox改質器及びcpox改質の方法 |
| KR101865032B1 (ko) | 2013-11-06 | 2018-06-07 | 와트 퓨얼 셀 코퍼레이션 | 액체 연료 cpox 개질장치-연료 전지 시스템, 및 전기 생산 방법 |
| MX352220B (es) | 2013-11-06 | 2017-11-15 | WATT Fuel Cell Corp | Reformadores de cpox de combustible gaseoso y métodos de reformación de cpox. |
| EP2886514A1 (de) * | 2013-12-20 | 2015-06-24 | Basf Se | Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid |
| JP5994808B2 (ja) | 2014-03-05 | 2016-09-21 | トヨタ自動車株式会社 | 排ガス浄化用触媒及びその製造方法 |
| WO2016010416A1 (en) | 2014-07-15 | 2016-01-21 | Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center | Method for revamping a urea production complex |
| PT3362405T (pt) | 2015-10-15 | 2022-11-17 | Stamicarbon B V Acting Under The Name Of Mt Innovation Center | Processo e unidade de produção para a produção de metanol |
| EP4021630A4 (en) | 2019-08-29 | 2023-04-26 | Watt Fuel Cell Corp. | MULTITUBULAR CHEMICAL REACTOR WITH IGNITOR TO INTRODUCE GAS PHASE REDUCED EXOTHERMAL REACTIONS |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0303438A3 (en) * | 1987-08-14 | 1989-12-27 | DAVY McKEE CORPORATION | Production of synthesis gas from hydrocarbonaceous feedstock |
| IT1238676B (it) * | 1990-01-26 | 1993-09-01 | Snam Progetti | Sistema catalitico e procedimento per la produzione di gas di sintesi mediante reazione di reforming di idrocarubri leggeri con co2 |
| JP3061399B2 (ja) * | 1990-06-20 | 2000-07-10 | 株式会社日本触媒 | ディーゼルエンジン排ガス浄化用触媒および浄化方法 |
| IT1256227B (it) | 1992-12-23 | 1995-11-29 | Snam Progetti | Procedimento catalitico per la produzione di gas di sintesi |
| NZ260621A (en) * | 1993-06-18 | 1996-03-26 | Shell Int Research | Process for catalytic partial oxidation of hydrocarbon feedstock |
| IT1272532B (it) * | 1993-08-27 | 1997-06-23 | Snam Progetti | Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide |
| US5658497A (en) * | 1995-12-05 | 1997-08-19 | Shell Oil Company | Process for the catalytic partial oxidation of hydrocarbons using a certain catalyst support |
| US5883138A (en) * | 1997-04-25 | 1999-03-16 | Exxon Research And Engineering Company | Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562) |
-
1999
- 1999-06-23 PL PL99345190A patent/PL345190A1/xx not_active Application Discontinuation
- 1999-06-23 BR BR9911654-5A patent/BR9911654A/pt not_active IP Right Cessation
- 1999-06-23 KR KR1020007014969A patent/KR20010053268A/ko not_active Withdrawn
- 1999-06-23 AT AT99931148T patent/ATE222214T1/de not_active IP Right Cessation
- 1999-06-23 ID IDW20002719A patent/ID28037A/id unknown
- 1999-06-23 CZ CZ20004900A patent/CZ20004900A3/cs unknown
- 1999-06-23 EP EP99931148A patent/EP1098840B1/en not_active Expired - Lifetime
- 1999-06-23 DK DK99931148T patent/DK1098840T3/da active
- 1999-06-23 PT PT99931148T patent/PT1098840E/pt unknown
- 1999-06-23 DE DE69902547T patent/DE69902547T2/de not_active Expired - Fee Related
- 1999-06-23 AU AU47762/99A patent/AU746783B2/en not_active Ceased
- 1999-06-23 CA CA002335970A patent/CA2335970C/en not_active Expired - Fee Related
- 1999-06-23 CN CN99808083A patent/CN1307539A/zh active Pending
- 1999-06-23 WO PCT/EP1999/004348 patent/WO2000000425A1/en not_active Ceased
- 1999-06-23 ES ES99931148T patent/ES2182544T3/es not_active Expired - Lifetime
- 1999-06-23 JP JP2000556988A patent/JP2002519181A/ja active Pending
- 1999-06-24 CA CA002335983A patent/CA2335983A1/en not_active Abandoned
- 1999-06-24 KR KR1020007014968A patent/KR20010053267A/ko not_active Withdrawn
- 1999-06-24 PL PL99345181A patent/PL345181A1/xx not_active Application Discontinuation
- 1999-06-24 WO PCT/EP1999/004408 patent/WO2000000426A1/en not_active Ceased
- 1999-06-24 JP JP2000556989A patent/JP2002519182A/ja active Pending
- 1999-06-24 AU AU47776/99A patent/AU743727B2/en not_active Ceased
- 1999-06-24 AT AT99931176T patent/ATE232836T1/de not_active IP Right Cessation
- 1999-06-24 BR BR9911739-8A patent/BR9911739A/pt not_active IP Right Cessation
- 1999-06-24 ID IDW20002722A patent/ID27777A/id unknown
- 1999-06-24 DE DE69905467T patent/DE69905467T2/de not_active Expired - Fee Related
- 1999-06-24 US US09/720,294 patent/US6702960B1/en not_active Expired - Fee Related
- 1999-06-24 EP EP99931176A patent/EP1093439B1/en not_active Expired - Lifetime
- 1999-06-24 CN CN99808082A patent/CN1307538A/zh active Pending
-
2000
- 2000-12-21 NO NO20006579A patent/NO20006579L/no not_active Application Discontinuation
- 2000-12-21 NO NO20006580A patent/NO20006580D0/no not_active Application Discontinuation
-
2001
- 2001-01-11 ZA ZA200100316A patent/ZA200100316B/en unknown
- 2001-01-11 ZA ZA200100317A patent/ZA200100317B/en unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69902547T2 (de) | Katalytische teiloxidation mit zwei katalytisch-aktiven metallen | |
| DE69810805T2 (de) | Verfahren zur herstellung von wasserstoff und kohlenmonoxid | |
| DE69425692T2 (de) | Verfahren zur katalytischen Teiloxydation von Kohlenwasserstoff | |
| DE69932869T2 (de) | Verfahren zur autothermen Dampfreformierung einer Kohlenwasserstoffeinspeisung | |
| DE60024462T2 (de) | Katalysatorstruktur und Verfahren zur Fischer-Tropsch-Synthese | |
| DE69418213T2 (de) | Verfahren zur katalytischen teiloxidation von kohlenwasserstoffen | |
| DE69428245T2 (de) | Verfahren zur partiellen Oxidation von Erdgas zur Herstellung von Synthesegas und Formaldehyd | |
| DE69322129T2 (de) | Verfahren zur katalytischen Kohlenwasserstoffteiloxidation | |
| DE69925052T2 (de) | Verfahren zur Herstellung von wasserstoffreichem Gas | |
| DE69801053T3 (de) | Autothermer reaktor mit einer sauerstoffionen leitenden dichten keramischen membran und dessen verwendung in einem verfahren zur erzeugung von synthesegas | |
| DE69825576T2 (de) | Katalysator für die herstellung von synthesegas und verfahren zur herstellung von kohlenmonoxid | |
| DE69702190T2 (de) | Anlage für teiloxidationsreaktionen | |
| DE69825577T2 (de) | Verfahren zur herstellung von synthesegas | |
| DE69517033T2 (de) | Verfahren zur katalytischen teiloxidation von kohlenwasserstoffen | |
| DE4102185C2 (de) | Katalysator zur Herstellung von Synthesegas durch Reformieren von leichten Kohlenwasserstoffen mit CO¶2¶ | |
| DE60016244T2 (de) | Mischvorrichtung | |
| DE60209484T2 (de) | Verfahren zum aktivieren eines getragenen katalysators der eine kobalthaltigen verbindung enthält | |
| DE60014671T2 (de) | Katalysatorstruktur und fischer-tropschsyntheseverfahren | |
| DE60105162T2 (de) | Katalysator und verfahren zur herstellung von kohlenwasserstoffen | |
| DE69212121T2 (de) | Verfahren und Vorrichtung zur Herstellung von Synthesegas und deren Anwendung | |
| DE60225404T2 (de) | Verfahren zur katalytischen autothermen Dampfreformierung von Gemischen von höheren Alkoholen, insbesondere Ethanol mit Kohlenwasserstoffen | |
| CH653571A5 (de) | Eisenoxidkatalysator fuer die dampfreformierung und verfahren zur dampfreformierung. | |
| DE10062578A1 (de) | Methanolreformierungskatalysator | |
| DE69424540T2 (de) | Ein stabiler und aktiver Nickelkatalysator für die Kohlendioxydreformierung von Methan zum Synthesegas | |
| EP0695279A1 (de) | Katalysator zur herstellung von synthesegas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8328 | Change in the person/name/address of the agent |
Representative=s name: JUNG, SCHIRDEWAHN, GRUENBERG, SCHNEIDER PATENTANWAELTE |
|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: ADVOTEC. PATENT- UND RECHTSANWAELTE, 80538 MUENCHE |
|
| 8339 | Ceased/non-payment of the annual fee |