JP2000133631A - 窒化ケイ素膜の選択的腐食組成物および方法 - Google Patents
窒化ケイ素膜の選択的腐食組成物および方法Info
- Publication number
- JP2000133631A JP2000133631A JP11240647A JP24064799A JP2000133631A JP 2000133631 A JP2000133631 A JP 2000133631A JP 11240647 A JP11240647 A JP 11240647A JP 24064799 A JP24064799 A JP 24064799A JP 2000133631 A JP2000133631 A JP 2000133631A
- Authority
- JP
- Japan
- Prior art keywords
- corrosion
- silicon
- composition
- solution
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005260 corrosion Methods 0.000 title claims abstract description 101
- 230000007797 corrosion Effects 0.000 title claims abstract description 100
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 229910052581 Si3N4 Inorganic materials 0.000 title claims abstract description 28
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 26
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000010703 silicon Substances 0.000 claims abstract description 49
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 48
- 239000004065 semiconductor Substances 0.000 claims abstract description 14
- -1 hexafluorosilicic acid Chemical compound 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 80
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 230000003628 erosive effect Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 3
- 239000002131 composite material Substances 0.000 abstract description 7
- 239000002245 particle Substances 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 2
- MMNSHNBVSJFTNA-UHFFFAOYSA-N 1h-phosphole-2-carboxylic acid Chemical compound OC(=O)C1=CC=CP1 MMNSHNBVSJFTNA-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 230000003190 augmentative effect Effects 0.000 abstract 1
- 239000008236 heating water Substances 0.000 abstract 1
- 150000001455 metallic ions Chemical class 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 20
- 238000002474 experimental method Methods 0.000 description 11
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 10
- 229910017604 nitric acid Inorganic materials 0.000 description 10
- 150000004767 nitrides Chemical class 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 235000019795 sodium metasilicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000000572 ellipsometry Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
- C09K13/04—Etching, surface-brightening or pickling compositions containing an inorganic acid
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
- H01L21/31116—Etching inorganic layers by chemical means by dry-etching
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Weting (AREA)
- Drying Of Semiconductors (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/141,897 US6162370A (en) | 1998-08-28 | 1998-08-28 | Composition and method for selectively etching a silicon nitride film |
| US09/141897 | 1998-08-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000133631A true JP2000133631A (ja) | 2000-05-12 |
| JP2000133631A5 JP2000133631A5 (enExample) | 2006-09-07 |
Family
ID=22497714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11240647A Pending JP2000133631A (ja) | 1998-08-28 | 1999-08-27 | 窒化ケイ素膜の選択的腐食組成物および方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6162370A (enExample) |
| EP (1) | EP0989597B1 (enExample) |
| JP (1) | JP2000133631A (enExample) |
| KR (1) | KR100741250B1 (enExample) |
| AT (1) | ATE254337T1 (enExample) |
| CA (1) | CA2279786C (enExample) |
| DE (1) | DE69912712T2 (enExample) |
| ES (1) | ES2210922T3 (enExample) |
| SG (1) | SG85120A1 (enExample) |
| TW (1) | TW576865B (enExample) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005203467A (ja) * | 2004-01-14 | 2005-07-28 | Tosoh Corp | エッチング用組成物 |
| JP2007318057A (ja) * | 2006-04-28 | 2007-12-06 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| JP2008047796A (ja) * | 2006-08-21 | 2008-02-28 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| JP2008311436A (ja) * | 2007-06-14 | 2008-12-25 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| JP2009206419A (ja) * | 2008-02-29 | 2009-09-10 | Dainippon Screen Mfg Co Ltd | 基板処理装置および基板処理方法 |
| JP2010515245A (ja) * | 2006-12-21 | 2010-05-06 | アドバンスド テクノロジー マテリアルズ,インコーポレイテッド | 窒化ケイ素の選択的除去のための組成物および方法 |
| JP2014072389A (ja) * | 2012-09-28 | 2014-04-21 | Dainippon Screen Mfg Co Ltd | 基板処理方法および基板処理装置 |
| KR20140079267A (ko) | 2012-12-18 | 2014-06-26 | 솔브레인 주식회사 | 식각 조성물, 식각 방법 및 반도체 소자 |
| JP2016092392A (ja) * | 2014-10-30 | 2016-05-23 | ラムテクノロジー株式会社Ram Technology Co.,Ltd. | 窒化膜エッチング組成物およびそれを用いた半導体装置の製造方法 |
| JP2016519424A (ja) * | 2013-03-15 | 2016-06-30 | ティーイーエル エフエスアイ,インコーポレイティド | 加熱されたエッチング溶液を供する処理システム及び方法 |
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| KR100307631B1 (ko) * | 1999-06-01 | 2001-09-29 | 윤종용 | 반도체소자의 미세패턴 형성방법 |
| US6699400B1 (en) * | 1999-06-04 | 2004-03-02 | Arne W. Ballantine | Etch process and apparatus therefor |
| US7618868B2 (en) * | 2006-05-03 | 2009-11-17 | Samsung Electronics Co., Ltd. | Method of manufacturing field effect transistors using sacrificial blocking layers |
| KR20080079999A (ko) * | 2007-02-28 | 2008-09-02 | 토소가부시키가이샤 | 에칭 방법 및 그것에 이용되는 에칭용 조성물 |
| TWI591158B (zh) * | 2008-03-07 | 2017-07-11 | 恩特葛瑞斯股份有限公司 | 非選擇性氧化物蝕刻濕清潔組合物及使用方法 |
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| JP5490071B2 (ja) * | 2011-09-12 | 2014-05-14 | 株式会社東芝 | エッチング方法 |
| KR101809192B1 (ko) | 2011-12-16 | 2017-12-15 | 에스케이하이닉스 주식회사 | 식각 조성물 및 이를 이용한 반도체 소자의 제조방법 |
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- 1999-08-27 EP EP99116743A patent/EP0989597B1/en not_active Expired - Lifetime
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2005203467A (ja) * | 2004-01-14 | 2005-07-28 | Tosoh Corp | エッチング用組成物 |
| JP2007318057A (ja) * | 2006-04-28 | 2007-12-06 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| JP2008047796A (ja) * | 2006-08-21 | 2008-02-28 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| US8778210B2 (en) | 2006-12-21 | 2014-07-15 | Advanced Technology Materials, Inc. | Compositions and methods for the selective removal of silicon nitride |
| US9691629B2 (en) | 2006-12-21 | 2017-06-27 | Entegris, Inc. | Compositions and methods for the selective removal of silicon nitride |
| JP2010515245A (ja) * | 2006-12-21 | 2010-05-06 | アドバンスド テクノロジー マテリアルズ,インコーポレイテッド | 窒化ケイ素の選択的除去のための組成物および方法 |
| US9158203B2 (en) | 2006-12-21 | 2015-10-13 | Advanced Technology Materials, Inc. | Compositions and methods for the selective removal of silicon nitride |
| JP2008311436A (ja) * | 2007-06-14 | 2008-12-25 | Tosoh Corp | エッチング用組成物及びエッチング方法 |
| JP2009206419A (ja) * | 2008-02-29 | 2009-09-10 | Dainippon Screen Mfg Co Ltd | 基板処理装置および基板処理方法 |
| JP2014072389A (ja) * | 2012-09-28 | 2014-04-21 | Dainippon Screen Mfg Co Ltd | 基板処理方法および基板処理装置 |
| US9364873B2 (en) | 2012-09-28 | 2016-06-14 | SCREEN Holdings Co., Ltd. | Substrate treatment method and substrate treatment apparatus |
| KR20140079267A (ko) | 2012-12-18 | 2014-06-26 | 솔브레인 주식회사 | 식각 조성물, 식각 방법 및 반도체 소자 |
| KR20220024378A (ko) | 2012-12-18 | 2022-03-03 | 솔브레인 주식회사 | 식각 조성물, 식각 방법 및 반도체 소자 |
| JP2016519424A (ja) * | 2013-03-15 | 2016-06-30 | ティーイーエル エフエスアイ,インコーポレイティド | 加熱されたエッチング溶液を供する処理システム及び方法 |
| JP2016092392A (ja) * | 2014-10-30 | 2016-05-23 | ラムテクノロジー株式会社Ram Technology Co.,Ltd. | 窒化膜エッチング組成物およびそれを用いた半導体装置の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0989597A1 (en) | 2000-03-29 |
| DE69912712D1 (de) | 2003-12-18 |
| KR20000017570A (ko) | 2000-03-25 |
| CA2279786C (en) | 2009-06-30 |
| TW576865B (en) | 2004-02-21 |
| CA2279786A1 (en) | 2000-02-28 |
| US6303514B1 (en) | 2001-10-16 |
| KR100741250B1 (ko) | 2007-07-19 |
| EP0989597B1 (en) | 2003-11-12 |
| ATE254337T1 (de) | 2003-11-15 |
| DE69912712T2 (de) | 2004-09-23 |
| SG85120A1 (en) | 2001-12-19 |
| US6162370A (en) | 2000-12-19 |
| ES2210922T3 (es) | 2004-07-01 |
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