ES549717A0 - Un procedimiento de carbonilacion - Google Patents
Un procedimiento de carbonilacionInfo
- Publication number
- ES549717A0 ES549717A0 ES549717A ES549717A ES549717A0 ES 549717 A0 ES549717 A0 ES 549717A0 ES 549717 A ES549717 A ES 549717A ES 549717 A ES549717 A ES 549717A ES 549717 A0 ES549717 A0 ES 549717A0
- Authority
- ES
- Spain
- Prior art keywords
- diorganophosphite
- transition metal
- carbonilation
- procedure
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 2
- 230000007704 transition Effects 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 2
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Materials For Medical Uses (AREA)
- Steroid Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US58135284A | 1984-02-17 | 1984-02-17 | |
US06/685,025 US4599206A (en) | 1984-02-17 | 1984-12-28 | Transition metal complex catalyzed reactions |
Publications (2)
Publication Number | Publication Date |
---|---|
ES549717A0 true ES549717A0 (es) | 1986-11-16 |
ES8701140A1 ES8701140A1 (es) | 1986-11-16 |
Family
ID=27078299
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES540439A Expired ES8609185A1 (es) | 1984-02-17 | 1985-02-15 | Un procedimiento para hidroformulacion para producir adheridos. |
ES549717A Expired ES8701140A1 (es) | 1984-02-17 | 1985-12-09 | Un procedimiento de carbonilacion |
ES554326A Expired ES8706480A1 (es) | 1984-02-17 | 1986-04-24 | Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES540439A Expired ES8609185A1 (es) | 1984-02-17 | 1985-02-15 | Un procedimiento para hidroformulacion para producir adheridos. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES554326A Expired ES8706480A1 (es) | 1984-02-17 | 1986-04-24 | Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion. |
Country Status (21)
Country | Link |
---|---|
US (1) | US4599206A (es) |
EP (1) | EP0155508B1 (es) |
JP (1) | JPH0645633B2 (es) |
KR (1) | KR920010519B1 (es) |
AT (1) | ATE83230T1 (es) |
AU (2) | AU579144B2 (es) |
BR (1) | BR8505278A (es) |
CA (1) | CA1262915A1 (es) |
CS (1) | CS271311B2 (es) |
DE (1) | DE3586878T2 (es) |
DK (1) | DK473485A (es) |
ES (3) | ES8609185A1 (es) |
FI (1) | FI88709C (es) |
HU (1) | HU202176B (es) |
MX (1) | MX164254B (es) |
NO (1) | NO165915C (es) |
PL (2) | PL251973A1 (es) |
RO (1) | RO92321B (es) |
SG (1) | SG32193G (es) |
WO (1) | WO1985003702A1 (es) |
YU (1) | YU44255B (es) |
Families Citing this family (154)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2710040A (en) * | 1953-10-29 | 1955-06-07 | Joseph L Boyd | Bending machine |
US4737588A (en) * | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
US4748261A (en) * | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
US4885401A (en) * | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
US4774361A (en) * | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
US4835299A (en) * | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
US5059710A (en) * | 1988-08-05 | 1991-10-22 | Union Carbide Chemicals And Plastics Technology Corporation | Ionic phosphites and their use in homogeneous transition metal catalyzed processes |
US5113022A (en) * | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
US5001274A (en) * | 1989-06-23 | 1991-03-19 | Union Carbide Chemicals And Plastics Company Inc. | Hydroformylation process |
US5210318A (en) * | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
DE4026406A1 (de) * | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
EP0545997B1 (en) * | 1990-08-31 | 1995-11-02 | The Governors Of The University Of Alberta | Carbonylation of methanol using a novel transition metal catalyst precursor |
US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
JP2946790B2 (ja) * | 1991-03-14 | 1999-09-06 | 三菱化学株式会社 | アルデヒド類の製造法 |
US5177019A (en) * | 1991-05-20 | 1993-01-05 | Eastman Kodak Company | Method of quantitative analysis of organophosphorus compounds |
TW213465B (es) * | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
US5360938A (en) * | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
US5292785A (en) * | 1992-05-05 | 1994-03-08 | Ciba-Geigy Corporation | Bis-phosphite stabilized compositions |
US5312996A (en) * | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
US5310889A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzo(d,f)(1,3,2)dioxaphosphepin stabilizers |
US5310890A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzoi(d,g)(1,3,2)dioxaphosphocin stabilizers |
US5364950A (en) * | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
DE4242723A1 (de) * | 1992-12-17 | 1994-06-23 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden |
DE69417961T2 (de) * | 1993-07-22 | 1999-12-02 | General Electric Co., Schenectady | Neoalkyl Alkyliden-2,2'-Biphenyl und Bisnenyl Phosphit-Ester |
KR100263138B1 (ko) * | 1993-11-23 | 2000-08-01 | 이.아이,듀우판드네모아앤드캄파니 | 모노올레핀의 하이드로시안화 방법 및 이를 위한 촉매 조성물 |
EP0755302B1 (en) | 1994-04-14 | 2000-10-04 | E.I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
US5512695A (en) * | 1994-04-14 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
US5543536A (en) * | 1994-04-26 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation |
SG44321A1 (en) * | 1994-07-18 | 1997-12-19 | Mitsubishi Chem Corp | Method for dimerizing an olefin |
US5756855A (en) * | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
TW315370B (es) * | 1994-10-07 | 1997-09-11 | Du Pont | |
US5512696A (en) * | 1995-07-21 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor |
US5672766A (en) * | 1994-12-12 | 1997-09-30 | Mitsubishi Chemical Corporation | Method for producing aldehydes |
US5520722A (en) * | 1995-01-18 | 1996-05-28 | Exxon Research And Engineering Company | Multiunsaturates removal process |
US5516965A (en) * | 1995-01-18 | 1996-05-14 | Exxon Research And Engineering Company | Unsaturates recovery and recycle process |
US5675041A (en) * | 1995-01-18 | 1997-10-07 | Exxon Research & Engineering Company | Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene |
IN187044B (es) * | 1995-01-27 | 2002-01-05 | Du Pont | |
US5821378A (en) * | 1995-01-27 | 1998-10-13 | E. I. Du Pont De Nemours And Company | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles |
US5744650A (en) * | 1995-12-06 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-Ligand complex catalyzed processes |
US5654455A (en) * | 1995-12-21 | 1997-08-05 | Ciba-Geigy Corporation | Tris-phosphite ligands and their use in transitioin metal catalyzed processes |
US5892119A (en) * | 1996-11-26 | 1999-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
US5962744A (en) * | 1998-03-27 | 1999-10-05 | The Research Foundation Of State University Of New York | Process for hydrocarbonylations in supercritical carbon dioxide |
JP3847466B2 (ja) * | 1998-09-01 | 2006-11-22 | 三菱化学株式会社 | オレフィンのヒドロホルミル化反応方法 |
EP1312598B1 (en) | 1998-12-10 | 2005-02-16 | Mitsubishi Chemical Corporation | Process for producing aldehyde |
JP3921853B2 (ja) * | 1998-12-10 | 2007-05-30 | 三菱化学株式会社 | アルデヒド類及びアルコール類の製造方法 |
JP3928315B2 (ja) * | 1998-12-14 | 2007-06-13 | 三菱化学株式会社 | アルデヒドの製造方法 |
US6610891B1 (en) | 1999-12-03 | 2003-08-26 | Mitsubishi Chemical Corporation | Method of producing aldehydes |
WO2001051441A1 (en) * | 2000-01-12 | 2001-07-19 | Eastman Chemical Company | Hydroformylation method for making aldehydes from sterically hindered olefins |
JP3864668B2 (ja) * | 2000-05-01 | 2007-01-10 | 三菱化学株式会社 | アルデヒド類の製造方法 |
DE10027505A1 (de) * | 2000-06-06 | 2001-12-13 | Studiengesellschaft Kohle Mbh | Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung |
GB0021715D0 (en) * | 2000-09-05 | 2000-10-18 | Ici Plc | Recovery of metals |
DE10058383A1 (de) | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
DE10140086A1 (de) | 2001-08-16 | 2003-02-27 | Oxeno Olefinchemie Gmbh | Neue Phosphitverbindungen und neue Phosphitmetallkomplexe |
DE10148551A1 (de) * | 2001-10-01 | 2003-04-10 | Bayer Ag | Chirale Monophosphorverbindungen |
DE10149349A1 (de) * | 2001-10-06 | 2003-04-17 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 6-Methylheptan-2-on und dessen Verwendung |
ATE320438T1 (de) * | 2002-03-11 | 2006-04-15 | Union Carbide Chem Plastic | Bisphosphit-ligande für carbonylierungsverfahren |
DE10220801A1 (de) | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
US7317130B2 (en) | 2002-08-31 | 2008-01-08 | Oxeno Olefinchemie Gmbh | Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters |
BR0314566A (pt) * | 2002-10-15 | 2006-06-27 | Union Carbide Chem Plastic | ligante bis-quelante e uso do mesmo em processos de carbonilação |
JP2007509093A (ja) * | 2003-10-21 | 2007-04-12 | ビーエーエスエフ アクチェンゲゼルシャフト | アルデヒドの連続的な製造方法 |
DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
US7291748B2 (en) | 2005-07-28 | 2007-11-06 | Basf Corporation | C10/C7 ester mixtures based on 2-propylheptanol |
DE102005042464A1 (de) | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
DE102006034442A1 (de) * | 2006-07-26 | 2008-01-31 | Oxeno Olefinchemie Gmbh | Katalysatorvorstufe für einen Rh-Komplexkatalysator |
US8084482B2 (en) | 2006-12-07 | 2011-12-27 | Basf Se | Compositions and kits comprising a fungicidal triazole and an alkoxylated alcohol, and their uses |
DE102006058682A1 (de) | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
US7586010B2 (en) * | 2006-12-21 | 2009-09-08 | Eastman Chemical Company | Phosphonite-containing catalysts for hydroformylation processes |
CA2680484C (en) * | 2007-03-20 | 2015-04-07 | Union Carbide Chemicals & Plastics Technology Llc | Hydroformylation process with improved control over product isomers |
JP5298119B2 (ja) * | 2007-04-09 | 2013-09-25 | エルジー・ケム・リミテッド | ホスファイト配位子を含む触媒組成物およびこれを用いたヒドロホルミル化方法 |
DE102007023514A1 (de) | 2007-05-18 | 2008-11-20 | Evonik Oxeno Gmbh | Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren |
EP2348015A3 (en) | 2007-09-07 | 2012-05-23 | Dow Global Technologies LLC | Preparation of cyano-aliphatic aldehydes |
US7872156B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Fluorophosphite containing catalysts for hydroformylation processes |
US7872157B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Phosphonite containing catalysts for hydroformylation processes |
US7708912B2 (en) * | 2008-06-16 | 2010-05-04 | Polytronics Technology Corporation | Variable impedance composition |
CN101981042B (zh) * | 2008-03-28 | 2014-02-19 | 联合碳化化学品及塑料技术公司 | 用于单氯代亚磷酸酯合成的淤浆方法 |
CA2729643C (en) | 2008-07-03 | 2016-08-16 | Dow Technology Investments Llc | Process of controlling heavies in a recycle catalyst stream |
WO2010021863A1 (en) * | 2008-08-19 | 2010-02-25 | Dow Technology Investments Llc | Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers |
CN102177171B (zh) * | 2008-10-08 | 2014-02-12 | 陶氏技术投资有限公司 | 合成二亚磷酸酯的淤浆方法 |
WO2010057099A1 (en) | 2008-11-14 | 2010-05-20 | University Of Kansas | Polymer-supported transition metal catalyst complexes and methods of use |
DE102009001225A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
US7928267B1 (en) * | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
DE102009029050A1 (de) | 2009-08-31 | 2011-03-03 | Evonik Oxeno Gmbh | Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen |
JP5823967B2 (ja) | 2009-10-16 | 2015-11-25 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 気相ヒドロホルミル化方法 |
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JP5912084B2 (ja) * | 2009-12-22 | 2016-04-27 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | オレフィン分圧の制御による、混合リガンドヒドロホルミル化プロセスにおけるノルマル:イソアルデヒド比の制御 |
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- 1985-02-15 KR KR1019850700257A patent/KR920010519B1/ko not_active IP Right Cessation
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