DE3773890D1 - Durch uebergangsmetallkomplexe katalysierte hydroformylierung. - Google Patents

Durch uebergangsmetallkomplexe katalysierte hydroformylierung.

Info

Publication number
DE3773890D1
DE3773890D1 DE8787903774T DE3773890T DE3773890D1 DE 3773890 D1 DE3773890 D1 DE 3773890D1 DE 8787903774 T DE8787903774 T DE 8787903774T DE 3773890 T DE3773890 T DE 3773890T DE 3773890 D1 DE3773890 D1 DE 3773890D1
Authority
DE
Germany
Prior art keywords
transition metal
metal complex
hydroformylation catalyzed
hydroformylation
catalyzed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8787903774T
Other languages
English (en)
Inventor
Michael Maher
Robert Bryant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of DE3773890D1 publication Critical patent/DE3773890D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE8787903774T 1986-05-20 1987-05-19 Durch uebergangsmetallkomplexe katalysierte hydroformylierung. Expired - Lifetime DE3773890D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions
PCT/US1987/001124 WO1987007261A2 (en) 1986-05-20 1987-05-19 Transition metal complex catalyzed hydroformulation

Publications (1)

Publication Number Publication Date
DE3773890D1 true DE3773890D1 (de) 1991-11-21

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787903774T Expired - Lifetime DE3773890D1 (de) 1986-05-20 1987-05-19 Durch uebergangsmetallkomplexe katalysierte hydroformylierung.

Country Status (12)

Country Link
US (1) US4774361A (de)
EP (1) EP0276231B1 (de)
JP (1) JPS63503385A (de)
CN (1) CN1010011B (de)
AU (1) AU613312B2 (de)
CA (1) CA1312094C (de)
DE (1) DE3773890D1 (de)
ES (1) ES2004935A6 (de)
IN (1) IN169727B (de)
MX (1) MX166107B (de)
NO (1) NO166583C (de)
WO (1) WO1987007261A2 (de)

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
IT1237530B (it) * 1989-12-12 1993-06-08 Eniricerche Spa Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
US5243099A (en) * 1991-12-06 1993-09-07 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5169981A (en) * 1991-12-06 1992-12-08 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
US5739352A (en) * 1995-10-19 1998-04-14 United Carbide Chemicals & Plastics Technology Corporation Process for preparing carboxylic acids
DE19605435A1 (de) * 1996-02-14 1997-08-21 Basf Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
CN1163463C (zh) 1998-12-10 2004-08-25 三菱化学株式会社 醛的制备方法
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
GB9918229D0 (en) † 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
AU779061B2 (en) 2000-06-27 2005-01-06 Dainippon Printing Co. Ltd. Multilayer volume hologram, and label for multilayer volume hologram fabrication
EP1249441A1 (de) 2001-04-13 2002-10-16 Dsm N.V. Kontinuierliches Hydroformylierungsverfahren
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
PL206145B1 (pl) * 2002-08-31 2010-07-30 Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych
KR100988732B1 (ko) 2002-08-31 2010-10-20 에보니크 옥세노 게엠베하 사이클릭 탄산 에스테르의 존재하에 개질되지 않은 금속 착물에 의해 촉매된 올레핀계 불포화 화합물의 하이드로포밀화에 의해 알데하이드를 제조하는 방법
EP1595984B1 (de) * 2003-01-16 2010-06-09 Teijin Fibers Limited Differential-shrinkage-filamentgarn in kombination mit polyester
EP2308817B1 (de) 2003-07-03 2016-10-05 Dow Technology Investments LLC Minimierung von Ligandenabbauprodukten oder deren Reversion zu nützlichen Phosphinliganden
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
WO2006020287A1 (en) 2004-08-02 2006-02-23 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
CA2680484C (en) * 2007-03-20 2015-04-07 Union Carbide Chemicals & Plastics Technology Llc Hydroformylation process with improved control over product isomers
KR100964098B1 (ko) * 2007-04-09 2010-06-16 주식회사 엘지화학 포스파이트 리간드를 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
ES2558465T3 (es) 2008-07-03 2016-02-04 Dow Technology Investments Llc Procedimiento de tratamiento de una descarga de hidroformilación
JP5670909B2 (ja) 2008-11-14 2015-02-18 ユニバーシティ・オブ・カンザス ポリマーに担持された遷移金属触媒錯体、及びその使用方法
JP5603407B2 (ja) 2009-03-31 2014-10-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 二重オープンエンド型ビスホスファイトリガンドによるヒドロホルミル化方法
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
US8586800B2 (en) 2009-10-16 2013-11-19 Dow Technology Investments Llc Gas phase hydroformylation process
MY159684A (en) 2009-12-22 2017-01-13 Dow Technology Investments Llc Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
US8664451B2 (en) 2009-12-22 2014-03-04 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
US8598390B2 (en) 2009-12-22 2013-12-03 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process
EP2624953B1 (de) 2010-10-05 2018-10-24 Dow Technology Investments LLC Hydroformylierungsverfahren
MX346922B (es) 2010-11-12 2017-04-05 Dow Technology Investments Llc Moderación de suciedad en procesos de hidroformilación mediante adición de agua.
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
KR20140143382A (ko) 2012-03-07 2014-12-16 바스프 에스이 Ｃ3-ｃ20-알데히드의 수소화 및 증류에서의 열 집적 방법
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
SG11201405863QA (en) 2012-04-12 2014-11-27 Basf Se Method for replenishing the catalyst in continuous hydroformylation
EP2855016A1 (de) 2012-06-04 2015-04-08 Dow Technology Investments LLC Hydroformylierungsverfahren
BR112015003762B1 (pt) 2012-08-29 2021-04-13 Dow Technology Investments Llc Processo para a formação de um catalisador de hidroformilação
PL2900373T3 (pl) 2012-09-25 2019-09-30 Dow Technology Investments Llc Sposób stabilizacji ligandu fosforynowego przeciwko degradacji
EP2740535A1 (de) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentat-Liganden für die Hydroformylation von Ethylen
US9382180B2 (en) 2012-12-06 2016-07-05 Dow Technology Investments Llc Hydroformylation process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
EP3083542A1 (de) 2013-12-19 2016-10-26 Dow Technology Investments LLC Hydroformylierungsverfahren
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
CA2943211C (en) 2014-03-31 2022-03-22 Dow Technology Investments Llc Hydroformylation process
US10501486B2 (en) 2014-05-14 2019-12-10 Dow Technology Investments Llc Stabilized organophosphorous compounds
MY184826A (en) * 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
EP3374340B1 (de) 2015-11-10 2021-12-29 Dow Technology Investments LLC Verfahren zur herstellung von aldehyden
ES2901236T3 (es) 2016-02-11 2022-03-21 Dow Technology Investments Llc Procesos para convertir olefinas en alcoholes, éteres o combinaciones de los mismos
WO2017160956A1 (en) 2016-03-18 2017-09-21 Dow Technology Investments Llc Hydroformylation process
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
CN111212826B (zh) 2017-10-25 2023-05-23 陶氏技术投资有限责任公司 减少在加氢甲酰化过程中形成的包含醛化合物的溶液中重物质形成的方法
US11033890B2 (en) 2017-11-13 2021-06-15 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
CN112074347A (zh) 2018-05-30 2020-12-11 陶氏技术投资有限责任公司 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法
WO2019231611A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods of controlling hydroformylation processes
EP3801898A1 (de) 2018-05-30 2021-04-14 Dow Technology Investments LLC Katalysatorzusammensetzung mit kombination eines monophopsphins, eines tetraphosphinliganden und ein hydroformylierungsverfahren unter verwendung davon
JP7447116B2 (ja) * 2018-11-29 2024-03-11 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
EP3990176A1 (de) 2019-06-27 2022-05-04 Dow Technology Investments LLC Verfahren zur herstellung einer lösung aus hydroformylierungsprozess zur rückgewinnung von edelmetallen
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
US11976017B2 (en) 2019-12-19 2024-05-07 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
JP2023553108A (ja) 2020-12-14 2023-12-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒金属の責務を改善するためのプロセス
EP4430218A1 (de) 2021-11-11 2024-09-18 Dow Technology Investments LLC Verfahren zur rückgewinnung von rhodium aus hydroformylierungsverfahren
WO2023114578A1 (en) 2021-12-16 2023-06-22 Dow Technology Investments Llc Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
CN118317834A (zh) 2021-12-16 2024-07-09 陶氏技术投资有限责任公司 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE156528C (de) *
US4482748A (en) * 1967-05-29 1984-11-13 Celanese Corporation Hydrocarbonylation
DE2145532C3 (de) * 1971-09-11 1975-02-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Aufarbeitung von Hydroformylierungsgemischen
DE2326489A1 (de) * 1973-05-24 1974-12-12 Ernst Prof Dr Bayer Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer
JPS5638576B2 (de) * 1974-07-25 1981-09-08
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
JPS6022688B2 (ja) * 1976-12-29 1985-06-03 和光純薬工業株式会社 アルデヒド化合物の蒸留方法
EP0008407B1 (de) * 1978-08-17 1983-10-26 Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG Polymere Hydrierkatalysatoren, Verfahren zur Herstellung dieser Katalysatoren und ihre Verwendung für katalytische Hydrierungen
US4235744A (en) * 1978-10-30 1980-11-25 Standard Oil Company (Ohio) Carbonylation of olefinically unsaturated compounds
US4504684A (en) * 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
EP0096988B1 (de) * 1982-06-11 1987-07-08 DAVY McKEE (LONDON) LIMITED Hydroformylierungsverfahren
US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US4528404A (en) * 1983-03-16 1985-07-09 Exxon Research And Engineering Co. High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4599456A (en) * 1984-12-20 1986-07-08 Phillips Petroleum Company Novel aldehyde-phosphine compositions and uses therefor
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4613701A (en) * 1985-09-19 1986-09-23 Celanese Corporation Recovery of rhodium from hydroformylation reaction product

Also Published As

Publication number Publication date
AU7489887A (en) 1987-12-22
EP0276231B1 (de) 1991-10-16
MX166107B (es) 1992-12-21
JPH0548215B2 (de) 1993-07-20
NO166583C (no) 1991-08-14
WO1987007261A3 (en) 1988-04-07
IN169727B (de) 1991-12-14
US4774361A (en) 1988-09-27
NO880207L (no) 1988-01-19
CN1010011B (zh) 1990-10-17
CN87104311A (zh) 1988-06-08
AU613312B2 (en) 1991-08-01
NO880207D0 (no) 1988-01-19
JPS63503385A (ja) 1988-12-08
NO166583B (no) 1991-05-06
WO1987007261A2 (en) 1987-12-03
CA1312094C (en) 1992-12-29
EP0276231A1 (de) 1988-08-03
ES2004935A6 (es) 1989-02-16

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