ATE26696T1 - Hydroformylierungsverfahren. - Google Patents

Hydroformylierungsverfahren.

Info

Publication number
ATE26696T1
ATE26696T1 AT83302994T AT83302994T ATE26696T1 AT E26696 T1 ATE26696 T1 AT E26696T1 AT 83302994 T AT83302994 T AT 83302994T AT 83302994 T AT83302994 T AT 83302994T AT E26696 T1 ATE26696 T1 AT E26696T1
Authority
AT
Austria
Prior art keywords
hydroformylation
alpha
olefin
zone
aldehyde
Prior art date
Application number
AT83302994T
Other languages
English (en)
Inventor
Alan James Dennis
George Edwin Harrison
James Peter Wyber
Original Assignee
Davy Mckee London
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Davy Mckee London filed Critical Davy Mckee London
Application granted granted Critical
Publication of ATE26696T1 publication Critical patent/ATE26696T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT83302994T 1982-06-11 1983-05-24 Hydroformylierungsverfahren. ATE26696T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8217037 1982-06-11
EP83302994A EP0096986B1 (de) 1982-06-11 1983-05-24 Hydroformylierungsverfahren

Publications (1)

Publication Number Publication Date
ATE26696T1 true ATE26696T1 (de) 1987-05-15

Family

ID=10530979

Family Applications (1)

Application Number Title Priority Date Filing Date
AT83302994T ATE26696T1 (de) 1982-06-11 1983-05-24 Hydroformylierungsverfahren.

Country Status (7)

Country Link
US (1) US4496768A (de)
EP (1) EP0096986B1 (de)
JP (1) JPS5951228A (de)
AT (1) ATE26696T1 (de)
CA (1) CA1191865A (de)
DE (1) DE3371067D1 (de)
MX (1) MX162685A (de)

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GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
GB8515656D0 (en) * 1985-06-20 1985-07-24 Shell Int Research Extraction of group metals from organic solutions
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4885401A (en) * 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4831159A (en) * 1986-06-20 1989-05-16 Texaco Inc. Process for hydroformylation of n-vinyl-2-pyrrolidinone
US5053551A (en) * 1986-07-01 1991-10-01 Davy Mckee (London) Limited Process for the production of aldehydes by hydroformylation
GB2192182B (en) * 1986-07-01 1990-05-23 Davy Mckee Process for the production of aldehydes
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
DE3902892A1 (de) * 1989-02-01 1990-08-02 Basf Ag Verfahren zur herstellung von 2,2-dialkylpropionaldehyden
DE3942954A1 (de) * 1989-12-23 1991-06-27 Hoechst Ag Verfahren zur herstellung von aldehyden
DE4026406A1 (de) * 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5364950A (en) * 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5663403A (en) * 1995-01-24 1997-09-02 Mitsubishi Chemical Corporation Bisphosphite compound and method for producing aldehydes
US5648554A (en) * 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
DE19631521A1 (de) * 1996-08-03 1998-02-05 Basf Ag Verfahren zur Herstellung von 6-Aminocapronitril
DE69923801T2 (de) * 1998-12-10 2006-03-23 Mitsubishi Chemical Corp. Verfahren zur Herstellung von Aldehyden
GB0113080D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
US6693219B2 (en) 2001-06-02 2004-02-17 Eastman Chemical Company Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
US7674937B2 (en) * 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
US8513468B2 (en) 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
JP5890535B2 (ja) 2011-12-20 2016-03-22 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 改良されたヒドロホルミル化プロセス
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
EP4267543A1 (de) 2020-12-22 2023-11-01 Dow Technology Investments LLC Hydroformylierungsreaktionsverfahren

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NL146830C (de) * 1960-07-22
US3239569A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3168553A (en) * 1961-08-25 1965-02-02 Shell Oil Co Reactions of olefins with carbon monoxide
US3933919A (en) * 1964-12-15 1976-01-20 Geoffrey Wilkinson Hydroformylation of mono-α-olefins and mono-α-acetylenes
DE1230010B (de) * 1965-02-13 1966-12-08 Basf Ag Verfahren zur Herstellung von Aldehyden
US3725483A (en) * 1966-08-23 1973-04-03 Gulf Research Development Co A process for the hydroformylation of olefins
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process
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US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
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US3641076A (en) * 1970-08-24 1972-02-08 Union Oil Co Catalyst recovery
US3956177A (en) * 1971-08-20 1976-05-11 Phillips Petroleum Company Rhodium hydroformylation catalyst
JPS521821B2 (de) * 1971-09-23 1977-01-18
CA1022934A (en) * 1972-11-29 1977-12-20 Donald E. Morris Hydroformylation process
IT1005691B (it) * 1973-04-07 1976-09-30 Basf Ag Processo per la preparazione di dialdeidi alifatiche o cicloalifa tiche e oppure dei loro acetali
US4101588A (en) * 1973-04-07 1978-07-18 Basf Aktiengesellschaft Production of bis-(dimethyl) acetals of hexane dialdehydes
US4107079A (en) * 1973-09-10 1978-08-15 Rhone-Poulenc Industries Insoluble metallic complexes and catalysts therefrom
US3929915A (en) * 1974-07-31 1975-12-30 Du Pont Process for the production of butanediol
GB1460870A (en) * 1974-07-31 1977-01-06 Du Pont 2-vinyl-5-methyl-1,3-dioxane and its use in the preparation of butanediol and propanediol
US3963755A (en) * 1974-07-31 1976-06-15 E. I. Du Pont De Nemours And Company Mixture of 2(2'-propanal)-5-methyl-1,3-dioxane and 2(3'-propanal)-5-methyl-1,3-dioxane
US4159999A (en) * 1974-11-22 1979-07-03 Celanese Corporation Hydroformylation of olefins
US4096192A (en) * 1976-03-30 1978-06-20 E. I. Du Pont De Nemours And Company Process for the preparation of 2-methyl-1,3-propanediol
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US4135911A (en) * 1977-07-28 1979-01-23 E. I. Du Pont De Nemours And Company Rhodium recovery from hydroformylation still heel with triaryl phosphite ligand
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EP0003753B1 (de) * 1978-02-21 1982-04-07 E.I. Du Pont De Nemours And Company Verfahren zur Hydroformylierung von cyclischen Acroleinacetalen
US4224255A (en) * 1978-06-15 1980-09-23 General Electric Company Process for the production of aldehydes and alcohols from olefinically unsaturated compounds by hydroformylation with suppression of olefin hydrogenation
DE16285T1 (de) * 1979-03-21 1983-04-28 Davy Mckee (London) Ltd., London Verfahren zur herstellung von aldehyden durch hydroformylierung von alkenen.
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Also Published As

Publication number Publication date
MX162685A (es) 1991-06-17
DE3371067D1 (en) 1987-05-27
CA1191865A (en) 1985-08-13
JPH054378B2 (de) 1993-01-19
EP0096986A2 (de) 1983-12-28
EP0096986A3 (en) 1984-04-11
US4496768A (en) 1985-01-29
JPS5951228A (ja) 1984-03-24
EP0096986B1 (de) 1987-04-22

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