ES472518A1 - Procedimiento para la fabricacion de aldehidos - Google Patents
Procedimiento para la fabricacion de aldehidosInfo
- Publication number
- ES472518A1 ES472518A1 ES472518A ES472518A ES472518A1 ES 472518 A1 ES472518 A1 ES 472518A1 ES 472518 A ES472518 A ES 472518A ES 472518 A ES472518 A ES 472518A ES 472518 A1 ES472518 A1 ES 472518A1
- Authority
- ES
- Spain
- Prior art keywords
- carbon monoxide
- reaction
- hydrogen
- improvement
- manufacture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001299 aldehydes Chemical class 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000007700 distillative separation Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 150000003284 rhodium compounds Chemical class 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la fabricación de aldehídos; por transformación de olefinas con monóxido de carbono y hidrógeno, en presencia de catalizadores de rodio a elevada temperatura y mayor presión y con separación, por destilación de las combinaciones de partida no transformadas y de las partes componentes de bajo punto de ebullición del producto de la reacción, caracterizado porque se emplea una mezcla de óxido de carbono y de hidrógeno con un contenido de azufre de 2 hasta 20 ppms., retornando el residuo de la destilación, que contienen combinaciones de rodio disueltas y rodio en suspensión, como el catalizador a la fase de síntesis.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2737633A DE2737633C2 (de) | 1977-08-20 | 1977-08-20 | Verfahren zur Herstellung von Aldehyden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES472518A1 true ES472518A1 (es) | 1979-03-16 |
Family
ID=6016912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES472518A Expired ES472518A1 (es) | 1977-08-20 | 1978-08-11 | Procedimiento para la fabricacion de aldehidos |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4222966A (es) |
| JP (1) | JPS5811931B2 (es) |
| AT (1) | AT356640B (es) |
| AU (1) | AU518880B2 (es) |
| BE (1) | BE869767A (es) |
| BR (1) | BR7805273A (es) |
| CA (1) | CA1081258A (es) |
| DE (1) | DE2737633C2 (es) |
| ES (1) | ES472518A1 (es) |
| FR (1) | FR2400497A1 (es) |
| GB (1) | GB2002768B (es) |
| HU (1) | HU179757B (es) |
| IT (1) | IT1106884B (es) |
| NL (1) | NL172051C (es) |
| PL (1) | PL118118B1 (es) |
| SE (1) | SE444312B (es) |
| SU (1) | SU1017166A3 (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374278A (en) * | 1980-02-28 | 1983-02-15 | Union Carbide Corporation | Hydroformylation catalyst reactivation |
| US4324695A (en) * | 1980-11-17 | 1982-04-13 | National Distillers & Chemical Corp. | Catalyst compositions of transition metal carbonyl complexes intercalcated with lamellar materials |
| DE3114147A1 (de) * | 1981-04-08 | 1982-10-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von aldehyden |
| US5082977A (en) * | 1990-02-15 | 1992-01-21 | University Of Akron | Aldehydes by olefin hydroformylation |
| DE102012014395B3 (de) | 2012-07-13 | 2013-08-22 | Oxea Gmbh | Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| DE102012013968A1 (de) | 2012-07-13 | 2014-04-03 | Oxea Gmbh | Carbonsäureester der Isononansäure ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1430719A (fr) * | 1965-04-16 | 1966-03-04 | Eastman Kodak Co | Perfectionnements au procédé d'hydroformylation |
| DE1945574B2 (de) * | 1968-09-14 | 1975-01-23 | Mitsubishi Chemical Industries, Ltd., Tokio | Verfahren zur Rückgewinnung eines Rhodiumkatalysators aus einem Oxo-Reaktionsprodukt |
| GB1326013A (en) * | 1969-07-14 | 1973-08-08 | Johnson Matthey Co Ltd | Catalytic hydroformylation process |
| US3994978A (en) * | 1972-08-13 | 1976-11-30 | Mobil Oil Corporation | Hydroformylation of olefins |
| DE2245565B1 (de) * | 1972-09-16 | 1974-04-04 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur abtrennung von kobalt aus den primaerprodukten der oxosynthese und dessen wiedereinsatz in der synthesestufe |
| DE2406323C3 (de) * | 1974-02-09 | 1979-07-12 | Ruhrchemie Ag, 4200 Oberhausen | Kontinuierliches Verfahren zur Herstellung sauerstoffhaltiger Verbindungen durch Oxo-Synthese unter Einsatz des zurückgewonnenen Rhodiumkatalysators |
| JPS5822453B2 (ja) * | 1974-07-15 | 1983-05-09 | 三菱化学株式会社 | ブチルアルデヒドの製造方法 |
| US4248802A (en) * | 1975-06-20 | 1981-02-03 | Rhone-Poulenc Industries | Catalytic hydroformylation of olefins |
-
1977
- 1977-08-20 DE DE2737633A patent/DE2737633C2/de not_active Expired
- 1977-09-28 NL NLAANVRAGE7710612,A patent/NL172051C/xx not_active IP Right Cessation
-
1978
- 1978-08-10 AT AT581578A patent/AT356640B/de not_active IP Right Cessation
- 1978-08-11 FR FR7823686A patent/FR2400497A1/fr active Granted
- 1978-08-11 ES ES472518A patent/ES472518A1/es not_active Expired
- 1978-08-14 PL PL1978209050A patent/PL118118B1/pl unknown
- 1978-08-14 HU HU78RU167A patent/HU179757B/hu not_active IP Right Cessation
- 1978-08-15 JP JP53098735A patent/JPS5811931B2/ja not_active Expired
- 1978-08-15 SE SE7808651A patent/SE444312B/sv not_active IP Right Cessation
- 1978-08-15 SU SU782648754A patent/SU1017166A3/ru active
- 1978-08-16 BR BR7805273A patent/BR7805273A/pt unknown
- 1978-08-16 BE BE189908A patent/BE869767A/xx not_active IP Right Cessation
- 1978-08-17 CA CA309,517A patent/CA1081258A/en not_active Expired
- 1978-08-17 AU AU39010/78A patent/AU518880B2/en not_active Expired
- 1978-08-17 US US05/934,668 patent/US4222966A/en not_active Expired - Lifetime
- 1978-08-18 IT IT7850777A patent/IT1106884B/it active
- 1978-08-18 GB GB7833835A patent/GB2002768B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US4222966A (en) | 1980-09-16 |
| NL172051B (nl) | 1983-02-01 |
| CA1081258A (en) | 1980-07-08 |
| GB2002768A (en) | 1979-02-28 |
| SE444312B (sv) | 1986-04-07 |
| FR2400497A1 (fr) | 1979-03-16 |
| HU179757B (en) | 1982-12-28 |
| SE7808651L (sv) | 1979-02-21 |
| PL209050A1 (pl) | 1979-05-07 |
| DE2737633C2 (de) | 1979-09-27 |
| JPS5436210A (en) | 1979-03-16 |
| IT7850777A0 (it) | 1978-08-18 |
| GB2002768B (en) | 1982-03-24 |
| NL172051C (nl) | 1983-07-01 |
| SU1017166A3 (ru) | 1983-05-07 |
| DE2737633B1 (de) | 1979-02-08 |
| AU3901078A (en) | 1980-02-21 |
| NL7710612A (nl) | 1979-02-22 |
| JPS5811931B2 (ja) | 1983-03-05 |
| IT1106884B (it) | 1985-11-18 |
| FR2400497B1 (es) | 1983-09-16 |
| BE869767A (fr) | 1979-02-16 |
| ATA581578A (de) | 1979-10-15 |
| PL118118B1 (en) | 1981-09-30 |
| AT356640B (de) | 1980-05-12 |
| AU518880B2 (en) | 1981-10-22 |
| BR7805273A (pt) | 1979-04-10 |
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| ES465674A1 (es) | Procedimiento mejorado para la preparacion ed hidrocarburos alcohilaromaticos. | |
| FR2272063B1 (es) | ||
| JPS56128723A (en) | Olefin manufacture | |
| FR2272064B1 (es) | ||
| ES449193A1 (es) | Un procedimiento mejorado para la reaccion de un gas de sin-tesis que contiene monoxido de carbono e hidrogeno. | |
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| MY139272A (en) | Process for producing aldehyde | |
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| FR2434793A1 (fr) | Procede de synthese d'hydrocarbures | |
| ES319466A1 (es) | Un procedimiento de hidrogenacion catalitica para preparar ciclohexano a partir de benceno. | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970612 |