ES8104978A1 - Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent - Google Patents

Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent

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Publication number
ES8104978A1
ES8104978A1 ES492882A ES492882A ES8104978A1 ES 8104978 A1 ES8104978 A1 ES 8104978A1 ES 492882 A ES492882 A ES 492882A ES 492882 A ES492882 A ES 492882A ES 8104978 A1 ES8104978 A1 ES 8104978A1
Authority
ES
Spain
Prior art keywords
carbon atom
methane
producing
synthesis gas
oxygenated compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES492882A
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English (en)
Other versions
ES492882A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES492882A0 publication Critical patent/ES492882A0/es
Publication of ES8104978A1 publication Critical patent/ES8104978A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

METODO PARA OBTENER HIDROCARBUROS OXIGENADOS DE DOS ATOMOS DE CARBONO A PARTIR DE UN GAS DE SINTESIS QUE CONTIENE MONOXIDO DE CARBONO E HIDROGENO, EN PRESENCIA DE UN CATALIZADOR DE HIDROGENACION. CONSISTE EN PONER EN CONTACTO CONTINUO DICHO GAS DE SINTESIS CON UN CATALIZADOR HETEROGENEO QUE COMPRENDE RODIO EN COMBINACION CON UNO O MAS METALES ALCALINOS ELEGIDOS ENTRE LITIO, POTASIO, CESIO Y RUBIDIO, BAJO CONDICIONES DE REACCION ADECUADAS PARA PRODUCIR SELECTIVAMENTE ACIDO ACETICO, ETANOL Y ACETALDEHIDO, EN CANTIDADES SUPERIORES AL 50 POR 100 EN PESO DE LOS COMPONENTES DE DOS O MAS ATOMOS DE CARBONO PRODUCIDOS POR LA REACCION. AL CATALIZADOR SE LE PUEDE AÑADIR MANGANESO PARA AUMENTAR LA VELOCIDAD DEL PROCESO. LA REACCION TIENE LUGAR A UNA TEMPERATURA COMPRENDIDA ENTRE 150 Y 450G Y A UNA PRESION DEL ORDEN DE 1,05 A 700 KG./CM. CUADRADOS. LA RELACION MOLAR DE HIDROGENO A MONOXIDO DE CARBONO VARIA DE 20:1 A 1:200.
ES492882A 1979-06-28 1980-06-27 Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent Expired ES8104978A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/052,841 US4235798A (en) 1979-06-28 1979-06-28 Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane

Publications (2)

Publication Number Publication Date
ES492882A0 ES492882A0 (es) 1981-06-01
ES8104978A1 true ES8104978A1 (es) 1981-06-01

Family

ID=21980246

Family Applications (1)

Application Number Title Priority Date Filing Date
ES492882A Expired ES8104978A1 (es) 1979-06-28 1980-06-27 Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent

Country Status (7)

Country Link
US (1) US4235798A (es)
EP (1) EP0021444A1 (es)
JP (1) JPS568334A (es)
AU (1) AU534960B2 (es)
CA (1) CA1146593A (es)
ES (1) ES8104978A1 (es)
NO (1) NO801917L (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4471075A (en) * 1979-06-28 1984-09-11 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4446251A (en) * 1980-02-15 1984-05-01 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
ZA814981B (en) * 1980-08-01 1983-02-23 British Petroleum Co Process for the production of c1 to c4 oxygenated hydrocarbons by the catalytic conversion of synthesis gas
US4348487A (en) * 1981-11-02 1982-09-07 Exxon Research And Engineering Co. Production of methanol via catalytic coal gasification
US4377643A (en) * 1981-12-21 1983-03-22 The Standard Oil Company Upgrading synthesis gas
US4478955A (en) * 1981-12-21 1984-10-23 The Standard Oil Company Upgrading synthesis gas
US4476247A (en) * 1981-12-21 1984-10-09 The Standard Oil Company Synthesis gas catalyst
CA1195678A (en) * 1981-12-21 1985-10-22 Frederick A. Pesa Upgrading synthesis gas
US4654321A (en) * 1981-12-21 1987-03-31 The Standard Oil Company Upgrading synthesis gas catalyst
DE3214584C2 (de) * 1982-04-20 1984-05-03 Standard Elektrik Lorenz Ag, 7000 Stuttgart Elektrooptische Vorrichtung
US4590314A (en) 1983-12-30 1986-05-20 Union Carbide Corporation Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins
US4790963A (en) * 1984-08-20 1988-12-13 The Standard Oil Company Process for synthesis of esters from gaseous reactants containing organic hydroxy compounds and mixtures of hydrogen and carbon monoxide
JPS62184547U (es) * 1986-05-14 1987-11-24
WO1994001461A1 (en) * 1992-07-13 1994-01-20 Corvas International, Inc. BOVINE PANCREATIC TRYPSIN INHIBITOR DERIVED INHIBITORS OF FACTOR Xa
AUPO902797A0 (en) * 1997-09-05 1997-10-02 Cortronix Pty Ltd A rotary blood pump with hydrodynamically suspended impeller
US7232918B2 (en) * 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
US7504525B2 (en) * 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
BR9913599A (pt) * 1998-09-14 2001-05-22 Shell Int Research Processos para preparação de um catalisador e para epoxidação catalìtica de um alqueno com um gás contendo oxigênio
CA2343836C (en) * 1998-09-14 2007-12-04 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst carrier, preparation and use thereof
US7232786B2 (en) * 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
JP3632071B2 (ja) 2000-07-04 2005-03-23 国立大学法人東北大学 硫化物触媒を用いた一酸化炭素の水素化法
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
MX2007003418A (es) * 2004-09-24 2007-05-07 Shell Int Research Proceso para seleccionar particulas moldeadas, proceso para instalar un sistema, proceso para hacer reaccionar una alimentacion gaseosa de este sistema, producto de programa de computo y sistema de computo.
CA2669585A1 (en) 2006-11-20 2008-05-29 Shell Internationale Research Maatschappij B.V. A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
WO2013031598A1 (ja) 2011-08-31 2013-03-07 積水化学工業株式会社 酸素化物合成用の触媒及びその製造方法、酸素化物の製造装置ならびに酸素化物の製造方法
US9272971B2 (en) 2012-02-28 2016-03-01 Sekisui Chemical Co., Ltd. Catalyst for C2 oxygenate synthesis, device for manufacturing C2 oxygenate, and method for manufacturing C2 oxygenate
US9333491B2 (en) 2012-03-07 2016-05-10 Sekisui Chemical Co., Ltd. Catalyst for oxygenate synthesis, oxygenate production apparatus, and method of producing oxygenate
ES2546118B1 (es) 2013-01-24 2016-08-09 Abengoa Bioenergía Nuevas Tecnologías, S.A Catalizador de rodio promovido para la conversión selectiva de gas de síntesis en etanol

Family Cites Families (8)

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GB712686A (en) * 1950-06-26 1954-07-28 Ruhrchemie Ag Process for the catalytic hydrogenation of carbon monoxide
GB1501892A (en) 1974-01-28 1978-02-22 Union Carbide Corp Process for producing acetic acid ethanol and acetaldehyde from synthesis gas
US3952039A (en) * 1974-07-12 1976-04-20 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4014913A (en) * 1975-06-26 1977-03-29 Union Carbide Corporation Process for producing oxygenated two carbon compounds
US4116994A (en) * 1976-04-05 1978-09-26 Exxon Research & Engineering Co. Hydrocarbon synthesis from CO and H2 using Rh supported on titanium oxides
US4154751A (en) * 1978-03-01 1979-05-15 Exxon Research & Engineering Co. Preparation and use of supported potassium (or rubidium)-Group VIII-metal cluster catalysts in CO/H2 Fischer-Tropsch synthesis reactions
DE2825598A1 (de) * 1978-06-10 1979-12-20 Hoechst Ag Verfahren zur herstellung sauerstoffhaltiger kohlenstoffverbindungen aus synthesegas
US4224236A (en) * 1978-04-04 1980-09-23 Hoechst Aktiengesellschaft Process for the manufacture of oxygen-containing carbon compounds from synthesis gas

Also Published As

Publication number Publication date
JPS6136731B2 (es) 1986-08-20
US4235798A (en) 1980-11-25
AU5972680A (en) 1981-01-08
ES492882A0 (es) 1981-06-01
CA1146593A (en) 1983-05-17
EP0021444A1 (en) 1981-01-07
NO801917L (no) 1980-12-29
JPS568334A (en) 1981-01-28
AU534960B2 (en) 1984-02-23

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