GB1501892A - Process for producing acetic acid ethanol and acetaldehyde from synthesis gas - Google Patents

Process for producing acetic acid ethanol and acetaldehyde from synthesis gas

Info

Publication number
GB1501892A
GB1501892A GB337075A GB337075A GB1501892A GB 1501892 A GB1501892 A GB 1501892A GB 337075 A GB337075 A GB 337075A GB 337075 A GB337075 A GB 337075A GB 1501892 A GB1501892 A GB 1501892A
Authority
GB
United Kingdom
Prior art keywords
acetaldehyde
acetic acid
synthesis gas
jan
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB337075A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1501892A publication Critical patent/GB1501892A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols

Abstract

1501892 Acetic acid, ethanol and acetaldehyde from synthesis gas UNION CARBIDE CORP 27 Jan 1975 [28 Jan 1974 16 Jan 1975] 3370/75 Heading C2C A synthesis gas containing carbon monoxide and hydrogen is continuously contacted with a heterogeneous catalyst comprising rhodium metal at reaction conditions of temperature, pressure, gas composition and space velocity correlated to produce acetic acid, ethanol and/or acetaldehyde in an amount which is at least 50 weight per cent of the two or more carbon atom compounds produced by the reaction, wherein the specified two-carbon atom oxygenated compounds are at least 10 per cent of the reacted carbon atoms. Other products obtained include methane, methanol and minor amounts of other alcohols, aldehydes and esters. In some comparison tests it was observed that Pt or Pd on silica gave methanol.
GB337075A 1974-01-28 1975-01-27 Process for producing acetic acid ethanol and acetaldehyde from synthesis gas Expired GB1501892A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43714174A 1974-01-28 1974-01-28
US54166175A 1975-01-16 1975-01-16

Publications (1)

Publication Number Publication Date
GB1501892A true GB1501892A (en) 1978-02-22

Family

ID=27031196

Family Applications (1)

Application Number Title Priority Date Filing Date
GB337075A Expired GB1501892A (en) 1974-01-28 1975-01-27 Process for producing acetic acid ethanol and acetaldehyde from synthesis gas

Country Status (7)

Country Link
CA (1) CA1060467A (en)
DE (1) DE2503233C3 (en)
FR (1) FR2259077B1 (en)
GB (1) GB1501892A (en)
IT (1) IT1031173B (en)
NL (1) NL7500916A (en)
SE (1) SE428682B (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4235798A (en) 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4268689A (en) * 1978-12-11 1981-05-19 Texaco Development Corp. Manufacture of vicinal glycol esters from synthesis gas
US4312955A (en) 1980-12-01 1982-01-26 Union Carbide Corporation Process for the production of methanol from synthesis gas
US4444909A (en) * 1980-04-07 1984-04-24 Mobil Oil Corporation Synthesis gas conversion to oxygenates
US4446251A (en) * 1980-02-15 1984-05-01 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4471075A (en) * 1979-06-28 1984-09-11 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
EP0526974A1 (en) * 1991-06-21 1993-02-10 Tokyo Gas Co., Ltd. Process for the preparation of acetic acid
US5510523A (en) * 1991-06-21 1996-04-23 Tokyo Gas Company, Limited Process for the preparation of acetic acid
CN115636739A (en) * 2022-09-27 2023-01-24 厦门大学 Method for preparing acetone by synthesis gas one-step method

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014913A (en) * 1975-06-26 1977-03-29 Union Carbide Corporation Process for producing oxygenated two carbon compounds
US4101450A (en) * 1977-05-09 1978-07-18 Celanese Corporation Catalyst for production of acetic acid
CA1146592A (en) * 1979-06-28 1983-05-17 Thomas P. Wilson Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
ZA814981B (en) * 1980-08-01 1983-02-23 British Petroleum Co Process for the production of c1 to c4 oxygenated hydrocarbons by the catalytic conversion of synthesis gas
DE102007055024A1 (en) 2007-11-15 2009-05-20 Rolf-Dieter Riesbeck Fire protection device for e.g. cultivated building area, has pipe system with pipes that are force-fitly connected with each other and arranged at intended location, where outlet devices are designed as groove shaped openings

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4268689A (en) * 1978-12-11 1981-05-19 Texaco Development Corp. Manufacture of vicinal glycol esters from synthesis gas
US4471075A (en) * 1979-06-28 1984-09-11 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4235798A (en) 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4446251A (en) * 1980-02-15 1984-05-01 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4444909A (en) * 1980-04-07 1984-04-24 Mobil Oil Corporation Synthesis gas conversion to oxygenates
US4312955A (en) 1980-12-01 1982-01-26 Union Carbide Corporation Process for the production of methanol from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
EP0526974A1 (en) * 1991-06-21 1993-02-10 Tokyo Gas Co., Ltd. Process for the preparation of acetic acid
US5510523A (en) * 1991-06-21 1996-04-23 Tokyo Gas Company, Limited Process for the preparation of acetic acid
US5663429A (en) * 1991-06-21 1997-09-02 Tokyo Gas Company, Ltd. Process for the preparation of acetic acid
CN115636739A (en) * 2022-09-27 2023-01-24 厦门大学 Method for preparing acetone by synthesis gas one-step method

Also Published As

Publication number Publication date
SE7500857L (en) 1975-07-29
CA1060467A (en) 1979-08-14
SE428682B (en) 1983-07-18
DE2503233B2 (en) 1977-07-28
FR2259077B1 (en) 1978-07-13
IT1031173B (en) 1979-04-30
NL7500916A (en) 1975-07-30
DE2503233A1 (en) 1975-07-31
DE2503233C3 (en) 1978-03-16
FR2259077A1 (en) 1975-08-22

Similar Documents

Publication Publication Date Title
GB1501892A (en) Process for producing acetic acid ethanol and acetaldehyde from synthesis gas
Takahashi et al. The mechanism of steam reforming of methanol over a copper-silica catalyst
ES8104978A1 (en) Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane.
US4133966A (en) Selective formation of ethanol from methanol, hydrogen and carbon monoxide
US4581473A (en) Preparation of ethylidene diacetate
CA1084709A (en) Process for the production of synthesis gas by the catalysed decomposition of methanol
US4151208A (en) Process for the selective preparation of acetaldehyde from methanol and synthesis gas
HUP9900184A2 (en) Process for producing oxygenated products and reaction products made by these processes
Frolich et al. Catalysts for the formation of alcohols from carbon monoxide and hydrogen
GB1477392A (en) Process for making ethylene glycol
ES449193A1 (en) Process for producing oxygenated two carbon compounds
US2729650A (en) Production of dialdehydes and derivatives thereof
US4171461A (en) Synthesis of ethanol by homologation of methanol
US4119656A (en) Preparation of hydroxylated compounds from synthesis of gas with palladium catalysts
US4210597A (en) Preparation of oxygenates from carbon monoxide and hydrogen
US4632774A (en) Process for reforming alcohols
US4239705A (en) Process for producing acetaldehyde
Jemier et al. Formaldehyde and formates as sources of synthesis gas via ruthenium-catalyzed decomposition reactions
US4239925A (en) Ethanol from methanol
GB1306863A (en) Production of acetic acid
GB1185332A (en) Rhodium Recovery.
US4246186A (en) Process for producing acetic acid, ethanol, and acetaldehyde from synthesis gas
EP0037586A1 (en) Process for the selective hydroformylation of methanol to acetaldehyde
ES8104979A1 (en) Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane.
US4370507A (en) Ethanol from methanol and synthesis gas

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee