GB1243190A - Oxo catalyst - Google Patents

Oxo catalyst

Info

Publication number
GB1243190A
GB1243190A GB38579/70A GB3857970A GB1243190A GB 1243190 A GB1243190 A GB 1243190A GB 38579/70 A GB38579/70 A GB 38579/70A GB 3857970 A GB3857970 A GB 3857970A GB 1243190 A GB1243190 A GB 1243190A
Authority
GB
United Kingdom
Prior art keywords
reaction
ligand
schiff
bases
neutral
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38579/70A
Inventor
Malcolm John Lawrenson
Gordon Foster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Priority to GB38579/70A priority Critical patent/GB1243190A/en
Publication of GB1243190A publication Critical patent/GB1243190A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Abstract

1,243,190. Complexes of rhodium, osmium or iridium. BRITISH PETROLEUM CO. Ltd. 20 Nov., 1968 [5 Dec., 1967], No. 38579/70. Divided out of 1,243,189. Heading C2C. Novel oxo process catalysts comprise complexes of Rh, Os or Ir containing at least one neutral complexing ligand, other than a triphenylphosphine, triphenylstibine or triphneylarsine ligand, containing a Group VB or VIB element having a single pair of electrons available for donation and a bidentate ligand coordinating through at least one oxygen atom. Specified neutral ligands include amines, NH 3 , NH 2 OH, ethers, phosphines, arsines, stibines, mercaptans, sulphoxides, phosphites, arsenites, stibinites, pyridines and phenanthroline. Specified bidentate ligands are keto-enolates and naono-Schiff's bases of ketoenolates, specifically acetylacetone, dibenzoylmethane, benzoylacetone, trifluoroacetylacetone, hexafluoroacetylacetone, dipivaloylmethane, 2-acetylcyclohexanone, 3 - ethylacetylacetone, 3 - propenylacetylacetone, 3 - isobutylacetylacetone, diisobutyrylmethane, 3 - allyl - 2,4 - pentanedione, benzoyltrifluoroacetone, 4 - methyliminopentanone - 2, 4 - p - tolyliminopentanone - 2, 4 - iminopentanone - 2, 4 - n - propyliminopentanone-2. Preparative methods used are the reaction of the neutral ligands with Rh(CO) a (diketonate) and the reaction of #-diketones or Schiff's bases thereof with rhodium carbonyl propionate dimer followed by reaction with a phosphine.
GB38579/70A 1967-12-05 1967-12-05 Oxo catalyst Expired GB1243190A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB38579/70A GB1243190A (en) 1967-12-05 1967-12-05 Oxo catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB38579/70A GB1243190A (en) 1967-12-05 1967-12-05 Oxo catalyst

Publications (1)

Publication Number Publication Date
GB1243190A true GB1243190A (en) 1971-08-18

Family

ID=10404394

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38579/70A Expired GB1243190A (en) 1967-12-05 1967-12-05 Oxo catalyst

Country Status (1)

Country Link
GB (1) GB1243190A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4496768A (en) * 1982-06-11 1985-01-29 Davy Mckee Limited Process for the production of aldehydes by hydroformylation of alpha-olefins
US4496769A (en) * 1982-06-11 1985-01-29 Davy Mckee (London) Limited Process for the preparation of aldehydes by hydroformylation of olefins
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US5756751A (en) * 1996-05-15 1998-05-26 Bayer Aktiengesellschaft Compounds containing alkoxysilane groups and hydantoin groups
US5908948A (en) * 1997-03-11 1999-06-01 Bayer Corporation Compounds containing urea and alkoxysilane groups
CN104169290A (en) * 2012-04-25 2014-11-26 优美科股份公司及两合公司 Process for preparing diketonato-rhodium(i)-carbonyl complexes

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4496768A (en) * 1982-06-11 1985-01-29 Davy Mckee Limited Process for the production of aldehydes by hydroformylation of alpha-olefins
US4496769A (en) * 1982-06-11 1985-01-29 Davy Mckee (London) Limited Process for the preparation of aldehydes by hydroformylation of olefins
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US5756751A (en) * 1996-05-15 1998-05-26 Bayer Aktiengesellschaft Compounds containing alkoxysilane groups and hydantoin groups
US5908948A (en) * 1997-03-11 1999-06-01 Bayer Corporation Compounds containing urea and alkoxysilane groups
CN104169290A (en) * 2012-04-25 2014-11-26 优美科股份公司及两合公司 Process for preparing diketonato-rhodium(i)-carbonyl complexes
US20150141685A1 (en) * 2012-04-25 2015-05-21 Umicore Ag & Co. Kg Process for preparing diketonato-rhodium(i)-carbonyl complexes
US9163045B2 (en) 2012-04-25 2015-10-20 Umicore Ag & Co. Kg Process for preparing diketonato-rhodium(I)-carbonyl complexes
CN104169290B (en) * 2012-04-25 2017-05-31 优美科股份公司及两合公司 Method for preparing diketone acidic group rhodium (I) carbonyl complex

Similar Documents

Publication Publication Date Title
HUT41724A (en) Process for the hydroformylation of olefins, catalyzed with complexes of transition metals
Levason et al. Coordination chemistry of organostibines
ES468343A1 (en) Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands
GB1391395A (en) Selective hydroformylation process using homogeneous catalysts
GB1243190A (en) Oxo catalyst
ES386876A1 (en) Catalytic reactions
ES434027A1 (en) Process for recovering catalyst systems from raw hydroformylation products
GB1138601A (en) Improvements in catalytic reactions
GB1254222A (en) Oxo process
Masters et al. Transfer hydrogenation in the presence of a homogeneous rhodium catalyst
GB1249303A (en) Preparation of rhodium complexes
GB1238703A (en)
GB1330644A (en) Process for the separation of metal ions or compounds
GB1233776A (en)
GB1260120A (en) Process for the preparation of transition metal complexes
GB1296435A (en)
GB1284615A (en) Hydroformylation process
GB1182932A (en) Transition Metal Complexes
Oro et al. Hydrogenation—Homogeneous
GB1377569A (en) Organometallic complexes and production of the same
GB1368434A (en) Hydroformylation of propylene
GB1207561A (en) Oxo process
Stanghellini et al. Chalcogen derivatives of iron carbonyls. III. Effect of the solvents in CO isotopic exchange reaction on Fe3 (CO) 9Te2
McAuliffe et al. The coordination of nickel (II) salts to a simple olefin in a quadridentate chelate
GB1224740A (en) Oxo process