ES2260283T3 - Masas de moldeo teñidas de poli(oximetileno) y piezas moldeadas producidas a partir de ellas. - Google Patents
Masas de moldeo teñidas de poli(oximetileno) y piezas moldeadas producidas a partir de ellas.Info
- Publication number
- ES2260283T3 ES2260283T3 ES01969726T ES01969726T ES2260283T3 ES 2260283 T3 ES2260283 T3 ES 2260283T3 ES 01969726 T ES01969726 T ES 01969726T ES 01969726 T ES01969726 T ES 01969726T ES 2260283 T3 ES2260283 T3 ES 2260283T3
- Authority
- ES
- Spain
- Prior art keywords
- component
- weight
- oxymethylene
- poly
- molding mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000465 moulding Methods 0.000 title claims abstract description 88
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 71
- 229920006324 polyoxymethylene Polymers 0.000 claims abstract description 118
- -1 polyoxymethylene Polymers 0.000 claims abstract description 81
- 239000000203 mixture Substances 0.000 claims abstract description 68
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 33
- 239000000194 fatty acid Substances 0.000 claims abstract description 33
- 229930195729 fatty acid Natural products 0.000 claims abstract description 33
- 150000002148 esters Chemical class 0.000 claims abstract description 32
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 32
- 150000003839 salts Chemical class 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 20
- 239000003381 stabilizer Substances 0.000 claims abstract description 20
- 239000003086 colorant Substances 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 27
- 229920000877 Melamine resin Polymers 0.000 claims description 25
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 claims description 11
- 230000007547 defect Effects 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 150000001298 alcohols Chemical class 0.000 claims description 10
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 claims description 10
- 125000004429 atom Chemical group 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 229930182556 Polyacetal Natural products 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 claims description 5
- 229960000458 allantoin Drugs 0.000 claims description 5
- 150000008366 benzophenones Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 230000006641 stabilisation Effects 0.000 claims description 5
- 238000011105 stabilization Methods 0.000 claims description 5
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 150000005690 diesters Chemical class 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 4
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 4
- ICSNLGPSRYBMBD-UHFFFAOYSA-N 2-aminopyridine Chemical compound NC1=CC=CC=N1 ICSNLGPSRYBMBD-UHFFFAOYSA-N 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 150000003927 aminopyridines Chemical class 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 claims description 2
- KMWIPXLIKIAZMT-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanehydrazide Chemical compound CC(C)(C)C1=CC(CCC(=O)NN)=CC(C(C)(C)C)=C1O KMWIPXLIKIAZMT-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 150000004056 anthraquinones Chemical class 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 claims description 2
- 229940091173 hydantoin Drugs 0.000 claims description 2
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 claims description 2
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013799 ultramarine blue Nutrition 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 2
- 150000001565 benzotriazoles Chemical class 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 239000011575 calcium Substances 0.000 claims 2
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 claims 1
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 claims 1
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims 1
- 229920006231 aramid fiber Polymers 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 claims 1
- 229940116224 behenate Drugs 0.000 claims 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims 1
- PPYIVKOTTQCYIV-UHFFFAOYSA-L beryllium;selenate Chemical compound [Be+2].[O-][Se]([O-])(=O)=O PPYIVKOTTQCYIV-UHFFFAOYSA-L 0.000 claims 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 claims 1
- 150000002391 heterocyclic compounds Chemical class 0.000 claims 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 claims 1
- 229940070765 laurate Drugs 0.000 claims 1
- 239000002667 nucleating agent Substances 0.000 claims 1
- UTOPWMOLSKOLTQ-UHFFFAOYSA-M octacosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O UTOPWMOLSKOLTQ-UHFFFAOYSA-M 0.000 claims 1
- 229940049964 oleate Drugs 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 150000004671 saturated fatty acids Chemical class 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 229940114926 stearate Drugs 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract description 2
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 26
- 238000001907 polarising light microscopy Methods 0.000 description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 20
- 229920005601 base polymer Polymers 0.000 description 17
- 239000008187 granular material Substances 0.000 description 16
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 235000019359 magnesium stearate Nutrition 0.000 description 13
- 238000001746 injection moulding Methods 0.000 description 10
- 239000001354 calcium citrate Substances 0.000 description 8
- 235000013337 tricalcium citrate Nutrition 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
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- 238000010521 absorption reaction Methods 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
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- 125000005704 oxymethylene group Chemical group [H]C([H])([*:2])O[*:1] 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical class [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
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- HCITUYXHCZGFEO-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.N=C1NC(=N)NC(=N)N1 HCITUYXHCZGFEO-UHFFFAOYSA-N 0.000 description 1
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- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
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- VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 1
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- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
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- 238000011835 investigation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
- C08L59/04—Copolyoxymethylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
- C08L59/02—Polyacetals containing polyoxymethylene sequences only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10047488 | 2000-09-26 | ||
| DE10047488A DE10047488B4 (de) | 2000-09-26 | 2000-09-26 | Eingefärbte Polyoxymethylen-Formmassen und daraus hergestellte Formteile |
| DE10126787 | 2001-06-01 | ||
| DE2001126787 DE10126787A1 (de) | 2001-06-01 | 2001-06-01 | Schlagzähe Polyoxymethylen-Formmassen mit geringer Emission, ihre Verwendung und daraus hergestellter Formkörper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2260283T3 true ES2260283T3 (es) | 2006-11-01 |
Family
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| ES01972066T Expired - Lifetime ES2278783T3 (es) | 2000-09-26 | 2001-09-17 | Masas de moldeo de poli(oximetileno) resistentes al impacto con pequeña emision, su utilizacion y cuerpos moldeados producidos a partir de ellas. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
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| ES01972066T Expired - Lifetime ES2278783T3 (es) | 2000-09-26 | 2001-09-17 | Masas de moldeo de poli(oximetileno) resistentes al impacto con pequeña emision, su utilizacion y cuerpos moldeados producidos a partir de ellas. |
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| EP (2) | EP1325078B1 (enExample) |
| JP (4) | JP2004522810A (enExample) |
| AT (2) | ATE348860T1 (enExample) |
| AU (2) | AU2001291868A1 (enExample) |
| DE (2) | DE50109172D1 (enExample) |
| ES (2) | ES2260283T3 (enExample) |
| WO (2) | WO2002026884A1 (enExample) |
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| DE19936715A1 (de) * | 1999-08-06 | 2001-02-15 | Ticona Gmbh | Emissionsarme eingefärbte Polyoxymethylen-Formmassen |
| DE10047614C2 (de) | 2000-09-26 | 2003-03-27 | Generis Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
| ES2260283T3 (es) * | 2000-09-26 | 2006-11-01 | Ticona Gmbh | Masas de moldeo teñidas de poli(oximetileno) y piezas moldeadas producidas a partir de ellas. |
| DE10238518A1 (de) * | 2002-08-21 | 2004-03-04 | Ticona Gmbh | Verschleißfeste Polyoxymethylen Formmassen und deren Verwendung |
| KR101121398B1 (ko) * | 2003-10-01 | 2012-03-14 | 폴리플라스틱스 가부시키가이샤 | 폴리아세탈 수지 조성물 |
| US20050080185A1 (en) * | 2003-10-10 | 2005-04-14 | Mhetar Vijay R. | Poly(arylene ether) composition and method of making |
| US7816433B2 (en) * | 2003-10-24 | 2010-10-19 | Asahi Kasei Chemicals Corporation | Polyacetal resin composition and article thereof |
| JP4516301B2 (ja) * | 2003-11-10 | 2010-08-04 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| KR100523361B1 (ko) * | 2003-12-22 | 2005-10-24 | 한국엔지니어링플라스틱 주식회사 | 내연료성이 우수한 폴리옥시메틸렌 조성물과 이의 성형품 |
| JP5008256B2 (ja) * | 2004-04-23 | 2012-08-22 | 東レ株式会社 | ポリオキシメチレン樹脂組成物の製造方法 |
| JP4815144B2 (ja) * | 2005-04-01 | 2011-11-16 | ジャパンコンポジット株式会社 | ラジカル硬化性樹脂組成物 |
| US7645821B2 (en) | 2005-07-28 | 2010-01-12 | Ticona Gmbh | Low-emission, tribologically modified polyoxymethylene molding compositions and moldings produced therefrom |
| DE102005035334A1 (de) * | 2005-07-28 | 2007-02-01 | Ticona Gmbh | Emissionsarme, tribologisch modifizierte Polyoxymethylen-Formmassen und daraus hergestellte Formteile |
| JP5325792B2 (ja) * | 2006-11-22 | 2013-10-23 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 静電気拡散性ポリアセタール組成物 |
| DE102007001578B4 (de) * | 2007-01-10 | 2018-10-11 | Diehl Aviation Laupheim Gmbh | Hinterleuchtbares Flugzeuginterieurbauteil |
| JP4876024B2 (ja) * | 2007-05-09 | 2012-02-15 | 旭化成ケミカルズ株式会社 | ボタン |
| JP5301794B2 (ja) * | 2007-05-23 | 2013-09-25 | 旭化成ケミカルズ株式会社 | ポリオキシメチレン樹脂組成物およびその成形体 |
| WO2009012003A1 (en) * | 2007-07-19 | 2009-01-22 | Ticona Llc | Stabilized thermoplastic copolyesters |
| US20090048388A1 (en) * | 2007-08-16 | 2009-02-19 | Elia Andri E | Wear resistant toughened and reinforced polyacetal compositions |
| JP5297640B2 (ja) * | 2007-11-29 | 2013-09-25 | ポリプラスチックス株式会社 | 耐酸性に優れたポリアセタール樹脂成形品 |
| JP5320222B2 (ja) | 2008-09-03 | 2013-10-23 | 三菱エンジニアリングプラスチックス株式会社 | ポリアセタール樹脂組成物、樹脂成形品、ポリアセタール樹脂原料組成物の改質方法及び改質剤 |
| EP2177155A1 (de) * | 2008-10-20 | 2010-04-21 | F. Hoffmann-Roche AG | Analytisches Testbandinstrument mit Gleichstrommotor und Getriebe |
| US8110632B2 (en) * | 2009-01-15 | 2012-02-07 | Sabic Innovative Plastics Ip B.V. | Poly(arylene ether) articles and compositions |
| ATE551389T1 (de) * | 2009-08-07 | 2012-04-15 | Ticona Llc | Polyacetalzusammensetzung mit geringer formaldeyd-emission |
| US9090769B2 (en) | 2011-04-05 | 2015-07-28 | Ticona Llc | Molded articles having a swirl-like or marble-like appearance and compositions for producing same |
| US9296874B2 (en) * | 2011-04-28 | 2016-03-29 | Ticona Llc | Polyacetal compositions and molded products made therefrom |
| BR112014007774B1 (pt) | 2011-09-29 | 2020-08-11 | Ticona Llc | Produto moldado, composição polimérica e processo para a produção de produtos moldados |
| EP2796505B1 (en) * | 2011-12-21 | 2017-08-23 | Mitsubishi Gas Chemical Company, Inc. | Resin composition and shaped article |
| US20140179840A1 (en) * | 2012-12-26 | 2014-06-26 | Ticona Llc | Low Emission, UV Stabilized High Strength Acetal Copolymer |
| US20140179841A1 (en) * | 2012-12-26 | 2014-06-26 | Ticona Llc | Stabilized Polymer Composition Containing an Impact Modifier |
| JP6700178B2 (ja) * | 2013-10-21 | 2020-05-27 | ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 本質的に低摩擦のポリオキシメチレン |
| JP2015101599A (ja) | 2013-11-21 | 2015-06-04 | ポリプラスチックス株式会社 | ポリオキシメチレン樹脂組成物の製造方法 |
| TWI488911B (zh) * | 2014-04-18 | 2015-06-21 | Fdc Lees Chemical Industry Co | 用於聚甲醛之無三聚氰胺複合式添加劑 |
| CN106795359A (zh) | 2014-09-05 | 2017-05-31 | Sabic环球技术有限责任公司 | 聚甲醛组合物、 用于制造的方法和由其制备的制品 |
| EP3263645B1 (en) * | 2015-02-25 | 2023-10-11 | Mitsubishi Chemical Corporation | Resin composition and article molded therefrom |
| JP6853020B2 (ja) * | 2015-12-11 | 2021-03-31 | 旭化成株式会社 | ポリアセタール樹脂用顆粒状組成物、及びポリアセタール樹脂組成物 |
| WO2017156053A1 (en) * | 2016-03-08 | 2017-09-14 | Ticona Llc | Orthopedic device and polymer compositions for making same |
| CN108699321B (zh) * | 2016-04-13 | 2020-11-24 | 株式会社钟化 | 强韧化环氧树脂组合物 |
| EP3526289A1 (en) | 2016-10-11 | 2019-08-21 | Celanese Sales Germany GmbH | Wear resistant polymer composition having improved surface appearance |
| US11485856B2 (en) | 2017-05-05 | 2022-11-01 | Ticona Llc | Polyoxymethylene polymer composition that is chemical resistant |
| KR102474348B1 (ko) | 2017-11-30 | 2022-12-05 | 현대자동차 주식회사 | 폴리 옥시 메틸렌 수지 조성물 및 이로부터 제조된 성형품 |
| KR102792993B1 (ko) * | 2018-05-03 | 2025-04-07 | 셀라니즈 세일즈 저머니 게엠베하 | 의료 기술 응용 분야에서 사용하기 위한 매스-착색된 중합체 조성물 |
| WO2019236368A1 (en) * | 2018-06-04 | 2019-12-12 | Celanese International Corporation | Polyoxymethylene composition in food handling applications |
| JPWO2021002315A1 (enExample) * | 2019-07-03 | 2021-01-07 | ||
| WO2021002314A1 (ja) * | 2019-07-03 | 2021-01-07 | 三菱エンジニアリングプラスチックス株式会社 | 樹脂組成物および成形品 |
| JPWO2021002316A1 (enExample) * | 2019-07-03 | 2021-01-07 | ||
| JP7257293B2 (ja) * | 2019-08-30 | 2023-04-13 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物及びその製造方法 |
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| DE3151814A1 (de) | 1981-12-29 | 1983-07-07 | Hoechst Ag, 6230 Frankfurt | "fuellstoff enthaltende kunststoff-formmasse, verfahren zu ihrer herstellung sowie deren verwendung" |
| JPS5996157A (ja) * | 1982-11-25 | 1984-06-02 | Polyplastics Co | ポリアセタ−ル樹脂組成物 |
| DE3505524A1 (de) * | 1984-03-28 | 1985-10-10 | Hoechst Ag, 6230 Frankfurt | Schlagzaeh modifiziertes polyoxymethylen und daraus hergestellte formkoerper |
| US5183858A (en) * | 1989-03-31 | 1993-02-02 | Takeda Chemical Industries, Ltd. | Core-shell polymer, production and use thereof |
| JP2993062B2 (ja) | 1990-07-02 | 1999-12-20 | 三菱瓦斯化学株式会社 | オキシメチレン共重合体組成物 |
| JPH0692476B2 (ja) * | 1990-10-05 | 1994-11-16 | 旭化成工業株式会社 | 安定化ポリオキシメチレンの製造法 |
| JP3024802B2 (ja) * | 1991-02-04 | 2000-03-27 | ポリプラスチックス株式会社 | ポリアセタール樹脂着色組成物 |
| JP3088159B2 (ja) * | 1991-12-04 | 2000-09-18 | ポリプラスチックス株式会社 | ポリアセタール成形体 |
| JPH06136234A (ja) * | 1992-10-28 | 1994-05-17 | Polyplastics Co | ポリオキシメチレン組成物 |
| CA2116241A1 (en) * | 1992-06-30 | 1994-01-06 | Noriyuki Sugiyama | Polyoxymethylene composition |
| DE4229760A1 (de) * | 1992-09-05 | 1994-03-10 | Basf Ag | UV-stabilisierte Polyoxymethylenformmassen |
| DE4236465A1 (de) * | 1992-10-24 | 1994-04-28 | Degussa | Polyoxymethylen mit verbesserter Stabilität gegen Säuren, Verfahren zu seiner Herstellung sowie Verwendung |
| JP3140618B2 (ja) * | 1993-09-02 | 2001-03-05 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| JP3399483B2 (ja) * | 1993-12-21 | 2003-04-21 | 三菱瓦斯化学株式会社 | オキシメチレン共重合体樹脂組成物 |
| EP0668317A1 (en) * | 1994-02-15 | 1995-08-23 | Rohm And Haas Company | Impact modified polyacetal compositions |
| JPH07268180A (ja) * | 1994-03-30 | 1995-10-17 | Polyplastics Co | ポリオキシメチレン組成物 |
| JP3374874B2 (ja) * | 1994-06-07 | 2003-02-10 | 三菱瓦斯化学株式会社 | オキシメチレン共重合体樹脂組成物の製造方法 |
| MY114026A (en) | 1995-09-01 | 2002-07-31 | Asahi Chemical Ind | Polyacetal resin molded article and process for producing the same |
| JP3808101B2 (ja) * | 1995-09-29 | 2006-08-09 | 旭化成ケミカルズ株式会社 | ポリアセタール樹脂組成物 |
| JP3087911B2 (ja) * | 1996-11-13 | 2000-09-18 | 旭化成工業株式会社 | 樹脂組成物 |
| WO1998029510A1 (en) * | 1996-12-27 | 1998-07-09 | Polyplastics Co., Ltd. | Polyacetal resin composition and moldings |
| DE19803227B4 (de) | 1998-01-27 | 2007-06-21 | Ticona Gmbh | Farbmittelzubereitung zur Einfärbung von Polyoxymethylen-Formmassen |
| JP4167341B2 (ja) * | 1998-03-25 | 2008-10-15 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物およびその製造方法 |
| JP4418553B2 (ja) * | 1998-05-07 | 2010-02-17 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| DE19828797A1 (de) | 1998-06-27 | 1999-12-30 | Basf Ag | Stabilisierte Polyoxymethylen-Formmassen |
| US5962623A (en) * | 1998-09-08 | 1999-10-05 | Ticona Gmbh | Process for the preparation of polyacetal copolymers |
| ES2260283T3 (es) * | 2000-09-26 | 2006-11-01 | Ticona Gmbh | Masas de moldeo teñidas de poli(oximetileno) y piezas moldeadas producidas a partir de ellas. |
-
2001
- 2001-09-17 ES ES01969726T patent/ES2260283T3/es not_active Expired - Lifetime
- 2001-09-17 AU AU2001291868A patent/AU2001291868A1/en not_active Abandoned
- 2001-09-17 JP JP2002530654A patent/JP2004522810A/ja active Pending
- 2001-09-17 AT AT01972066T patent/ATE348860T1/de not_active IP Right Cessation
- 2001-09-17 ES ES01972066T patent/ES2278783T3/es not_active Expired - Lifetime
- 2001-09-17 AU AU2001289888A patent/AU2001289888A1/en not_active Abandoned
- 2001-09-17 WO PCT/EP2001/010710 patent/WO2002026884A1/de not_active Ceased
- 2001-09-17 WO PCT/EP2001/010711 patent/WO2002026885A1/de not_active Ceased
- 2001-09-17 DE DE50109172T patent/DE50109172D1/de not_active Expired - Lifetime
- 2001-09-17 DE DE50111709T patent/DE50111709D1/de not_active Expired - Lifetime
- 2001-09-17 EP EP01969726A patent/EP1325078B1/de not_active Expired - Lifetime
- 2001-09-17 EP EP01972066A patent/EP1339794B1/de not_active Expired - Lifetime
- 2001-09-17 US US10/381,501 patent/US20030162912A1/en not_active Abandoned
- 2001-09-17 AT AT01969726T patent/ATE319774T1/de not_active IP Right Cessation
- 2001-09-17 JP JP2002530653A patent/JP5362165B2/ja not_active Expired - Lifetime
-
2008
- 2008-05-22 US US12/125,603 patent/US8053499B2/en not_active Expired - Lifetime
-
2012
- 2012-08-10 JP JP2012178198A patent/JP2012237010A/ja active Pending
- 2012-08-10 JP JP2012178174A patent/JP5355763B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012237009A (ja) | 2012-12-06 |
| AU2001291868A1 (en) | 2002-04-08 |
| JP5355763B2 (ja) | 2013-11-27 |
| DE50109172D1 (de) | 2006-05-04 |
| EP1339794A1 (de) | 2003-09-03 |
| WO2002026884A1 (de) | 2002-04-04 |
| JP2012237010A (ja) | 2012-12-06 |
| EP1325078A1 (de) | 2003-07-09 |
| US20080287580A1 (en) | 2008-11-20 |
| JP2004522810A (ja) | 2004-07-29 |
| ATE348860T1 (de) | 2007-01-15 |
| WO2002026885A1 (de) | 2002-04-04 |
| US8053499B2 (en) | 2011-11-08 |
| DE50111709D1 (de) | 2007-02-01 |
| ATE319774T1 (de) | 2006-03-15 |
| US20030162912A1 (en) | 2003-08-28 |
| JP5362165B2 (ja) | 2013-12-11 |
| EP1325078B1 (de) | 2006-03-08 |
| JP2004510024A (ja) | 2004-04-02 |
| EP1339794B1 (de) | 2006-12-20 |
| ES2278783T3 (es) | 2007-08-16 |
| AU2001289888A1 (en) | 2002-04-08 |
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