EP2022877B1 - Thermobondierbare verbundfaser und herstellungsverfahren dafür - Google Patents

Thermobondierbare verbundfaser und herstellungsverfahren dafür Download PDF

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Publication number
EP2022877B1
EP2022877B1 EP20070743519 EP07743519A EP2022877B1 EP 2022877 B1 EP2022877 B1 EP 2022877B1 EP 20070743519 EP20070743519 EP 20070743519 EP 07743519 A EP07743519 A EP 07743519A EP 2022877 B1 EP2022877 B1 EP 2022877B1
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EP
European Patent Office
Prior art keywords
thermal
fiber
adhesive
resin component
bicomponent fiber
Prior art date
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Not-in-force
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EP20070743519
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English (en)
French (fr)
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EP2022877A1 (de
EP2022877A4 (de
Inventor
Hironori Goda
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Teijin Frontier Co Ltd
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Teijin Fibers Ltd
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Publication date
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Publication of EP2022877A1 publication Critical patent/EP2022877A1/de
Publication of EP2022877A4 publication Critical patent/EP2022877A4/de
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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/34—Core-skin structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y10T442/641—Sheath-core multicomponent strand or fiber material

Definitions

  • the present invention relates to a method for producing a self-extensible thermal-adhesive bicomponent fiber, which has a low modulus and is self-extensible in thermal adhesion and which has a soft feel when formed into a thermal-adhesive nonwoven fabric.
  • a thermal-adhesive bicomponent fiber such as typically a core/sheath thermal-adhesive bicomponent fiber that comprises a thermal-adhesive resin component as the sheath and a fiber-forming resin component as the core is used as a nonwoven fabric by forming a fiber web according to a carding method, an air-laid method or a wet sheet-making method and then melting the thermal-adhesive resin component through hot air drier treatment or hot roll treatment to thereby form fiber-fiber bonding to give a nonwoven fabric.
  • this does not use an adhesive comprising an organic solvent, and its advantage is that the amount of a harmful substance such as an organic solvent to be released from it is small.
  • it since its other advantages of high producibility and cost reduction are great, it has been widely used as fiber structures such as fiber cushions (hard cotton) and bed mats, and as nonwoven fabrics.
  • thermal-adhesive nonwoven fabric typically for sanitary materials such as paper diapers and sanitary napkins is required to have softness and drapability like a fabric and have a suitable, non-paperlike bulkiness, since the nonwoven fabric may be kept in direct contact with users' skin.
  • thermoly adhering a web obtained from thermal-adhesive fibers there is known a heat-roll method comprising thermally pressing and softening a part of the web by the use of an embossing roll and melt-sealing it.
  • the nonwoven fabric may be readily folded at the boundary between the heat-sealed region and the non-heat-sealed region, and the obtained nonwoven fabric may have excellent drapability.
  • the fibers in the heat-sealed region are pressed and flattened, the heat-sealed part may become hard and may lose the bulkiness of nonwoven fabric, and therefore the obtained nonwoven fabric may have a paperlike feel.
  • an air-through method that comprises applying a hot air jet to the whole of a web to thereby soften or melt the intersections of the fibers.
  • the applied hot air runs through the web while the bulkiness of the web is left as such in some degree, and therefore the obtained nonwoven fabric is bulky, not having a partly hardened region, and the touch of its surface is smooth.
  • the nonwoven fabric when the nonwoven fabric is folded, it may have irregular folds and may lose drapability.
  • Patent Reference 1 For solving the problems, a method is disclosed in Patent Reference 1. Specifically, according to a high-speed spinning method, the orientation index of a thermal-adhesive resin component is made to be at most 25 % and the orientation index of a fiber-forming resin component is made to be at least 40 %, thereby giving a thermal-adhesive bicomponent fiber having a strong adhering point strength, melt-fusible at a lower temperature and having a small degree of thermal shrinkage.
  • the disclosed technique comprises adhering a blended web of the thermal-adhesive bicomponent fibers and non-thermal-adhesive fibers according to an air-through method, thereby producing a nonwoven fabric having drapability and bulkiness and having a sufficient nonwoven fabric strength.
  • the process stability of the high-speed spinning method could not as yet be said sufficient, and the yield in the method is low.
  • the cost performance is not sufficient and that there may be still many difficult problems in commercial-base production of staple fibers according to the high-speed spinning method.
  • the number of the adhering intersections in the nonwoven fabric may increase, and therefore, a nonwoven fabric having a soft feel may be difficult to obtain and a nonwoven fabric having poor drapability may be obtained.
  • non-thermal-adhesive fibers are mixed to produce a nonwoven fabric, but in this case, since the number of the adhering intersections in the nonwoven fabric decreases, the nonwoven fabric strength may lower. Accordingly, the nonwoven fabric strength and the soft feel could not always be on a sufficient level.
  • thermal-adhesive bicomponent fiber in which the core component is a fiber-forming resin component and the core component is polyethylene terephthalate (hereinafter referred to as PET), is not disclosed in Patent Reference 1.
  • PET polyethylene terephthalate
  • the melting point of the core component in the fiber may be sufficiently higher than the melting point of the sheath component therein, as compared with a thermal-adhesive bicomponent fiber in which the core component is polypropylene (hereinafter referred to as PP), and therefore, the thermal-adhesive strength of the obtained nonwoven fabric may be further improved.
  • PP thermal-adhesive bicomponent fiber in which the core component is polypropylene
  • the bicomponent fiber in which the core component is PET is relatively highly rigid, it has a potential to give a nonwoven fabric having higher bulkiness.
  • the bicomponent fibers undrawn at a low draw ratio or the undrawn bicomponent fibers described in Patent Reference 1 are formed into nonwoven fabrics, the thermal shrinkage of the fabrics is still large since the orientation crystallinity of the core component of the bicomponent fibers used is insufficient.
  • Patent Reference 1 JP-A-2005-350836
  • the invention has been made under the background of the above-mentioned prior art techniques, and its object is to provide a method for producing a low-modulus, self-extensible thermal-adhesive bicomponent fiber comprising polyethylene terephthalate as the fiber-forming resin component thereof and capable of producing a nonwoven fabric or a fiber structure that has a high adhesive strength and is bulky and well drapable.
  • the present inventors have assiduously investigated for the purpose of solving the above-mentioned problems, and as a result, have invented a method for producing a low-modulus, self-extensible thermal-adhesive bicomponent fiber that comprises PET as the fiber-forming resin component thereof and satisfies high adhesive strength, sufficient bulkiness and drapability, using a crystalline thermoplastic resin having a lower melting point than PET by at least 20°C, as the thermal-adhesive resin component of the fiber, and cold-drawing an undrawn yarn of the fiber taken out at a spinning speed of not higher than 1300 m/min, by from 1.05 times to 1.30 times under no heat or with cooling in a coolant, followed by relaxing and thermally shrinking it at a temperature higher by at least 10°C than both the glass transition point of the thermal-adhesive resin component and the glass transition point of the fiber-forming resin component.
  • the above-mentioned problems can be solved by the invention of a method for producing a self-extensible thermal-adhesive bicomponent fiber that comprises a fiber-forming resin component and a thermal-adhesive resin component and is characterized in that the fiber-forming resin component comprises polyethylene terephthalate (PET), that the thermal-adhesive resin component comprises a crystalline thermoplastic resin having a melting point lower by at least 20°C than that of the fiber-forming resin component, and that its breaking elongation is from 130 to 600 %, its 100 % elongation tensile strength is from 0.3 to 1.0 cN/dtex and its 120°C dry heat shrinkage is smaller than -1.0 %.
  • PET polyethylene terephthalate
  • the above-mentioned problems can be solved by the invention of a method for producing the thermal-adhesive bicomponent fiber, which comprises cold-drawing an undrawn yarn of a bicomponent fiber taken out at a spinning speed of not higher than 1300 m/min, by from 1.05 to 1.30 times, and then relaxing and thermally shrinking it at a temperature higher by at least 10°C than both the glass transition point of the thermal-adhesive resin component and the glass transition point of the fiber-forming resin component.
  • a nonwoven fabric formed of the low-modulus, self-extensible thermal-adhesive bicomponent fiber formed by the method of the invention can have a soft feel based on the low-modulus characteristic and the self-extensibility of the thermal-adhesive bicomponent fiber itself.
  • the nonwoven fabric may have a high adhesive strength intrinsic to a thermal-adhesive nonwoven fabric formed of only thermal-adhesive bicomponent fibers.
  • the invention is a method of producing a bicomponent fiber comprising a fiber-forming resin component and a thermal-adhesive resin component. More precisely, the invention is a method of producing a low-modulus, self-extensible thermal-adhesive bicomponent fiber that comprises PET as the fiber-forming resin component thereof and a crystalline thermoplastic resin having a melting point lower by at least 20°C than that of PET as the thermal-adhesive resin component thereof.
  • the melting point difference between PET and the thermal-adhesive resin component is less than 20°C, then it is unfavorable since the fiber-forming resin component may also melt in a step of melting and adhering the thermal-adhesive resin component and since a nonwoven fabric or a fiber structure having a high adhesive strength could not be produced.
  • the melting point difference range is from 20 to 180°C.
  • the bicomponent fiber may be produced by obtaining an undrawn yarn of the fiber at a spinning speed of from 100 to 1300 m/min, then cold-drawing it by from 1.05 to 1.30 times, and further relaxing and thermally shrinking it at a temperature higher by at least 10°C than both the glass transition point (hereinafter this is referred to as Tg) of PET and Tg of the thermoplastic crystalline resin constituting the thermal-adhesive resin component and lower by at least 10°C than the melting point of the thermal-adhesive resin component, preferably at a temperature higher by at least 20°C than Tg of the two and lower by at least 20°C than the melting point of the thermal-adhesive resin component.
  • Tg glass transition point
  • the temperature higher than both Tg of PET and Tg of the thermoplastic crystalline resin of the thermal-adhesive resin component is, in many cases, a temperature higher than Tg (about 70°C) of PET. Accordingly, it is desirable that the relaxing and thermal-shrinking treatment is effected at a temperature not lower than 80°C, more preferably not lower than 90°C. Even more preferably, the temperature is not lower than 100°C.
  • the relaxing and thermal-shrinking treatment may be attained in hot air or in hot water.
  • the melting point of the crystalline thermoplastic resin that constitutes the thermal-adhesive resin component is lower by at least 20°C than the melting point of PET, as so mentioned in the above, and therefore Tg of the thermoplastic crystalline resin constituting the thermal-adhesive resin component is mostly lower than Tg of PET.
  • Tg of the thermoplastic crystalline resin constituting the thermal-adhesive resin component is mostly lower than Tg of PET.
  • the relaxing and thermal-shrinking treatment may be attained according to a method of leading a drawn tow to pass through hot air under no tension at all, or according to a method of overfeeding it in hot air at from 0.5 to 0.85 times under no tension given thereto.
  • the low-drawn fiber may form crystals having a crystal axis inclined in random directions from the fiber axis direction, while shrunk in the fiber axis direction by the residual strain therein. Further, when the fiber is heated, then the crystal size of the crystals constituting it increases, and therefore when the crystals existing near to each other are kept in contact with each other, the crystal size may further increase. Accordingly, there may occur a phenomenon that the fiber would seemingly extend. This phenomenon is referred to as self-extension, and the bicomponent fiber produced by the method of the invention exhibit the self-extensibility.
  • the self-extension degree of the fiber increases when the draw ratio is higher than 1.00 time, and the self-extension degree thereof reaches a maximum level when the draw ratio is 1.20 times.
  • the fiber For expressing the self-extensibility of the fiber, it may be a key point how the orientation of the crystals constituting the fiber could be kept random relative to the fiber axis before the crystals grow thick, and for it, therefore, the fiber may well be greatly shrunk before its crystallization. Accordingly, in a step of drawing it, when the fiber is cold-drawn by from 1.05 to 1.30 times at a drawing temperature further lower than the drawing temperature in hot drawing treatment to be effected by the use of hot water, steam or a plate heater, then the residual strain in the amorphous part of the fiber may be increased with inhibiting the orientation crystallization by the drawing, and therefore this is favorable for obtaining the bicomponent fiber produced by the method of the invention.
  • Cold-drawing includes not only drawing at room temperature but also drawing in an atmosphere positively cooled to a temperature lower than room temperature. Concretely, it includes a method of drawing under no heat at room temperature, or in a coolant cooled to a temperature lower than room temperature. More concretely, a method of cold-drawing in air or drawing in a cold water bath is preferred.
  • the coolant includes not only air and water mentioned above, but also vapors such as rare gas, nitrogen or carbon dioxide inert to the fiber-forming resin component and the thermal-adhesive resin component that form the bicomponent fiber produced by the method of the invention without swelling or dissolving them, as well as other liquids such as various oils not dissolving PET and the thermal-adhesive resin component; and the coolant may be suitably selected from them.
  • the temperature of the coolant in cold-drawing may be from 0 to 30°C, preferably from 10 to 25°C.
  • the self-extension degree at 120°C of the bicomponent fiber could be more than 1.0 %, or that is, the dry heat shrinkage at 120°C of the bicomponent fiber could be smaller than -1.0 %, and that the 100 % elongation tensile strength of the bicomponent fiber could be from 0.3 to 1.0 cN/dtex
  • the draw ratio must fall within a range of from 1.05 to 1.30 times.
  • the 100 % elongation tensile strength of the bicomponent fiber could be at most 1.0 cN/dtex but the self-extension degree thereof is less than 1.0 % and the fiber could not attain the object of the invention.
  • the drawing temperature is preferably lower; and when cold water is used as the coolant, then the drawing temperature is more preferably from 0°C to 25°C.
  • the drawing operation at such a low temperature greatly contributes to increasing the thermal shrinkage of the obtained bicomponent fiber, since the crystallization of the fiber owing to orientation and heat generation may be prevented by removing the heat generated by the bicomponent fiber during drawing.
  • the 100 % elongation tensile strength of the bicomponent fiber produced by the method of the invention must be from 0.3 to 1.0 cN/dtex.
  • the spinning speed In the method of the invention for producing the bicomponent fiber, the spinning speed must be at most 1300 m/min, preferably at most 1200 m/min, even more preferably from 100 to 1100 m/min.
  • the spinning speed is higher than 1300 m/min, then the orientation of the undrawn yarn may increase but the effect of expressing a high self-extension degree through low-drawing treatment, which is a characteristic of the bicomponent fiber produced by the method of the invention, may decrease.
  • the low-modulus, self-extensible thermal-adhesive bicomponent fiber produced by the method of the invention may be in any form of a side-by-side laminated bicomponent fiber of a fiber-forming resin component and a thermal-adhesive resin component, or a core-sheath bicomponent fiber where the core component is a fiber-forming resin component and the sheath component is a thermal-adhesive resin component.
  • a core-sheath bicomponent fiber where the core component is a fiber-forming resin component and the sheath component is a thermal-adhesive resin component, since the thermal-adhesive resin component may be disposed in all directions vertical to the fiber axis direction of the fiber.
  • the core-sheath bicomponent fiber includes a concentric core-sheath bicomponent fiber and an eccentric core-sheath bicomponent fiber.
  • thermoplastic resin For the thermal-adhesive resin component, a crystalline thermoplastic resin must be selected. When an amorphous thermoplastic resin is selected for it, then the molecular chains oriented during spinning may be disoriented while melted and therefore the fiber may thereby greatly shrink.
  • Preferred examples of the crystalline thermoplastic resin are polyolefin resin and crystalline copolyester.
  • the polyolefin resin examples include crystalline polyolefin resins such as crystalline polypropylene, high-density polyethylene, middle-density polyethylene, low-density polyethylene, linear low-density polyethylene.
  • the crystalline thermoplastic resin to constitute the thermal-adhesive resin component may be a copolyolefin prepared through copolymerization of the above-mentioned polyolefin with at least one unsaturated compound selected from ethylene, propylene, butene-1, pentene-1, or acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, isocrotonic acid, mesaconic acid, citraconic acid or himic acid or their esters or acid anhydrides.
  • Preferred examples of the crystalline copolyester for the thermal-adhesive resin component are mentioned below.
  • Preferred for it are copolyesters prepared through copolymerization of an alkylene terephthalate with any of substituted or sulfonic acid group-having aromatic dicarboxylic acids such as isophthalic acid, naphthalene-2,6-dicarboxylic acid, sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate, aliphatic dicarboxylic acids such as adipic acid or sebacic acid, alicyclic dicarboxylic acids such as 1,4-cyclohexamethylene-dicarboxylic acid, ⁇ -hydroxyalkylcarboxylic acid, aliphatic diols such as polyethylene glycol or polytetramethylene glycol, or alicyclic diols such as cyclohexamethylene-1,4-dimethanol, so that the formed copolyester may have an intended
  • the alkylene terephthalate may be a polyester obtained starting from 1 to 3 combinations selected from terephthalic acid or its ester-forming derivatives as the essential dicarboxylic acid component, and ethylene glycol, diethylene glycol, trimethylene glycol, tetramethylene glycol, hexamethylene glycol or their derivatives as the essential diol component.
  • the ester-forming derivative includes lower dialkyl esters having from 1 to 6 carbon atoms, and a lower diaryl esters having from 6 to 10 carbon atoms.
  • the ester-forming derivative is are dimethyl ester or diphenyl ester.
  • the copolymerization ratio of these components is variously regulated, depending on the copolymerization components, so that the formed copolymer may have a desired melting point. Preferably, it is from 5 to 50 mol%.
  • the thermal-adhesive resin component may be a polymer blend of at least two crystalline thermoplastic resins having a melting point lower than that of PET by at least 20°C, and it may contain an amorphous thermoplastic resin and a crystalline thermoplastic resin of which the melting point difference between PET is less than 20°C within a range not greatly interfering with the adhesiveness and the low thermal shrinkability of the fiber.
  • the breaking elongation of the low-modulus, self-extensible thermal-adhesive bicomponent fiber produced by the method of the invention must be within a range of from 130 to 600 %, preferably from 170 to 450 %.
  • the breaking elongation of the bicomponent fiber produced by the method of the invention is less than 130 %, then the orientation of the thermal-adhesive resin component is too high and the adhesiveness of the fiber may be poor and therefore the nonwoven fabric strength lowers.
  • the breaking elongation of the bicomponent fiber produced by the method of the invention is more than 600 %, then the strength of the bicomponent fiber is substantially too low and the strength of the thermal-adhesive nonwoven fabric could not be increased.
  • the breaking elongation of the bicomponent fiber For controlling the breaking elongation of the bicomponent fiber to fall within a range of from 130 to 600 %, herein employable is a method of suitably selecting the nozzle orifice diameter through which the polymer is spun out and the spinning speed, though varying depending the type of the polymers to be combined and on the melt viscosity thereof. Above all, the method of suitably selecting the spinning speed is more effective. Further in the invention, in order that the breaking elongation is controlled to fall within the above-mentioned range, it is desirable that the spinning speed is controlled within a range of from 100 to 1300 m/min, though depending on the type of the polymers and the combination thereof. When the spinning speed is higher, then the breaking elongation may be smaller; and when the spinning speed is lower, then the breaking elongation may be higher.
  • the low-modulus, self-extensible thermal-adhesive bicomponent fiber produced by the method of the invention is characterized in that its 120°C dry heat shrinkage is smaller than -1.0 %. Not specifically defined, the lowermost limit of the dry heat shrinkage may be -20.0 % or so.
  • the bicomponent fibers therein may self-extend before thermal adhesion, thereby further increasing the thickness thereof in the thickness direction and, in addition, the low-modulus fibers may be oriented in the thickness direction of the nonwoven fabric, and therefore, when the compression in the thickness direction thereof is taken into consideration, then the nonwoven fabric may have a soft feel, and when it is used as the surface component of sanitary materials, then the pressing feel to users' skin in the vertical direction of the fabric may be reduced and further the drapability of the fabric may be bettered.
  • the thermal-adhesive bicomponent fiber produced by the method of the invention preferably has a concentric core/sheath cross section or an eccentric core/sheath cross section.
  • the bicomponent fiber When the bicomponent fiber has a side-by-side cross section and when it is formed into a web, then the web may crimp three-dimensionally and may be thereby greatly shrunk. In such a case, in addition, the web adhesion strength may be small and the effect of the invention may be reduced in some degree.
  • the bicomponent fiber may be a solid fiber or a hollow fiber.
  • a round cross section it may have a modified cross section, for example, an oval cross section, a multi-leaved cross section such as a 3- to 8-leaved cross section, or a multi-angular cross section such as 3- to 8-angular cross section.
  • the multi-leaved cross section is meant to indicate a cross-sectional profile that has plural protruding leaves extending from the center part toward the outer peripheral direction.
  • the fineness of the thermal-adhesive bicomponent fiber produced by the method of the invention may be selected depending on the object of the fiber. Not specifically limited, it may be generally from 0.01 to 500 dtex or so. By controlling the diameter of the orifice through which resin is jetted out in spinning, the fiber fineness range may be attained.
  • the ratio of the fiber-forming resin component and the thermal-adhesive resin component may be selected in accordance with the necessary strength, bulkiness or thermal shrinkage of the intended nonwoven fabric or fiber structure.
  • the ratio by weight of the fiber-forming resin component to the thermal-adhesive resin component is from 10/90 to 90/10 or so.
  • the fiber may be in any form of multifilament, monofilament, staple fiber, chop or tow, depending on the use and the object thereof.
  • the fiber is preferably crimped to a suitable degree in order to make the fiber have good card-through runnability.
  • the thermal-adhesive bicomponent fiber produced by the method of the invention is especially effective for improving the drapability the nonwoven fabric having a random fiber structure.
  • the self-extensible thermal-adhesive bicomponent fibers produced by the method of the invention may be formed into a nonwoven fabric by themselves. If desired, they may be mixed with any other fibers to produce a nonwoven fabric.
  • employable is any of a carding method, an air-laid method or a wet sheet-making method, in which the fibers are formed into a web, and then predetermined heat is applied thereto in a hot air drier or by an embossing roll, thereby thermally adhering the fibers together to give a soft thermal-adhesive nonwoven fabric of good drapability having a cantilever value of at most 10 cm.
  • the intrinsic viscosity of the polyester was determined as follows : A predetermined amount of the polymer was weighed, then dissolved in o-chlorophenol to have a concentration of 0.012 g/ml, and its viscosity was determined at 35°C according to an ordinary method.
  • the melt flow rate was determined according to JIS K-7210, Condition 4 (temperature 190°C, load 21.18 N). Briefly, polymer pellets before melt spinning were sampled, and the melt flow rate of the sample was measured.
  • the melting point and the glass transition point of the polymer were measured, using TA Instrument Japan's Thermal Analyst 2200, at a heating rate of 20°C/min.
  • the fineness of the bicomponent fiber was measured according to the method described in JIS L-1015:2005, 8.5.1A Method.
  • the breaking tensile strength, the breaking elongation and the 100 % elongation tensile strength of the bicomponent fiber were measured according to the method described in JIS L-1015:2005, 8.7.1 Method.
  • the breaking tensile strength, the breaking elongation and the 100 % elongation tensile strength of the bicomponent fiber produced by the method of the invention may vary; and therefore, when the breaking tensile strength, the breaking elongation and the 100 % elongation tensile strength of the fiber are measured as a single yarn thereof, then the number of the points of the sample to be analyzed must increase.
  • the number of the points for measurement is preferably at least 50.
  • the number of the points for measurement was 50, and the data of all those points were averaged to give a mean value for the intended physical data.
  • the breaking tensile strength and the breaking elongation the tensile strength at a point of 100 % elongation in the load-stress curve is read, and this is the 100 % elongation tensile strength value.
  • the number of crimps and the percentage of crimps of the bicomponent fiber were determined according to the method described in JIS L-1015:2005, 8.12.1 and 8.12.2 Methods.
  • the 120°C dry heat shrinkage of the bicomponent fiber was measured according to JIS L-1015:2005, 8.15 b), at 120°C.
  • the cantilever value was measured according to the following method: On a horizontal bed having a surface smooth and having a 45-degree inclined surface at its one end, the sample test piece is put along the bed. Next, one end of the test piece is accurately registered to one end of the horizontal bed on its inclined side (joint part of the 45-degree inclined surface and the horizontal bed), and the position of the other end of the test piece is measured as the length thereof from one end of the 45-degree inclined surface of the bed. Since the length of the test piece is 25 cm, this should be 25 cm.
  • test piece is gradually slid in the inclined direction according to a suitable method, and when the center point of one end of the test piece has reached the same surface as the inclined surface, then the position of the other end is measured as the length from one end of the 45-degree inclined surface.
  • This value is referred to as A.
  • the difference between 25 cm and A is the cantilever value of the sample. 5 sample pieces are thus analyzed on both their surface and back, and the mean value of the obtained data indicates the cantilever value of the test sample. Test samples having a larger cantilever value are harder, and their drapability are worse; and those having a smaller cantilever value are softer, and their drapability are better.
  • core component fiber-forming resin component
  • sheath component thermal-adhesive resin component
  • HDPE high-density polyethylene
  • the undrawn yarn was cold-drawn by 1.20 times, and then the cold-drawn yarn was dipped in an aqueous solution of an oily agent of potassium lauryl phosphate/polyoxyethylene-modified silicone of 80 wt.%/20 wt.%. Then, using a staffing box-equipped forced crimper, this was mechanically crimped at 11 crimps/25 mm.
  • the crimped yarn was subj ected to relaxing and thermal shrinkage treatment and drying treatment with hot air at 110°C, higher by 40°C than the glass transition point of the core component, under no tension, and then cut into pieces having a fiber length of 51 mm.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.4 dtex, the breaking tensile strength thereof was 0.76 cN/dtex, the breaking elongation thereof was 442 %, the 100 % elongation tensile strength thereof was 0.37 cN/dtex, and the 120°C dry heat shrinkage thereof was -2.6 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -7.5 %, the nonwoven fabric strength thereof was 15.1 kg/g, and the cantilever value thereof was 8.50 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn obtained in Example 1 was drawn by 2.5 times in hot water at 70°C, and then further drawn by 1. 2 times in hot water at 90°C.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 2.6 dtex, the breaking tensile strength thereof was 2.49 cN/dtex, the breaking elongation thereof was 37.1 %, and the 120°C dry heat shrinkage thereof was 2.5 %. Since the elongation of the thermal-adhesive bicomponent fiber was less than 100 %, the 100 % elongation tensile strength thereof could not be measured.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was 5 %, the nonwoven fabric strength thereof was 20.5 kg/g, and the cantilever value thereof was 12.90 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn was not drawn.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.47 dtex, the breaking tensile strength thereof was 0.60 cN/dtex, the breaking elongation thereof was 460.3 %, the 100 % elongation tensile strength thereof was 0.37 cN/dtex, and the 120°C dry heat shrinkage thereof was -0.7 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -1.45 %, the nonwoven fabric strength thereof was 14.5 kg/g, and the cantilever value thereof was 7.90 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.1 times.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.41 dtex, the breaking tensile strength thereof was 0.65 cN/dtex, the breaking elongation thereof was 424.1 %, the 100 % elongation tensile strength thereof was 0.41 cN/dtex, and the 120°C dry heat shrinkage thereof was -1.9 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -5.6 %, the nonwoven fabric strength thereof was 16.5 kg/g, and the cantilever value thereof was 8.10 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.30 times.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.22 dtex, the breaking tensile strength thereof was 0.72 cN/dtex, the breaking elongation thereof was 381.8 %, the 100 % elongation tensile strength thereof was 0.46 cN/dtex, and the 120°C dry heat shrinkage thereof was -2.0 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -6.1 %, the nonwoven fabric strength thereof was 17.1 kg/g, and the cantilever value thereof was 8.90 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.4 times.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.14 dtex, the breaking tensile strength thereof was 0.75 cN/dtex, the breaking elongation thereof was 346.8 %, the 100 % elongation tensile strength thereof was 0.53 cN/dtex, and the 120°C dry heat shrinkage thereof was -0.6 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -1.8 %, the nonwoven fabric strength thereof was 18.4 kg/g, and the cantilever value thereof was 10.1 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn was cold-drawn while cooled in a water bath having a controlled temperature of 20°C.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.52 dtex, the breaking tensile strength thereof was 0.65 cN/dtex, the breaking elongation thereof was 459.3 %, the 100 % elongation tensile strength thereof was 0.39 cN/dtex, and the 120°C dry heat shrinkage thereof was -3.2 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -9.5 %, the nonwoven fabric strength thereof was 15.3 kg/g, and the cantilever value thereof was 8.13 cm.
  • a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the yarn was subjected to relaxing and thermal shrinking treatment and heat treatment in a hot water bath at 95°C with overfeeding it at 0.7 times, but thereafter it was not dried with hot air.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.58 dtex, the breaking tensile strength thereof was 0.68 cN/dtex, the breaking elongation thereof was 443.3 %, the 100 % elongation tensile strength thereof was 0.41 cN/dtex, and the 120°C dry heat shrinkage thereof was -3.9 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -11.4 %, the nonwoven fabric strength thereof was 14.9 kg/g, and the cantilever value thereof was 8.90 cm.
  • the core component fiber-forming resin component
  • PET polyethylene terephthalate
  • sheath component thermal-adhesive resin component
  • crystalline copolyester polyethylene terephthalate prepared through copolymerization with 20 mol% of isophthalic acid and 50 mol% of tetramethylene glycol
  • MFR 40 g/10 min
  • the crimped yarn was subj ected to drying treatment and relaxing and thermal shrinkage treatment with hot air at 90°C under no tension, and then cut into pieces having a fiber length of 51 mm.
  • the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 5.7 dtex, the breaking tensile strength thereof was 0.94 cN/dtex, the breaking elongation thereof was 392 %, the 100 % elongation tensile strength thereof was 0.35 cN/dtex, and the 120°C dry heat shrinkage thereof was -3.8 %.
  • the web area shrinkage of the web of 100 % the thermal-adhesive bicomponent fibers was -11.2 %, the nonwoven fabric strength thereof was 12.3 kg/g, and the cantilever value thereof was 8.30 cm.
  • the low-modulus, self-extensible thermal-adhesive bicomponent fiber produced by the method of the invention comprises PET as the fiber-forming resin component, and since the spinning speed in producing it is low, fiber breakage frequency during spinning is extremely low. Further, when the bicomponent fiber is used in producing a nonwoven fabric, then the produced nonwoven fabric is bulky and has high adhesiveness, high drapability and good feel.

Claims (6)

  1. Verfahren zur Herstellung einer eigendehnbaren, wärmehaftenden Zweikomponentenfaser, die eine faserbildende Harzkomponente und eine wärmehaftende Harzkomponente umfasst, wobei in der Faser die faserbildende Harzkomponente Polyethylenterephthalat umfasst, die wärmehaftende Harzkomponente ein kristallines thermoplastisches Harz mit einem Schmelzpunkt von mindestens 20°C niedriger als der der faserbildenden Harzkomponente umfasst, und wobei ihre Bruchdehnung 130 bis 600% beträgt, ihre Zugfestigkeit bei 100% Dehnung 0,3 bis 1,0 cN/dtex beträgt und ihre 120°C Trockenwärmeschrumpfung kleiner als -1,0% ist, wobei das Verfahren das Kaltziehen eines ungereckten Garns einer Zweikomponentenfaser, das bei einer Spinngeschwindigkeit von nicht mehr als 1300 m/min entnommen wird, um das 1,05-bis 1,30-fache und anschließend das Entspannen und Wärmeschrumpfen dieses bei einer mindestens 10°C höheren Temperatur als sowohl der Glasübergangspunkt der wärmehaftenden Harzkomponente als auch der Glasübergangspunkt der faserbildenden Harzkomponente umfasst.
  2. Verfahren zur Herstellung einer wärmehaftenden Zweikomponentenfaser nach Anspruch 1, welche eine Kern/Hülle-Zweikomponentenfaser ist, und in welcher die faserbildende Harzkomponente die Kernkomponente bildet und die wärmehaftende Harzkomponente die Hüllkomponente davon bildet.
  3. Verfahren zur Herstellung einer wärmehaftenden Zweikomponentenfaser nach Anspruch 1, wobei die wärmehaftende Harzkomponente ein Polyolefinharz ist.
  4. Verfahren zur Herstellung einer wärmehaftenden Zweikomponentenfaser nach Anspruch 1, wobei die wärmehaftende Harzkomponente ein kristalliner Copolyester ist.
  5. Verfahren zur Herstellung einer wärmehaftenden Zweikomponentenfaser nach Anspruch 1, wobei die Entspannungs- und Wärmeschrumpfungsbehandlung in warmer Luft erfolgt.
  6. Verfahren zur Herstellung einer wärmehaftenden Zweikomponentenfaser nach Anspruch 1, wobei die Entspannungs- und Wärmeschrumpfungsbehandlung in warmem Wasser erfolgt.
EP20070743519 2006-05-12 2007-05-10 Thermobondierbare verbundfaser und herstellungsverfahren dafür Not-in-force EP2022877B1 (de)

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