DK2718395T3 - Ny belysningsindretning der omfatter en farvekonverter - Google Patents
Ny belysningsindretning der omfatter en farvekonverter Download PDFInfo
- Publication number
- DK2718395T3 DK2718395T3 DK12726790.4T DK12726790T DK2718395T3 DK 2718395 T3 DK2718395 T3 DK 2718395T3 DK 12726790 T DK12726790 T DK 12726790T DK 2718395 T3 DK2718395 T3 DK 2718395T3
- Authority
- DK
- Denmark
- Prior art keywords
- mono
- polysubstituted
- alkyl
- aryl
- alkoxy
- Prior art date
Links
- -1 aliphatic radical Chemical group 0.000 claims description 1133
- 239000007850 fluorescent dye Substances 0.000 claims description 127
- 239000000203 mixture Substances 0.000 claims description 100
- 229920000642 polymer Polymers 0.000 claims description 92
- 125000003118 aryl group Chemical group 0.000 claims description 84
- 229910052757 nitrogen Inorganic materials 0.000 claims description 76
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 68
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 65
- 150000003254 radicals Chemical class 0.000 claims description 64
- 229910052736 halogen Inorganic materials 0.000 claims description 43
- 150000002367 halogens Chemical class 0.000 claims description 43
- 125000001072 heteroaryl group Chemical group 0.000 claims description 42
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 40
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 40
- 125000004122 cyclic group Chemical group 0.000 claims description 34
- 125000001424 substituent group Chemical group 0.000 claims description 34
- 239000004793 Polystyrene Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 32
- 229920006395 saturated elastomer Polymers 0.000 claims description 32
- 229920002223 polystyrene Polymers 0.000 claims description 31
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 30
- 238000005286 illumination Methods 0.000 claims description 28
- 125000003396 thiol group Chemical class [H]S* 0.000 claims description 26
- 239000004417 polycarbonate Substances 0.000 claims description 24
- 229920000515 polycarbonate Polymers 0.000 claims description 24
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 23
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 23
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims description 13
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 13
- 229910052794 bromium Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 12
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 11
- 229920002959 polymer blend Polymers 0.000 claims description 11
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 9
- 150000005840 aryl radicals Chemical class 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 125000005427 anthranyl group Chemical group 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 8
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 8
- 125000001624 naphthyl group Chemical group 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 239000004800 polyvinyl chloride Substances 0.000 claims description 8
- 125000001725 pyrenyl group Chemical group 0.000 claims description 8
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 7
- 230000004888 barrier function Effects 0.000 claims description 7
- 125000003392 indanyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 claims description 7
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 7
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 125000005329 tetralinyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 claims description 7
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims description 6
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000004642 Polyimide Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001601 polyetherimide Polymers 0.000 claims description 5
- 229920001721 polyimide Polymers 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 239000004697 Polyetherimide Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920001083 polybutene Polymers 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 230000035699 permeability Effects 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 1
- DFMXJRGGNCRUHZ-UHFFFAOYSA-N 6h-isoquinolin-7-one Chemical compound C1=CN=CC2=CC(=O)CC=C21 DFMXJRGGNCRUHZ-UHFFFAOYSA-N 0.000 claims 1
- 125000005605 benzo group Chemical group 0.000 claims 1
- 239000012463 white pigment Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 159
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 84
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 69
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 54
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 48
- 239000010410 layer Substances 0.000 description 47
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 42
- 238000002360 preparation method Methods 0.000 description 37
- 150000001875 compounds Chemical class 0.000 description 35
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 34
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 32
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 32
- 239000000047 product Substances 0.000 description 30
- 229910052786 argon Inorganic materials 0.000 description 27
- 239000000725 suspension Substances 0.000 description 25
- 238000004440 column chromatography Methods 0.000 description 23
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 18
- 239000007787 solid Substances 0.000 description 18
- 239000003086 colorant Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 229910000027 potassium carbonate Inorganic materials 0.000 description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 16
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical compound OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 14
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 14
- 239000011159 matrix material Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 230000005855 radiation Effects 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 10
- 239000012074 organic phase Substances 0.000 description 10
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 10
- 238000006862 quantum yield reaction Methods 0.000 description 10
- 239000004246 zinc acetate Substances 0.000 description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 9
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 9
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000002390 rotary evaporation Methods 0.000 description 9
- 229940123457 Free radical scavenger Drugs 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000002516 radical scavenger Substances 0.000 description 8
- 125000005842 heteroatom Chemical group 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- DTUOTSLAFJCQHN-UHFFFAOYSA-N 4-bromo-1,8-naphthalic anhydride Chemical compound O=C1OC(=O)C2=CC=CC3=C2C1=CC=C3Br DTUOTSLAFJCQHN-UHFFFAOYSA-N 0.000 description 6
- KYEFUIBOKLKQPD-UHFFFAOYSA-N 4-phenylbenzene-1,2-diamine Chemical compound C1=C(N)C(N)=CC=C1C1=CC=CC=C1 KYEFUIBOKLKQPD-UHFFFAOYSA-N 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229920000592 inorganic polymer Polymers 0.000 description 6
- 229920000620 organic polymer Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000000741 silica gel Substances 0.000 description 6
- 229910002027 silica gel Inorganic materials 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 150000003440 styrenes Chemical class 0.000 description 6
- ZFWSPMZRGMPMCW-UHFFFAOYSA-N 5,7,17-triphenyl-3,10-diazapentacyclo[10.7.1.02,10.04,9.016,20]icosa-1(20),2,4,6,8,12,14,16,18-nonaen-11-one Chemical compound C1=C2N3C(=O)C(C=45)=CC=CC5=C(C=5C=CC=CC=5)C=CC=4C3=NC2=C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 ZFWSPMZRGMPMCW-UHFFFAOYSA-N 0.000 description 5
- GRSMWKLPSNHDHA-UHFFFAOYSA-N Naphthalic anhydride Chemical compound C1=CC(C(=O)OC2=O)=C3C2=CC=CC3=C1 GRSMWKLPSNHDHA-UHFFFAOYSA-N 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- KPTRDYONBVUWPD-UHFFFAOYSA-N naphthalen-2-ylboronic acid Chemical compound C1=CC=CC2=CC(B(O)O)=CC=C21 KPTRDYONBVUWPD-UHFFFAOYSA-N 0.000 description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- NTZWCETUJVYTIW-UHFFFAOYSA-N 3,5-dinaphthalen-2-ylbenzene-1,2-diamine Chemical compound C1=CC=CC2=CC(C=3C=C(C(=C(C=3)C=3C=C4C=CC=CC4=CC=3)N)N)=CC=C21 NTZWCETUJVYTIW-UHFFFAOYSA-N 0.000 description 4
- KAIUSRVLCDMZHB-UHFFFAOYSA-N 3,5-diphenylbenzene-1,2-diamine Chemical compound NC=1C(N)=CC(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 KAIUSRVLCDMZHB-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000611421 Elia Species 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 238000000295 emission spectrum Methods 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 238000004949 mass spectrometry Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 229920006324 polyoxymethylene Polymers 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 238000009877 rendering Methods 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- LDOWPJVMNLXCLN-UHFFFAOYSA-N 2,4-dinaphthalen-2-yl-5-nitroaniline Chemical compound C1=CC=CC2=CC(C3=C(C=C(C(=C3)C=3C=C4C=CC=CC4=CC=3)N)[N+]([O-])=O)=CC=C21 LDOWPJVMNLXCLN-UHFFFAOYSA-N 0.000 description 3
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- IPWKHHSGDUIRAH-UHFFFAOYSA-N bis(pinacolato)diboron Chemical compound O1C(C)(C)C(C)(C)OB1B1OC(C)(C)C(C)(C)O1 IPWKHHSGDUIRAH-UHFFFAOYSA-N 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000002596 correlated effect Effects 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000002950 monocyclic group Chemical group 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 125000003367 polycyclic group Chemical group 0.000 description 3
- 239000012279 sodium borohydride Substances 0.000 description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 125000005023 xylyl group Chemical group 0.000 description 3
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- 125000006219 1-ethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 2
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 2
- OBTUHOVIVLDLLD-UHFFFAOYSA-N 2,4-dibromo-6-nitroaniline Chemical compound NC1=C(Br)C=C(Br)C=C1[N+]([O-])=O OBTUHOVIVLDLLD-UHFFFAOYSA-N 0.000 description 2
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 description 2
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- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- JIQNWFBLYKVZFY-UHFFFAOYSA-N methoxycyclohexatriene Chemical compound COC1=C[C]=CC=C1 JIQNWFBLYKVZFY-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 125000005322 morpholin-1-yl group Chemical group 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HAGWGWQUZPWZER-UHFFFAOYSA-N n-prop-1-enylbutan-2-imine Chemical group CCC(C)=NC=CC HAGWGWQUZPWZER-UHFFFAOYSA-N 0.000 description 1
- HUMMCEUVDBVXTQ-UHFFFAOYSA-N naphthalen-1-ylboronic acid Chemical compound C1=CC=C2C(B(O)O)=CC=CC2=C1 HUMMCEUVDBVXTQ-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000006678 phenoxycarbonyl group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920005553 polystyrene-acrylate Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- 230000006798 recombination Effects 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 125000006413 ring segment Chemical group 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001935 tetracenyl group Chemical group C1(=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C12)* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/06—Naphtholactam dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1003—Carbocyclic compounds
- C09K2211/1007—Non-condensed systems
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1003—Carbocyclic compounds
- C09K2211/1011—Condensed systems
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1044—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
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- Nitrogen Condensed Heterocyclic Rings (AREA)
- Plural Heterocyclic Compounds (AREA)
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Claims (16)
1. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter, der omfatter i det mindste en polymer og i det mindste et organisk fluorescerende farvestof, der omfatter i det mindste en strukturel enhed med formlen (I)
(I) hvor den strukturelle enhed kan være mono- eller polysubstitueret med identiske eller forskellige substituenter, og hvor en eller flere CH grupper af den viste seks-ledede ring af benzimidazolstrukturen kan erstattes af nitrogen.
2. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge krav 1, hvor det i det mindste et organisk fluorescerende farvestof omfatter i det mindste en strukturel enhed med formlen (II)
(II) hvor en eller flere CH grupper af den seks-ledede ring af den viste benzimidazolstruktur kan erstattes af nitrogen, og hvor symbolerne hver er defineret som følger: n er et antal fra 0 til (10-p) for hver strukturelle enhed med formlen (II) ; hvor p er antallet af CH enheder, som er blevet erstattet af nitrogen i den viste seks-ledede ring af benzimidazolstrukturen; X er en kemisk binding, 0, S, SO, SO2, NR1; og R er en alifatisk radikal, cycloalifatisk radikal, aryl, hetaryl, som hver især kan bære hvilke som helst ønskede substituenter, et aromatisk eller heteroaromatisk ring eller ringsystem, som hver især er sammensmeltet til andre aromatiske ringe af den strukturelle enhed med formlen (II), er F, Cl, Br, CN, H, når X ikke er en kemisk binding; hvor to R radikaler kan være forbundet for at give én cyklisk radikal, og hvor X og R, når n > én, kan være den samme eller forskellige; R1 hver er uafhængige hydrogener, Ci-Cis-alkyl eller cycloalkyl, hvor kulstofkæden hver kan omfatte en eller flere -0-, -S-, - CO-, -SO- og/eller -SO2- molekyledele, og som kan være monoeller polysubstitueret; aryl eller hetaryl, som kan være mono- eller polysubstitueret.
3. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge krav 2, hvor det i det mindste ene organisk fluorescerende farvestof omfatter i det mindste en strukturel enhed med formlen (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XX), (XXI), (XXII), (XXIII), (XIV), (XXV) or (XXVI):
hvor R og X er som defineret i krav 2; n er 0, 1, 2, 3, 4, 5, 6, 7, 8, 9 eller 10 for hver strukturelle enhed med formlen (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XX), eller n er 0, 1, 2, 3, 4, 5, 6, 7, 8 eller 9 for hver strukturelle enhed med formlen (XX), (XXI), (XXII) or (XXIII); eller n er 0, 1, 2, 3, 4, 5, 6, 7 eller 8 for hver strukturelle enhed med formlen (XXIV), (XXV) eller (XXVI); Z er CR2R2, NR1 eller O, R1 er som defineret i krav 2; og R2 har en af betydningerne, der er givet for R1.
4. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af kravene 2 eller 3, hvor symbolerne i den strukturelle enhed med formlen (II), (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XX), (XXI), (XXII), (XXIII), (XIV), (XXV) eller (XXVI) hver er defineret som følger: X er en kemisk binding, 0, S, SO, SO2, NR1; R er en alifatisk eller cycloalifatisk radikal, der er udvalgt fra Ci til C100 alkyl eller cycloalkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -C ξ= c-, -CR1 = CR1-, -CO-, -SO- og/eller -SO2- molekyledele, kan have en eller flere dobbelte eller tredobbelte bindinger og kan være mono- eller polysubstitueret med: Ci-Ci2~alkoxy, Ci-C6_alkylthio, -C ξ CR1, -CR1 = CR1!, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, -CONR2R3, -S02NR2R3, -C00R2, -SO3R2, aryl og/eller mættet eller umættet C4-C7-cycloalkyl, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO-, -SO- og/eller -SO2- molekyledele, hvor aryl- og cycloalkylradikaler hver kan være mono- eller polysubstituerede med Ci-Cis-alkyl og/eller de ovenstående radikaler, der er nævnt som substituenter for alkyl; aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes mættet eller umættet 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, N = CR1-, -CO-, -SO- og/eller -SO2- molekyledele, hvor hele aryl- eller hetarylringsystemet kan være mono- eller polysubstitueret med radikalerne (i) , (ii), (iii), (iv) og/eller (v): (i) Ci-C3o-alkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -C ξ C-, -CR1 = CR1-, -CO-, -S0- og/eller -SO2- molekyledele, og som kan være mono- eller polysubstitueret med: Ci-Ci2-alkoxy, Ci-C6-alkylthio, -C Ξ CR1, -CR1 = CR1!, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, -CONR2R3,-S02NR2R3, -C00R2, -SO3R2, aryl og/eller mættet eller umættet C4-C7-cycloalkyl, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO, - SO- og/eller -SO2- molekyledele, hvor aryl- og cycloalkylradikaler hver kan være mono- eller polysubstituerede med Ci-Cis-alkyl og/eller de ovenstående radikaler, der er nævnt som substituenter for alkyl; (ii) C3-C8-cycloalkyl, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO-, -S0- og/eller -SO2- molekyledele, og til hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstof skelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO-, -SO- og/eller -SO2- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med: Ci-Cis-alkyl, Ci-Ci2~alkoxy, C1-C6- alkylthio, -C ξ CR1, -CR1 = CR22, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, -CONR2R3, -S02NR2R3, -C00R2 og/eller -SO3R2; (iii) aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO-, -SO- og/eller -S02- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med: Ci-Cie-alkyl, Ci-Ci2-alkoxy, C1-C6- alkylthio, -C ξ CR1, -CR1 = CR12, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, -CONR2R3, -S02NR2R3, -C00R2,- SO3R2, aryl og/eller hetaryl, hvor hver af hvilke kan være mono- eller polysubstitueret med Ci-Cis-alkyl, Ci-Ci2-alkoxy, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, CONR2R3, -S02NR2R3, -C00R2 og/eller -SO3R2; (iv) en -U-aryl radikal, som kan være mono- eller polysubstitueret med de ovenstående radikaler, der er nævnt som substituenter for arylradikalerne (iii) , hvor U er en -0-, -S-, -NR1-, -CO-, -SO- or -SO2- molekyledel; (v) Ci-Ci2-alkoxy, Ci-C6-alkylthio, -C ξ CR1, -CR1 = CR12, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, C0NR2R3, -S02NR2R3, -C00R2 og/eller -SO3R2; aromatisk eller heteroaromatisk ring eller ringsystem, som hver især er sammensmeltet til andre aromatiske ringe af den strukturelle enhed med formlen (II) til (X) eller (XX) til (XXVI), og til hver af hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, N = CR1-, -CO-, -SO- og/eller -SO2- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med radikalerne (i), (i i), (iii), (iv) og/eller (v); F, Cl, Br, CN, H når X ikke er en kemisk binding; hvor to R radikaler kan være forbundet for at danne en cyklisk radikal, hvor X og R, når n > 1, kan være den samme eller forskellige; R1, R2, R3 hver er uafhængige hydrogener; Ci-Ci8-alkyl hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -CO-, -SO-og/eller -SO2- molekyledele, og som kan være mono- eller polysubstitueret med Ci-Ci2-alkoxy, Ci-C6-alkylthio, hydroxyl, mercapto, halogen, cyano, nitro og/eller -C00R1; aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -C0- og/eller -SO2- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstituerede med Ci-Ci2-alkyl og/eller de ovenstående radikaler, der er nævnt som substituenter for alkyl.
5. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af kravene 2 til 4, hvor symbolerne i den strukturelle enheds med formlen (II), (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XX), (XXI), (XXII), (XXIII), (XIV), (XXV) eller (XXVI) hver er defineret som følger: n er et antal fra 1 til 6, X er en kemisk binding, 0, S eller NR1; R er en alifatisk eller cycloalifatisk radikal, der er udvalgt fra Ci til C100 alkyl eller cycloalkyl; C 6 til C22 aryl eller C6 til C15 hetaryl, hvor ringsystemet deraf kan være mono- eller polysubstitueret med radikalerne (i), (ii), (iii), (iv) og/eller (v): (i) Ci-C3o-alkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -NR1-C ξ c-, -CR1 = CR1 molekyledele, og som kan være mono- eller polysubstitueret med: Ci-Ci2-alkoxy, C1-C6- alkylthio, hydroxyl, halogen, cyano, nitro, -NR2R3; (ii) C3-C8-cycloalkyl, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -CR 1= CR1- molekyledele, og som kan være mono- eller polysubstitueret med: Ci-Cie-alkyl, C1-C12-alkoxy; (iii) aryl eller hetaryl, hvor ringsystemet kan være monoeller polysubstitueret med: Ci-Cis-alkyl, Ci-Ci2-alkoxy; (iv) en -U-aryl radikal, der kan være mono- eller polysubstitueret med de ovenstående radikaler, der er nævnt som substituenter for arylradikalerne (iii), hvor U er en -0-, -S-, -NR1-, -CO-, -SO- or -SO2- molekyledel; (v) Ci-Ci2-alkoxy, hydroxyl, halogen, cyano, nitro, -NR2R3, NR2COR3, -CONR2R3, -S02NR2R3, -C00R2 eller -SO3R2; C6 til C22 aromatisk eller C6 til C15 heteroaromatisk ring eller ringsystem, som hver især er sammensmeltet til andre aromatiske ringe af den strukturelle enhed med formlen (II) til (X) eller (XX) til (XXVI), hvor den aromatiske ring eller det aromatiske ringsystem kan være mono- eller polysubstitueret med radikalerne (i) , (ii), (iii) , (iv) og/eller (v); H, når X ikke er en kemisk binding; R1, R2, R3 hver er uafhængige hydrogener; Ci-Cie-alkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -CO-, -S0- og/eller -S02- molekyledele, og som kan være mono- eller polysubstitueret med Ci-Ci2-alkoxy, Ci-C6-alkylthio, hydroxyl, mercapto, halogen, cyano, nitro og/eller -COOR1; aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -C0- og/eller -S02- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med Ci-Ci2-alkyl og/eller de ovenstående radikaler, der er nævnt som substituenter for alkyl.
6. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af kravene 2 til 5, hvor symbolerne i den strukturelle enhed med formlen (II), (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XX), (XXI), (XXII), (XXIII), (XIV), (XXV) eller (XXVI) hver er defineret som følger: n er et antal fra 1 til 5, (X-R) er phenyl, naphthyl, anthranyl, phenanthrenyl, pyrenyl, benzopyrenyl, fluorenyl, indanyl, indenyl, tetralinyl, phenoxy, thiophenoxy, C1-C12 alkoxyphenyl, hvor hver af hvilke kan være mono- eller polysubstitueret med identiske eller forskellige radikaler (i), (ii), (iii), (iv) og/eller (v): (i) Ci-C3o-alkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -NR1-, -C ξ c-, -CR1 = CR1- og/eller -CO- molekyledele, og som kan være mono- eller polysubstitueret med: C1-C12-alkoxy, hydroxyl, halogen, cyano og/eller aryl, der kan være mono- eller polysubstitueret med Ci-Cis-alkyl og/eller C1-C6-alkoxy; (ii) C3-C8-cycloalkyl, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -CR1=CR1- og/eller -CO- molekyledele, og som kan være mono- eller polysubstitueret med Ci-Cis-alkyl, Ci-Ci2-alkoxy og/eller Ci-C6~alkylthio; (iii) aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes 5- til 7-ledede mættede eller umættede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -NR1-, -N = CR1-, -CR1 = CR1-, -CO-, -SO- og/eller -S02-molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med: Ci-Cis-alkyl, Ci-Ci2-alkoxy, -C = CR1-, CR1 = CR1-, hydroxyl, halogen, cyano, -NR2R3, -NR2COR3, -CONR2R3, -S02NR2R3, -C00R2 og/eller -SO3R2; (iv) en -U-aryl radikal, der kan være mono- eller polysubstitueret med de ovenstående radikaler, der er nævnt som substituenter for arylradikalerne (iii) , hvor U er en -0-, -S-, -NR1-, -CO-, -SO- eller -SO2- molekyledel; (v) Ci-Ci2-alkoxy, Ci-C6-alkylthio, -C ξ CR1, -CR1 = CR32, hydroxyl, mercapto, halogen, cyano, nitro, -NR2R3, -NR2COR3, -CONR2R3, -S02NR2R3, -C00R2 eller -SO3R2; R1, R2, R3 hver er uafhængige hydrogener; Ci-Ci8-alkyl, hvis kulstofkæde kan omfatte en eller flere -0-, -S-, -CO-, -SO-og/eller -SO2- molekyledele, og som kan være mono- eller polysubstitueret med Ci-Ci2-alkoxy, Ci-C6_alkylthio, hydroxyl, mercapto, halogen, cyano, nitro og/eller -C00R1; aryl eller hetaryl, til hver af hvilke der yderligere kan sammensmeltes mættede eller umættede 5- til 7-ledede ringe, hvis kulstofskelet kan omfatte en eller flere -0-, -S-, -C0- og/eller -SO2- molekyledele, hvor det samlede ringsystem kan være mono- eller polysubstitueret med Ci-Ci2-alkyl og/eller de ovenstående radikaler, der er nævnt som substituenter for alkyl.
7. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav, hvor det i det mindste ene organiske fluorescerende farvestof har en struktur som vist i formlen (XV) : A-Fm (XV) hvor m er et tal med en værdi på i det mindste 2, F repræsenterer identiske eller forskellige strukturelle enheder (I) til (X) eller (XX) til (XXVI) ifølge et hvilket som helst af de foregående krav, og A er et hvilket som helst organisk radikal, til hvilken F er kemisk bundet, hvor A er udvalgt fra en polymer P, et aromatisk ringsystem, et molekyle med en flerhed af aromatiske ringsystemer, en polyvalent alkohol, en polyfunktionel amin.
8. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav, hvor det i det mindste ene organiske fluorescerende farvestof er udvalgt fra de følgende farvestoffer:
eller blandinger deraf, hvor R1 og n hver er som defineret i krav 2.
9. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav 1 til 8, hvor det organiske fluorescerende farvestof er udvalgt fra 3,10,12-triphenylbenzo[de]benzo[4,5]imidazo[2,l-a]isoquinolin-7-one og
10. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav, hvor den i det mindste ene polymer består hovedsageligt af polystyren, polycarbonat, polymethylmethacrylat, polyvinylpyrrolidon, polymethacrylat, polyvinylacetat, polyvinylchlorid, polybuten, polyethylenglykol, silikone, polyacrylat, epoxyharpiks, polyvinylalkohol, polyacrylonitril, polvinylidenchlorid (PVDC), polystyren-acrylonitril (SAN), polybutylenterephthalat (PBT), polyethylenterephthalat (PET) , polyvinylbutyrat (PVB), polyvinylchlorid (PVC), polyamider, polyoxymethylener, polyimider, polyetherimid eller blandinger deraf.
11. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge i det mindste et af de foregående krav, hvor farvekonverteren derudover omfatter i det mindste et uorganisk hvidt pigment som et spredende legeme.
12. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav, der omfatter i det mindste et yderligere organisk fluorescerende farvestof, der er udvalgt fra N, N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxy-perylene-3,4;9,10-tetracarboximid, N, N'-bis(2,6- diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylen- 3.4 ; 9, 10-tetracarboximid, N, N'-bis(2, 6-diisopropylphenyl)- 1.6- di(2,6-diisopropylphenoxy)perylen-3,4;9,10-tetracarboximid eller blandinger deraf, fortrinsvis N, N'-bis(2,6- diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylen- 3.4 ; 9, 10-tetracarboximid, N, N'-bis(2,6-diisopropylphenyl)- 1.6- di(2,6-diisopropylphenoxy)perylen-3,4;9,10-tetracarboximid eller blandinger deraf.
13. Belysningsindretning, der omfatter i det mindste en LED og i det mindste en farvekonverter ifølge et hvilket som helst af de foregående krav, hvor farvekonverteren har, på i det mindste en side, et spærrelag med en lav oxygenpermeabilitet.
14. Anvendelse af farvekonvertere ifølge i det mindste et af de foregående krav til omdannelse af lys, der er frembragt af LED'er.
15. Fluorescerende farvestof, der er udvalgt fra:
eller blandinger deraf, hvor R1 og n hver er som defineret i krav 2.
16. Polymerblanding, der omfatter i det mindste en polymer og i det mindste et organisk fluorescerende farvestof som defineret i krav 15.
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PCT/EP2012/060844 WO2012168395A1 (en) | 2011-06-10 | 2012-06-08 | Novel color converter |
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WO2012168395A1 (en) | 2012-12-13 |
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RU2013158678A (ru) | 2015-07-20 |
TW201307525A (zh) | 2013-02-16 |
KR20140051214A (ko) | 2014-04-30 |
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CN103619987A (zh) | 2014-03-05 |
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RU2608411C2 (ru) | 2017-01-18 |
US9406848B2 (en) | 2016-08-02 |
JP2014532288A (ja) | 2014-12-04 |
US20160284947A1 (en) | 2016-09-29 |
BR112013030704B1 (pt) | 2021-06-15 |
EP2718395A1 (en) | 2014-04-16 |
TWI561612B (en) | 2016-12-11 |
US10230023B2 (en) | 2019-03-12 |
US20140103374A1 (en) | 2014-04-17 |
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