DE102007036653A1 - Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder - Google Patents

Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder Download PDF

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Publication number
DE102007036653A1
DE102007036653A1 DE102007036653A DE102007036653A DE102007036653A1 DE 102007036653 A1 DE102007036653 A1 DE 102007036653A1 DE 102007036653 A DE102007036653 A DE 102007036653A DE 102007036653 A DE102007036653 A DE 102007036653A DE 102007036653 A1 DE102007036653 A1 DE 102007036653A1
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DE
Germany
Prior art keywords
electrode according
electrode
lithium
matrix
polysaccharide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102007036653A
Other languages
German (de)
English (en)
Inventor
Nikolaus Stefan Dipl.-Ing. Hochgatterer
Stefan Dipl.-Ing. Koller
Mario Rene Dipl.-Ing. Schweiger
Martin Univ.Prof. Dipl.-Chem. Dr.rer.nat. Winter
Calin Dr.rer.nat. Dipl.-Chem. Wurm
Arno Dr.rer.nat. Dipl.-Chem. Perner
Thomas Dipl.-Chem. Dr.rer.nat. Wöhrle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VARTA Microbattery GmbH
VW VM Forschungs GmbH and Co KG
Original Assignee
VARTA Microbattery GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VARTA Microbattery GmbH filed Critical VARTA Microbattery GmbH
Priority to DE102007036653A priority Critical patent/DE102007036653A1/de
Priority to ES08784714T priority patent/ES2378006T3/es
Priority to PCT/EP2008/005673 priority patent/WO2009012899A1/de
Priority to EP08784714A priority patent/EP2179464B1/de
Priority to CN200880100231A priority patent/CN101796675A/zh
Priority to AT08784714T priority patent/ATE538510T1/de
Priority to US12/668,916 priority patent/US9653733B2/en
Priority to KR1020107000824A priority patent/KR20100034007A/ko
Priority to JP2010517292A priority patent/JP2010534392A/ja
Publication of DE102007036653A1 publication Critical patent/DE102007036653A1/de
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
DE102007036653A 2007-07-25 2007-07-25 Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder Withdrawn DE102007036653A1 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
DE102007036653A DE102007036653A1 (de) 2007-07-25 2007-07-25 Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder
ES08784714T ES2378006T3 (es) 2007-07-25 2008-07-11 Electrodos y celdas de iones de litio con novedoso ligante de electrodos
PCT/EP2008/005673 WO2009012899A1 (de) 2007-07-25 2008-07-11 Elektroden und lithium-ionen-zellen mit neuartigem elektrodenbinder
EP08784714A EP2179464B1 (de) 2007-07-25 2008-07-11 Elektroden und lithium-ionen-zellen mit neuartigem elektrodenbinder
CN200880100231A CN101796675A (zh) 2007-07-25 2008-07-11 具有新型电极粘合剂的电极和锂离子电池
AT08784714T ATE538510T1 (de) 2007-07-25 2008-07-11 Elektroden und lithium-ionen-zellen mit neuartigem elektrodenbinder
US12/668,916 US9653733B2 (en) 2007-07-25 2008-07-11 Electrodes and lithium-ion cells with a novel electrode binder
KR1020107000824A KR20100034007A (ko) 2007-07-25 2008-07-11 신규한 전극 결합제를 갖는 리튬-이온 전지 및 전극
JP2010517292A JP2010534392A (ja) 2007-07-25 2008-07-11 電極、および新規電極結合剤を備えるリチウムイオン電池

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102007036653A DE102007036653A1 (de) 2007-07-25 2007-07-25 Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder

Publications (1)

Publication Number Publication Date
DE102007036653A1 true DE102007036653A1 (de) 2009-02-05

Family

ID=39765262

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102007036653A Withdrawn DE102007036653A1 (de) 2007-07-25 2007-07-25 Elektroden und Lithium-Ionen-Zellen mit neuartigem Elektrodenbinder

Country Status (9)

Country Link
US (1) US9653733B2 (und)
EP (1) EP2179464B1 (und)
JP (1) JP2010534392A (und)
KR (1) KR20100034007A (und)
CN (1) CN101796675A (und)
AT (1) ATE538510T1 (und)
DE (1) DE102007036653A1 (und)
ES (1) ES2378006T3 (und)
WO (1) WO2009012899A1 (und)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008063552A1 (de) 2008-12-05 2010-06-10 Varta Microbattery Gmbh Neues Elektrodenaktivmaterial für elektrochemische Elemente
CN109086469A (zh) * 2018-03-09 2018-12-25 重庆科技学院 基于递归神经网络与偏好信息的铝电解建模与优化方法

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2228854B1 (en) * 2009-03-12 2014-03-05 Belenos Clean Power Holding AG Nitride and carbide anode materials
KR101198295B1 (ko) 2009-10-22 2012-11-07 주식회사 엘지화학 리튬 이차전지용 음극 활물질층의 형성방법, 이로부터 형성된 리튬 이차전지용 음극 및 이를 구비한 리튬 이차전지
DE102009056756B4 (de) 2009-12-04 2020-10-15 Schott Ag Material für Batterie-Elektroden, dieses enthaltende Batterie-Elektroden sowie Batterien mit diesen Elektroden und Verfahren zu deren Herstellung
IT1396948B1 (it) * 2009-12-16 2012-12-20 Italghisa S P A Pasta elettrodica per elettrodi in grafite privi di "binder" a base idrocarburica
DE102010039416A1 (de) 2010-08-17 2012-02-23 Varta Micro Innovation Gmbh Flexible Batterieelektroden und ihre Herstellung
DE102010044008A1 (de) 2010-11-16 2012-05-16 Varta Micro Innovation Gmbh Lithium-Ionen-Zelle mit verbessertem Alterungsverhalten
DE102011004233A1 (de) 2011-02-16 2012-08-16 Varta Micro Innovation Gmbh Elektroden für Batterien, insbesondere für Lithium-Ionen-Batterien, und ihre Herstellung
US10763490B2 (en) 2011-09-30 2020-09-01 Ppg Industries Ohio, Inc. Methods of coating an electrically conductive substrate and related electrodepositable compositions including graphenic carbon particles
US9150736B2 (en) * 2012-11-27 2015-10-06 Ppg Industries Ohio, Inc. Methods of coating an electrically conductive substrate and related electrodepositable compositions
US9870844B2 (en) 2012-11-27 2018-01-16 Ppg Industries Ohio, Inc. Methods of coating an electrically conductive substrate and related electrodepositable compositions
KR101875950B1 (ko) * 2011-12-20 2018-07-12 한국과학기술원 실리콘-기공성 탄소 복합 나노입자를 포함하는 리튬이차전지 음극 활물질 제조방법, 이에 의하여 제조된 리튬이차전지 음극 활물질 및 이를 포함하는 리튬이차전지
DE102012203447A1 (de) 2012-03-05 2013-09-05 Volkswagen Varta Microbattery Forschungsgesellschaft Mbh & Co. Kg Elektrolyt für Lithium-Ionen-Batterien
CN103782428B (zh) * 2012-08-28 2019-04-09 株式会社Lg化学 无内部短路的锂离子二次电池
KR101428246B1 (ko) * 2012-12-05 2014-08-08 한국과학기술원 금속이온 이동 억제용 리튬이차전지 전극 바인더 물질 및 이를 포함하는 리튬이차전지
EP2793303B1 (de) 2013-04-16 2017-08-09 VARTA Micro Innovation GmbH Lithium-Ionen-Zelle mit optimierter Elektrodenkinetik
WO2014197242A1 (en) 2013-06-04 2014-12-11 Dow Global Technologies Llc Process for manufacturing lithium carboxymethyl cellulose
EP3295501A4 (en) * 2015-05-15 2019-01-23 COMPOSITE MATERIALS TECHNOLOGY, Inc. IMPROVED HIGH CAPACITIVE BATTERY
EP3358658A4 (en) * 2015-10-01 2019-06-26 Showa Denko K.K. GRANULAR COMPOUND FOR PREPARING A NEGATIVE ELECTRODE OF A LITHIUM ION SECONDARY CELL
WO2018045339A1 (en) 2016-09-01 2018-03-08 Composite Materials Technology, Inc. Nano-scale/nanostructured si coating on valve metal substrate for lib anodes
JP6965534B2 (ja) * 2017-03-14 2021-11-10 Jsr株式会社 蓄電デバイス電極用組成物、蓄電デバイス電極用スラリー、蓄電デバイス電極及び蓄電デバイス
KR20200090820A (ko) * 2017-11-24 2020-07-29 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 흑연/규소 애노드용 pvdf 결합제

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5296318A (en) 1993-03-05 1994-03-22 Bell Communications Research, Inc. Rechargeable lithium intercalation battery with hybrid polymeric electrolyte
EP0836238A1 (en) * 1995-06-28 1998-04-15 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery
EP0895295A1 (en) * 1996-02-16 1999-02-03 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery
DE69900860T2 (de) * 1998-07-16 2002-10-02 Koninkl Philips Electronics Nv Lithium-sekundärbatterie
EP1261048A2 (de) 2001-05-25 2002-11-27 Microbatterie GmbH Verfahren zur Herstellung von Elektrodenfolien für galvanische Elemente
EP1489673A1 (en) 2003-06-20 2004-12-22 Samsung SDI Co., Ltd. Anode compostition for lithium battery, and anode and lithium battery using the same

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3877983A (en) * 1973-05-14 1975-04-15 Du Pont Thin film polymer-bonded cathode
EP0762521B1 (en) 1995-09-06 1999-03-10 Fuji Photo Film Co., Ltd. Lithium ion secondary battery
EP0855752B1 (en) 1997-01-28 2006-11-29 Canon Kabushiki Kaisha Electrode structural body, rechargeable battery provided with said electrode structural body, and process for the production of said electrode structural body and said rechargeable battery
JP4227581B2 (ja) * 1997-01-28 2009-02-18 キヤノン株式会社 電極構造体及び二次電池
JPH10233207A (ja) 1997-02-17 1998-09-02 Toyota Central Res & Dev Lab Inc リチウム二次電池用負極
JPH11219724A (ja) * 1998-01-30 1999-08-10 Hitachi Maxell Ltd アルカリ金属イオン電池の製造方法
JP2000012014A (ja) 1998-06-10 2000-01-14 Jurgen Otto Besenhard 非水系二次電池
JP4636650B2 (ja) * 2000-04-06 2011-02-23 日立マクセル株式会社 非水二次電池
JP2002008647A (ja) * 2000-06-23 2002-01-11 Ryoji Mishima 非水電解質二次電池負極材
JP2003142103A (ja) * 2001-11-07 2003-05-16 Matsushita Electric Ind Co Ltd 非水電解質二次電池
JP2003168433A (ja) * 2001-12-03 2003-06-13 Hitachi Powdered Metals Co Ltd 非水系二次電池の負極用黒鉛粒子
JP2004087227A (ja) 2002-08-26 2004-03-18 Mitsui Mining Co Ltd リチウム二次電池用負極
US6852449B2 (en) 2002-08-29 2005-02-08 Quallion Llc Negative electrode including a carbonaceous material for a nonaqueous battery
JP2004146296A (ja) * 2002-10-28 2004-05-20 Matsushita Electric Ind Co Ltd リチウムイオン二次電池
JP4385589B2 (ja) * 2002-11-26 2009-12-16 昭和電工株式会社 負極材料及びそれを用いた二次電池
JP2005005113A (ja) * 2003-06-11 2005-01-06 Toshiba Corp 非水電解質二次電池
KR100560546B1 (ko) 2003-11-27 2006-03-15 삼성에스디아이 주식회사 리튬 이차 전지용 음극 및 이를 포함하는 리튬 이차 전지
JP4815805B2 (ja) * 2005-01-14 2011-11-16 パナソニック株式会社 非水電解質二次電池
JP2007087789A (ja) 2005-09-22 2007-04-05 Hitachi Cable Ltd リチウムイオン二次電池用負極及びその製造方法
JP2007095641A (ja) * 2005-09-26 2007-04-12 Masaru Sugita 電池構成材料
CN101313428B (zh) * 2005-12-06 2010-08-25 Lg化学株式会社 安全性加强的电极以及具有该电极的电化学装置
KR100906250B1 (ko) * 2006-09-04 2009-07-07 주식회사 엘지화학 바인더로서 고중합도 폴리비닐알콜과 폴리비닐피롤리돈의혼합물을 포함하는 전극 합제 및 이를 포함하는 리튬이차전지
JP5078330B2 (ja) * 2006-11-29 2012-11-21 三洋電機株式会社 非水電解質二次電池用負極極板及びこの負極極板を用いた非水電解質二次電池

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5296318A (en) 1993-03-05 1994-03-22 Bell Communications Research, Inc. Rechargeable lithium intercalation battery with hybrid polymeric electrolyte
EP0836238A1 (en) * 1995-06-28 1998-04-15 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery
EP0895295A1 (en) * 1996-02-16 1999-02-03 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery
DE69900860T2 (de) * 1998-07-16 2002-10-02 Koninkl Philips Electronics Nv Lithium-sekundärbatterie
EP1261048A2 (de) 2001-05-25 2002-11-27 Microbatterie GmbH Verfahren zur Herstellung von Elektrodenfolien für galvanische Elemente
EP1489673A1 (en) 2003-06-20 2004-12-22 Samsung SDI Co., Ltd. Anode compostition for lithium battery, and anode and lithium battery using the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008063552A1 (de) 2008-12-05 2010-06-10 Varta Microbattery Gmbh Neues Elektrodenaktivmaterial für elektrochemische Elemente
CN109086469A (zh) * 2018-03-09 2018-12-25 重庆科技学院 基于递归神经网络与偏好信息的铝电解建模与优化方法
CN109086469B (zh) * 2018-03-09 2022-11-11 重庆科技学院 基于递归神经网络与偏好信息的铝电解建模与优化方法

Also Published As

Publication number Publication date
CN101796675A (zh) 2010-08-04
EP2179464A1 (de) 2010-04-28
EP2179464B1 (de) 2011-12-21
JP2010534392A (ja) 2010-11-04
US9653733B2 (en) 2017-05-16
KR20100034007A (ko) 2010-03-31
ES2378006T3 (es) 2012-04-04
WO2009012899A1 (de) 2009-01-29
ATE538510T1 (de) 2012-01-15
US20100239915A1 (en) 2010-09-23

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