DE09739136T1 - Verfahren und vorrichtung zur carbonylierung von methanol mit einem mit essigsäure angereicherten flashstrom - Google Patents
Verfahren und vorrichtung zur carbonylierung von methanol mit einem mit essigsäure angereicherten flashstrom Download PDFInfo
- Publication number
- DE09739136T1 DE09739136T1 DE9739136T DE09739136T DE09739136T1 DE 09739136 T1 DE09739136 T1 DE 09739136T1 DE 9739136 T DE9739136 T DE 9739136T DE 09739136 T DE09739136 T DE 09739136T DE 09739136 T1 DE09739136 T1 DE 09739136T1
- Authority
- DE
- Germany
- Prior art keywords
- reaction mixture
- temperature
- product stream
- carbonylation process
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract 45
- 238000000034 method Methods 0.000 title claims abstract 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract 15
- 239000011541 reaction mixture Substances 0.000 claims abstract 36
- 230000006315 carbonylation Effects 0.000 claims abstract 23
- 238000005810 carbonylation reaction Methods 0.000 claims abstract 23
- 239000012043 crude product Substances 0.000 claims abstract 15
- 239000007788 liquid Substances 0.000 claims abstract 13
- 239000003054 catalyst Substances 0.000 claims abstract 9
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims abstract 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 7
- 229910052751 metal Inorganic materials 0.000 claims abstract 6
- 239000002184 metal Substances 0.000 claims abstract 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims abstract 5
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims abstract 5
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims abstract 3
- 239000000047 product Substances 0.000 claims 8
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims 5
- 150000004694 iodide salts Chemical class 0.000 claims 2
- 239000012264 purified product Substances 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 239000010948 rhodium Substances 0.000 claims 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/06—Flash distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
- B01J14/005—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
- B01L3/06—Crystallising dishes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C07C51/445—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by steam distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
- B01J2219/00213—Fixed parameter value
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
- B01J2219/0024—Control algorithm taking actions modifying the operating conditions other than of the reactor or heat exchange system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Clinical Laboratory Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US150481 | 1980-05-16 | ||
| US12/150,481 US7820855B2 (en) | 2008-04-29 | 2008-04-29 | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| EP09739136.1A EP2323755B1 (en) | 2008-04-29 | 2009-04-23 | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| PCT/US2009/002506 WO2009134333A1 (en) | 2008-04-29 | 2009-04-23 | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE09739136T1 true DE09739136T1 (de) | 2012-01-19 |
Family
ID=41018460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE9739136T Pending DE09739136T1 (de) | 2008-04-29 | 2009-04-23 | Verfahren und vorrichtung zur carbonylierung von methanol mit einem mit essigsäure angereicherten flashstrom |
Country Status (19)
| Country | Link |
|---|---|
| US (7) | US7820855B2 (enExample) |
| EP (2) | EP3002057B1 (enExample) |
| JP (1) | JP5507544B2 (enExample) |
| KR (1) | KR20110003555A (enExample) |
| CN (1) | CN102015088B (enExample) |
| AR (1) | AR074141A1 (enExample) |
| AU (1) | AU2009241844A1 (enExample) |
| BR (1) | BRPI0911487B1 (enExample) |
| CA (1) | CA2721922C (enExample) |
| CL (1) | CL2009001003A1 (enExample) |
| DE (1) | DE09739136T1 (enExample) |
| ES (2) | ES2365906T3 (enExample) |
| MX (3) | MX2010011852A (enExample) |
| NZ (1) | NZ588701A (enExample) |
| RU (1) | RU2508162C2 (enExample) |
| SG (1) | SG190600A1 (enExample) |
| TW (1) | TW200946493A (enExample) |
| WO (1) | WO2009134333A1 (enExample) |
| ZA (2) | ZA201007491B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| KR101020844B1 (ko) * | 2008-09-04 | 2011-03-09 | 삼성전기주식회사 | 구리 나노입자의 저온 환원 소결을 위한 환원제 및 이를이용한 저온 소결 방법 |
| CN102093198B (zh) * | 2009-12-15 | 2012-12-05 | 上海吴泾化工有限公司 | 一种生产乙酸的方法 |
| CN102093196B (zh) * | 2009-12-15 | 2013-03-06 | 上海吴泾化工有限公司 | 一种链烷醇和/或其活性衍生物的羰基化制备羧酸的方法 |
| US8877963B2 (en) * | 2010-09-28 | 2014-11-04 | Celanese International Corporation | Production of acetic acid with high conversion rate |
| US8394988B2 (en) | 2010-09-28 | 2013-03-12 | Celanese International Corporation | Production of acetic acid with high conversion rate |
| US8637698B2 (en) * | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
| MY161174A (en) | 2010-12-15 | 2017-04-14 | Daicel Corp | Process for producing acetic acid |
| WO2012081417A1 (ja) | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
| US9663437B2 (en) | 2011-09-13 | 2017-05-30 | Celanese International Corporation | Production of acetic acid with high conversion rate |
| BR112013007324B1 (pt) * | 2012-02-08 | 2020-10-20 | Celanese International Corporation | produção de ácido acético com alta taxa de conversão |
| TWI547477B (zh) * | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| AR094541A1 (es) * | 2013-01-25 | 2015-08-12 | Daicel Corp | Procedimiento para producir ácido carboxílico |
| US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
| ES2773602T3 (es) * | 2014-11-14 | 2020-07-13 | Celanese Int Corp | Procedimiento de vaporización instantánea de un medio de reacción que comprende acetato de litio |
| US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9382186B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for producing acetic acid |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| WO2017057142A1 (ja) * | 2015-09-30 | 2017-04-06 | 株式会社ダイセル | 酢酸の製造方法及び製造装置 |
| US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
| WO2018163448A1 (ja) * | 2017-03-08 | 2018-09-13 | 株式会社ダイセル | 酢酸の製造方法 |
| US10457622B2 (en) | 2017-03-08 | 2019-10-29 | Daicel Corporation | Method for producing acetic acid |
| CN110191874A (zh) * | 2017-03-28 | 2019-08-30 | 株式会社大赛璐 | 乙酸的制备方法 |
| US10308581B2 (en) | 2017-03-28 | 2019-06-04 | Daicel Corporation | Method for producing acetic acid |
| CN111646894B (zh) * | 2019-09-10 | 2021-12-10 | 上海浦景化工技术股份有限公司 | 一种低压甲醇羰基化合成醋酸的方法 |
| GB202015833D0 (en) | 2020-10-06 | 2020-11-18 | Bp Chem Int Ltd | Separation process and apparatus |
| CN117120408B (zh) * | 2021-04-02 | 2024-05-07 | 利安德巴塞尔乙酰有限责任公司 | 用于生产乙酸的方法和系统 |
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| US7790920B2 (en) | 2008-09-11 | 2010-09-07 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| US8637699B2 (en) | 2011-04-15 | 2014-01-28 | Lyondell Chemical Technology, L.P. | Process for the manufacture of acetic acid |
| JP5802550B2 (ja) | 2011-12-28 | 2015-10-28 | 株式会社東芝 | 水位計測装置 |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
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