AR074141A1 - Metodo y aparato para carbonilar metanol con corriente de expansion enriquecida con acido acetico - Google Patents
Metodo y aparato para carbonilar metanol con corriente de expansion enriquecida con acido aceticoInfo
- Publication number
- AR074141A1 AR074141A1 ARP090101531A ARP090101531A AR074141A1 AR 074141 A1 AR074141 A1 AR 074141A1 AR P090101531 A ARP090101531 A AR P090101531A AR P090101531 A ARP090101531 A AR P090101531A AR 074141 A1 AR074141 A1 AR 074141A1
- Authority
- AR
- Argentina
- Prior art keywords
- reaction mixture
- acetic acid
- crude product
- vessel
- temperature
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/06—Flash distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
- B01J14/005—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
- B01L3/06—Crystallising dishes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C07C51/445—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by steam distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
- B01J2219/00213—Fixed parameter value
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
- B01J2219/0024—Control algorithm taking actions modifying the operating conditions other than of the reactor or heat exchange system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Clinical Laboratory Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Un procedimiento de carbonilacion para producir ácido acético que incluye: (a) carbonilar metanol o sus derivados reactivos en presencia de un catalizador de metal de Grupo VIII y promotor de ioduro metilo para producir una mezcla de reaccion líquida que incluye ácido acético, agua, acetato de metilo e ioduro de metilo; (b) alimentar la mezcla de reaccion líquida a una temperatura de alimentacion hasta un vaso de expansion que se mantiene a presion reducida; (c) calentar el vaso de expansion mientras concurrentemente se expande por vaporizacion la mezcla de reaccion para producir una corriente de vapor de producto crudo, en donde la mezcla de reaccion es seleccionada y el caudal de flujo de la mezcla de reaccion alimentada al vaso de expansion así como la cantidad de calor suministrado al vaso de expansion se controla de modo que la temperatura de la corriente de vapor de producto crudo se mantiene a una temperatura de menos de 90°F más fría que la temperatura de alimentacion de la mezcla de reaccion líquida hasta la caldera de vaporizacion rápida y la concentracion de ácido acético en la corriente de vapor de producto crudo es mayor al 70% en peso de la corriente de vapor de producto crudo. Reivindicacion 23: El aparato de acuerdo con la reivindicacion 22, que además comprende un vaso de convertidor acoplado al reactor y a la caldera de vaporizacion rápida.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/150,481 US7820855B2 (en) | 2008-04-29 | 2008-04-29 | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
Publications (1)
Publication Number | Publication Date |
---|---|
AR074141A1 true AR074141A1 (es) | 2010-12-29 |
Family
ID=41018460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP090101531A AR074141A1 (es) | 2008-04-29 | 2009-04-29 | Metodo y aparato para carbonilar metanol con corriente de expansion enriquecida con acido acetico |
Country Status (20)
Country | Link |
---|---|
US (7) | US7820855B2 (es) |
EP (2) | EP3002057B1 (es) |
JP (1) | JP5507544B2 (es) |
KR (1) | KR20110003555A (es) |
CN (1) | CN102015088B (es) |
AR (1) | AR074141A1 (es) |
AU (1) | AU2009241844A1 (es) |
BR (1) | BRPI0911487B1 (es) |
CA (1) | CA2721922C (es) |
CL (1) | CL2009001003A1 (es) |
DE (1) | DE09739136T1 (es) |
ES (2) | ES2365906T3 (es) |
HK (1) | HK1156560A1 (es) |
MX (3) | MX338852B (es) |
NZ (1) | NZ588701A (es) |
RU (1) | RU2508162C2 (es) |
SG (1) | SG190600A1 (es) |
TW (1) | TW200946493A (es) |
WO (1) | WO2009134333A1 (es) |
ZA (2) | ZA201007491B (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
KR101020844B1 (ko) * | 2008-09-04 | 2011-03-09 | 삼성전기주식회사 | 구리 나노입자의 저온 환원 소결을 위한 환원제 및 이를이용한 저온 소결 방법 |
CN102093198B (zh) * | 2009-12-15 | 2012-12-05 | 上海吴泾化工有限公司 | 一种生产乙酸的方法 |
CN102093196B (zh) * | 2009-12-15 | 2013-03-06 | 上海吴泾化工有限公司 | 一种链烷醇和/或其活性衍生物的羰基化制备羧酸的方法 |
US8877963B2 (en) * | 2010-09-28 | 2014-11-04 | Celanese International Corporation | Production of acetic acid with high conversion rate |
US8394988B2 (en) | 2010-09-28 | 2013-03-12 | Celanese International Corporation | Production of acetic acid with high conversion rate |
US8637698B2 (en) * | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
CN103370300B (zh) * | 2010-12-15 | 2016-07-06 | 株式会社大赛璐 | 乙酸的制备方法 |
SG190941A1 (en) | 2010-12-15 | 2013-08-30 | Daicel Corp | Process for producing acetic acid |
US9663437B2 (en) | 2011-09-13 | 2017-05-30 | Celanese International Corporation | Production of acetic acid with high conversion rate |
CN103402965A (zh) * | 2012-02-08 | 2013-11-20 | 国际人造丝公司 | 以高的转化率生产乙酸 |
TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
AR094541A1 (es) * | 2013-01-25 | 2015-08-12 | Daicel Corp | Procedimiento para producir ácido carboxílico |
EP3218346B1 (en) * | 2014-11-14 | 2019-11-27 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
US9382186B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for producing acetic acid |
US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
WO2017057142A1 (ja) | 2015-09-30 | 2017-04-06 | 株式会社ダイセル | 酢酸の製造方法及び製造装置 |
US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
BR112019017819A2 (pt) * | 2017-03-08 | 2020-03-31 | Daicel Corporation | Método para produzir ácido acético |
US10457622B2 (en) | 2017-03-08 | 2019-10-29 | Daicel Corporation | Method for producing acetic acid |
WO2018179457A1 (ja) * | 2017-03-28 | 2018-10-04 | 株式会社ダイセル | 酢酸の製造方法 |
US10308581B2 (en) | 2017-03-28 | 2019-06-04 | Daicel Corporation | Method for producing acetic acid |
CN111646894B (zh) * | 2019-09-10 | 2021-12-10 | 上海浦景化工技术股份有限公司 | 一种低压甲醇羰基化合成醋酸的方法 |
CN117120408B (zh) * | 2021-04-02 | 2024-05-07 | 利安德巴塞尔乙酰有限责任公司 | 用于生产乙酸的方法和系统 |
Family Cites Families (51)
Publication number | Priority date | Publication date | Assignee | Title |
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US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
SU791735A1 (ru) * | 1977-07-27 | 1980-12-30 | Ереванский ордена Трудового Красного Знамени государственный университет | Способ очистки соли карбоновой кислоты |
NL8204901A (nl) | 1981-12-30 | 1983-07-18 | Halcon Sd Group Inc | Zuivering van carbonyleringsprodukten. |
US5144068A (en) * | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5026908A (en) * | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5001259A (en) * | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
ES2055322T3 (es) * | 1989-04-06 | 1994-08-16 | Bp Chem Int Ltd | Proceso para preparar acidos carboxilicos. |
US4976947A (en) * | 1990-02-20 | 1990-12-11 | Eastman Kodak Company | Process for the recovery of elemental iodine from alkyl iodides |
GB9120902D0 (en) * | 1991-10-02 | 1991-11-13 | Bp Chem Int Ltd | Purification process |
US5334755A (en) | 1992-04-24 | 1994-08-02 | Chiyoda Corporation | Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst |
GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
CN1043525C (zh) | 1992-08-13 | 1999-06-02 | 化学工业部西南化工研究院 | 甲醇低压液相羰基合成醋酸反应方法 |
US5672743A (en) | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
US5990347A (en) * | 1993-03-26 | 1999-11-23 | Bp Chemicals Limited | Process for preparing a carboxylic acid |
GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
US5352415A (en) | 1993-09-29 | 1994-10-04 | Hoechst Celanese Corporation | Control system for acetic acid manufacturing process |
JP3308392B2 (ja) * | 1994-06-02 | 2002-07-29 | ダイセル化学工業株式会社 | カルボニル化反応方法 |
JP3306227B2 (ja) | 1994-07-06 | 2002-07-24 | ダイセル化学工業株式会社 | 酢酸および/または無水酢酸の製造法 |
JP3413536B2 (ja) | 1994-06-20 | 2003-06-03 | 石川島播磨重工業株式会社 | 液圧駆動型水中音源装置 |
FR2726556B1 (fr) * | 1994-11-04 | 1996-12-20 | Rhone Poulenc Chimie | Procede de preparation d'acides carboxyliques par carbonylation en presence d'iridium |
GB9503385D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
WO1996033965A1 (fr) * | 1995-04-27 | 1996-10-31 | Daicel Chemical Industries, Ltd. | Procede de production d'acide acetique |
US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
GB9517184D0 (en) | 1995-08-22 | 1995-10-25 | Bp Chem Int Ltd | Process |
KR100462697B1 (ko) * | 1995-10-27 | 2005-02-28 | 씨엔에이 홀딩즈 인코포레이티드 | 부식금속을제거하여카보닐화촉매용액의생산성을증진시키는방법 |
IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
GB9625335D0 (en) * | 1996-12-05 | 1997-01-22 | Bp Chem Int Ltd | Process |
GB9626428D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9626324D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9626317D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9626429D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
US6066762A (en) * | 1996-12-30 | 2000-05-23 | Chiyoda Corporation | Process for the production of carbonyl compound |
US6114576A (en) * | 1997-12-18 | 2000-09-05 | Uop Llc | Carbonylation process with integrated heat exchange |
US6153792A (en) * | 1997-12-18 | 2000-11-28 | Uop Llc | Carbonylation process using a flash step with washing |
JP4242952B2 (ja) | 1998-08-31 | 2009-03-25 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
US6552221B1 (en) | 1998-12-18 | 2003-04-22 | Millenium Petrochemicals, Inc. | Process control for acetic acid manufacture |
US6221405B1 (en) | 1999-05-11 | 2001-04-24 | Jac Pac Foods, Ltd. | Method of bonding and tenderizing meat |
US6303813B1 (en) | 1999-08-31 | 2001-10-16 | Celanese International Corporation | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
US6627770B1 (en) * | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
US6657078B2 (en) * | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
JP4489487B2 (ja) | 2004-04-02 | 2010-06-23 | ダイセル化学工業株式会社 | ヨウ化水素の分離方法 |
JP4732743B2 (ja) | 2004-12-06 | 2011-07-27 | ダイセル化学工業株式会社 | 蒸留方法 |
US7855306B2 (en) | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
EP2093209A1 (en) * | 2008-02-19 | 2009-08-26 | BP Chemicals Limited | Process for the production of acetic acid |
US7820855B2 (en) * | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
EP2297080A2 (en) | 2008-06-28 | 2011-03-23 | Pretium Ventures AA, LLC | Compositions for carboxylic acid production and methods for making and using same |
US7790920B2 (en) | 2008-09-11 | 2010-09-07 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
US8637699B2 (en) | 2011-04-15 | 2014-01-28 | Lyondell Chemical Technology, L.P. | Process for the manufacture of acetic acid |
JP5802550B2 (ja) | 2011-12-28 | 2015-10-28 | 株式会社東芝 | 水位計測装置 |
TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
-
2008
- 2008-04-29 US US12/150,481 patent/US7820855B2/en active Active
-
2009
- 2009-04-08 TW TW098111613A patent/TW200946493A/zh unknown
- 2009-04-23 SG SG2013032586A patent/SG190600A1/en unknown
- 2009-04-23 NZ NZ588701A patent/NZ588701A/en not_active IP Right Cessation
- 2009-04-23 EP EP15002793.6A patent/EP3002057B1/en active Active
- 2009-04-23 EP EP09739136.1A patent/EP2323755B1/en active Active
- 2009-04-23 WO PCT/US2009/002506 patent/WO2009134333A1/en active Application Filing
- 2009-04-23 MX MX2014001618A patent/MX338852B/es unknown
- 2009-04-23 CN CN200980115410.8A patent/CN102015088B/zh active Active
- 2009-04-23 MX MX2010011852A patent/MX2010011852A/es active IP Right Grant
- 2009-04-23 MX MX2015017656A patent/MX364125B/es unknown
- 2009-04-23 ES ES09739136.1T patent/ES2365906T3/es active Active
- 2009-04-23 KR KR1020107026617A patent/KR20110003555A/ko not_active Application Discontinuation
- 2009-04-23 ES ES15002793.6T patent/ES2694014T3/es active Active
- 2009-04-23 BR BRPI0911487-4A patent/BRPI0911487B1/pt active IP Right Grant
- 2009-04-23 RU RU2010148399/05A patent/RU2508162C2/ru not_active IP Right Cessation
- 2009-04-23 CA CA2721922A patent/CA2721922C/en active Active
- 2009-04-23 DE DE9739136T patent/DE09739136T1/de active Pending
- 2009-04-23 JP JP2011507417A patent/JP5507544B2/ja active Active
- 2009-04-23 AU AU2009241844A patent/AU2009241844A1/en not_active Abandoned
- 2009-04-28 CL CL2009001003A patent/CL2009001003A1/es unknown
- 2009-04-29 AR ARP090101531A patent/AR074141A1/es not_active Application Discontinuation
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2010
- 2010-09-23 US US12/924,234 patent/US8329944B2/en active Active
- 2010-10-20 ZA ZA2010/07491A patent/ZA201007491B/en unknown
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2011
- 2011-03-22 ZA ZA2011/02114A patent/ZA201102114B/en unknown
- 2011-10-13 HK HK11110937.2A patent/HK1156560A1/xx not_active IP Right Cessation
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2012
- 2012-11-05 US US13/668,577 patent/US8771616B2/en active Active
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2014
- 2014-07-08 US US14/325,773 patent/US8987512B2/en active Active
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2015
- 2015-03-09 US US14/642,327 patent/US9840451B2/en active Active
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2017
- 2017-11-09 US US15/808,401 patent/US10118885B2/en active Active
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2018
- 2018-10-25 US US16/170,781 patent/US10519089B2/en active Active
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