BRPI0911487A2 - método e aparelho de carbonilação para produzir ácido acético - Google Patents

método e aparelho de carbonilação para produzir ácido acético

Info

Publication number
BRPI0911487A2
BRPI0911487A2 BRPI0911487A BRPI0911487A BRPI0911487A2 BR PI0911487 A2 BRPI0911487 A2 BR PI0911487A2 BR PI0911487 A BRPI0911487 A BR PI0911487A BR PI0911487 A BRPI0911487 A BR PI0911487A BR PI0911487 A2 BRPI0911487 A2 BR PI0911487A2
Authority
BR
Brazil
Prior art keywords
acetic acid
producing acetic
carbonylation method
carbonylation
producing
Prior art date
Application number
BRPI0911487A
Other languages
English (en)
Inventor
Jeremy J Patt
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BRPI0911487A2 publication Critical patent/BRPI0911487A2/pt
Publication of BRPI0911487B1 publication Critical patent/BRPI0911487B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06Flash distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • B01J14/005Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01LCHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/06Crystallising dishes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/43Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C07C51/445Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by steam distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08Acetic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00193Sensing a parameter
    • B01J2219/00195Sensing a parameter of the reaction system
    • B01J2219/00202Sensing a parameter of the reaction system at the reactor outlet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00211Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/00213Fixed parameter value
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00222Control algorithm taking actions
    • B01J2219/00227Control algorithm taking actions modifying the operating conditions
    • B01J2219/0024Control algorithm taking actions modifying the operating conditions other than of the reactor or heat exchange system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231Halogen-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
BRPI0911487-4A 2008-04-29 2009-04-23 “Processo de carbonilação para produção de ácido acético e aparelho para produção de ácido acético" BRPI0911487B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/150,481 US7820855B2 (en) 2008-04-29 2008-04-29 Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
US12/150,481 2008-04-29
PCT/US2009/002506 WO2009134333A1 (en) 2008-04-29 2009-04-23 Method and apparatus for carbonylating methanol with acetic acid enriched flash stream

Publications (2)

Publication Number Publication Date
BRPI0911487A2 true BRPI0911487A2 (pt) 2016-01-05
BRPI0911487B1 BRPI0911487B1 (pt) 2018-02-06

Family

ID=41018460

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0911487-4A BRPI0911487B1 (pt) 2008-04-29 2009-04-23 “Processo de carbonilação para produção de ácido acético e aparelho para produção de ácido acético"

Country Status (20)

Country Link
US (7) US7820855B2 (pt)
EP (2) EP3002057B1 (pt)
JP (1) JP5507544B2 (pt)
KR (1) KR20110003555A (pt)
CN (1) CN102015088B (pt)
AR (1) AR074141A1 (pt)
AU (1) AU2009241844A1 (pt)
BR (1) BRPI0911487B1 (pt)
CA (1) CA2721922C (pt)
CL (1) CL2009001003A1 (pt)
DE (1) DE09739136T1 (pt)
ES (2) ES2365906T3 (pt)
HK (1) HK1156560A1 (pt)
MX (3) MX338852B (pt)
NZ (1) NZ588701A (pt)
RU (1) RU2508162C2 (pt)
SG (1) SG190600A1 (pt)
TW (1) TW200946493A (pt)
WO (1) WO2009134333A1 (pt)
ZA (2) ZA201007491B (pt)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7820855B2 (en) * 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
KR101020844B1 (ko) * 2008-09-04 2011-03-09 삼성전기주식회사 구리 나노입자의 저온 환원 소결을 위한 환원제 및 이를이용한 저온 소결 방법
CN102093198B (zh) * 2009-12-15 2012-12-05 上海吴泾化工有限公司 一种生产乙酸的方法
CN102093196B (zh) * 2009-12-15 2013-03-06 上海吴泾化工有限公司 一种链烷醇和/或其活性衍生物的羰基化制备羧酸的方法
US8394988B2 (en) 2010-09-28 2013-03-12 Celanese International Corporation Production of acetic acid with high conversion rate
US8877963B2 (en) * 2010-09-28 2014-11-04 Celanese International Corporation Production of acetic acid with high conversion rate
US8637698B2 (en) * 2010-11-19 2014-01-28 Celanese International Corporation Production of acetic acid with an increased production rate
JP6166043B2 (ja) * 2010-12-15 2017-07-19 株式会社ダイセル 酢酸の製造方法
MX338849B (es) 2010-12-15 2016-05-02 Daicel Corp Procedimiento para producir acido acetico.
US9663437B2 (en) 2011-09-13 2017-05-30 Celanese International Corporation Production of acetic acid with high conversion rate
BR112013007324B1 (pt) * 2012-02-08 2020-10-20 Celanese International Corporation produção de ácido acético com alta taxa de conversão
TWI547477B (zh) * 2012-03-14 2016-09-01 大賽璐股份有限公司 醋酸之製造方法
AR094541A1 (es) * 2013-01-25 2015-08-12 Daicel Corp Procedimiento para producir ácido carboxílico
US9302975B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for flashing a reaction medium
US9340481B1 (en) 2014-11-14 2016-05-17 Celanese International Corporation Process for flashing a reaction medium comprising lithium acetate
ES2773602T3 (es) * 2014-11-14 2020-07-13 Celanese Int Corp Procedimiento de vaporización instantánea de un medio de reacción que comprende acetato de litio
US9540303B2 (en) 2015-04-01 2017-01-10 Celanese International Corporation Processes for producing acetic acid
US9382186B1 (en) 2015-07-01 2016-07-05 Celanese International Corporation Process for producing acetic acid
US9302974B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for producing acetic acid
US9382183B1 (en) 2015-07-01 2016-07-05 Celanese International Corporation Process for flashing a reaction medium
US10428006B2 (en) * 2015-09-30 2019-10-01 Daicel Corporation Method and apparatus for producing acetic acid
US9416088B1 (en) 2015-10-02 2016-08-16 Celanese International Corporation Process to produce acetic acid with recycle of water
ES2817406T3 (es) * 2017-03-08 2021-04-07 Daicel Corp Método para la producción de ácido acético
US10457622B2 (en) 2017-03-08 2019-10-29 Daicel Corporation Method for producing acetic acid
US10308581B2 (en) 2017-03-28 2019-06-04 Daicel Corporation Method for producing acetic acid
ES2779805T3 (es) 2017-03-28 2020-08-19 Daicel Corp Método para la producción de ácido acético
CN111646894B (zh) * 2019-09-10 2021-12-10 上海浦景化工技术股份有限公司 一种低压甲醇羰基化合成醋酸的方法
EP4313928A1 (en) * 2021-04-02 2024-02-07 LyondellBasell Acetyls, LLC Methods and systems for producing acetic acid

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3769329A (en) 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
SU791735A1 (ru) * 1977-07-27 1980-12-30 Ереванский ордена Трудового Красного Знамени государственный университет Способ очистки соли карбоновой кислоты
NL8204901A (nl) 1981-12-30 1983-07-18 Halcon Sd Group Inc Zuivering van carbonyleringsprodukten.
US5144068A (en) * 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US5026908A (en) * 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
DE69009829T2 (de) * 1989-04-06 1994-10-13 Bp Chem Int Ltd Verfahren zur Herstellung von Carbonsäuren.
US4976947A (en) * 1990-02-20 1990-12-11 Eastman Kodak Company Process for the recovery of elemental iodine from alkyl iodides
GB9120902D0 (en) * 1991-10-02 1991-11-13 Bp Chem Int Ltd Purification process
US5334755A (en) 1992-04-24 1994-08-02 Chiyoda Corporation Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst
GB9211671D0 (en) * 1992-06-02 1992-07-15 Bp Chem Int Ltd Process
CN1043525C (zh) 1992-08-13 1999-06-02 化学工业部西南化工研究院 甲醇低压液相羰基合成醋酸反应方法
US5990347A (en) * 1993-03-26 1999-11-23 Bp Chemicals Limited Process for preparing a carboxylic acid
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
US5672743A (en) 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5352415A (en) 1993-09-29 1994-10-04 Hoechst Celanese Corporation Control system for acetic acid manufacturing process
JP3308392B2 (ja) * 1994-06-02 2002-07-29 ダイセル化学工業株式会社 カルボニル化反応方法
JP3306227B2 (ja) 1994-07-06 2002-07-24 ダイセル化学工業株式会社 酢酸および/または無水酢酸の製造法
JP3413536B2 (ja) 1994-06-20 2003-06-03 石川島播磨重工業株式会社 液圧駆動型水中音源装置
FR2726556B1 (fr) * 1994-11-04 1996-12-20 Rhone Poulenc Chimie Procede de preparation d'acides carboxyliques par carbonylation en presence d'iridium
GB9503385D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
WO1996033965A1 (fr) * 1995-04-27 1996-10-31 Daicel Chemical Industries, Ltd. Procede de production d'acide acetique
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9517184D0 (en) 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
EP0920407B1 (en) * 1995-10-27 2002-12-11 Hoechst Celanese Corporation Process for improving productivity of a carbonylation catalyst solution by removing corrosion metals
IN192600B (pt) 1996-10-18 2004-05-08 Hoechst Celanese Corp
GB9625335D0 (en) * 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626324D0 (en) 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626428D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
SG65716A1 (en) * 1996-12-30 1999-06-22 Chiyoda Chem Eng Construct Co Process for the production of carbonyl compound
US6153792A (en) * 1997-12-18 2000-11-28 Uop Llc Carbonylation process using a flash step with washing
US6114576A (en) * 1997-12-18 2000-09-05 Uop Llc Carbonylation process with integrated heat exchange
JP4242952B2 (ja) 1998-08-31 2009-03-25 ダイセル化学工業株式会社 酢酸の製造方法
US6552221B1 (en) 1998-12-18 2003-04-22 Millenium Petrochemicals, Inc. Process control for acetic acid manufacture
US6221405B1 (en) 1999-05-11 2001-04-24 Jac Pac Foods, Ltd. Method of bonding and tenderizing meat
US6303813B1 (en) 1999-08-31 2001-10-16 Celanese International Corporation Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile
US6627770B1 (en) * 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6657078B2 (en) * 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US7005541B2 (en) 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
JP4489487B2 (ja) 2004-04-02 2010-06-23 ダイセル化学工業株式会社 ヨウ化水素の分離方法
JP4732743B2 (ja) 2004-12-06 2011-07-27 ダイセル化学工業株式会社 蒸留方法
US7855306B2 (en) 2005-04-28 2010-12-21 Celanese International Corporation Process for the production of acetic acid
EP2093209A1 (en) * 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
US7820855B2 (en) * 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
CN102131758A (zh) 2008-06-28 2011-07-20 Aa保费投资公司 用于生产羧酸的组合物及其制备方法和使用方法
US7790920B2 (en) 2008-09-11 2010-09-07 Lyondell Chemical Technology, L.P. Preparation of acetic acid
US8637699B2 (en) 2011-04-15 2014-01-28 Lyondell Chemical Technology, L.P. Process for the manufacture of acetic acid
JP5802550B2 (ja) 2011-12-28 2015-10-28 株式会社東芝 水位計測装置
TWI547477B (zh) 2012-03-14 2016-09-01 大賽璐股份有限公司 醋酸之製造方法

Also Published As

Publication number Publication date
US10118885B2 (en) 2018-11-06
US8329944B2 (en) 2012-12-11
WO2009134333A1 (en) 2009-11-05
NZ588701A (en) 2012-03-30
US20130058842A1 (en) 2013-03-07
CN102015088B (zh) 2014-06-11
US20110021817A1 (en) 2011-01-27
US20140323760A1 (en) 2014-10-30
MX338852B (es) 2016-05-02
TW200946493A (en) 2009-11-16
US8987512B2 (en) 2015-03-24
ES2365906T1 (es) 2011-10-13
US20180065911A1 (en) 2018-03-08
JP5507544B2 (ja) 2014-05-28
CA2721922A1 (en) 2009-11-05
US20150175516A1 (en) 2015-06-25
US8771616B2 (en) 2014-07-08
RU2508162C2 (ru) 2014-02-27
CN102015088A (zh) 2011-04-13
KR20110003555A (ko) 2011-01-12
ES2694014T3 (es) 2018-12-17
EP2323755A1 (en) 2011-05-25
BRPI0911487B1 (pt) 2018-02-06
AR074141A1 (es) 2010-12-29
CA2721922C (en) 2013-09-24
US20090270650A1 (en) 2009-10-29
SG190600A1 (en) 2013-06-28
MX2010011852A (es) 2010-12-02
ZA201102114B (en) 2012-01-25
US7820855B2 (en) 2010-10-26
RU2010148399A (ru) 2012-06-10
HK1156560A1 (en) 2012-06-15
US10519089B2 (en) 2019-12-31
MX364125B (es) 2019-04-12
ZA201007491B (en) 2012-01-25
CL2009001003A1 (es) 2010-06-04
ES2365906T3 (es) 2017-11-30
DE09739136T1 (de) 2012-01-19
EP2323755B1 (en) 2017-07-26
EP3002057A1 (en) 2016-04-06
US9840451B2 (en) 2017-12-12
EP3002057B1 (en) 2018-10-24
JP2011518880A (ja) 2011-06-30
US20190062249A1 (en) 2019-02-28
AU2009241844A1 (en) 2009-11-05

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