CN1398272A - 丙烯抗冲共聚物 - Google Patents

丙烯抗冲共聚物 Download PDF

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Publication number
CN1398272A
CN1398272A CN01804671A CN01804671A CN1398272A CN 1398272 A CN1398272 A CN 1398272A CN 01804671 A CN01804671 A CN 01804671A CN 01804671 A CN01804671 A CN 01804671A CN 1398272 A CN1398272 A CN 1398272A
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component
zirconium
rac
ipr
propylene
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Chinese (zh)
Inventor
T·J·伯克哈特
D·C·怀泽
R·T·李
U·M·斯特林
W·T·小海古德
F·C·里克斯
A·K·梅塔
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication of CN1398272A publication Critical patent/CN1398272A/zh
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN01804671A 2000-02-08 2001-02-08 丙烯抗冲共聚物 Pending CN1398272A (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US18101600P 2000-02-08 2000-02-08
US60/181,016 2000-02-08
US09/535,357 2000-03-24
US09/534,556 US6492465B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers
US09/534,556 2000-03-24
US09/535,357 US6384142B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers

Publications (1)

Publication Number Publication Date
CN1398272A true CN1398272A (zh) 2003-02-19

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CN01804671A Pending CN1398272A (zh) 2000-02-08 2001-02-08 丙烯抗冲共聚物

Country Status (10)

Country Link
US (4) US6384142B1 (https=)
EP (2) EP1254186B1 (https=)
JP (1) JP2003522259A (https=)
KR (2) KR20020074509A (https=)
CN (1) CN1398272A (https=)
AT (1) ATE286082T1 (https=)
BR (1) BR0108150A (https=)
CA (1) CA2398509A1 (https=)
DE (1) DE60108075T2 (https=)
WO (1) WO2001058970A1 (https=)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102056980A (zh) * 2007-12-17 2011-05-11 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102459453A (zh) * 2009-06-26 2012-05-16 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102612538A (zh) * 2009-10-13 2012-07-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
CN101415737B (zh) * 2006-02-02 2013-06-12 巴塞尔聚烯烃股份有限公司 丙烯熔喷树脂、丙烯熔喷树脂纤维和用所述纤维制备的非织造织物及其制备方法
CN104204069A (zh) * 2012-04-05 2014-12-10 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN105452364A (zh) * 2013-08-14 2016-03-30 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
CN106795239A (zh) * 2014-09-12 2017-05-31 博里利斯股份公司 制备丙烯共聚物的方法
CN107922537A (zh) * 2015-06-05 2018-04-17 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
CN116648535A (zh) * 2021-03-26 2023-08-25 株式会社Lg化学 聚丙烯树脂组合物和使用其制备的无纺布
CN116670189A (zh) * 2021-03-26 2023-08-29 株式会社Lg化学 聚丙烯树脂组合物及其制备方法

Families Citing this family (204)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1115360C (zh) 1996-09-04 2003-07-23 埃克森美孚化学专利公司 改进的用于取向薄膜的丙烯聚合物
US6583227B2 (en) 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US7919561B2 (en) * 1996-09-04 2011-04-05 Exxonmobil Chemical Patents Inc. Process of producing thermoplastic polymer blends
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
EP1522553B1 (en) * 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
JP2000072933A (ja) * 1998-08-31 2000-03-07 Asahi Chem Ind Co Ltd オレフィン系エラストマー組成物
WO2001058913A1 (en) * 2000-02-08 2001-08-16 Exxonmobil Chemical Patents Inc. Method of preparing group 14 bridged biscyclopentadienyl ligands
US6384142B1 (en) * 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers
GB0008690D0 (en) * 2000-04-07 2000-05-31 Borealis Polymers Oy Process
US6870016B1 (en) * 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
JP2005522406A (ja) 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
CA2480727C (en) * 2002-03-29 2010-06-01 Kumiai Chemical Industry Co., Ltd. Gene coding for acetolactate synthase
DE60306147T2 (de) * 2002-04-23 2007-04-19 Dow Global Technologies, Inc., Midland Alkarylsubstituierte komplexe von gruppe-4-metallen, katalysatoren und verfahren zur polymerisierung von olefinen
KR101186268B1 (ko) 2002-06-26 2012-09-27 애버리 데니슨 코포레이션 폴리프로필렌/올레핀 탄성체 혼합물을 포함하는 배향된 필름
US7998579B2 (en) * 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US8003725B2 (en) * 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
CN100345896C (zh) * 2002-08-12 2007-10-31 埃克森美孚化学专利公司 增塑聚烯烃组合物
US7271209B2 (en) * 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7531594B2 (en) * 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
DE60329691D1 (de) * 2002-09-06 2009-11-26 Basell Polyolefine Gmbh Verfahren zur copolymerisation von ethylen
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
WO2004037872A2 (en) 2002-10-24 2004-05-06 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US7579407B2 (en) 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US20040147169A1 (en) 2003-01-28 2004-07-29 Allison Jeffrey W. Power connector with safety feature
WO2004106430A1 (ja) * 2003-05-28 2004-12-09 Mitsui Chemicals, Inc. プロピレン系重合体組成物およびその用途
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
DE602004018516D1 (de) * 2003-09-11 2009-01-29 Basell Polyolefine Gmbh Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren
CN1849350A (zh) * 2003-09-11 2006-10-18 巴塞尔聚烯烃股份有限公司 制备多相丙烯共聚物的多步方法
US6995213B2 (en) * 2003-09-29 2006-02-07 Fina Technology, Inc. Oriented films prepared using impact copolymer polypropylene
JP4590037B2 (ja) * 2003-09-30 2010-12-01 日本ポリプロ株式会社 オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
US7258562B2 (en) 2003-12-31 2007-08-21 Fci Americas Technology, Inc. Electrical power contacts and connectors comprising same
US7458839B2 (en) 2006-02-21 2008-12-02 Fci Americas Technology, Inc. Electrical connectors having power contacts with alignment and/or restraining features
WO2005080495A1 (en) 2004-02-12 2005-09-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US20050234172A1 (en) * 2004-04-19 2005-10-20 Fina Technology, Inc. Random copolymer-impact copolymer blend
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
JP4982365B2 (ja) * 2004-07-30 2012-07-25 サウディ ベーシック インダストリーズ コーポレイション 高透明性のプロピレンコポリマー組成物
CA2578590A1 (en) * 2004-09-10 2006-03-23 Exxonmobil Oil Corporation Cavitated opaque polymer film and methods related thereto
CN101065437B (zh) † 2004-10-04 2010-12-08 巴塞尔聚烯烃意大利有限责任公司 弹性体聚烯烃组合物
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
US7384289B2 (en) 2005-01-31 2008-06-10 Fci Americas Technology, Inc. Surface-mount connector
ES2581598T3 (es) * 2005-03-18 2016-09-06 Mitsui Chemicals, Inc. Composición polimérica de propileno, uso de la misma, y procedimiento para la producción de una composición polimérica termoplástica
DE602006005645D1 (de) 2005-05-12 2009-04-23 Dow Global Technologies Inc Thermogeformte und extrudierte folie mit reduziertem glanz
CN101218296B (zh) 2005-07-15 2010-12-08 埃克森美孚化学专利公司 弹性体组合物
CN101248132A (zh) * 2005-08-22 2008-08-20 三井化学株式会社 丙烯类树脂组合物
CN101291986B (zh) * 2005-10-21 2011-12-14 巴塞尔聚烯烃股份有限公司 用于注射模塑的聚丙烯
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US9662867B2 (en) 2006-06-14 2017-05-30 Avery Dennison Corporation Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing
US7726982B2 (en) 2006-06-15 2010-06-01 Fci Americas Technology, Inc. Electrical connectors with air-circulation features
WO2007149900A2 (en) 2006-06-20 2007-12-27 Avery Dennison Corporation Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof
ES2313510T5 (es) * 2006-07-10 2012-04-09 Borealis Technology Oy Polipropileno ramificado de cadena corta
US20080093784A1 (en) * 2006-08-29 2008-04-24 Rawls-Meehan Martin B Foam spring mattress configured with variable firmness
US8198373B2 (en) * 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
US7256240B1 (en) * 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7641500B2 (en) 2007-04-04 2010-01-05 Fci Americas Technology, Inc. Power cable connector system
US7905731B2 (en) 2007-05-21 2011-03-15 Fci Americas Technology, Inc. Electrical connector with stress-distribution features
JP5340292B2 (ja) * 2007-09-07 2013-11-13 ダウ グローバル テクノロジーズ エルエルシー 良好な低温延性を有する充填材入りｔｐｏ組成物
US7762857B2 (en) * 2007-10-01 2010-07-27 Fci Americas Technology, Inc. Power connectors with contact-retention features
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
US8299287B2 (en) 2007-10-25 2012-10-30 Lammus Novolen Technology GmbH Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
EP2062937A1 (en) * 2007-11-26 2009-05-27 Total Petrochemicals Research Feluy Heterophasic propylene copolymer for corrugated sheet and cast film applications
US20090171030A1 (en) * 2007-12-26 2009-07-02 Sumitomo Chemical Company, Limited Polypropylene-based copolymer and film comprising the polypropylene-based copolymer
JP5156415B2 (ja) * 2008-02-01 2013-03-06 トピー工業株式会社 高剛性・高耐衝撃性樹脂組成物
US8404773B2 (en) 2008-03-17 2013-03-26 Dow Global Technologies Llc Coating composition, method of producing the same, articles made therefrom, and method of making such articles
EP2291285A4 (en) 2008-06-12 2011-11-02 3M Innovative Properties Co BIOCOMPATIBLE HYDROPHILIC COMPOSITIONS
WO2009152349A1 (en) * 2008-06-12 2009-12-17 3M Innovative Properties Company Melt blown fine fibers and methods of manufacture
US8062051B2 (en) 2008-07-29 2011-11-22 Fci Americas Technology Llc Electrical communication system having latching and strain relief features
US8246918B2 (en) * 2008-10-21 2012-08-21 Fina Technology, Inc. Propylene polymers for lab/medical devices
US7851554B2 (en) * 2008-10-27 2010-12-14 Exxonmobil Chemical Patents Inc. Propylene impact copolymers with balanced impact strength and stiffness
USD619099S1 (en) 2009-01-30 2010-07-06 Fci Americas Technology, Inc. Electrical connector
US8323049B2 (en) 2009-01-30 2012-12-04 Fci Americas Technology Llc Electrical connector having power contacts
US8366485B2 (en) 2009-03-19 2013-02-05 Fci Americas Technology Llc Electrical connector having ribbed ground plate
US9487893B2 (en) 2009-03-31 2016-11-08 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
USD618180S1 (en) 2009-04-03 2010-06-22 Fci Americas Technology, Inc. Asymmetrical electrical connector
USD618181S1 (en) 2009-04-03 2010-06-22 Fci Americas Technology, Inc. Asymmetrical electrical connector
EP2454317B1 (en) 2009-07-14 2013-05-01 Dow Global Technologies LLC Vacuum thermoformed, extruded sheeting with improved reduced gloss
CN102482386A (zh) * 2009-07-14 2012-05-30 陶氏环球技术有限责任公司 具有高熔体流动性和伊佐德延性的聚丙烯抗冲共聚物
WO2011032917A1 (en) * 2009-09-21 2011-03-24 Basell Poliolefine Italia S.R.L. Polymer filament
US8721943B2 (en) 2009-12-17 2014-05-13 3M Innovative Properties Company Process of making dimensionally stable nonwoven fibrous webs
BR112012014963A2 (pt) * 2009-12-17 2018-06-05 3M Innovative Properties Co mantas fibrosas não tecidas dimensionalmente estáveis e métodos de fabricação e uso das mesmas
WO2011106205A2 (en) 2010-02-23 2011-09-01 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
TW201221714A (en) 2010-10-14 2012-06-01 3M Innovative Properties Co Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US8980415B2 (en) 2010-12-03 2015-03-17 Benoit Ambroise Antistatic films and methods to manufacture the same
WO2012087832A1 (en) * 2010-12-20 2012-06-28 Braskem America, Inc. Propylene-based compositions of enhanced appearance and excellent mold flowability
US20120272468A1 (en) 2011-04-26 2012-11-01 The Procter & Gamble Company Oral Care Device Comprising A Synthetic Polymer Derived From A Renewable Resource And Methods Of Producing Said Device
US8809461B2 (en) * 2011-04-28 2014-08-19 Braskem America, Inc. Multimodal heterophasic copolymer and thermoformed articles from same
US8530581B2 (en) 2011-12-12 2013-09-10 Exxonmobil Chemical Patents Inc. Powder, compositions thereof, processes for making the same, and articles made therefrom
EP2624034A1 (en) 2012-01-31 2013-08-07 Fci Dismountable optical coupling device
US8944831B2 (en) 2012-04-13 2015-02-03 Fci Americas Technology Llc Electrical connector having ribbed ground plate with engagement members
USD727852S1 (en) 2012-04-13 2015-04-28 Fci Americas Technology Llc Ground shield for a right angle electrical connector
USD718253S1 (en) 2012-04-13 2014-11-25 Fci Americas Technology Llc Electrical cable connector
USD727268S1 (en) 2012-04-13 2015-04-21 Fci Americas Technology Llc Vertical electrical connector
US9257778B2 (en) 2012-04-13 2016-02-09 Fci Americas Technology High speed electrical connector
USD751507S1 (en) 2012-07-11 2016-03-15 Fci Americas Technology Llc Electrical connector
US9543703B2 (en) 2012-07-11 2017-01-10 Fci Americas Technology Llc Electrical connector with reduced stack height
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
KR102124226B1 (ko) 2012-09-11 2020-06-18 시카 테크놀러지 아게 높은 가요성 및 높은 융점을 지니는 열가소성 혼합물
EP2914638A4 (en) 2012-10-31 2016-07-27 Exxonmobil Chem Patents Inc PROPYLENE COPOLYMER COMPOSITIONS AND METHODS OF MAKING THE SAME
US9322114B2 (en) 2012-12-03 2016-04-26 Exxonmobil Chemical Patents Inc. Polypropylene fibers and fabrics
EP2928958B1 (en) 2012-12-05 2019-08-21 ExxonMobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
BR112015014093A2 (pt) 2012-12-18 2017-07-11 Exxonmobil Chemical Patents Inc películas de polietileno e método para fazê-las
USD745852S1 (en) 2013-01-25 2015-12-22 Fci Americas Technology Llc Electrical connector
USD720698S1 (en) 2013-03-15 2015-01-06 Fci Americas Technology Llc Electrical cable connector
CN105209505B (zh) 2013-05-14 2017-04-19 埃克森美孚化学专利公司 基于乙烯的聚合物和由其制得的制品
WO2014193985A1 (en) 2013-05-28 2014-12-04 Tredegar Film Products Corporation Polyolefin volumetric diffuser
US11549201B2 (en) * 2013-06-18 2023-01-10 Exxonmobil Chemicals Patents Inc. Fibers and nonwoven materials prepared therefrom
EP3022238B1 (en) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
PT2853563T (pt) 2013-09-27 2016-07-14 Borealis Ag Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado
WO2015047988A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Compositions, wipes, and methods
BR112016006896A2 (pt) 2013-09-30 2017-08-01 3M Innovative Properties Co fibra, manta, lenços umedecidos e processo para melhorar a estabilidade hidrolítica das fibras compreendendo um poliéster alifático
US10006165B2 (en) 2013-09-30 2018-06-26 3M Innovative Properties Company Fibers and wipes with epoxidized fatty ester disposed thereon, and methods
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
EP2865713B1 (en) 2013-10-24 2016-04-20 Borealis AG Blow molded article based on bimodal random copolymer
ES2661108T3 (es) 2013-10-24 2018-03-27 Borealis Ag Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
MX368147B (es) 2013-11-22 2019-09-20 Borealis Ag Homopolímero de propileno de baja emisión con alto flujo de masa fundida.
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
WO2015082379A1 (en) 2013-12-04 2015-06-11 Borealis Ag Phthalate-free pp homopolymers for meltblown fibers
WO2015085446A1 (en) 2013-12-10 2015-06-18 Exxonmobil Chemical Patents Inc. Methods for making multilayer films and films made thereby
CN105980457B (zh) 2013-12-18 2019-03-22 博里利斯股份公司 具有改善的刚性/韧性平衡的bopp膜
WO2015091151A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Polyolefin composition
US10696829B2 (en) 2013-12-20 2020-06-30 Saudi Basic Industries Corporation Heterophasic propylene copolymer
US10465025B2 (en) * 2014-01-15 2019-11-05 Exxonmobil Chemical Patents Inc. Low comonomer propylene-based impact copolymers
EP3094660B1 (en) 2014-01-17 2018-12-19 Borealis AG Process for preparing propylene/1-butene copolymers
US10100186B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft and transparent impact copolymers
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
WO2015126797A1 (en) 2014-02-24 2015-08-27 Dow Global Technologies Llc Thermoplastic polyolefin with reduced gloss for non-carpeted flooring
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
CA2951030C (en) 2014-06-02 2023-03-28 Christopher J. Blackwell Films with enhanced scuff resistance, clarity, and conformability
WO2016053483A1 (en) 2014-10-03 2016-04-07 Exxonmobil Chemical Patents Inc. Polyethylene polymers, films made therefrom, and methods of making the same
JP6663096B2 (ja) * 2015-02-19 2020-03-11 住友化学株式会社 熱可塑性エラストマー組成物
WO2016145549A1 (en) 2015-03-17 2016-09-22 Exxonmobil Chemical Patents Inc. Multilayer films and methods thereof
EP3274381B1 (en) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
WO2016196334A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10557023B2 (en) 2015-06-11 2020-02-11 Dow Global Technologies Llc Cable insulation comprising a blend of LDPE and polypropylene
CN109070531B (zh) 2016-03-11 2020-09-18 埃克森美孚化学专利公司 多层膜及其制造方法
WO2017184234A1 (en) 2016-04-22 2017-10-26 Exxonmobil Chemical Patents Inc. Polyethylene sheets
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
US20190322088A1 (en) 2017-01-26 2019-10-24 Exxonmobil Chemical Patents Inc. Multilayer Films and Methods of Making the Same
EP3583140B1 (en) 2017-02-20 2023-03-08 ExxonMobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US20200108539A1 (en) 2017-04-06 2020-04-09 ExxonMobil Chemica Patents Inc. Cast Films and Processes for Making the Same
WO2018194740A1 (en) 2017-04-19 2018-10-25 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018226311A1 (en) 2017-06-08 2018-12-13 Exxonmobil Chemical Patents Inc. Polyethylene blends and extrudates and methods of making the same
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
EP3661981B1 (en) 2017-08-04 2025-09-17 ExxonMobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
EP3661984B1 (en) 2017-08-04 2022-01-19 ExxonMobil Chemical Patents Inc. Films made from polyethylene compositions and processes for making the same
WO2019027585A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING UNDRAWNED HAFNOCENES WITH -CH2-SIME3 FRACTIONS
WO2019027586A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING 2,6-BIS (IMINO) PYRIDYL-IRON COMPLEXES AND BRONZED HAFNOCENES
US10920053B2 (en) 2017-10-16 2021-02-16 Exxonmobil Chemical Patents Inc. Propylene impact copolymer blends with improved gloss
EP3717241B1 (en) 2017-11-28 2021-08-04 ExxonMobil Chemical Patents Inc. Multilayer films and methods of making the same
CN115850552B (zh) 2017-12-01 2024-08-06 埃克森美孚化学专利公司 催化剂体系和使用其的聚合方法
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
CN117986722A (zh) * 2017-12-18 2024-05-07 博里利斯股份公司 具有优越电性能的用于电线电缆应用的聚合物组合物
CN111902467B (zh) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性
WO2019236349A1 (en) 2018-06-04 2019-12-12 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
ES2970673T3 (es) 2018-06-13 2024-05-30 Exxonmobil Chemical Patents Inc Composiciones de mezclas de poliolefinas
US11787881B2 (en) 2018-06-19 2023-10-17 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2020068497A1 (en) 2018-09-25 2020-04-02 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
US20220033535A1 (en) 2018-11-01 2022-02-03 Exxonmobil Chemical Patents Inc. On-Line Adjustment of Mixed Catalyst Ratio and Olefin Polymerization
US20220056168A1 (en) 2018-11-01 2022-02-24 Exxonmobil Chemical Patents Inc. Slurry Trim Feeder Modifications
WO2020092584A2 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. In-line trimming of dry catalyst feed
EP3873950B1 (en) 2018-11-01 2025-07-23 ExxonMobil Chemical Patents Inc. On-line adjustment of catalysts by trim and olefin polymerization
EP3873947B1 (en) 2018-11-01 2025-09-10 ExxonMobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio by trim and olefin polymerization with the same
WO2020139499A1 (en) 2018-12-26 2020-07-02 Exxonmobil Chemical Patents Inc. Multilayer metallized cast polypropylene films doped with hydrocarbon resin
WO2020167929A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Methods for making films and films made thereby
WO2020167441A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Oriented multilayer polyethylene films and laminates thereof
WO2020170046A1 (en) 2019-02-19 2020-08-27 Braskem S.A. No break polypropylene impact copolymers with melt flow rate higher than 90 g/10 min
WO2020190507A1 (en) 2019-03-19 2020-09-24 Exxonmobil Chemical Patents Inc. Multilayer oriented films
EP3722363A1 (en) * 2019-04-12 2020-10-14 Thai Polyethylene Co., Ltd. Impact copolymer polypropylene for thin-wall injection packaging
EP4017915B1 (en) 2019-08-20 2023-03-08 ExxonMobil Chemical Patents Inc. Films and methods of making the same
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US11518154B2 (en) 2020-01-27 2022-12-06 Exxonmobil Chemical Patents Inc. Barrier films for packaging
WO2021167739A1 (en) 2020-02-18 2021-08-26 Exxonmobil Chemical Patents Inc. High tenacity handwrap stretch film for improved pallet stability
WO2021195070A1 (en) 2020-03-26 2021-09-30 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers
EP4301792A2 (en) 2021-03-05 2024-01-10 ExxonMobil Chemical Patents Inc. Processes for making and using slurry catalyst mixtures
WO2022203461A1 (ko) * 2021-03-26 2022-09-29 주식회사 엘지화학 폴리프로필렌 수지 조성물 및 그의 제조방법
US20240052074A1 (en) * 2021-03-26 2024-02-15 Lg Chem, Ltd. Polypropylene Resin Composition and Non-Woven Fabric Prepared Using the Same
CN118891293A (zh) 2022-02-07 2024-11-01 埃克森美孚化学专利公司 C1对称5-OMe-6-烷基取代金属茂

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
DE3942363A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
US5258464A (en) 1990-01-29 1993-11-02 Shell Oil Company Impact copolymer compositions
US5118757A (en) 1990-03-26 1992-06-02 Shell Oil Company Polymer production
US5166268A (en) 1990-04-12 1992-11-24 Union Carbide Chemicals & Plastics Technology Corporation Process for cold forming propylene copolymers
US5362782A (en) 1990-05-14 1994-11-08 Shell Oil Company Polymer compositions
US5250631A (en) 1990-06-13 1993-10-05 Shell Oil Company Polymer compositions
DE4130429A1 (de) 1991-09-13 1993-03-18 Basf Ag Verfahren zur herstellung von mehrphasigen blockcopolymerisaten auf der basis von alk-1-enen
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
TW294669B (https=) 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
EP0629632B2 (en) 1993-06-07 2015-01-21 Mitsui Chemicals, Inc. Polypropylene
CA2143429C (en) * 1993-06-30 1999-01-26 Takao Nomura Polypropylene composition
TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
JP3483163B2 (ja) * 1993-08-13 2004-01-06 三井化学株式会社 プロピレン系ブロック共重合体の製造方法
KR100353463B1 (ko) * 1994-04-11 2003-01-24 미쓰이 가가쿠 가부시키가이샤 프로필렌중합체조성물의제조방법및프로필렌중합체조성물
DE69506821T2 (de) 1994-04-11 1999-06-10 Mitsui Chemicals, Inc., Tokio/Tokyo Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
JP3357186B2 (ja) 1994-07-14 2002-12-16 三菱化学株式会社 プロピレンブロック共重合体の製造法
US5840808A (en) 1995-02-07 1998-11-24 Mitsui Petrochemical Industries, Ltd. Process for preparing olefin polymer
US5674630A (en) 1995-05-08 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions and cast films
JPH09151294A (ja) 1995-09-29 1997-06-10 Mitsubishi Chem Corp タルク含有プロピレン系樹脂組成物
US5712344A (en) 1996-01-04 1998-01-27 Union Carbide Chemicals & Plastics Technology Corporation Modified polypropylene impact copolymer compositions
JPH09208881A (ja) 1996-02-07 1997-08-12 Mitsubishi Chem Corp 塗装用プロピレン系樹脂組成物
SG67392A1 (en) 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same
KR100286167B1 (ko) 1997-01-10 2001-04-16 고토 기치 프로필렌/에틸렌공중합체,이의제조방법,및이의성형품
AU6401098A (en) 1997-03-07 1998-09-29 Targor Gmbh Preparation of preparing substituted indanones
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
KR20000068860A (ko) * 1997-08-29 2000-11-25 고토 기치 폴리프로필렌/프로필렌-에틸렌 공중합체 조성물 및 이의 제조방법
DE19739946A1 (de) 1997-09-11 1999-03-18 Targor Gmbh Verfahren zur Herstellung von Metallocenen
US5942587A (en) 1997-11-21 1999-08-24 Exxon Chemical Patents Inc. Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production
US5986009A (en) * 1997-12-03 1999-11-16 The Dow Chemical Company Blends of polypropylenes
JPH11286584A (ja) * 1998-02-04 1999-10-19 Mitsui Chem Inc ポリプロピレン系樹脂成形品
EP0962474B1 (en) 1998-06-04 2004-04-07 Japan Polychem Corporation Propylene block copolymer and resin composition
US6384142B1 (en) * 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415737B (zh) * 2006-02-02 2013-06-12 巴塞尔聚烯烃股份有限公司 丙烯熔喷树脂、丙烯熔喷树脂纤维和用所述纤维制备的非织造织物及其制备方法
CN102056980B (zh) * 2007-12-17 2013-11-27 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102056980A (zh) * 2007-12-17 2011-05-11 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102459453A (zh) * 2009-06-26 2012-05-16 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102459453B (zh) * 2009-06-26 2013-07-31 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102612538A (zh) * 2009-10-13 2012-07-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
US8735497B2 (en) 2009-10-13 2014-05-27 Basell Poliolefine Italia S.R.L. Propylene polymers compositions
CN102612538B (zh) * 2009-10-13 2015-11-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
CN104204069B (zh) * 2012-04-05 2016-08-24 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN104204069A (zh) * 2012-04-05 2014-12-10 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN105452364B (zh) * 2013-08-14 2018-05-11 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
US9670347B2 (en) 2013-08-14 2017-06-06 Borealis Ag Propylene composition with improved impact resistance at low temperature
CN105452364A (zh) * 2013-08-14 2016-03-30 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
CN106795239A (zh) * 2014-09-12 2017-05-31 博里利斯股份公司 制备丙烯共聚物的方法
CN107922537A (zh) * 2015-06-05 2018-04-17 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
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