CN1398272A - 丙烯抗冲共聚物 - Google Patents

丙烯抗冲共聚物 Download PDF

Info

Publication number
CN1398272A
CN1398272A CN01804671A CN01804671A CN1398272A CN 1398272 A CN1398272 A CN 1398272A CN 01804671 A CN01804671 A CN 01804671A CN 01804671 A CN01804671 A CN 01804671A CN 1398272 A CN1398272 A CN 1398272A
Authority
CN
China
Prior art keywords
component
zirconium
rac
ipr
propylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN01804671A
Other languages
English (en)
Chinese (zh)
Inventor
T·J·伯克哈特
D·C·怀泽
R·T·李
U·M·斯特林
W·T·小海古德
F·C·里克斯
A·K·梅塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN1398272A publication Critical patent/CN1398272A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/081Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/0825Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827Syntheses with formation of a Si-C bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22Tin compounds
    • C07F7/2208Compounds having tin linked only to carbon, hydrogen and/or halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30Germanium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN01804671A 2000-02-08 2001-02-08 丙烯抗冲共聚物 Pending CN1398272A (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US18101600P 2000-02-08 2000-02-08
US60/181,016 2000-02-08
US09/534,556 2000-03-24
US09/534,556 US6492465B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers
US09/535,357 2000-03-24
US09/535,357 US6384142B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers

Publications (1)

Publication Number Publication Date
CN1398272A true CN1398272A (zh) 2003-02-19

Family

ID=22662533

Family Applications (1)

Application Number Title Priority Date Filing Date
CN01804671A Pending CN1398272A (zh) 2000-02-08 2001-02-08 丙烯抗冲共聚物

Country Status (10)

Country Link
US (4) US6384142B1 (https=)
EP (2) EP1254186B1 (https=)
JP (1) JP2003522259A (https=)
KR (2) KR20020074509A (https=)
CN (1) CN1398272A (https=)
AT (1) ATE286082T1 (https=)
BR (1) BR0108150A (https=)
CA (1) CA2398509A1 (https=)
DE (1) DE60108075T2 (https=)
WO (1) WO2001058970A1 (https=)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102056980A (zh) * 2007-12-17 2011-05-11 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102459453A (zh) * 2009-06-26 2012-05-16 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102612538A (zh) * 2009-10-13 2012-07-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
CN101415737B (zh) * 2006-02-02 2013-06-12 巴塞尔聚烯烃股份有限公司 丙烯熔喷树脂、丙烯熔喷树脂纤维和用所述纤维制备的非织造织物及其制备方法
CN104204069A (zh) * 2012-04-05 2014-12-10 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN105452364A (zh) * 2013-08-14 2016-03-30 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
CN106795239A (zh) * 2014-09-12 2017-05-31 博里利斯股份公司 制备丙烯共聚物的方法
CN107922537A (zh) * 2015-06-05 2018-04-17 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
CN116648535A (zh) * 2021-03-26 2023-08-25 株式会社Lg化学 聚丙烯树脂组合物和使用其制备的无纺布
CN116670189A (zh) * 2021-03-26 2023-08-29 株式会社Lg化学 聚丙烯树脂组合物及其制备方法

Families Citing this family (204)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919561B2 (en) * 1996-09-04 2011-04-05 Exxonmobil Chemical Patents Inc. Process of producing thermoplastic polymer blends
WO1998010016A1 (en) 1996-09-04 1998-03-12 Exxon Chemical Patents Inc. Improved propylene polymers for oriented films
US6583227B2 (en) 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
JP2002519497A (ja) * 1998-07-01 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド
JP2000072933A (ja) * 1998-08-31 2000-03-07 Asahi Chem Ind Co Ltd オレフィン系エラストマー組成物
US6384142B1 (en) * 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers
DE60122396T2 (de) * 2000-02-08 2007-09-06 Exxonmobil Chemical Patents Inc., Baytown Schlagzähe Propylencopolymerisate
GB0008690D0 (en) * 2000-04-07 2000-05-31 Borealis Polymers Oy Process
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6870016B1 (en) * 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
DE60238049D1 (de) 2001-04-12 2010-12-02 Exxonmobil Chem Patents Inc Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
JP2005522406A (ja) 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
DE10158656A1 (de) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
BRPI0308946B1 (pt) 2002-03-29 2016-08-30 Kumiai Chemical Industry Co ácido nucleico, proteína, vetor recombinante, bactéria, processos para cultivar planta que apresenta o referido ácido nucleico, para cultivar planta que apresenta a referida proteína, para seleção de célula transformante que apresenta o referido ácido nucleico e para selecionar célula transformante que apresenta a referida proteína
WO2003091265A1 (en) * 2002-04-23 2003-11-06 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
AU2003247735B2 (en) 2002-06-26 2010-03-11 Avery Dennison Corporation Oriented films comprising polypropylene / olefin elastomer blends
US8003725B2 (en) * 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7998579B2 (en) * 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
CN100345896C (zh) * 2002-08-12 2007-10-31 埃克森美孚化学专利公司 增塑聚烯烃组合物
US7271209B2 (en) * 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7531594B2 (en) * 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
WO2004022613A1 (en) * 2002-09-06 2004-03-18 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7439312B2 (en) 2002-10-24 2008-10-21 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US7579407B2 (en) 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US20040147169A1 (en) 2003-01-28 2004-07-29 Allison Jeffrey W. Power connector with safety feature
DE602004031607D1 (de) * 2003-05-28 2011-04-14 Mitsui Chemicals Inc Propylenpolymerzusammensetzung und verwendung davon
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
CN1878806A (zh) * 2003-09-11 2006-12-13 巴塞尔聚烯烃股份有限公司 制备多相丙烯共聚物的多步法
JP2007505174A (ja) * 2003-09-11 2007-03-08 バセル ポリオレフィン ジーエムビーエイチ ヘテロ相プロピレンコポリマーを製造するための多段方法
US6995213B2 (en) * 2003-09-29 2006-02-07 Fina Technology, Inc. Oriented films prepared using impact copolymer polypropylene
JP4590037B2 (ja) * 2003-09-30 2010-12-01 日本ポリプロ株式会社 オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
US7458839B2 (en) 2006-02-21 2008-12-02 Fci Americas Technology, Inc. Electrical connectors having power contacts with alignment and/or restraining features
CN101882718B (zh) 2003-12-31 2012-11-21 Fci公司 电源触头及包括电源触头的连接器
CN1918226B (zh) 2004-02-12 2011-04-06 埃克森美孚化学专利公司 增塑聚烯烃组合物
US20050234172A1 (en) * 2004-04-19 2005-10-20 Fina Technology, Inc. Random copolymer-impact copolymer blend
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
EP1781737B1 (en) * 2004-07-30 2008-12-03 Saudi Basic Industries Corporation Propylene copolymer compositions with high transparency
CA2578590A1 (en) * 2004-09-10 2006-03-23 Exxonmobil Oil Corporation Cavitated opaque polymer film and methods related thereto
AU2005291326A1 (en) 2004-10-04 2006-04-13 Basell Poliolefine Italia S.R.L. Elastomeric polyolefin compositions
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
US7384289B2 (en) 2005-01-31 2008-06-10 Fci Americas Technology, Inc. Surface-mount connector
ES2581598T3 (es) * 2005-03-18 2016-09-06 Mitsui Chemicals, Inc. Composición polimérica de propileno, uso de la misma, y procedimiento para la producción de una composición polimérica termoplástica
JP5318567B2 (ja) 2005-05-12 2013-10-16 ダウ グローバル テクノロジーズ エルエルシー 光沢の少ない熱成形押出しシート材
WO2007011530A2 (en) 2005-07-15 2007-01-25 Exxonmobil Chemical Patents, Inc. Elastomeric compositions
EP1917304B1 (en) * 2005-08-22 2011-06-22 Mitsui Chemicals, Inc. Propylene based resin composition
CN101291986B (zh) * 2005-10-21 2011-12-14 巴塞尔聚烯烃股份有限公司 用于注射模塑的聚丙烯
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
ES2398725T3 (es) 2006-06-14 2013-03-21 Avery Dennison Corporation Material para etiquetas orientado en la dirección longitudinal que se puede conformar y cortar con troquel y etiquetas y proceso para su preparación
US7726982B2 (en) 2006-06-15 2010-06-01 Fci Americas Technology, Inc. Electrical connectors with air-circulation features
BRPI0713492A2 (pt) 2006-06-20 2012-01-24 Avery Dennison Corp filme polimérico de multi-camadas para rotulagem de adesivos de derretimento a quente e etiqueta e rótulo dos mesmos
DE602006002512D1 (de) * 2006-07-10 2008-10-09 Borealis Tech Oy Kurzkettig verzweigtes Polypropylen
WO2008048743A2 (en) * 2006-08-29 2008-04-24 Ascion Llc A foam spring mattress configured with variable firmness
US8198373B2 (en) * 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
US7256240B1 (en) * 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7641500B2 (en) 2007-04-04 2010-01-05 Fci Americas Technology, Inc. Power cable connector system
US7905731B2 (en) 2007-05-21 2011-03-15 Fci Americas Technology, Inc. Electrical connector with stress-distribution features
US8283399B2 (en) * 2007-09-07 2012-10-09 Dow Global Technologies Llc Filled TPO compositions with good low temperature ductility
US7762857B2 (en) * 2007-10-01 2010-07-27 Fci Americas Technology, Inc. Power connectors with contact-retention features
BRPI0722162A2 (pt) * 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
WO2009054833A2 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
EP2062937A1 (en) * 2007-11-26 2009-05-27 Total Petrochemicals Research Feluy Heterophasic propylene copolymer for corrugated sheet and cast film applications
US20090171030A1 (en) * 2007-12-26 2009-07-02 Sumitomo Chemical Company, Limited Polypropylene-based copolymer and film comprising the polypropylene-based copolymer
JP5156415B2 (ja) * 2008-02-01 2013-03-06 トピー工業株式会社 高剛性・高耐衝撃性樹脂組成物
US8404773B2 (en) 2008-03-17 2013-03-26 Dow Global Technologies Llc Coating composition, method of producing the same, articles made therefrom, and method of making such articles
EP2291558B1 (en) * 2008-06-12 2017-07-26 3M Innovative Properties Company Melt blown fine fibers and methods of manufacture
CA2727701A1 (en) 2008-06-12 2009-12-17 3M Innovative Properties Company Biocompatible hydrophilic compositions
US8062051B2 (en) 2008-07-29 2011-11-22 Fci Americas Technology Llc Electrical communication system having latching and strain relief features
US8246918B2 (en) * 2008-10-21 2012-08-21 Fina Technology, Inc. Propylene polymers for lab/medical devices
US7851554B2 (en) * 2008-10-27 2010-12-14 Exxonmobil Chemical Patents Inc. Propylene impact copolymers with balanced impact strength and stiffness
USD619099S1 (en) 2009-01-30 2010-07-06 Fci Americas Technology, Inc. Electrical connector
US8323049B2 (en) 2009-01-30 2012-12-04 Fci Americas Technology Llc Electrical connector having power contacts
US8366485B2 (en) 2009-03-19 2013-02-05 Fci Americas Technology Llc Electrical connector having ribbed ground plate
US9487893B2 (en) 2009-03-31 2016-11-08 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
USD618181S1 (en) 2009-04-03 2010-06-22 Fci Americas Technology, Inc. Asymmetrical electrical connector
USD618180S1 (en) 2009-04-03 2010-06-22 Fci Americas Technology, Inc. Asymmetrical electrical connector
KR20120051687A (ko) * 2009-07-14 2012-05-22 다우 글로벌 테크놀로지스 엘엘씨 높은 용융 유동 및 아이조드 연성을 갖는 폴리프로필렌 충격 공중합체
US8431651B2 (en) 2009-07-14 2013-04-30 Dow Global Technologies Llc Vacuum thermoformed, extruded sheeting with improved reduced gloss
WO2011032917A1 (en) * 2009-09-21 2011-03-24 Basell Poliolefine Italia S.R.L. Polymer filament
MX347302B (es) * 2009-12-17 2017-04-21 3M Innovative Properties Company * Telas fibrosas no tejidas dimensionalmente estables y metodos para fabricar y utilizar las mismas.
AU2010330866A1 (en) * 2009-12-17 2012-07-12 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, melt blown fine fibers, and methods of making and using the same
BR112012021246A2 (pt) 2010-02-23 2018-04-03 3M Innovative Properties Co mantas fibrosas de não tecido dimensionalmente estáveis e métodos de preparo e uso das mesmas.
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
TW201221714A (en) 2010-10-14 2012-06-01 3M Innovative Properties Co Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US8980415B2 (en) 2010-12-03 2015-03-17 Benoit Ambroise Antistatic films and methods to manufacture the same
JP5851519B2 (ja) * 2010-12-20 2016-02-03 ブラスケム アメリカ インコーポレイテッドBraskem America,Inc. 耐衝撃性コポリマー・ポリプロピレン組成物を製造する方法、および耐衝撃性コポリマー・ポリプロピレン組成物を含む充填配合物を製造する方法
US20120272468A1 (en) 2011-04-26 2012-11-01 The Procter & Gamble Company Oral Care Device Comprising A Synthetic Polymer Derived From A Renewable Resource And Methods Of Producing Said Device
US8809461B2 (en) * 2011-04-28 2014-08-19 Braskem America, Inc. Multimodal heterophasic copolymer and thermoformed articles from same
US8530581B2 (en) 2011-12-12 2013-09-10 Exxonmobil Chemical Patents Inc. Powder, compositions thereof, processes for making the same, and articles made therefrom
EP2624034A1 (en) 2012-01-31 2013-08-07 Fci Dismountable optical coupling device
US9257778B2 (en) 2012-04-13 2016-02-09 Fci Americas Technology High speed electrical connector
USD727852S1 (en) 2012-04-13 2015-04-28 Fci Americas Technology Llc Ground shield for a right angle electrical connector
US8944831B2 (en) 2012-04-13 2015-02-03 Fci Americas Technology Llc Electrical connector having ribbed ground plate with engagement members
USD718253S1 (en) 2012-04-13 2014-11-25 Fci Americas Technology Llc Electrical cable connector
USD727268S1 (en) 2012-04-13 2015-04-21 Fci Americas Technology Llc Vertical electrical connector
USD751507S1 (en) 2012-07-11 2016-03-15 Fci Americas Technology Llc Electrical connector
US9543703B2 (en) 2012-07-11 2017-01-10 Fci Americas Technology Llc Electrical connector with reduced stack height
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
JP2015527472A (ja) 2012-09-11 2015-09-17 シーカ・テクノロジー・アーゲー 高い柔軟性及び高い融点を有する熱可塑性混合物
US9321914B2 (en) 2012-10-31 2016-04-26 Exxonmobil Chemical Patents Inc. Propylene copolymer compositions and processes to produce them
US9322114B2 (en) 2012-12-03 2016-04-26 Exxonmobil Chemical Patents Inc. Polypropylene fibers and fabrics
CN104812828B (zh) 2012-12-05 2016-10-12 埃克森美孚化学专利公司 具有优异的膜泡稳定性的hdpe 改性聚乙烯吹塑膜组合物
CN106113851A (zh) 2012-12-18 2016-11-16 埃克森美孚化学专利公司 聚乙烯膜及其制造方法
USD745852S1 (en) 2013-01-25 2015-12-22 Fci Americas Technology Llc Electrical connector
USD720698S1 (en) 2013-03-15 2015-01-06 Fci Americas Technology Llc Electrical cable connector
BR112015026427B1 (pt) 2013-05-14 2020-07-21 Exxonmobil Chemical Patents Inc. polímeros à base de etileno e artigos feitos do mesmo
EP3004952A1 (en) 2013-05-28 2016-04-13 Tredegar Film Products Corporation Polyolefin volumetric diffuser
WO2014204780A1 (en) * 2013-06-18 2014-12-24 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
EP3539993A1 (en) 2013-07-17 2019-09-18 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
WO2015024887A1 (en) 2013-08-21 2015-02-26 Borealis Ag High flow polyolefin composition with high stiffness and toughness
EP2853563B1 (en) 2013-09-27 2016-06-15 Borealis AG Films suitable for BOPP processing from polymers with high XS and high Tm
JP2016535112A (ja) 2013-09-30 2016-11-10 スリーエム イノベイティブ プロパティズ カンパニー 組成物、ワイプ、及び方法
KR20160058952A (ko) 2013-09-30 2016-05-25 쓰리엠 이노베이티브 프로퍼티즈 컴파니 에폭시화 지방 에스테르가 그 상에 배치된 섬유 및 와이프, 및 방법
EP3052678A1 (en) 2013-09-30 2016-08-10 3M Innovative Properties Company Fibers, wipes, and methods
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
US10519259B2 (en) 2013-10-24 2019-12-31 Borealis Ag Low melting PP homopolymer with high content of regioerrors and high molecular weight
ES2574428T3 (es) 2013-10-24 2016-06-17 Borealis Ag Artículo moldeado por soplado basado en copolímero al azar bimodal
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
CA2927448C (en) 2013-11-22 2017-01-17 Borealis Ag Low emission propylene homopolymer with high melt flow
EP3077426B1 (en) 2013-12-04 2022-10-05 Borealis AG Phthalate-free pp homopolymers for meltblown fibers
WO2015085446A1 (en) 2013-12-10 2015-06-18 Exxonmobil Chemical Patents Inc. Methods for making multilayer films and films made thereby
KR101873134B1 (ko) 2013-12-18 2018-06-29 보레알리스 아게 향상된 강성/인성 균형을 가진 bopp 필름
EP3083819B1 (en) 2013-12-20 2019-01-30 Saudi Basic Industries Corporation Polyolefin composition
EP3083822B1 (en) 2013-12-20 2021-09-08 Saudi Basic Industries Corporation Heterophasic propylene copolymer
US10465025B2 (en) * 2014-01-15 2019-11-05 Exxonmobil Chemical Patents Inc. Low comonomer propylene-based impact copolymers
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
JP2017508032A (ja) 2014-02-06 2017-03-23 ボレアリス エージー 高衝撃強さを有する軟質コポリマー
BR112016017227B1 (pt) 2014-02-06 2021-06-29 Borealis Ag Copolímero de propileno heterofásico, película não orientada, recipiente, e uso de um copolímero de propileno heterofásico
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
WO2015126797A1 (en) 2014-02-24 2015-08-27 Dow Global Technologies Llc Thermoplastic polyolefin with reduced gloss for non-carpeted flooring
EP2947118B1 (en) 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications
JP2017520642A (ja) 2014-06-02 2017-07-27 アベリー・デニソン・コーポレイションAvery Dennison Corporation 耐スカッフ性、透明性、及び順応性が改善されたフィルム
WO2016053483A1 (en) 2014-10-03 2016-04-07 Exxonmobil Chemical Patents Inc. Polyethylene polymers, films made therefrom, and methods of making the same
CN105906929B (zh) * 2015-02-19 2020-07-17 住友化学株式会社 热塑性弹性体组合物
CN107531035B (zh) 2015-03-17 2022-11-22 埃克森美孚化学专利公司 多层膜及其制造方法
WO2016172099A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Polyethylene composition
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
CA2987910C (en) 2015-06-11 2023-08-29 Dow Global Technologies Llc Cable insulation comprising a blend of ldpe and polypropylene
EP3426481A1 (en) 2016-03-11 2019-01-16 ExxonMobil Chemical Patents Inc. Multilayer films and methods of making the same
US11299607B2 (en) 2016-04-22 2022-04-12 Exxon Mobil Chemical Patents Inc. Polyethylene sheets
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
US20190322088A1 (en) 2017-01-26 2019-10-24 Exxonmobil Chemical Patents Inc. Multilayer Films and Methods of Making the Same
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US20200108539A1 (en) 2017-04-06 2020-04-09 ExxonMobil Chemica Patents Inc. Cast Films and Processes for Making the Same
WO2018194740A1 (en) 2017-04-19 2018-10-25 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018226311A1 (en) 2017-06-08 2018-12-13 Exxonmobil Chemical Patents Inc. Polyethylene blends and extrudates and methods of making the same
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
EP3661984B1 (en) 2017-08-04 2022-01-19 ExxonMobil Chemical Patents Inc. Films made from polyethylene compositions and processes for making the same
EP3697822B1 (en) 2017-08-04 2025-07-30 ExxonMobil Chemical Patents Inc. Mixed catalysts with unbridged hafnocenes with -ch2-sime3 moieties
WO2019027586A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING 2,6-BIS (IMINO) PYRIDYL-IRON COMPLEXES AND BRONZED HAFNOCENES
EP3661981B1 (en) 2017-08-04 2025-09-17 ExxonMobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
US10920053B2 (en) 2017-10-16 2021-02-16 Exxonmobil Chemical Patents Inc. Propylene impact copolymer blends with improved gloss
US11691398B2 (en) 2017-11-28 2023-07-04 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
CN115850552B (zh) 2017-12-01 2024-08-06 埃克森美孚化学专利公司 催化剂体系和使用其的聚合方法
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
KR102727961B1 (ko) * 2017-12-18 2024-11-08 보레알리스 아게 유리한 전기적 특성을 갖는 와이어 및 케이블 용도를 위한 중합체 블렌드 조성물
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
CN112218900B (zh) 2018-06-04 2023-07-04 埃克森美孚化学专利公司 包括两种二茂铪催化剂化合物的催化剂体系
EP3807358B1 (en) 2018-06-13 2023-11-15 ExxonMobil Chemical Patents Inc. Polyolefin blend compositions
CN112313254B (zh) 2018-06-19 2023-04-18 埃克森美孚化学专利公司 聚乙烯组合物和由其制备的膜
WO2020068497A1 (en) 2018-09-25 2020-04-02 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2020092587A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio by trim and olefin polymerization with the same
CN113056489B (zh) 2018-11-01 2023-04-14 埃克森美孚化学专利公司 淤浆修整催化剂进料器修改
US11976140B2 (en) 2018-11-01 2024-05-07 Exxonmobil Chemical Patents Inc. In-line trimming of dry catalyst feed
US12091476B2 (en) 2018-11-01 2024-09-17 Exxonmobil Chemical Patents Inc. On-line adjustment of catalysts by trim and olefin polymerization
WO2020092606A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio and olefin polymerization
WO2020139499A1 (en) 2018-12-26 2020-07-02 Exxonmobil Chemical Patents Inc. Multilayer metallized cast polypropylene films doped with hydrocarbon resin
CN113518715B (zh) 2019-02-13 2024-03-22 埃克森美孚化学专利公司 取向的多层聚乙烯膜及其层合材料
WO2020167929A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Methods for making films and films made thereby
WO2020170046A1 (en) * 2019-02-19 2020-08-27 Braskem S.A. No break polypropylene impact copolymers with melt flow rate higher than 90 g/10 min
WO2020190507A1 (en) 2019-03-19 2020-09-24 Exxonmobil Chemical Patents Inc. Multilayer oriented films
EP3722363A1 (en) * 2019-04-12 2020-10-14 Thai Polyethylene Co., Ltd. Impact copolymer polypropylene for thin-wall injection packaging
EP4017915B1 (en) 2019-08-20 2023-03-08 ExxonMobil Chemical Patents Inc. Films and methods of making the same
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US11518154B2 (en) 2020-01-27 2022-12-06 Exxonmobil Chemical Patents Inc. Barrier films for packaging
WO2021167739A1 (en) 2020-02-18 2021-08-26 Exxonmobil Chemical Patents Inc. High tenacity handwrap stretch film for improved pallet stability
WO2021195070A1 (en) 2020-03-26 2021-09-30 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers
US20240066514A1 (en) 2021-03-05 2024-02-29 Exxonmobil Chemical Patents Inc. Processes for making and using slurry catalyst mixtures
WO2022203461A1 (ko) * 2021-03-26 2022-09-29 주식회사 엘지화학 폴리프로필렌 수지 조성물 및 그의 제조방법
US20240052074A1 (en) * 2021-03-26 2024-02-15 Lg Chem, Ltd. Polypropylene Resin Composition and Non-Woven Fabric Prepared Using the Same
KR20240144385A (ko) 2022-02-07 2024-10-02 엑손모빌 케미칼 패턴츠 인코포레이티드 C1 대칭 5-ome-6-알킬 치환 메탈로센

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
DE3942363A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
US5258464A (en) 1990-01-29 1993-11-02 Shell Oil Company Impact copolymer compositions
US5118757A (en) 1990-03-26 1992-06-02 Shell Oil Company Polymer production
US5166268A (en) 1990-04-12 1992-11-24 Union Carbide Chemicals & Plastics Technology Corporation Process for cold forming propylene copolymers
US5362782A (en) 1990-05-14 1994-11-08 Shell Oil Company Polymer compositions
US5250631A (en) 1990-06-13 1993-10-05 Shell Oil Company Polymer compositions
DE4130429A1 (de) 1991-09-13 1993-03-18 Basf Ag Verfahren zur herstellung von mehrphasigen blockcopolymerisaten auf der basis von alk-1-enen
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
TW294669B (https=) 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
EP0812854B2 (en) 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
CA2143429C (en) * 1993-06-30 1999-01-26 Takao Nomura Polypropylene composition
TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
JP3483163B2 (ja) * 1993-08-13 2004-01-06 三井化学株式会社 プロピレン系ブロック共重合体の製造方法
KR100388331B1 (ko) 1994-04-11 2003-10-11 미쓰이 가가쿠 가부시키가이샤 프로필렌중합체조성물의제조방법및프로필렌중합체조성물
CN1104444C (zh) * 1994-04-11 2003-04-02 三井化学株式会社 丙烯聚合物组合物的制备方法
JP3357186B2 (ja) 1994-07-14 2002-12-16 三菱化学株式会社 プロピレンブロック共重合体の製造法
WO1996024627A1 (en) 1995-02-07 1996-08-15 Mitsui Petrochemical Industries, Ltd. Process for preparing olefin polymer
US5674630A (en) 1995-05-08 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions and cast films
JPH09151294A (ja) 1995-09-29 1997-06-10 Mitsubishi Chem Corp タルク含有プロピレン系樹脂組成物
US5712344A (en) 1996-01-04 1998-01-27 Union Carbide Chemicals & Plastics Technology Corporation Modified polypropylene impact copolymer compositions
JPH09208881A (ja) 1996-02-07 1997-08-12 Mitsubishi Chem Corp 塗装用プロピレン系樹脂組成物
SG67392A1 (en) 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same
US6156856A (en) 1997-01-10 2000-12-05 Chisso Corporation Propylene-ethylene copolymers processes for the production thereof and molded articles made therefrom
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
KR20000068860A (ko) * 1997-08-29 2000-11-25 고토 기치 폴리프로필렌/프로필렌-에틸렌 공중합체 조성물 및 이의 제조방법
DE19739946A1 (de) 1997-09-11 1999-03-18 Targor Gmbh Verfahren zur Herstellung von Metallocenen
US5942587A (en) 1997-11-21 1999-08-24 Exxon Chemical Patents Inc. Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production
US5986009A (en) * 1997-12-03 1999-11-16 The Dow Chemical Company Blends of polypropylenes
JPH11286584A (ja) * 1998-02-04 1999-10-19 Mitsui Chem Inc ポリプロピレン系樹脂成形品
US6469100B2 (en) 1998-06-04 2002-10-22 Japan Polychem Corporation Propylene block copolymer and resin composition
US6384142B1 (en) * 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415737B (zh) * 2006-02-02 2013-06-12 巴塞尔聚烯烃股份有限公司 丙烯熔喷树脂、丙烯熔喷树脂纤维和用所述纤维制备的非织造织物及其制备方法
CN102056980B (zh) * 2007-12-17 2013-11-27 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102056980A (zh) * 2007-12-17 2011-05-11 波利亚里斯技术有限公司 具有高流动性和优异的低温抗冲击特性的多相聚丙烯
CN102459453A (zh) * 2009-06-26 2012-05-16 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102459453B (zh) * 2009-06-26 2013-07-31 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
CN102612538A (zh) * 2009-10-13 2012-07-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
US8735497B2 (en) 2009-10-13 2014-05-27 Basell Poliolefine Italia S.R.L. Propylene polymers compositions
CN102612538B (zh) * 2009-10-13 2015-11-25 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物组合物
CN104204069B (zh) * 2012-04-05 2016-08-24 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN104204069A (zh) * 2012-04-05 2014-12-10 北欧化工公司 机械性能和低收缩率及低线性热膨胀系数均衡的高流动性热塑性聚烯烃
CN105452364B (zh) * 2013-08-14 2018-05-11 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
US9670347B2 (en) 2013-08-14 2017-06-06 Borealis Ag Propylene composition with improved impact resistance at low temperature
CN105452364A (zh) * 2013-08-14 2016-03-30 博里利斯股份公司 低温下具有改进的耐冲击性的丙烯组合物
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
CN106795239A (zh) * 2014-09-12 2017-05-31 博里利斯股份公司 制备丙烯共聚物的方法
CN107922537A (zh) * 2015-06-05 2018-04-17 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
CN107922537B (zh) * 2015-06-05 2021-07-27 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
CN116648535A (zh) * 2021-03-26 2023-08-25 株式会社Lg化学 聚丙烯树脂组合物和使用其制备的无纺布
CN116670189A (zh) * 2021-03-26 2023-08-29 株式会社Lg化学 聚丙烯树脂组合物及其制备方法
CN116648535B (zh) * 2021-03-26 2025-11-25 株式会社Lg化学 聚丙烯树脂组合物和使用其制备的无纺布

Also Published As

Publication number Publication date
US6384142B1 (en) 2002-05-07
KR20020073209A (ko) 2002-09-19
BR0108150A (pt) 2003-01-21
US20020086947A1 (en) 2002-07-04
EP1254186A1 (en) 2002-11-06
KR20020074509A (ko) 2002-09-30
DE60108075T2 (de) 2005-12-08
EP1481997A1 (en) 2004-12-01
JP2003522259A (ja) 2003-07-22
DE60108075D1 (de) 2005-02-03
ATE286082T1 (de) 2005-01-15
WO2001058970A1 (en) 2001-08-16
CA2398509A1 (en) 2001-08-16
US6492465B1 (en) 2002-12-10
US6472474B2 (en) 2002-10-29
EP1481997B1 (en) 2006-08-16
US6342566B2 (en) 2002-01-29
US20010034411A1 (en) 2001-10-25
EP1254186B1 (en) 2004-12-29

Similar Documents

Publication Publication Date Title
CN1398272A (zh) 丙烯抗冲共聚物
US10723821B2 (en) Supported metallocene catalyst systems for polymerization
EP2419210B1 (en) Cyclic organosilicon compounds as electron donors for polyolefin catalysts
CN1157623A (zh) 载附的离子型催化剂组合物
CN102481569B (zh) 作为给电子体用于聚烯烃催化剂的双环有机硅化合物
CN100396706C (zh) 聚烯烃嵌段共聚物
US6635733B2 (en) Elastomeric polypropylene
CN1408011A (zh) 无定形和结晶聚合物的交联共混物的制备方法
CN1659224A (zh) 具有良好的低温冲击韧性和高透明性的丙烯共聚物组合物
CN1500100A (zh) 生产支链聚合物组合物的烯烃聚合方法
CN1809596A (zh) 烯烃聚合的多催化剂体系
WO2016197037A1 (en) Catalyst system comprising supported alumoxane and unsupported alumoxane particles
CN112020522A (zh) 混杂负载型茂金属催化剂及使用其制备烯烃聚合物的方法
CN1708517A (zh) 双金属茚并吲哚基催化剂
EP3786195B1 (en) Novel transition metal compound and method for preparing polypropylene using the same
US7081543B2 (en) Bridged biscyclopentadienyl ligands and method of preparation
CN111164111A (zh) 催化剂组合物和使用其制备烯烃聚合物的方法
KR102905354B1 (ko) 폴리에틸렌 및 이의 제조방법
JP2019143035A (ja) 架橋ポリエチレン管用ポリエチレン樹脂組成物、及び、架橋ポリエチレン管
EP1040132A1 (en) Process for polymerizing olefins with supported ziegler-natta catalyst systems
CN1209384C (zh) 带有环丙烯基衍生的配体的过渡金属烯烃聚合催化剂
CN108290975B (zh) 利用茂金属催化剂体系生产具有内部不饱和结构的聚烯烃

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned
C20 Patent right or utility model deemed to be abandoned or is abandoned