CN1327943A - 一种流化床连续化制备碳纳米管的方法及其反应装置 - Google Patents
一种流化床连续化制备碳纳米管的方法及其反应装置 Download PDFInfo
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- CN1327943A CN1327943A CN01118349A CN01118349A CN1327943A CN 1327943 A CN1327943 A CN 1327943A CN 01118349 A CN01118349 A CN 01118349A CN 01118349 A CN01118349 A CN 01118349A CN 1327943 A CN1327943 A CN 1327943A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 17
- 230000008569 process Effects 0.000 title abstract description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000007789 gas Substances 0.000 claims abstract description 32
- 239000003054 catalyst Substances 0.000 claims abstract description 29
- 239000001257 hydrogen Substances 0.000 claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000006722 reduction reaction Methods 0.000 claims abstract description 9
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 238000007872 degassing Methods 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 7
- 239000012190 activator Substances 0.000 claims description 7
- 239000002041 carbon nanotube Substances 0.000 claims description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
- 229910052723 transition metal Inorganic materials 0.000 claims description 7
- 150000003624 transition metals Chemical class 0.000 claims description 7
- 239000011800 void material Substances 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 2
- 230000008021 deposition Effects 0.000 abstract 1
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 1
- 239000012495 reaction gas Substances 0.000 abstract 1
- 239000002086 nanomaterial Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005243 fluidization Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000007233 catalytic pyrolysis Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 229910018054 Ni-Cu Inorganic materials 0.000 description 2
- 229910018481 Ni—Cu Inorganic materials 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910020632 Co Mn Inorganic materials 0.000 description 1
- 229910020678 Co—Mn Inorganic materials 0.000 description 1
- 229910002549 Fe–Cu Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/164—Preparation involving continuous processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
- B01J21/185—Carbon nanotubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00132—Tubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Composite Materials (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
Claims (2)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011183497A CN1141250C (zh) | 2001-05-25 | 2001-05-25 | 一种流化床连续化制备碳纳米管的方法及其反应装置 |
AT02700107T ATE478031T1 (de) | 2001-05-25 | 2002-01-29 | Kontinuierliche massenproduktion von kohlenstoffnanoröhren in einer nanoagglomerat- wirbelschicht |
EP02700107A EP1391425B1 (en) | 2001-05-25 | 2002-01-29 | Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed |
PCT/CN2002/000044 WO2002094713A1 (fr) | 2001-05-25 | 2002-01-29 | Production de nanotubes de carbone a grande echelle dans un reacteur a lit fluidise a base de nano-agglomerats |
US10/478,512 US7563427B2 (en) | 2001-05-25 | 2002-01-29 | Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor |
DE60237361T DE60237361D1 (de) | 2001-05-25 | 2002-01-29 | Kontinuierliche massenproduktion von kohlenstoffnanoröhren in einer nanoagglomerat-wirbelschicht |
JP2002591391A JP3878555B2 (ja) | 2001-05-25 | 2002-01-29 | ナノ凝集体流動層を用いたカーボンナノチューブの連続製造方法及びその反応装置 |
US12/400,713 US20090286675A1 (en) | 2001-05-25 | 2009-03-09 | Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011183497A CN1141250C (zh) | 2001-05-25 | 2001-05-25 | 一种流化床连续化制备碳纳米管的方法及其反应装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1327943A true CN1327943A (zh) | 2001-12-26 |
CN1141250C CN1141250C (zh) | 2004-03-10 |
Family
ID=4663122
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011183497A Expired - Lifetime CN1141250C (zh) | 2001-05-25 | 2001-05-25 | 一种流化床连续化制备碳纳米管的方法及其反应装置 |
Country Status (7)
Country | Link |
---|---|
US (1) | US7563427B2 (zh) |
EP (1) | EP1391425B1 (zh) |
JP (1) | JP3878555B2 (zh) |
CN (1) | CN1141250C (zh) |
AT (1) | ATE478031T1 (zh) |
DE (1) | DE60237361D1 (zh) |
WO (1) | WO2002094713A1 (zh) |
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6905544B2 (en) | 2002-06-26 | 2005-06-14 | Mitsubishi Heavy Industries, Ltd. | Manufacturing method for a carbon nanomaterial, a manufacturing apparatus for a carbon nanomaterial, and manufacturing facility for a carbon nanomaterial |
CN1323029C (zh) * | 2004-12-10 | 2007-06-27 | 中国科学院长春应用化学研究所 | 燃烧聚烯烃合成碳纳米管的方法 |
CN100371241C (zh) * | 2004-11-24 | 2008-02-27 | 中国科学院金属研究所 | 一种制备大尺寸机械密封用各向同性热解炭材料的设备 |
CN100391831C (zh) * | 2004-09-20 | 2008-06-04 | 三星Sdi株式会社 | 制备碳纳米笼的方法 |
CN100393616C (zh) * | 2003-02-05 | 2008-06-11 | 列日大学 | 制造碳纳米管的方法和设备 |
WO2008128437A1 (en) * | 2007-04-18 | 2008-10-30 | Tsinghua University | Multistage reactors for continuous production of carbon nanotubes |
CN101137574B (zh) * | 2005-03-08 | 2011-02-02 | Cnt株式会社 | 碳纳米管批量生产系统和批量生产方法 |
CN101348249B (zh) * | 2008-09-05 | 2011-03-30 | 清华大学 | 一种在颗粒内表面制备碳纳米管阵列的方法 |
CN102120570A (zh) * | 2011-01-22 | 2011-07-13 | 广州市白云化工实业有限公司 | 一种连续化生产碳纳米管的装置及工艺方法 |
CN101372329B (zh) * | 2007-08-21 | 2012-04-25 | 锦湖石油化学株式会社 | 生成碳纳米管的方法和装置 |
WO2012068781A1 (en) * | 2010-11-25 | 2012-05-31 | Bestrong International Limited | System and method for producing hydrogen gas |
US8226902B2 (en) | 2007-09-28 | 2012-07-24 | Korea Kumho Petrochemical Co., Ltd. | Apparatus for manufacturing carbon nanotubes and method of manufacturing carbon nanotubes with the same |
CN101384358B (zh) * | 2006-02-16 | 2013-07-24 | 拜尔材料科学股份公司 | 催化剂的连续制备方法 |
CN103253650A (zh) * | 2013-05-22 | 2013-08-21 | 恒正科技(苏州)有限公司 | 一种纳米碳材的制备方法 |
CN103420359A (zh) * | 2013-08-08 | 2013-12-04 | 山东大展纳米材料有限公司 | 赤泥催化制备碳纳米管的方法、反应装置及应用 |
CN101421447B (zh) * | 2006-04-15 | 2014-02-12 | 拜尔材料科学股份公司 | 流化床制备碳纳米管的方法 |
CN106379885A (zh) * | 2016-08-31 | 2017-02-08 | 潍坊昊晟碳材料有限公司 | 一种碳纳米管或石墨烯的高效制备方法 |
CN106395795A (zh) * | 2016-08-31 | 2017-02-15 | 潍坊昊晟碳材料有限公司 | 一种连续的碳纳米管流化床制备方法 |
CN106395791A (zh) * | 2016-08-26 | 2017-02-15 | 宁波埃飞化工科技有限公司 | 一种碳纳米管的喷雾式窑炉及其生产方法 |
CN106395794A (zh) * | 2016-08-31 | 2017-02-15 | 潍坊昊晟碳材料有限公司 | 一种耦合流化床碳纳米管高效连续制备方法 |
CN106395793A (zh) * | 2016-08-31 | 2017-02-15 | 潍坊昊晟碳材料有限公司 | 一种还原活化‑反应耦合一体的碳纳米管高效制备方法 |
CN106430150A (zh) * | 2016-08-31 | 2017-02-22 | 潍坊昊晟碳材料有限公司 | 一种连续高效的碳纳米管流化床制备方法 |
CN106477556A (zh) * | 2016-09-06 | 2017-03-08 | 南昌大学 | 一种全自动碳纳米材料连续生产设备及生产方法 |
CN106914190A (zh) * | 2017-04-14 | 2017-07-04 | 青岛科技大学 | 一种反应时间可控的气固两相反应器 |
CN107108221A (zh) * | 2015-03-09 | 2017-08-29 | Lg化学株式会社 | 碳纳米结构体的制备方法,由该方法制备的碳纳米结构体及包含该碳纳米结构体的复合材料 |
CN107311150A (zh) * | 2017-08-25 | 2017-11-03 | 安徽智博新材料科技有限公司 | 一种高效连续化流化床制备碳纳米管的方法 |
CN107697903A (zh) * | 2017-09-29 | 2018-02-16 | 中山国安火炬科技发展有限公司 | 一种用流化床生产碳纳米管的设备及其制备方法 |
CN108467024A (zh) * | 2018-05-30 | 2018-08-31 | 合肥百思新材料研究院有限公司 | 一种基于化学气相沉积法批量制备碳纳米管的流化床 |
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US7563427B2 (en) | 2009-07-21 |
WO2002094713A1 (fr) | 2002-11-28 |
EP1391425A4 (en) | 2005-08-03 |
JP2004526660A (ja) | 2004-09-02 |
US20040151654A1 (en) | 2004-08-05 |
DE60237361D1 (de) | 2010-09-30 |
EP1391425A1 (en) | 2004-02-25 |
ATE478031T1 (de) | 2010-09-15 |
CN1141250C (zh) | 2004-03-10 |
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