CN110013881B - 原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 - Google Patents
原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 Download PDFInfo
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- CN110013881B CN110013881B CN201910365277.7A CN201910365277A CN110013881B CN 110013881 B CN110013881 B CN 110013881B CN 201910365277 A CN201910365277 A CN 201910365277A CN 110013881 B CN110013881 B CN 110013881B
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 23
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 239000001301 oxygen Substances 0.000 title claims abstract description 15
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 15
- 238000006722 reduction reaction Methods 0.000 title claims abstract description 15
- 239000007809 chemical reaction catalyst Substances 0.000 title claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 51
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 26
- 239000002243 precursor Substances 0.000 claims abstract description 15
- -1 transition metal salt Chemical class 0.000 claims abstract description 13
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 12
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 7
- 238000009210 therapy by ultrasound Methods 0.000 claims abstract description 7
- 239000012298 atmosphere Substances 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000010000 carbonizing Methods 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910021389 graphene Inorganic materials 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 2
- GFHNAMRJFCEERV-UHFFFAOYSA-L cobalt chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Co+2] GFHNAMRJFCEERV-UHFFFAOYSA-L 0.000 claims description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 claims description 2
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 claims description 2
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- WVSZBAHKLHXQFN-UHFFFAOYSA-N tetrahydrate;dihydrochloride Chemical compound O.O.O.O.Cl.Cl WVSZBAHKLHXQFN-UHFFFAOYSA-N 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 238000007725 thermal activation Methods 0.000 abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 238000001994 activation Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 239000013154 zeolitic imidazolate framework-8 Substances 0.000 description 1
- MFLKDEMTKSVIBK-UHFFFAOYSA-N zinc;2-methylimidazol-3-ide Chemical compound [Zn+2].CC1=NC=C[N-]1.CC1=NC=C[N-]1 MFLKDEMTKSVIBK-UHFFFAOYSA-N 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
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CN111211333A (zh) * | 2020-03-05 | 2020-05-29 | 南京航空航天大学 | 一种富含二价铁位点的内凹型十二面体材料及其制备方法 |
CN112044437B (zh) * | 2020-08-17 | 2022-04-12 | 河北省科学院能源研究所 | 一种珊瑚状Fe-基/碳复合催化剂及其制备方法和应用 |
CN111841616A (zh) * | 2020-08-25 | 2020-10-30 | 南昌航空大学 | 一种双功能原子分散铁氮配位材料催化剂的制备方法 |
CN112086652B (zh) * | 2020-09-15 | 2022-02-25 | 香港科技大学深圳研究院 | 一种空心碳球/石墨烯双功能催化剂及其制备方法和应用 |
CN112331866B (zh) * | 2020-11-06 | 2022-06-07 | 中北大学 | 一种燃料电池用Fe/Co-N-MCF复合催化剂及其制备方法 |
CN112687894B (zh) * | 2020-12-14 | 2021-10-22 | 西北大学 | 一种通过二次热分散制备原子级分散金属氮掺杂碳材料的方法 |
CN112615014A (zh) * | 2020-12-17 | 2021-04-06 | 中国科学技术大学 | 一种催化剂及其制备方法和应用 |
CN112958136B (zh) * | 2021-03-04 | 2023-02-07 | 中国科学院上海高等研究院 | 改性氮碳材料负载原子级非贵金属的催化剂、制备及应用 |
CN113351236A (zh) * | 2021-06-08 | 2021-09-07 | 哈尔滨工业大学(深圳) | 多孔氮掺杂碳基过渡金属单原子催化剂及制备方法和应用 |
CN113471452B (zh) * | 2021-06-30 | 2022-07-12 | 南京大学 | 一种用于析氢氧还原的多位点复合纳米管及其制法与应用 |
CN113611881B (zh) * | 2021-07-09 | 2022-08-16 | 中国海洋大学 | 一种原子级分散Fe/氮掺杂介孔碳球及其制备方法和应用 |
CN113578251A (zh) * | 2021-08-30 | 2021-11-02 | 西华大学 | 一种氮掺杂改性介孔吸附剂及其制备方法和应用 |
CN114267847B (zh) * | 2021-12-15 | 2024-01-23 | 常州大学 | 一种双金属氧还原电催化剂 |
CN114944494B (zh) * | 2022-06-01 | 2024-05-24 | 厦门大学 | 一种在低温条件下大批量制备高纯度m-n型单原子碳基催化剂的方法和应用 |
CN114976067B (zh) * | 2022-06-09 | 2023-04-07 | 中南大学 | 一种金属氧族化合物异质结合单位点催化剂及其制备方法 |
CN115400777B (zh) * | 2022-08-17 | 2024-07-09 | 大连大学 | 一种石墨烯负载核壳结构纳米粒子材料及其制备方法 |
CN115548357A (zh) * | 2022-10-17 | 2022-12-30 | 河南农业大学 | 一种锌空气电池空气电极催化剂及其制备方法和应用 |
CN115739161B (zh) * | 2022-12-13 | 2024-07-02 | 南京理工大学 | 铁单原子催化剂及其制备方法和在催化制备五唑阴离子盐反应中的应用 |
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KR100797138B1 (ko) * | 2002-06-26 | 2008-01-22 | 세미이큅, 인코포레이티드 | 상보형 금속 산화막 반도체 디바이스, 및 금속 산화막 반도체 디바이스와 상보형 금속 산화막 반도체 디바이스를 형성하는 방법 |
BR112016026174B1 (pt) * | 2014-05-16 | 2021-10-13 | Dow Global Technologies Llc | Processo para preparação de um catalisador de síntese de fischer-tropsch |
CN104505523B (zh) * | 2015-01-13 | 2017-01-04 | 哈尔滨工业大学 | 一种铂基催化剂/石墨烯复合材料及其制备方法 |
CN107754836B (zh) * | 2016-08-15 | 2020-04-07 | 中国科学院大连化学物理研究所 | 一种含氮炭材料负载的铱单原子催化剂及制备和应用 |
CN106876728B (zh) * | 2017-02-14 | 2020-01-03 | 中国科学技术大学 | 高密度过渡金属单原子负载石墨烯基催化剂及其制备方法 |
CN109248712B (zh) * | 2017-07-14 | 2021-07-16 | 中国科学院苏州纳米技术与纳米仿生研究所 | 金属单原子掺杂纳米碳材料催化载体及其制备方法和应用 |
CN108636437B (zh) * | 2018-05-09 | 2021-03-26 | 天津理工大学 | 一种氮掺杂碳负载金属单原子催化剂的制备方法 |
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- 2019-04-30 CN CN201910365277.7A patent/CN110013881B/zh active Active
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Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN4 Sites for Oxygen Reduction;Jiazhan Li等;《Angew. Chem. Int. Ed. 》;20191021;第58卷(第52期);第18971-18980页 * |
铁锰掺杂碳基氧还原催化剂的制备与性能;李加展;《中国优秀博硕士学位论文全文数据库(博士)工程科技Ⅰ辑》;20210115(第01期);B014-238 * |
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