CN110013881A - 原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 - Google Patents
原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 Download PDFInfo
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- CN110013881A CN110013881A CN201910365277.7A CN201910365277A CN110013881A CN 110013881 A CN110013881 A CN 110013881A CN 201910365277 A CN201910365277 A CN 201910365277A CN 110013881 A CN110013881 A CN 110013881A
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000006185 dispersion Substances 0.000 title claims abstract description 32
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 17
- 239000002184 metal Substances 0.000 title claims abstract description 17
- 239000001301 oxygen Substances 0.000 title claims abstract description 17
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 17
- 238000006722 reduction reaction Methods 0.000 title claims abstract description 17
- 239000007809 chemical reaction catalyst Substances 0.000 title claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 15
- -1 transition metal salt Chemical class 0.000 claims abstract description 13
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 11
- 238000007725 thermal activation Methods 0.000 claims abstract description 9
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000001291 vacuum drying Methods 0.000 claims abstract description 5
- 238000005119 centrifugation Methods 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001994 activation Methods 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- 230000036571 hydration Effects 0.000 claims description 4
- 238000006703 hydration reaction Methods 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910016874 Fe(NO3) Inorganic materials 0.000 claims description 2
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 2
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 229960002089 ferrous chloride Drugs 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical group O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 claims description 2
- 235000002867 manganese chloride Nutrition 0.000 claims description 2
- 239000011565 manganese chloride Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 3
- 125000004429 atom Chemical group 0.000 description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000013019 agitation Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 239000013049 sediment Substances 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000009790 rate-determining step (RDS) Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000013154 zeolitic imidazolate framework-8 Substances 0.000 description 1
- MFLKDEMTKSVIBK-UHFFFAOYSA-N zinc;2-methylimidazol-3-ide Chemical compound [Zn+2].CC1=NC=C[N-]1.CC1=NC=C[N-]1 MFLKDEMTKSVIBK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (10)
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CN201910365277.7A CN110013881B (zh) | 2019-04-30 | 2019-04-30 | 原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111211333A (zh) * | 2020-03-05 | 2020-05-29 | 南京航空航天大学 | 一种富含二价铁位点的内凹型十二面体材料及其制备方法 |
CN111841616A (zh) * | 2020-08-25 | 2020-10-30 | 南昌航空大学 | 一种双功能原子分散铁氮配位材料催化剂的制备方法 |
CN112044437A (zh) * | 2020-08-17 | 2020-12-08 | 河北省科学院能源研究所 | 一种珊瑚状Fe-基/碳复合催化剂及其制备方法和应用 |
CN112086652A (zh) * | 2020-09-15 | 2020-12-15 | 香港科技大学深圳研究院 | 一种空心碳球/石墨烯双功能催化剂及其制备方法和应用 |
CN112331866A (zh) * | 2020-11-06 | 2021-02-05 | 中北大学 | 一种燃料电池用Fe/Co-N-MCF复合催化剂及其制备方法 |
CN112615014A (zh) * | 2020-12-17 | 2021-04-06 | 中国科学技术大学 | 一种催化剂及其制备方法和应用 |
CN112687894A (zh) * | 2020-12-14 | 2021-04-20 | 西北大学 | 一种通过二次热分散制备原子级分散金属氮掺杂碳材料的方法 |
CN112958136A (zh) * | 2021-03-04 | 2021-06-15 | 中国科学院上海高等研究院 | 改性氮碳材料负载原子级非贵金属的催化剂、制备及应用 |
CN113351236A (zh) * | 2021-06-08 | 2021-09-07 | 哈尔滨工业大学(深圳) | 多孔氮掺杂碳基过渡金属单原子催化剂及制备方法和应用 |
CN113471452A (zh) * | 2021-06-30 | 2021-10-01 | 南京大学 | 一种用于析氢氧还原的多位点复合纳米管及其制法与应用 |
CN113578251A (zh) * | 2021-08-30 | 2021-11-02 | 西华大学 | 一种氮掺杂改性介孔吸附剂及其制备方法和应用 |
CN113611881A (zh) * | 2021-07-09 | 2021-11-05 | 中国海洋大学 | 一种原子级分散Fe/氮掺杂介孔碳球及其制备方法和应用 |
CN114267847A (zh) * | 2021-12-15 | 2022-04-01 | 常州大学 | 一种新型双金属氧还原电催化剂 |
CN114944494A (zh) * | 2022-06-01 | 2022-08-26 | 厦门大学 | 一种在低温条件下大批量制备高纯度m-n型单原子碳基催化剂的方法和应用 |
CN114976067A (zh) * | 2022-06-09 | 2022-08-30 | 中南大学 | 一种金属氧族化合物异质结合单位点催化剂及其制备方法 |
CN115548357A (zh) * | 2022-10-17 | 2022-12-30 | 河南农业大学 | 一种锌空气电池空气电极催化剂及其制备方法和应用 |
CN115739161A (zh) * | 2022-12-13 | 2023-03-07 | 南京理工大学 | 铁单原子催化剂及其制备方法和在催化制备五唑阴离子盐反应中的应用 |
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Cited By (20)
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CN111211333A (zh) * | 2020-03-05 | 2020-05-29 | 南京航空航天大学 | 一种富含二价铁位点的内凹型十二面体材料及其制备方法 |
CN112044437A (zh) * | 2020-08-17 | 2020-12-08 | 河北省科学院能源研究所 | 一种珊瑚状Fe-基/碳复合催化剂及其制备方法和应用 |
CN111841616A (zh) * | 2020-08-25 | 2020-10-30 | 南昌航空大学 | 一种双功能原子分散铁氮配位材料催化剂的制备方法 |
CN112086652A (zh) * | 2020-09-15 | 2020-12-15 | 香港科技大学深圳研究院 | 一种空心碳球/石墨烯双功能催化剂及其制备方法和应用 |
CN112331866A (zh) * | 2020-11-06 | 2021-02-05 | 中北大学 | 一种燃料电池用Fe/Co-N-MCF复合催化剂及其制备方法 |
CN112687894B (zh) * | 2020-12-14 | 2021-10-22 | 西北大学 | 一种通过二次热分散制备原子级分散金属氮掺杂碳材料的方法 |
CN112687894A (zh) * | 2020-12-14 | 2021-04-20 | 西北大学 | 一种通过二次热分散制备原子级分散金属氮掺杂碳材料的方法 |
CN112615014A (zh) * | 2020-12-17 | 2021-04-06 | 中国科学技术大学 | 一种催化剂及其制备方法和应用 |
CN112958136A (zh) * | 2021-03-04 | 2021-06-15 | 中国科学院上海高等研究院 | 改性氮碳材料负载原子级非贵金属的催化剂、制备及应用 |
CN113351236A (zh) * | 2021-06-08 | 2021-09-07 | 哈尔滨工业大学(深圳) | 多孔氮掺杂碳基过渡金属单原子催化剂及制备方法和应用 |
CN113471452A (zh) * | 2021-06-30 | 2021-10-01 | 南京大学 | 一种用于析氢氧还原的多位点复合纳米管及其制法与应用 |
CN113611881A (zh) * | 2021-07-09 | 2021-11-05 | 中国海洋大学 | 一种原子级分散Fe/氮掺杂介孔碳球及其制备方法和应用 |
CN113578251A (zh) * | 2021-08-30 | 2021-11-02 | 西华大学 | 一种氮掺杂改性介孔吸附剂及其制备方法和应用 |
CN114267847A (zh) * | 2021-12-15 | 2022-04-01 | 常州大学 | 一种新型双金属氧还原电催化剂 |
CN114267847B (zh) * | 2021-12-15 | 2024-01-23 | 常州大学 | 一种双金属氧还原电催化剂 |
CN114944494A (zh) * | 2022-06-01 | 2022-08-26 | 厦门大学 | 一种在低温条件下大批量制备高纯度m-n型单原子碳基催化剂的方法和应用 |
CN114944494B (zh) * | 2022-06-01 | 2024-05-24 | 厦门大学 | 一种在低温条件下大批量制备高纯度m-n型单原子碳基催化剂的方法和应用 |
CN114976067A (zh) * | 2022-06-09 | 2022-08-30 | 中南大学 | 一种金属氧族化合物异质结合单位点催化剂及其制备方法 |
CN115548357A (zh) * | 2022-10-17 | 2022-12-30 | 河南农业大学 | 一种锌空气电池空气电极催化剂及其制备方法和应用 |
CN115739161A (zh) * | 2022-12-13 | 2023-03-07 | 南京理工大学 | 铁单原子催化剂及其制备方法和在催化制备五唑阴离子盐反应中的应用 |
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